University of Waterloo DEPARTMENT OF CHEMISTRY Chemistry 120 - Term Test #1 Lecture time: 12:30 pm Instructor: XXXXXXXXX 13 October 2000

Name (Print Clearly): _______________________________________________________________ Student Number: On your computer answer card: Signature: Fill in ovals 004 for the Section Number. Fill in ovals 001 for the Card Number.

Aids Allowed: Time Allowed: Instructions: 1.

Electronic Calculator 50 minutes

This test booklet has 10 questions and 7 pages (including this Cover Page and the Data Sheet). Check now to ensure no pages are missing. If pages are missing, ask for a new test booklet immediately. There is only one correct answer for each question. Circle your answer on this booklet. Attempt all questions. No marks are deducted for wrong answers. Do all rough work on this test booklet. Use an ordinary HB lead pencil for filling in the computer card. Print your name and other information in top right corner of the front of the computer card. On the computer answer card, fill in your ID number, Section Number (004) and the appropriate Card Number (001) in the designated fields. Make sure you fill in the appropriate ovals in pencil. Make sure any erasures are complete and clean. When you have finished, or before time is up, transfer your answers to the computer card by filling in the appropriate oval (A,B,C,D or E) in the column for that question on the card. At the end of the test, turn in this test booklet and your computer card, and leave immediately.

1. 2. 3. 4. 5. 6.

7. 8.

9.

Note: The last page is a DATA SHEET. You may tear it off.

SAMPLE

CHEM 120 (Section 4) 1.

Test #1 (Version 1)

Page 2 of 8

What volume of O2, measured at 0.00oC and 101 kPa, is required for the complete combustion of 0.0390 mol C10H8 ?

A. B. C. D. E.

0.877 L 126 L 0.104 L 0.0731 L 10.5 L

2.

What is the density of O2 gas at 55.0oC and 103 kPa? 1.43 g L1 122 g L1 1.21 g L1 7.21 g L1 4.35 g L1

A. B. C. D. E.

SAMPLE

CHEM 120 (Section 4) 3.

Test #1 (Version 1)

Page 3 of 8

What mass of AgCl(s) forms when 100.0 mL of 0.400 M BaCl2 solution is mixed with 100.0 mL of 0.500 M AgNO3 solution?

A. B. C. D. E.

5.73 g 7.17 g 2.87 g 11.5 g 3.58 g

4.

An aqueous solution of ethylene glycol, HO-CH2CH2-OH, has a density of 1.046 g mL1 and is 32.22% (by mass) ethylene glycol. What is the molarity of ethylene glycol in this solution?

A. B. C. D. E.

5.43 M 16.8 M 0.523 M 1.91 M 0.184 M

SAMPLE

CHEM 120 (Section 4) 5.

Test #1 (Version 1)

Page 4 of 8

A sample of a compound of iron, Fe, and sulfur, S, was reacted with oxygen, O2. The products were 0.1688 g Fe2O3 and 0.2708 g SO2. What is the empirical formula of the compound?

A. B. C. D. E.

FeS Fe2S Fe2S3 FeS2 FeS4

6.

Which of the following statements is true?

A. B.

A 22.4-L sample of O2 gas must contain one mole of O2 molecules. In a gaseous mixture of helium and argon, helium atoms move faster, on average, than argon atoms.

C.

The volume of one mole of O2 is only two-thirds that of one mole of O3 under the same conditions of temperature and pressure.

D.

If a gas mixture contains one mole of H2 and one mole of O2, the pressure exerted by O2 is about sixteen times greater than that exerted by H2.

E.

If the temperature of a sample of ideal gas is increased from 10oC to 20oC at constant pressure, the volume will double.

SAMPLE

CHEM 120 (Section 4) 7.

Test #1 (Version 1)

Page 5 of 8

Complete and balance the equation below using the smallest whole number coefficients. VO2+(aq) + Zn(s) V3+(aq) + Zn2+(aq) (acidic solution)

In the complete and balanced equation, there are A. B. C. D. E. 3 H+ on the left-hand side of the equation. 4 H2O on the right-hand side of the equation 4 H+ on the left-hand side of the equation. one O2 on the right-hand side of the equation 2 H2O on the left-hand side of the equation.

8.

Exactly 1.0 L of helium gas at 760 torr and 1.0 L of argon gas at 380 torr are introduced into a 4.0-L vessel. Assuming a constant temperature, what is the final pressure? A. B. C. D. E. 95 torr 190 torr 285 torr 475 torr 570 torr

SAMPLE

CHEM 120 (Section 4) 9.

Test #1 (Version 1)

Page 6 of 8

When a 1.00-g sample of a mixture of NaCl and AlCl3 is treated with excess AgNO3 solution, 0.02142 moles of solid AgCl are obtained. What is the percentage by mass of NaCl in the mixture? NaCl, 58.44 g mol1 AlCl3, 133.33 g mol1

Molar masses:

A. B. C. D. E.

less than 10% 20% 25% 31% 42%

10.

When solid potassium hydrogen carbonate, KHCO3, is heated, it decomposes: 2 KHCO3(s) K2CO3(s) + CO2(g) + H2O(l).

When a 0.50-g sample of KHCO3 is heated, 0.32 g K2CO3 is obtained. What is the percent yield for this experiment? A. B. C. D. E. 93% 64% 46% 23% none of the above

SAMPLE

CHEM 120 (Section 4)

Test #1 (Version 1)

Page 7 of 8

DETACH THIS DATA SHEET FOR EASY REFERENCE

1 H 1.008 3 Li 6.941 11 Na 22.99 19 K 39.10 37 Rb 85.47 55 Cs 132.9 87 Fr (223)

4 Be 9.012 12 Mg 24.31 20 21 22 Ca Sc Ti 40.08 44.96 47.88 38 39 40 Sr Y Zr 87.62 88.91 91.22 56 (57-71) 72 Ba La-Lu Hf 137.3 178.5 (89-103) 88 104 Ac-Lr Ra Rf 226

23 V 50.94 41 Nb 92.91 73 Ta 180.9 105 Db

24 Cr 52.00 42 Mo 95.94 74 W 183.9 106 Sg

25 Mn 54.94 43 Tc (98) 75 Re 186.2 107 Bh

26 Fe 55.85 44 Ru 101.1 76 Os 190.2 108 Hs

27 Co 58.93 45 Rh 102.9 77 Ir 192.2 109 Mt

28 Ni 58.69 46 Pd 106.4 78 Pt 195.1 110 Uun

29 Cu 63.55 47 Ag 107.9 79 Au 197.0 111 Uuu

30 Zn 65.38 48 Cd 112.4 80 Hg 200.6 112 Uub

5 B 10.81 13 Al 26.98 31 Ga 69.72 49 In 114.8 81 Tl 204.4 113 Uut

6 C 12.01 14 Si 28.09 32 Ge 72.59 50 Sn 118.7 82 Pb 207.2

7 N 14.01 15 P 30.97 33 As 74.92 51 Sb 121.8 83 Bi 209.0

8 O 16.00 16 S 32.07 34 Se 78.96 52 Te 127.6 84 Po (209)

9 F 19.00 17 Cl 35.45 35 Br 79.90 53 I 126.9 85 At (210)

2 He 4.003 10 Ne 20.18 18 Ar 39.95 36 Kr 83.80 54 Xe 131.3 86 Rn (222)

Constants: NA = 6.022 1023 mol1 R = 0.082058 atm L K1 mol1 = 8.3145 kPa L K1 mol1 = 8.3145 J K1 mol1

Conversion factors: 1 atm = 101.325 kPa = 760 torr = 760 mmHg 0oC = 273.15 K

SAMPLE

CHEM 120 (Section 4) ANSWERS: 1E 2C 3B 4A 5D 6B

Test #1 (Version 1)

Page 8 of 8

7C 8C

9B 10A

SAMPLE