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FBC99-0014
F. Miccio*
Istituto Ricerche sulla Combustione – Consiglio Nazionale delle Ricerche IRC-CNR
via Metastasio 17, 80125 Napoli, Italy - Tel +39-81-5935379 - Fax +39-81-5931567
O. Moersch, H. Spliethoff, K.R.G. Hein
Institut für Verfahrenstechnik und Dampfkesselwesen IVD-Universität Stuttgart
Pfaffenwaldring 23 - 70550 Stuttgart, Germany - Tel. +49-711+6853565 - Fax. +49-711+6853491
age sludge. The final products are rather spheri- off (C), the latter two being produced by fast
cal granules (Fig. 2A), gray in color and uniform heating up to 800 °C in a muffle furnace. It ap-
in size. The dry sewage sludge is dust-free, not pears that there is not a significant change of
smelling and storable for a long period. Differ- shape and volume of the particle upon its con-
ently from beech wood, it presents a high ash version. Furthermore, the char particle (Fig. 2B)
content (56.11 %) and, consequently, the calo- shows an increased internal porosity with re-
rific value evaluated on mass basis is low spect to the raw granule (Fig. 2A); the porosity
(7.85 MJ/kg). The granules of dry sewage disappears in the exhausted particle (Fig 2C)
sludge have a fairly good mechanical resistance; because of ash fusion and re-arrangement during
the particle breaks if subjected to a compression char conversion.
stress - hand operated by means of a pencil - The granulometric distributions of both
approximately equal to 10 N and fragments can fuels are reported in Table I. The top particle
be rather easily pulverized. size was 5 mm in both cases; fines (i.e. lower
For dry sewage sludge, Fig. 2 reports than 1.0 mm) were retrieved only for beech
SEM pictures of a raw granule (A), a char parti- wood. A blend was prepared by mixing equal
cle (B) and an ash particle after complete burn- masses of both fuels. The feeding of such a
velocity Umf in air at the temperature of 800 °C
A was 11 cm/s and the expanded bed height
ranged between 80 and 90 cm.
The main operating variables of experi-
ments were the process temperature T and the
equivalence ratio λ, defined as the mass ratio
between the actual flow rate of the air and the
stoichiometric flow rate required for the fuel
combustion. The fluidization air was preheated
up to 500 °C. The reactor worked at fixed gas
velocities in the freeboard (i.e. 0.38 m/s). Con-
sequently, the undisturbed fluidization velocity
U was in the range 30 - 40 cm s-1 corresponding
to the beginning of the slugging regime for the
B given bed diameter and sand size.
Laboratory analyses were performed on following the experimental procedure for the
samples taken from the bed in order to give a determination of the bed carbon load [Miccio et
confirmation of the deposition of elements from al., 1998]. In such a situation the bed tempera-
ashes over particle surface. Table II reports the ture increases over the set-point (up to 980 °C),
results of off-line analyses carried out by means the cooling of the bed in the actual reactor being
of atomic adsorption spectroscopy (AAS) and not possible, and the temperature of char parti-
surface analysis via scanning electron micro- cles increases with respect to bed temperature.
scope (SEM). The comparison between fresh
and fatigued sand (i.e. after approximately 10 Producer gas
hours of operation with dry sewage sludge at Table III reports the average results of
800 °C) shows that fatigued sand was particu- gasification tests operated using both fuels and
larly enriched of some elements which are pres- their blend (50% by weight). The concentration
ent in sewage sludge ashes, as reported in Tab. I of principal gaseous species on dry basis, the tar
(Ca, Fe and Mg). Their deposition occurred concentration in the producer gas, the carbon
along the particle surface, since the measured elutriation rates at the reactor exit (EC) and in
value of the area covered by Si in fatigued sand the freeboard (EC,fr) and the carbon load in the
drastically falls down in SEM analysis. Of bed are reported. The carbon elutriation rate is
course, the large deposition of iron oxides normalized with respect to the total carbon
(∆ = 317 % and 2171 % for AAS and SEM, feeding rate.
respectively) is responsible of the observed The quality of the producer gas (i.e. con-
change in sand color. centration of combustible species) is improved in
Aggregates with a size up to 40 mm were all cases by decreasing the equivalence ratio and
also retrieved in the bed after experiments car- increasing the process temperature. The com-
ried out at a temperature of 900 °C; such aggre- parison between the results of the two fuels
gates have a dark color and a porous structure shows that the hydrogen concentration attained
with a good mechanical resistance. Their forma- with dry sewage sludge is higher than that with
tion must be ascribed to the fusion of ashes beech wood, except in the case λ=0.35 and
and/or sintering of ash and bed materials, be- T=800 °C. The result can be explained taking
cause of the higher temperature during such into account that the ratio between volatiles and
tests. However, it is reasonable to suppose that fixed carbon is higher for DSS than for BW
the aggregates were produced at the end of the (18.25 and 6.03, respectively). As a conse-
gasification experiment, when the fuel feeding is quence, the role of homogeneous reactions is
switched off and the carbon in the bed is burned, more important during dry sewage sludge gasifi-
Table III - Experiments of biomass gasification
1 2 3 4 5 6 7 8 9 10 11
Equivalence Process CO2 CO H2 CH4 tar Carbon Carbon Carbon Carbon
ratio temperature elutriation elutriation conversion load
exit freeboard in freeboard
- °C % % % % mg/m3 % % % g
Beech wood
0.15 800 17.9 18.6 14.8 6.2 14000 5.5 15.0 9.5 81
0.25 800 18.8 14.5 12.8 4.0 8200 3.8 6.2 2.4 37
0.35 800 19.2 11.4 10.8 3.0 4500 2.9 2.9 0.0 17
0.25 900 16.4 17.7 15.3 3.8 4970 2.2 3.6 1.4 19
Dry sewage sludge
0.15 800 16.0 13.5 19.7 2.2 11400 6.4 8.1 1.7 176
0.25 800 16.7 11.5 14.7 2.5 6860 5.4 7.9 2.5 104
0.35 800 17.5 9.6 9.0 2.9 2620 4.7 8.2 3.5 57
0.25 900 11.0 20.0 21.0 2.7 3750 3.9 5.0 1.1 81
Beech wood - dry sewage sludge blend
0.25 800 17.3 13.5 14.7 3.8 5540 5.3 6.4 1.1 81
0.25 900 13.5 19.0 19.0 2.5 3050 3.0 4.0 1.0 44
cation, leading to increased formation of hydro- large amount and Mg in traces, leading to en-
gen by cracking and partial oxidation of gaseous hance the cracking of tar species in the regions
hydrocarbons [Littlewood, 1977]. During gasifi- of the bed and freeboard. However, this effect is
cation of the biomass blend, the gas composition not able to drastically reduce the tar concentra-
is always at an intermediate level with respect to tion and principally operates on tar species from
BW and DSS gasification operated at the same beech wood pyrolysis, because the tar abatement
conditions. is less marked in the gasification of DSS alone.
The tar concentration in the producer gas
is high for both fuels and drastically decreases
with the equivalence ratio (Fig. 3) and the tem- Particle conversion
perature (Fig. 4). It is worth to note that dry Figures 5 and 6 report the dependence on
sewage sludge gasification results in a lower tar the equivalence ratio of the carbon elutriation
yield, in spite of the higher ratio between vola- rate and bed carbon load, respectively. Dry sew-
tiles and fixed carbon. Among various variables age sludge shows higher values of such vari-
influencing tar genesis, the different organic ables, if compared to beech wood. The differ-
structure of the fuel and the ash content could ence is more pronounced in the case of the bed
be considered. The former influences the nature carbon load, which always increases at least by
of vapors from the fuel pyrolysis resulting in the 100 %, when switching from BW to DSS gasifi-
generation of more refractory species when cation. Furthermore, the results are consistent
beech wood is pyrolyzed; the latter modifies the with the experimental findings of Donsì et al.
particle temperature and the duration of the de- [1978] for coal combustion, which show the
volatilization stage, which are known to influ- increasing of the carbon elutriation rate with the
ence the tar yield [Moersch, 1998]. The tar con- bed carbon load. The different fragmentation
centration with the biomass blend is unexpect- behavior of the two fuels could provide an inter-
edly lower than the values of BW and DSS at pretation of the large difference in the bed car-
both the temperatures of 800 and 900 °C bon load. A ligneous biomass, similar to beech
(Fig. 4). The experimental finding could be at- wood, has been characterized by Chirone et al.
tributed to a catalytic effect [Bridgewater, 1995] [1997], which demonstrated the occurrence of
operated by DSS ash, where Ca is present in a primary and percolative fragmentation, during
15000
beech wood
12500
dry sewage sludge
Tar concentration, mg m-3
10000
7500
5000
2500
0
0.1 0.15 0.2 0.25 0.3 0.35 0.4
Equivalence ratio
combustion, with the consequent generation of beech wood gasification particles with a size
smaller fragments. DSS granules do not undergo larger than the upper detection limit of the appa-
fragmentation, conserving their original size and ratus (i.e. 564 µm) are collected at the cyclone.
shape during conversion. The larger the particle These particles must be very porous and light in
size, the higher the resistance to mass diffusion, order to be elutriable. Again, results reported in
the lower is the global kinetics of char gasifica- Fig. 7 confirm the main difference in the evolu-
tion. It is also known from literature [Smooth tion of the fuel particle during its conversion, as
and Smith, 1985] that the reactivity of carbona- far as comminution phenomena are concerned.
ceous particles appreciably decreases at a late The beech wood undergoes fragmentation (pri-
state of their conversion, because carbon is di- mary, secondary and percolative) because of the
luted in the ashes and the internal diffusion of absence of a coherent ash skeleton and the in-
gaseous reactants is more difficult. Similarly, the creasing porosity with the particle conversion.
high ash content of DSS represents an obstacle Elutriable particles of relatively large size are
to the gas diffusion; as a consequence, the in- produced in the bed via fragmentation and suc-
trinsic kinetics of the particle conversion is cessively separated by the cyclone. On the con-
lower than for low-ash fuels. In conclusion, the trary, the fines generation during dry sewage
bed carbon load increases, a longer time being sludge gasification is principally caused by the
required for the complete conversion of fuel mechanical abrasion along the external surface
particles in the bed. of the particle, leading to the formation of fines
Figure 7 reports the size distribution with smaller sizes.
measured by means of a Malvern equipment of Results of particle sampling by means of
powders collected at the cyclone (Fig. 7A) and the freeboard probe are also reported in Ta-
the ceramic filter (Fig. 7B). It clearly appears ble III in terms of the percent carbon elutriation
that the size of elutriated fines is shifted toward rate EC,F (col. 9) and percent carbon conversion
smaller diameters, passing from beech wood to in the freeboard (col. 10). The latter is the dif-
dry sewage sludge. Furthermore, during the ference between columns 9 and 8. The residence
9000
T=800°C
8000
T=900°C
Tar concentration, mg m -3
7000
6000
5000
4000
3000
2000
1000
0
beech wood blend dry sewage sludge
Fuel
Figure 4: Tar concentration as a function of the fuel type (λ=0.25)
beech wood
dry sewage sludge
Carbon elutriation rate, %
0
0.1 0.15 0.2 0.25 0.3 0.35 0.4
Equivalence ratio
Figure 5: Carbon elutriation rate versus the equivalence ratio (T=800 °C)
Anyway, the finding that the terminal velocity is bon conversion in the freeboard during beech
comparable with the gas velocity, leads to an wood gasification with respect to dry sewage
appreciable increasing of the residence time in sludge, in particular under unfavorable condi-
the freeboard, via Eq. 2. Furthermore, it is rea- tions of gasification.
sonable to suppose that the highest generation Finally, as far as results of the particle
rate of large fragments is obtained at λ=0.15, conversion are concerned, the blend fuel shows
i.e. under unfavorable conditions of gasification. an intermediate behavior with respect to the
Differently from beech wood, particles elutriated single fuels (Tab. 3). The results confirms the
during DSS gasification are smaller than 150 µm absence of mutual effects or interactions be-
(Fig. 7), corresponding to low values of the ter- tween the particles of different fuels (e.g. cataly-
minal velocity (e.g. Ut = 0.08 m/s at dp=80 mm sis by ashes), which can expected only if the fuel
and rp=1000 kg m-3) and the residence time of mixing is more intense and at the particle scale.
the particles is practically equal to that of the
gas. A further effort to explain the difference of
freeboard carbon conversion could be done
looking at the carbon content of elutriated fines.
This latter is much lower for dry sewage sludge
(< 5%) than for beech wood (approximately
50%), because of the huge ash content in char
particles of DSS. Again, elutriated fines which
leave the bed are less reactive for dry sewage
sludge than for beech wood [Smooth and Smith,
1985]. The cooperation of the above mentioned
factors, longer residence time and higher char
reactivity, leads to an enhancement of the car-
250
beech wood
dry sewage sludge
200
Bed carbon load, g
150
100
50
0
0.1 0.15 0.2 0.25 0.3 0.35 0.4
Equivalence ratio
Figure 6: Bed carbon load versus the equivalence ratio (T=800 °C)
10
9 beech wood
A
dry sewage sludge
8
Size distribution, %
2 Cyclone
0
10 1 10 100 1000
9 B beech wood
dry sewage sludge
8
Size distribution, %
3
Filter
2
0
1 10 Particle size, µm 100 1000
Figure 7: Size distribution of collected fines at the cyclone (A) and the filter (B)
(λ=0.15 and T=800°C)
Cenni, R., Frandsen, F., Gerhardt, T., Spli-
ethoff, H., Hein, K.R.G. (1998), "Study on Metal
Species Partitioning along the Flue Gas Path in
Combustion of Bituminous Coal and Dry Sewage
Sludge", Proc. of 1998 Int. Conf. on Incineration &
Thermal Treatment Technologies, May 11-15 Salt
Lake City, Utah, p. 689
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Phenomena in the Fluidized Bed Combustion of a
Biomass (Robinia Pseudoacacia)", Proc. of 14th
ASME FBC Conference, Vol. 1, p. 145
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(1991), "Comminution of Carbons in Fluidized Bed
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297
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Kunii, D. and Levenspiel, O. (1991), Fluidiza-
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and Application", Prog. Energy Combust. Sci., Vol.
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"Combustion Rates of Chars from High Volatile
Fuels for FBC Application", Proc. of 14th ASME
FBC Conference, Vol. 1, p. 135
Miccio, F., Moersch, O., Spliethoff, H., Hein,
K.R.G. (1998), "Generation and Conversion of
Carbonaceous Fine Particles during Bubbling Flu-
idised Bed Gasification of a Biomass Fuel", sub-
mitted to Fuel
Moersch, O., Spliethoff, H., Hein, K.R.G.
(1998), "Untersuchung der Moeglichkeiten zur
Minderung des Teergehalts bei der Wirbelschicht-
vergasung von Biomasse", DBU Contract Report
Moersch, O., Spliethoff, H., Hein, K.R.G.
(1998), "Quasi Continuous Tar Quantification with
a New Online Analyzing Method", Proc. of 10th
European Conf. and Technology Exhibition, Wür-
zburg, 8-11 June 1998, Vol. 1, p. 1638
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bustion and Gasification, Plenum Press, New York
NY