Material Safety Data Sheet Buffer Solution for Water Hardness (Schwarzenback) MSDS# 03489 Section 1 - Chemical Product

and Company Identification MSDS Name: Catalog Numbers: Synonyms: Company Identification: For information in the US, call: Emergency Number US: CHEMTREC Phone Number, US: ---------------------------------------Risk Phrases: CAS#: Chemical Name: %: EINECS#: Hazard Symbols: ------------------------------------------------------------------------------Risk Phrases: CAS#: Chemical Name: %: EINECS#: Hazard Symbols: ------------------------------------------------------------------------------Risk Phrases: CAS#: Chemical Name: %: EINECS#: Hazard Symbols: ------------------------------------------------------------------------------Risk Phrases: CAS#: Chemical Name: %: EINECS#: Hazard Symbols: ---------------------------------------7791-18-6 Magnesium chloride, hexahydrate <10.0 unlisted 7732-18-5 Water >50 231-791-2 6381-92-6 Disodium EDTA dihydrate <10.0 unlisted 1336-21-6 Ammonium hydroxide <20.0 215-647-6 Buffer Solution for Water Hardness (Schwarzenback) SB119-1, SB119-B1 None Fisher Scientific One Reagent Lane Fair Lawn, NJ 07410 201-796-7100 201-796-7100 800-424-9300 Section 2 - Composition, Information on Ingredients

---------------------------------------Risk Phrases: CAS#: Chemical Name: %: EINECS#: Hazard Symbols: ---------------------------------------Text for R-phrases: see Section 16 Hazard Symbols: 12125-02-9 Ammonium chloride <10.0 235-186-4

Risk Phrases:

34 Section 3 - Hazards Identification

EMERGENCY OVERVIEW Danger! Corrosive. Causes burns by all exposure routes. Target Organs: Respiratory system, eyes, skin. Potential Health Effects Eye: Skin: Causes eye irritation and possible burns. Causes skin irritation and possible burns. May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. May cause gastric Ingestion: disturbances and electrolytic imbalance. Inhalation: Causes respiratory tract irritation with possible burns. Chronic inhalation may cause nasal septum ulceration and perforation. Prolonged or repeated contact may cause Chronic: skin necrosis and/or ulceration of the skin. Section 4 - First Aid Measures Eyes: Skin: Ingestion: Inhalation: Notes to Physician: Section 5 - Fire Fighting Measures Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained General Information: breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Extinguishing Use water fog, dry chemical, carbon dioxide, or regular foam. Media: Autoignition Not applicable. Temperature: Flash Point: Not applicable. Explosion Limits: Not available Lower: Explosion Limits: Not available Upper: NFPA Rating: health: 3; flammability: 0; instability: 0; Section 6 - Accidental Release Measures Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

General Information: Spills/Leaks:

Use proper personal protective equipment as indicated in Section 8. Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Section 7 - Handling and Storage

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Storage: Store in a cool, dry place. Keep container closed when not in use. Do not store in metal containers. Handling: Section 8 - Exposure Controls, Personal Protection
+-------------------- +------------------- +------------------- +----------------- + | Chemical Name | ACGIH | NIOSH |OSHA - Final PELs| |-------------------- |------------------- |------------------- |----------------- | | Ammonium hydroxide |none listed |none listed |none listed | |-------------------- |------------------- |------------------- |----------------- | | Disodium EDTA dihyd|none listed |none listed |none listed | | rate | | | | |-------------------- |------------------- |------------------- |----------------- | | Water |none listed |none listed |none listed | |-------------------- |------------------- |------------------- |----------------- | | Magnesium chloride,|none listed |none listed |none listed | | hexahydrate | | | | |-------------------- |------------------- |------------------- |----------------- | | Ammonium chloride |10 mg/m3 (fume); |10 mg/m3 TWA |none listed | | |20 mg/m3 STEL | (fume) | | | |(fume) | | | +-------------------- +------------------- +------------------- +----------------- +

OSHA Vacated PELs: Ammonium hydroxide: None listed Disodium EDTA dihydrate: None listed Water: None listed Magnesium chloride, hexahydrate: None listed Ammonium chloride: 10 mg/m3 TWA Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits Personal Protective Equipment Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face Eyes: protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a Respirators: NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - Physical and Chemical Properties Physical State: Liquid Color: clear, colorless Odor: none reported pH: >=10.3 Vapor Pressure: Not available Vapor Density: Not available Evaporation Rate: >1 (ether=1) Viscosity: Not available Boiling Point: decomposes. Freezing/Melting Point: -35 deg C ( -31.00 F) Decomposition Temperature: Not available Solubility in water: Not available. Specific Gravity/Density: 0.96 Molecular Formula: Mixture

Molecular Weight: 0 Section 10 - Stability and Reactivity Chemical Stability: Conditions to Avoid: Incompatibilities with Other Materials Hazardous Decomposition Products Hazardous Polymerization Stable under normal temperatures and pressures. None reported. Not available None. Has not been reported. Section 11 - Toxicological Information CAS# 1336-21-6: BQ9625000 CAS# 6381-92-6: AH4410000 RTECS#: CAS# 7732-18-5: ZC0110000 CAS# 7791-18-6: OM2975000 CAS# 12125-02-9: BP4550000 BP4570000 RTECS: CAS# 1336-21-6: Draize test, rabbit, eye: 250 ug Severe; Draize test, rabbit, eye: 44 ug Severe; Oral, rat: LD50 = 350 mg/kg; . RTECS: CAS# 6381-92-6:. RTECS: CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg; . LD50/LC50: RTECS: CAS# 7791-18-6: Oral, mouse: LD50 = 7600 mg/kg; Oral, rat: LD50 = 8100 mg/kg; . RTECS: CAS# 12125-02-9: Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, eye: 100 mg Severe; Oral, mouse: LD50 = 1300 mg/kg; Oral, rat: LD50 = 1650 mg/kg; . Ammonium hydroxide - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. Disodium EDTA dihydrate - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. Carcinogenicity: Water - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. Magnesium chloride, hexahydrate - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. Ammonium chloride - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. Other: See actual entry in RTECS for complete information. Section 12 - Ecological Information Other: No information available. Section 13 - Disposal Considerations Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - Transport Information US DOT Shipping Name: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. Hazard Class: 8 UN Number: UN3266 Packing Group: II Canada TDG Shipping Name: Not available Hazard Class: UN Number: Packing Group:

USA RQ: CAS# 1336-21-6: 1000 lb final RQ; 454 kg final RQ USA RQ: CAS# 12125-02-9: 5000 lb final RQ; 2270 kg final RQ Section 15 - Regulatory Information European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: WGK (Water Danger/Protection) CAS# 1336-21-6: 2 CAS# 6381-92-6: 2 CAS# 7732-18-5: Not available CAS# 7791-18-6: 0 CAS# 12125-02-9: 1 Canada CAS# 1336-21-6 is listed on Canada's DSL List CAS# 6381-92-6 is listed on Canada's DSL List CAS# 7732-18-5 is listed on Canada's DSL List CAS# 12125-02-9 is listed on Canada's DSL List Canadian WHMIS Classifications: E This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. CAS# 1336-21-6 is listed on Canada's Ingredient Disclosure List CAS# 6381-92-6 is not listed on Canada's Ingredient Disclosure List. CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List. CAS# 7791-18-6 is not listed on Canada's Ingredient Disclosure List. CAS# 12125-02-9 is listed on Canada's Ingredient Disclosure List US Federal TSCA CAS# 1336-21-6 is listed on the TSCA Inventory. CAS# 6381-92-6 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form in on the Inventory (40CFR720.3(u)(2)). CAS# 7732-18-5 is listed on the TSCA Inventory. CAS# 7791-18-6 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form in on the Inventory (40CFR720.3(u)(2)). CAS# 12125-02-9 is listed on the TSCA Inventory. Section 16 - Other Information MSDS Creation Date: 9/02/1997 Revision #7 Date 7/20/2009 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantibility or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the company has been advised of the possibility of such damages.

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