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SULIT 4541/1 Chemistry Kertas 1 Oktober 2010 1 jam

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BAHAGIAN PENGURUSAN SEKOLAH BERASRAMA PENUH DAN SEKOLAH KECEMERLANGAN KEMENTERIAN PELAJARAN MALAYSIA

PEPERIKSAAN SELARAS AKHIR TAHUN TINGKATAN 4 TAHUN 2010 CHEMISTRY Kertas 1 Satu jam lima belas minit

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

1. 2. 3. Kertas soalan ini mengandungi 50 soalan. Jawab semua soalan Tiap-tiap soalan diikuti oleh empat pilihan jawapan, iaitu A, B, C dan D. Bagi setiap soalan, pilih satu jawapan sahaja. Hitamkan jawapan anda pada kertas jawapan objektif yang disediakan. Jika anda hendak menukar jawapan, padamkan tanda yang telah dibuat, kemudian hitamkan jawapan yang baru. Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan.

4. 5. 6.

Kertas soalan ini mengandungi 17 halaman bercetak

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Table 1 shows the contributions of scientists X and Y towards atomic model. Scientist X Y Contribution Electrons are spread across the positively charged atom. Atoms are hard spheres which cannot be split.

Table 1 Which of the following represents scientists X and Y? X J.J Thomson Neils Bohr J.J. Thomson James Chadwick Y John Dalton J.J. Thomson Ernest Rutherford John Dalton

A B C D 2

A beaker contains 6.02 x 1023 water molecules? What is the number of moles of water in the beaker? [Avogadro constant = 6.02 X 1023 mol-1] A B C D 0.5 1.0 3.0 6.0

Proton number of element P is 8. What is the position of this element in the Periodic Table of Elements? Group A 16 B 16 C 18 D 18 Period 2 3 2 3

4 Which of the following statements is true about the elements in Group 17 of the Periodic Table? A B C D All elements exist as a monoatomic molecule. All atoms of elements have six valence electrons. All elements are found in the same period. All elements can react with sodium hydroxide at room temperature.

5 How does an ionic compound form? A B C D the transfer of electrons from non-metallic to metallic atoms. the transfer of electrons from metallic to non-metallic atoms. the sharing of electron between metallic atoms. the sharing of electrons between non-metallic atoms.

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The ammeter in the Diagram 1 showed that no current is flowing in the circuit. What is liquid X?

Diagram 1 A B C D Aqueous sodium chloride solution Molten magnesium oxide Dilute sulphuric acid Tetrachloromethane

7 Which of the following statements are true for both dilute ethanoic acid and dilute hydrochloric acid of the same concentration? I II III IV They have different concentration of hydrogen ions. Their degree of ionisation in water is the same. They have different pH value. They neutralise equal amount of sodium hydroxide.

A I and II only B I and III only C II and IV only D III and IV only 8 The following word equation shows a chemical reaction. X + magnesium oxide magnesium chloride + water What is acid X? A B C D Hydrochloric acid Sulphuric acid Phosphoric acid Nitric acid

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9 Diagram 2 shows the set-up of apparatus used to investigate diffusion in a solid gel.

Gel Potassium manganate(VII) cystal

Diagram 2 After a few days, the entire solid gel turned purple. What can we deduce from the above investigation? A B C D Potassium manganate(VII) dissolves in the gel. Potassium manganate(VII) is less dense than the gel. Potassium manganate(VII) reacts with the gel to produce purple colour Potassium manganate(VII) particles diffuse through spaces between the gel particles.

10 Which of the following is a synthetic polymer? A B C D Rubber PVC Protein Starch

11 Why inert gases do not react with other elements? A B C D They exist as monoatoms. They have lower melting points. Atoms of inert gases have stable electron arrangement. Atoms of inert gases are attracted by weak forces of attraction.

12 Which of the following is true about covalent compound? A B C D High volatility Soluble in water. Have higher melting and boiling point. Can conduct electricity in all physical state.

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13 Diagram 3 shows a chemical cell.

Cu CuCl2

Diagram 3 A voltage is produced by the apparatus as shown in Diagram 3. What is the metal X that generate the highest voltage? A Iron B Magnesium C Aluminium D Zinc 14 Hydrogen chloride in methylbenzene does not show any acidic property. Which of the followings explain the observation? A B C D Hydrogen choride is a covalent compound. Hydrogen choride molecules ionises in the solution. This solution does not contain hydrogen ions. This solution show the electrical conductivity.

15 Which of the following are insoluble salts? I II III IV Silver chloride Magnesium nitrate Barium sulphate Zinc carbonate

A I and III only B II and IV only C I, II and III only D I, III and IV only 16 What is the type of glass used to make laboratory glass wares? A B C D Lead glass Fused glass Borosilicate glass Soda glass
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17 Table 2 shows the melting points and boiling points of substances S, T, U and V. Substance Melting point/oC S - 182 T - 23 U - 97 V 41 Table 2 Boiling point/ o C - 162 77 65 182

Which substance exists as a gas at room temperature? A B C D S T U V

18 The following information shows the properties of element L. Exhibits oxidation numbers of +2, +3 and +6 in its compounds Forms complex ions

Which of the following is true about element L? A It can conduct electricity in solid and liquid states. B It is in Group 17 of the Periodic Table. C It forms coloured compounds. D It has a high melting point. 19 Diagram 4 shows the electron arrangement of a compound formed between P and Q.

Diagram 4 Which of the following statements is true about the compound? A B C D It is an ionic compound. The compound is formed by covalent bonds. The compound dissolve in water. The compound is formed by electron transfer.

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20 Which of the following factors influence the products of electrolysis? I II III IV Concentration of electrolyte Type of electrode Position of ion in the electrochemical series The solubility of the ions in water

A IV only B I and III only C II and IV only D I, II and III only

21 Table 3 shows some of the steps for preparing a standard solution but they are not in order. P SQRDissolve the solute in distilled water Transfer the solution into a volumetric flask Add distilled water until the mark of the flask Weigh the mass of the solute needed Table 3 Which of the following sequence of steps is correct? A B C D PQRS RPSQ RPQS R Q P S

22 Which pairs of substances are suitable to prepare copper(II) sulphate in the laboratory? I Copper and dilute suphuric acid II Copper(II) carbonate and dilute sulphuric acid III Aqueous copper(II) nitrate solution and dilute sulphuric acid IV Copper(II) hydroxide and sulphuric acid A I and II only B I and III only C II and IV only D I, II and III only

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23 Diagram 5 shows the atomic symbol of element X.

16 8

Diagram 5 Which of the following is true about element X? Proton number A B C D 8 8 16 16 Nucleon number 16 16 8 8 Electron arrangement 2.6 2.8.6 2.6 2.8.6

24 Which of the following pair of empirical formula and molecular formula is true for ethanoic acid? Empirical Formula A B C D CH2O CH2O C2H4O2 C2H4O2 Molecular Formula CH2O C2H4O2 CH2O C2H4O2

25 Two elements P and Q have proton numbers of 6 and 17 respectively. Which of the following formulae and type of bond is true for the compound formed between elements P and Q? Formula A B C D P4Q7 P7Q4 P4Q PQ4 Types of bond Ionic bond Covalent bond Ionic bond Covalent bond

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26 Diagram 6 shows the set-up of the apparatus to prevent the iron spoon from rusting.

Iron spoon

Silver plate Silver nitrate solution Diagram 6

What is the process involved? A B C D Extraction Purification Electroplating Neutralization

27 Which of the following shows a precipitation reaction? A B C D K2CO3 2HCl Na2SO4 NaOH + + + + Pb(NO3)2 PbO Mg(NO3)2 K2CO3 2KNO3 + PbCO3 PbCl2 + H2O MgSO4 + 2NaNO3 Na2CO3 + 2KOH

28 Table 4 shows the ions formed from elements of S,T,U and V. Element S T U V Proton number 8 9 11 20 Table 4 Formula ion S2TU+ V2+

Which ion has the same number of electron as one chloride ion? [Proton number of Cl = 17] A B C D S2TU+ V2+

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29 Diagram 7 shows the apparatus for the electrolysis of molten lead(II) oxide.

Electrode X

Electrode Y

Diagram 7 Which of the following half equation show the reaction occurs at electrode X and Y? A B C D Electrode X 2O2- O2 + 4e4OH- O2 + 2H2O + 4e2O2- O2 + 4ePb2+ + 2e- Pb Electrode Y 2H+ + 2e- H2 Pb2+ + 2e- Pb Pb2+ + 2e- Pb 2O2- O2 + 4e-

30 Sodium and rubidium are elements of Group 1 in the Periodic Table. Which of the following statements is correct? A B C D Both metals form acidic oxides A rubidium atom has more electrons in its outermost shell than sodium Rubidium has higher melting point than sodium Rubidium reacts more vigorously with water than sodium

31 Diagram 8 shows an electrolysis of dilute sulphuric acid.

carbon

Diagram 8 What is gas X ? A B C D Carbon dioxide Hydrogen Oxygen Sulphur dioxide

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32 Diagram 9 show the set-up of the apparatus for displacement reaction on test tube X,Y and Z.

Iron(II) sulphate Tin

Lead(II) nitrate Copper

Copper(II) sulphate Zinc S Diagram 9

Magnesium nitrate

Aluminium

In which of the follwing test tubes the replacement reaction occurs? A B C D P Q R S

33 Diagram 10 shows the industrial preparation of sulphuric acid through the Contact Process. I S oxygen SO2 oxygen II SO3 III H2S2O7 IV H2SO4 water

concentrated H2SO4 Diagram 10

Which stage involves the use of a catalyst? A B C D I II III IV

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34 Which of the following reactions does not show the role of benzoic acids as an acid? A The burning of benzoic acid to produce carbon dioxide and water B The reaction that occurs between benzoic acid and sodium hydroxide to produce salt and water C The reaction that occurs between benzoic acid and limestone to produce carbon dioxide D The reaction that occurs between benzoic acid and magnesium ribbon to produce hydrogen

35 The pie chart in Diagram 11 shows the composition of stainless steel.

Diagram 11 What is element X? A Tin B Copper C Iron D Aluminium 36 Compound with formula Y(NO3)2 has a relative formula mass of 148. What is the relative atomic mass of Y? [Relative atomic mass of N= 14, O= 16] A B C D 24 56 38 86

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37 Table 5 describe the composition of an atom Y. 12 neutral subatomic particle 12 positively charge subatomic particle 12 negatively charge subatomic particle

Table 5 Which one of the following statements about an atom Y is true? A B C D The nucleon number is 24. The symbol of an atom Y is . The total number of protons and neutrons is 12. The number of neutrons and electrons are not the same.

38 If the formula of the sulphate salt of M is M2(SO4)3, what is the formula of the chloride salt of M? A B C D MCl MCl3 M2Cl3 M3Cl

39 Diagram 12 shows the atomic structure for atoms of two elements, X and Y.

X Diagram 12

When these two elements react to form a compound, what is the relative molecular mass of the compound? A 74 B 83 C 117 D 152
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Diagram 6 shows the pH values of five different solutions.

V W X Y

pH = 1

pH = 4

pH = 8

pH = 12

Diagram 13 Which of the solutions has the highest concentration of hydrogen ions? A B C D V W X Y

41 Diagram 14 shows the electron arrangement for an ion of element J.

2-

Diagram 14 What are the number of protons and electrons in an atom of element J? A B C D Number of protons 20 20 16 16 Number of electrons 20 18 18 16

42 Ascorbic acid contains 40.92% carbon, 4.58% hydrogen and 54.50% oxygen. What is the empirical formula for ascorbic acid? [Relative atomic mass: H = 1, C = 12, O = 16] A B C D CHO CH2O C2H3O2 C3H4O3
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If 150 cm3 of a 4 mol dm3 solution Y is added to 250 cm3 of water, what is the molarity of the diluted solution? A B C D 1.50 mol dm3 2.40 mol dm3 2.80 mol dm3 3.00 mol dm3

44 Which of the following substances used by a farmer to neutralize an acidic soil? A B C D Calcium oxide Sulphuric acid Sodium hydroxide Ammonium hydroxide

45 The equation below represents a chemical reaction. xFe (s) + yO2 (g) zFe2O3(s) What are the values of x, y and z? A B C D x 1 2 3 4 y 2 4 4 3 z 3 3 2 2

46 The equation shows a decomposition reaction of copper(II) nitrate. 2Cu(NO3)2 2CuO + 4NO2 + O2

What is the number of oxygen molecules is produced when 9.4 g copper(II) nitrate is heated. [Relative formula mass of Cu(NO3)2 = 188 ; Avogadro constant = 6.02 1023 mol-1] A B C D 1.505 1022 3.010 1022 1.505 1023 3.010 1023

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Element X, Y and Z are located in Period 3 of the Periodic Table. Table 6 below shows the properties of the oxide of element X, Y and Z. Element X Y Z Property of the oxide formed Base oxide Acidic oxide Amphoteric oxide Table 6 What is the correct arrangement of element X, Y and Z from left to right in Period 3 of the Periodic Table? A B Z, X, Y X, Z, Y

C X, Y, Z D Y, Z, X

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Table 7 shows the voltage reading of three simple chemical cells. Electrodes W/X X/Y Y/Z Voltage / V 2.7 2.0 0.5 Table 7 What is the voltage produced by using Z and W electrodes? A B C D 1.5 V 1.2 V 0.8 V 0.6 V Negative terminal W Y Y

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49 Table 8 shows the electrical conductivity of three substances in solid and molten states. Electrical conductivity in Substance Solid state Molten state P Q R X X Table 8 What are the likely substances for P, Q and R ? P A B C D Copper Sodium chloride Ethanol Zinc oxide Q Sodium chloride Iron Lead Sodium chloride R Ethanol Ethanol Sodium chloride Glucose X

50 Diagram 15 shows the setup of apparatus for the titration of potassium hydroxide solution with sulphuric acid.

Sulphuric acid 1.0 mol dm-3 25 cm3 of potassium hydroxide solution 1.0 mol dm-3 and phenolphthalein as an indicator

Diagram 15 What is the volume of sulphuric acid at the end point of the titration? A B C D 10 cm3 25 cm3 30 cm3 50 cm3 END OF QUESTION PAPER
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