A GUIDE TO THE SAFE USE OF SALON HAIR PRODUCTS

MATERIAL SAFETY DATA SHEETS

IMPORTANT
KEEP THIS BOOK IN THE SALON FOR REFERENCE PURPOSES JULY 2002

SUMMARY HAIR PREPARATIONS should generally not present a risk to the health and safety of hairdressers or their clients if used sensibly and manufacturers' instructions are followed. Manufacturers are required by law to supply health and safety information on any products used in hairdressing salons (a place of work) that contain potentially hazardous substances. Details must also be provided on the precautions that should be taken to reduce any risks. The information that manufacturers must give their customers (hairdressing salon owners or wholesalers) is given in this booklet. The purpose of this booklet is to provide sufficient information on the HAIR PRODUCTS used in salons, for you to make a workplace Hazard assessment and Management as required by Hazardous Substances Regulations for New Zealand under the Health and Safety in Employment Act, Toxic Substances Act, Dangerous Goods Act and Hazardous Substances and New Organisms Act. This book contains 14 Material Safety Data Sheets (MSDS). They cover the categories of products commonly used in hairdressing salons. The MSDS tells you how to safely handle a product. It provides information for workers and professionals to help them make decisions and to prevent or deal with emergencies. Use the product lists issued by manufacturers to determine which MSDS applies to a particular haircare product. The information given in this booklet is ONLY PART of what is required to meet the requirement for workplace Hazard assessment and management. Information will be also required on any other products used in the salon which may be hazardous to health, such as those used for cleaning, disinfecting and nail care products. This Guide should also be used in conjunction with the Guide to Occupational Safety and Health for hairdressing published by the New Zealand Association of Hairdressers OHS New Zealand has been consulted during the preparation of this booklet and their comments have been incorporated. All manufacturers/distributors must supply their customers (salons) with a list specifying which MSDS in this booklet is relevant to each of their products. If you do not have such a list, contact your supplier. If any of the products supplied by manufacturers do not comply with the information in this booklet then the correct information (i.e. product specific Material safety Data Sheet) will be provided separately. 1

This booklet was written by the CTFA New Zealand and based on the Australian Publication of the same name. This publication has been made possible by the following companies:

- American Crew (New Zealand - L'Oreal - Matrix Essentials New Zealand - Sabre Corporation (New Zealand) - Sebastian International - Schwarzkopf New Zealand - Shisiedo New Zealand - Wella
Foreword
I commend the Cosmetic Toiletry and Fragrance Association of New Zealand for their initiative in producing this guide. It is a useful document that provides practical guidance on managing health and safety in the hairdressing industry. Adopting the safe work practices in this guide will assist employers to meet their obligations under the Health and Safety in Employment Act 1992. The guide will also assist employees to be aware of the health and safety hazards they may encounter at work and how to take the necessary precautions. The Occupational Safety and Health Service of the Department of Labour encourages the use of this guide by all those working in the hairdressing industry.

R.J.M. Hill General Manager Occupational Safety and Health

A GUIDE TO THE SAFE USE OF SALON HAIR PRODUCTS

The aim of this guide is to provide relevant information on hair products used in Salons for you, the hairdresser to make an assessment of possible health and safety risks associated with storing and handling of these products in the environment in which you work. The guide complies with the requirements of the Health and Safety in Employment Act and related regulation. The guide is not intended to be a complete encyclopaedia of safety information, rather, it is designed to highlight some of the most important points you should be aware of. Your regular training, product's label information, other safety information that is available to you and use of good judgement on the job will help you avoid injury to yourself, your clients and your fellow employees. Are professional cosmetic products safe? A great deal of effort and resources are directed towards product safety on the part of manufacturers and regulators. The Food and Drug Administration (FSA) in the USA, COLIPA (The European federation of the national associations of the perfumery, cosmetics and toiletries industry) in Europe, The Australian National Health and Medical Research Council (NHRMC), Therapeutic Goods Administration (TGA), Australian and New Zealand Health departments, and other bodies combine to ensure that products offered for sale in the market place are safe. However, poor practice resulting in extended skin contact or respiratory exposure to particular products may cause ill health to some hair and beauty practitioners. Cosmetic products are safe when used according to manufacturers instructions and recommendations. Ingredients Listing While responsible manufacturers and suppliers will have ingredients listed there is no legal obligation other than those set out in the Toxic Substances Act Regulations for Scheduled Poisons. If unable to locate this information on the packs you currently use or offer for sale, contact your supplier or distributor and ask that the information be provided to you. Ingredient lists inform about the substances present in the products. If you or some of your clients are allergic to certain ingredients, a look at the list will tell you whether those ingredients are present in the product. This information will help you and your clients avoid unwanted allergic reactions and/or to find products that do not present the potential for that problem.

Ingredient names are listed according to a standardised international format and therefore should make no difference as to where the products are sourced from. To help you avoid ingredients to which you may be allergic, make sure to find out from your doctor the chemical name or other commonly used names for that ingredient; then compare those names with those on the ingredients list. If you are unsure consult your doctor or the supplier to confirm one way or another. Material safety Data Sheets (MSDS) There is no requirement under the Health and Safety in Employment Act that a material safety data sheet be prepared by the manufacturer or the supplier if the product being supplied is assessed as being a hazardous substance; however it is implied under sections 7 & 10. This guide has attempted to cover the majority of products supplied to hairdressers and in so doing 14 product groups have been created. Some of the groups list the products contained within them as hazardous, others list the products as non hazardous. Manufacturers have assessed all product groups and have prepared a Material Safety Data Sheet (MSDS) for each one of them. In each case the information provided in the MSDS should be read and clearly understood by everyone. *Refer to LEGEND on page 7. Please keep this guide available in the workplace for employees to look at whenever they wish. What can you learn from a Material Safety Data Sheet (MSDS)? The MSDS enables the user to answer some basic questions. a). b). c). d). What is the product I am about to use? What do I need to know before and while I use it? What do I do if a hazardous situation occurs? How can I prevent a hazardous situation from occurring?

The MSDS will tell you how to safely handle the product so that you do not place yourself or others at risk. The MSDS provides information to both workers and professionals to help them make decisions and to prevent or deal with emergencies. Such people may include managers, supervisors, transport drivers, the police, fire fighters, occupational hygienists, doctors, poison information centres personnel, government authorities and so on. These people will often need to know additional technical information associated with the product; information which is not often understood by personnel who have not had specialist training in that area. For this reason some of the information on a MSDS may appear too technical and unnecessary, but you are required by Law to make sure all employees know about information pertaining to a hazard and the information is

contained on the MSDS is an excellent means of conveying this information and what it means for them. Physical description and properties APPEARANCE - In addition to explaining what the products look like (ie. liquid, powder etc) it will also include the likely product colour and product odour. This subsection also contains additional information useful in determining the likely hazards which further characterise the product. BOILING POINT - The temperature at which a liquid boils. VAPOUR PRESSURE - Is a measure of how much of a substance can accumulate as a vapour in the air above a liquid or solid. Useful in determining potential fire hazards and for determining potential respiratory hazard FLAMMABILITY LIMITS - The range of concentrations of flammable vapours in the air which will burn if ignited. SOLUBILITY IN WATER - This information is useful in determining effective fire extinguishing methods and spill clean up procedures. FLASH POINT - Is the lowest temperature at which a liquid will produce enough vapours to ignite if an ignition source is present. SPECIFIC GRAVITY - Less than 1.0 indicates that the product is lighter than water and if not miscible with water then the product could separate. pH - Is a measure of acidity and alkalinity. Low pH means the product is acidic; high pH means the product is alkaline. For example 1 = highly acidic and 14 = highly alkaline Ingredients This subsection provides the chemical name, CAS No (Chemical Abstract No) and proportion within a mixture for each hazardous component. Non hazardous ingredients may also be described. Health Hazards Information This section describes the potential health hazards of short term (acute) and long term (chronic) exposure to the products within the group. The effects are divided into major routes of exposure -- ingestion (swallowing), inhalation (breathing), skin and eye contact. Similarly, the first aid instructions for initial treatment of over exposure are divided into routes of exposure. There is also additional advice to doctors in this section. 5

Precautions For Use This is the most important section for users as it details how users can protect themselves and how the manufacturer can advise users of potential harm. Workplace exposure standards used in New Zealand are set by Occupational Safety and Health. One of these standards is the Time Weighted Average (TWA), airborne concentration of a substance over an eight hour working day, for a five day working and over an entire working life. According to current knowledge, this concentration should neither impair the health of, nor cause undue discomfort to users. Exposure standards are guides to be used in the control of occupational health hazards and to evaluate how well equipment is working (i.e. ventilation). ? Engineering controls detail the mechanical ventilation required during use of the product. Use in well ventilated areas explains the need to ensure that the product is not used in areas without ventilation or air flow. Personal protection details the specific equipment (gloves - safety glasses) required to work safely with the product. Disposable gloves use refers to compounds such as nitrile or vinyl and not latex which is a poor chemical barrier. Flammability section details what is needed to prevent a fire or explosion hazard. The advice may include the need to avoid ignition sources and information on whether the substance should be used in well ventilated areas and away from confined spaces.

Note: It is not the individual products that are hazardous but excessive exposure of professionals to a cocktail of different chemicals without adequate protection that may cause irritant reactions such as dermatitis. Safe Handling Information Storage and transport requirements for the product may be found in this section. Some products have special requirements set in regulations (Flammable products and aerosol products) and the MSDS will state the codes and restrictions which may apply. Spill and disposal will contain advice on how to minimise a spill or leak, a suitable method for cleaning up and how to dispose of collected material. A description of the fire and explosion hazard for the product and the type of extinguisher to be used in case of fire complete this section.

Other Information This section can contain any other useful information pertinent to the product.

LEGEND
MSDS No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 DESCRIPTION Flammable Products Peroxide Solutions 7 - 12% Bleach Powders Peroxide Solutions 3 - 6% Acid Perms (Containing glyceryl thioglycolate ester) Acid Perms (Ester Free) Alkaline Perms & Relaxers Hair Colours (Flammable Liquid) Hair Colours (Permanent/Semipermanent Cream or Liquid Hair Colours (Aerosol) Hairsprays/Lacquers (Aerosol) Aerosol Mousses (Styling and Conditioning) Shampoos Conditioners and Treatments

THE MATERIAL SAFETY DATA SHEET RELEVANT SECTION OF MSDS Company Name and Address PLAIN LANGUAGE EXPLANATION - The name, address and emergency telephone number of the New Zealand manufacturer or supplier - What is the name of the product? - What does it look like? - Does it smell? - What does it contain? What might happen if too much of the product is: -- Breathed in? -- Gets into eyes? -- Gets onto skin? -- Swallowed? What should I do if someone is over exposed?

Identification Physical description: Properties: Ingredients: Health Hazard Information Acute: Swallowed: Chronic: Eye: First Aid: Skin: Inhaled:

Precautions for Use: Exposure standards: Engineering controls: Personal protection: Flammability: Safe Handling Information Storage and transport: Spills and disposal: Fire/explosion hazard: Other Information

Are there special handling precautions I should follow? - Use in well ventilated areas - What protective clothing or equipment do I need? Gloves, apron, mask? - What ventilation is required? How should the material be stored? Are there materials this product should not come in contract with? How do I clean up s spill? How do I dispose of it properly? Will it burn or explode?

FLAMMABLE PRODUCTS MATERIAL SAFETY DATA SHEET NO.1 v Non-hazardous according to criteria of Occupational Safety & Health. Date of Issue: 1.7.2002 PRODUCT IDENTIFICATION PRODUCT NAME: CODE: UN No: 1170 or 1219 DANGEROUS GOODS CLASS: 3 SUBSIDIARY RISK: None Available PACKAGING GROUP No:ll Refer to individual company listing HAZCHEM CODE: 2SE POISION SCHEDULE: Not applicable PRODUCT USE: Hair Styling

PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Clear pale yellow liquid BOILING POINT: > 35oC VAPOUR PRESSURE: Not determined FLAMMABILITY LIMITS: Highly flammable SOLUBILITY IN WATER: Completely Soluble INGREDIENTS Ethyl Alcohol and/or Isopropyl Alcohol and/or Cyclomethicone CAS No. 64 - 17 - 5 67 - 63 - 0 { { { { 69430 - 24 - 6 540 - 97 - 6 541 - 02 - 6 541 - 05 - 9 FLASH POINT: < 23oC SPECIFIC GRAVITY: 0.82-0.93 g/ml pH: 3.5 - 9.0 % w/w Content } } } } 25 to 95 } } } } to 100

Other ingredients HEALTH EFFECTS ACUTE EFFECTS: Swallow: Eye: Skin: Inhaled:

HEALTH HAZARD INFORMATION

Low toxicity by the oral route. May cause irritation of the gastrointestinal tract. Depression of the central nervous system may result in headache and dizziness. Splashes in the eye may cause immediate stinging sensation and tears. Transient reddening of the eye may also occur. No appreciable irritation of the skin is expected. At relatively high vapour concentrations ethyl and isopropyl alcohol are irritants to the nose and throat and may cause central nervous system depression. Chronic exposure to ethyl or isopropyl alcohol may result in irritation of the mucous membrane, headache, lack of concentration and drowsiness. Prolonged or repeated skin contact may result in dermatitis. 9

CHRONIC EFFECTS:

FIRST AID: Swallowed: Eyes: Skin: Inhaled: Advice to Doctor:

If swallowed do not induce vomiting give one or two glasses of water. If in eyes hold open and flood with water for at least 15 minutes. See a doctor if pain persists. Wash affected area with water. Remove contaminated clothing and wash before reuse. Remove person to fresh air. Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA* CHEMICAL NAME: Ethyl alcohol 1880mg/m 3(1000ppm) or Isopropyl alcohol 983mg/m 3(400ppm) *New Zealand Workplace Exposure Standards ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Under normal use conditions, no specific protection required. Eyes: Protect eyes when using. Flammability: Highly Flammable. Keep away from heat, flame or ignition source. STORAGE AND TRANSPORT: SPILL AND DISPOSAL: SAFE HANDLING INFORMATION Store product upright in a cool place and out of direct sunlight. Store away from corrosive and oxidising products. Store in accordance with Dangerous Goods Regulations and transport in accordance with the ADG Code for Dangerous Goods Class 3. Remove possible leaking containers. Remove all ignition sources and ventilate area. Dilute small spills with water. For larger spills, dilute with water and absorb in inert material (sand or vermiculate). Dispose of in accordance with local regulations. Highly Flammable. If spilled or ruptured will increase the intensity of the fire. In case of fire water, water fog, dry chemical, CO2 or foam can be used. OTHER INFORMATION

FIRE / EXPLOSION HAZARD:

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PEROXIDE SOLUTIONS 7 - 12% MATERIAL SAFETY DATA SHEET 2 v Hazardous according to criteria of Occupational Safety & Health. Date of Issue: 1.7.2002 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: UN No: 2984 DANGEROUS GOODS CLASS: 5.1 (> 8%) SUBSIDIARY RISK: None Available PACKAGING GROUP No: lll Refer to individual company listing HAZCHEM CODE: 2P POISION SCHEDULE: 4 PRODUCT USE: To mix with hair colours and bleaches.

PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Low viscosity liquid BOILING POINT: Approx 100 oC VAPOUR PRESSURE: Not determined FLAMMABILITY LIMITS: Not flammable SOLUBILITY IN WATER: Miscible FLASH POINT: Not determined SPECIFIC GRAVITY: 1.02-1.05 g/ml pH: 2.0 - 4.0 % w/w Content 7 to 12 to 100

INGREDIENTS CAS No. Hydrogen peroxide 7722 - 84 - 1 Other ingredients determined not to be hazardous. HEALTH EFFECTS ACUTE EFFECTS: Swallow: Eye: Skin: Inhaled: CHRONIC EFFECTS: FIRST AID: Swallowed: Eyes: Skin: Inhaled: Advice to Doctor:

HEALTH HAZARD INFORMATION Irritant. Attacks eyes. Protect eyes when using. Severe systemic poisoning may cause headache, dizziness, vomiting diarrhoea, tremors, numbness, convulsions, pulmonary oedema, unconsciousness and shock. Eye contract may cause ulceration of the cornea. The appearance of eye damage may be delayed. Avoid contact. Temporary whitening or bleaching of the skin may occur. Irritation and formation of blisters may also occur. Exposure to high vapour concentration may cause irritation of nose and throat. Long term skin contact may cause dermatitis. If swallowed do not induce vomiting. Give a glass of water. Contact a doctor or the National Poison Information Centre Phone: 0800-764766 If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor. Remove contaminated clothing and wash skin thoroughly with water. Remove person to fresh air. Treat symptomatically. If in eyes, recheck after one week.

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PRECAUTIONS FOR USE EXPOSURE LIMITS: CHEMICAL NAME: Hydrogen peroxide TWA* 1.4mg/m 3(1ppm)

*New Zealand Workplace Exposure Standards

ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves, (vinyl, rubber or plastic) must be worn when handling this product. Disposable gloves must not be latex Eyes: Eye protection must be worn (safety glasses) to avoid accidental splashes into eyes. Flammability:Product is not flammable, but can start a fire if spilled on combustible materials, eg: paper, wood, cardboard. STORAGE AND TRANSPORT: SAFE HANDLING INFORMATION Store product upright in a cool place away from heat and direct sunlight. Store away from corrosive and flammable products. Store in accordance with Dangerous Goods Regulations and transport in accordance with the NZDG Code for Dangerous Goods Class 5. Dilute small spills with water, contain and absorb larger spills in inert material (sand). Dispose of in accordance with local regulations. Will not burn, but may release oxygen when subjected to heat. At concentration above 10%, hydrogen peroxide may ignite a fire if spilled on combustible materials (ie wood, paper, cardboard). In case of fire water, water fog, dry chemical CO2 or foam can be used. OTHER INFORMATION Solutions containing hydrogen peroxide and bleach powders may sometimes produce heat when applied to hair. This may be further enhanced by the presence of metallic impurities (ie aluminium as in glitter sprays or other forms). Should this occur, remove mixture from the hair by rinsing at the basin! Do not mix with perm lotions.

SPILL AND DISPOSAL: FIRE / EXPLOSION HAZARD:

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BLEACH POWDERS MATERIAL SAFETY DATA SHEET NO 3. v Hazardous according to criteria of Occupational Safety & Health. Date of Issue 1.7.2002 PRODUCT IDENTIFICATION PRODUCT NAME: Refer to individual company listing UN No: Not applicable HAZCHEM CODE: Not applicable DANGEROUS GOODS CLASS: Not applicable POISION SCHEDULE: 4 SUBSIDIARY RISK: Not applicable PRODUCT USE: Mixed with solutions PACKAGING GROUP No: Not applicable containing hydrogen peroxide to bleach/lighten the colour of hair. PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Fine to granular powder. BOILING POINT: Not applicable FLASH POINT: Not applicable VAPOUR PRESSURE: Not determined SPECIFIC GRAVITY: Not determined FLAMMABILITY LIMITS: Not determined pH: 9.0 - 10.0 (when mixed) SOLUBILITY IN WATER: Miscible with water. INGREDIENTS Persulphate salts (Ammonium sodium, potassium) Silica Sodium Silicate Sodium Metasilicate Strontium peroxide Other ingredients determined not HEALTH EFFECTS ACUTE EFFECTS: Swallow: Eye: Skin: Inhaled: CHRONIC EFFECTS: Harmful if swallowed can cause irritation of the gastro intestinal tract. Irritating to eyes. Irritating to skin. May cause sensitisation by skin contact. Irritating to the respiratory system. May cause sensitisation by inhalation. May cause allergic dermatitis. Prolonged or repeated inhalation may cause sensitisation. CAS No. {7727 - 54 - 0 {7775 - 27 - 1 {7727 - 53 - 2 {7631 - 86 - 9 {112945 - 52 -5 1344 - 09 - 8 6834 - 92 - 0 1314 - 18 - 7 to be hazardous % w/w Content < 70 < 10 < 40 < 30 < 12 to 100

HEALTH HAZARD INFORMATION

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FIRST AID: Swallowed: Eyes: Skin: Inhaled: Advice to Doctor:

If swallowed do not induce vomiting. Give a glass of water. Contact a doctor or the National Poison Information centre Phone 0800-764766 If in eyes hold open and flood with water for at least 15 minutes and see a Doctor. Remove contaminated clothing and wash skin thoroughly with water. Remove person to fresh air and see a Doctor. Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA* CHEMICAL NAME: Amorphous fumed silica (respirable dust) 2mg/m3 Persulphate (ACGIH TLV standard) 5mg/m3 *New Zealand workplace Exposure Standards ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this product or its mixtures with solutions containing hydrogen peroxide. Disposable gloves must not be latex Eyes: Safety glasses must be worn to avoid product or dust entering the eyes. Flammability:Product is not flammable but its mixtures with peroxide can start a fire if spilled on combustible materials, eg: paper, wood, cardboard. SAFE HANDLING INFORMATION STORAGE AND TRANSPORT: SPILL AND DISPOSAL: FIRE / EXPLOSION HAZARD: Store product in a cool dry place away from heat and direct sunlight. Store away from corrosive, combustible and flammable products. Avoid creating dust. Collect into clean plastic containers and dispose in accordance with local regulations. Wipe area with wet mop/cloth. When heated product can release oxygen. This can cause other materials to burn. On decomposition can release fumes or ammonia, sulfates and oxides of nitrogen and potassium. Respirators and eye protection is required. In case of fire water, water fog, dry chemical CO 2 or foam can be used. OTHER INFORMATION Mixtures of bleach powders and solutions containing hydrogen peroxide (6, 9 and 12%) may produce heat when applied to hair. This may be further enhanced by the presence of metallic impurities (ie aluminium as in glitter sprays or other forms). Should a reaction occur, remove mixture from the hair by rinsing at the basin! Do not mix with perm lotions. Skin sensitivity test: follow manufacturers instructions Added heat during application: follow manufacturers instructions 14

PEROXIDE SOLUTIONS 3 - 6% MATERIAL SAFETY DATA SHEET NO.4 v Hazardous according to criteria of Occupational Safety & Health. Date of Issue: 1.7.2002 PRODUCT IDENTIFICATION PRODUCT NAME: Refer to individual company listing UN No: Not applicable HAZCHEM CODE: Not applicable DANGEROUS GOODS CLASS: Not applicable POISION SCHEDULE: 4 SUBSIDIARY RISK: Not applicable PRODUCT USE: To mix with hair colours PACKAGING GROUP No: Not applicable PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Low viscosity liquid BOILING POINT: Not Determined FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY: 1.01-1.03 g/ml FLAMMABILITY LIMITS: Not Flammable pH: 2.0 - 4.0 SOLUBILITY IN WATER: Completely soluble INGREDIENTS CAS No. Hydrogen Peroxide {7727 - 84 - 1 Other ingredients determined not to be hazardous HEALTH EFFECTS ACUTE EFFECTS: Swallow: Eye: Skin: Inhaled: CHRONIC EFFECTS: FIRST AID: Swallowed: Eyes: Skin: Inhaled: Advice to Doctor: % w/w Content 3 to 6 to 100

HEALTH HAZARD INFORMATION Irritant. Avoid contact with eyes Can cause irritation of the gastrointestinal tract. Eye contact can cause irritation. Temporary whitening of the skin may occur. Prolonged skin contact should be avoided. May cause skin irritation. Inhalation of vapours may cause irritation of nose and throat. Long term skin contact may cause dermatitis. If swallowed do not induce vomiting. Give a glass of water. Contact a doctor or the National Poison Information centre. Phone 0800-764766 If in eyes hold open, flood with water for at least 15 minutes and see a Doctor. Remove contaminated clothing and wash skin thoroughly with water. Remove person to fresh air. Treat symptomatically. If in eyes, recheck after one week.

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PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA* CHEMICAL NAME: Hydrogen peroxide 1.4mg/m 3(1ppm) *New Zealand workplace Exposure Standards ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) are recommended when handling this product. Disposable gloves must not be latex Eyes: Eye protection (safety glasses) must be worn to avoid accidental splashes into eyes. Flammability:Product is not flammable. SAFE HANDLING INFORMATION STORAGE AND TRANSPORT: SPILL AND DISPOSAL: FIRE / EXPLOSION HAZARD: Store product upright in a cool dry place, away from heat and direct sunlight. Store away from corrosive and flammable products. Dilute small spills with water. Dilute with water, contain and absorb larger spills in inert material (sand). Dispose of in accordance with local regulations. Will not burn, but may release oxygen when subjected to heat. In case of fire, water, water fog, dry chemical, CO 2 or foam can be used. OTHER INFORMATION

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ACID PERM (Containing glyceryl thioglycolate ester) MATERIAL SAFETY DATA SHEET NO 5. v Hazardous according to criteria of Occupational Safety & Health. Date of Issue: 1.7.2002 PRODUCT IDENTIFICATION Refer to individual company listing Not applicable HAZCHEM CODE: Not applicable POISION SCHEDULE: Not applicable Not applicable PRODUCT USE:

PRODUCT NAME: UN No: DANGEROUS GOODS CLASS: SUBSIDIARY RISK: PACKAGING GROUP No:

Not applicable Not applicable Permanent waving of hair

PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Liquid with characteristic odour BOILING POINT: Not Determined FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY: 1.0 - 1.06g/ml FLAMMABILITY LIMITS: Not flammable pH: 5.5 - 9.5 SOLUBILITY IN WATER: Completely soluble INGREDIENTS Ammonia Hydrogen Peroxide Glyceryl thioglycolate when mixed with solution as activator concentrate Other ingredients determined not to CAS No. 7664 41 7 7722 - 84 1 30618 - 84 9 be hazardous % w/w Content < 0.5 <3 < 28 > 90 to 100

HEALTH EFFECTS ACUTE EFFECTS: Swallow: Eye: Skin: Inhaled: CHRONIC EFFECTS: FIRST AID: Swallowed: Eyes: Skin: Inhaled: Advice to Doctor:

HEALTH HAZARD INFORMATION Irritant. Avoid contact with eyes and skin. May cause sensitisation. Harmful if swallowed. May cause irritation of the gastrointestinal tract. Corrosive in concentrated form. Contact may cause serious eye damage. Avoid contact. May cause skin irritation and sensitisation. Inhalation of vapours may cause irritation of nose and throat. Long term or repeated exposure may result in dermatitis. If swallowed do not induce vomiting, give a glass of water. Contact a doctor or the National Poison Information centre. Phone 0800-764766 If in eyes hold open, flood with water for at least 15 minutes and see a Doctor. Do not rub. Rinse with water. Remove contaminated clothing. Remove person to fresh air. Treat symptomatically. If in eyes, recheck after one week. 17

PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA* CHEMICAL NAME: Ammonia 17mg/m 3(25ppm) Hydrogen peroxide 1.4mg/m 3(1ppm) *New Zealand workplace Exposure Standards ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (rubber or plastic) must be worn when handling this product. Disposable gloves must not be latex. Eyes: Safety glasses must be worn mixing and application to avoid product contacting the eyes. Flammability:Product is not flammable. SAFE HANDLING INFORMATION STORAGE AND TRANSPORT: SPILL AND DISPOSAL: FIRE / EXPLOSION HAZARD: Store product in a cool place away from foodstuffs and oxidising agents. Dilute small spills with water. Absorb larger spill in inert materials (sand or vermiculate). Dispose of in accordance with local regulations. Product is not flammable. May release toxic hydrogen sulphide fumes if heated to decomposition. In case of fire, water, water fog, dry chemical, CO2 or foam can be used. OTHER INFORMATION Corrosive in concentrated form. Closely follow usage instructions when handling and mixing activator and lotion.

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ACID PERM (ester free) MATERIAL SAFETY DATA SHEET NO 6. v Hazardous according to criteria of Occupational Safety & Health. Date of Issue: 1.7.2002 PRODUCT IDENTIFICATION PRODUCT NAME: Refer to individual company listing UN No: Not applicable HAZCHEM CODE: Not applicable DANGEROUS GOODS Not applicable POISON SCHEDULE: Not applicable CLASS: SUBSIDIARY RISK: Not applicable PRODUCT USE: Permanent waving of hair PACKAGING GROUP No: Not applicable PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Liquid with characteristic odour BOILING POINT: Not Determined FLASH POINT: Not applicable VAPOUR PRESSURE: Not applicable SPECIFIC GRAVITY: 1.0 - 1.05g/ml FLAMMABILITY LIMITS: Not flammable pH:7.0 - 8.0 (when mixed) SOLUBILITY IN WATER: Completely soluble INGREDIENTS CAS No. Ammonia 7664 - 41 - 7 Hydrogen Peroxide 7722 - 84 - 1 Ammonium thioglycolate }(when 5421 - 46 - 5 Thiolactic acid }mixed with 79 - 42 - 5 Ammonium thiolactate }solution) 13419 - 67 - 5 Ammonium thioglycolate }(as 5421 - 46 - 5 Ammonium thiolactate }activator 13419 - 67 - 5 Thiolactic acid }concentrate) 79 - 42 - 5 Other ingredients determined not to be hazardous HEALTH HAZARD INFORMATION Irritant. Avoid contact with eyes. Harmful if swallowed. May cause irritation of the gastrointestinal tract. Avoid contact. Corrosive in concentrated form. Avoid contact. May cause skin irritation. Inhalation of vapours may cause irritation of the nose and throat. Long term or repeated exposure may result in skin irritation in some individuals. % w/w Content < 0.5 <3 < 11 < 10 < 22 < 60 to 100

HEALTH EFFECTS ACUTE EFFECTS: Swallow: Eye: Skin: Inhaled: CHRONIC EFFECTS:

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FIRST AID: Swallowed: Eyes: Skin: Inhaled: Advice to Doctor:

If swallowed do not induce vomiting. Give a glass of water. Contact a doctor or the National Poison Information centre. Phone 0800-764766 If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor if pain persists.. Do not rub. Rinse with water. Remove contaminated clothing. Remove person to fresh air. Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA* CHEMICAL NAME: Ammonia 17mg/m 3(25ppm) Hydrogen peroxide 1.4mg/m 3(1ppm) *New Zealand workplace Exposure Standards ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this product. Disposable gloves must not be latex Eyes: Safety glasses must be worn to avoid product contacting the eyes. Flammability:Product is not flammable. SAFE HANDLING INFORMATION STORAGE AND TRANSPORT: SPILL AND DISPOSAL: FIRE / EXPLOSION HAZARD: Store product in a cool place away from foodstuffs and oxidising agents. Dilute small spills with water. Contain and absorb larger spills in inert materials (sand or vermiculate). Dispose of in accordance with local regulations. Product is not flammable. May release toxic hydrogen sulphide fumes if heated to decomposition. In case of fire water, water fog, dry chemical, CO2 or foam can be used. OTHER INFORMATION

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ALKALINE PERMS & RELAXERS MATERIAL SAFETY DATA SHEET NO 7 v Hazardous according to criteria of Occupational Safety & Health. Date of Issue: 1.7.2002 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing UN No: Not applicable HAZCHEM CODE: Not applicable DANGEROUS GOODS Not applicable POISON SCHEDULE: 4 CLASS: SUBSIDIARY RISK: Not applicable PRODUCT USE: Permanent waving of hair PACKAGING GROUP No: Not applicable PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Liquid with characteristic odour BOILING POINT: Not Determined FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY: 1.03- 1.05g/ml FLAMMABILITY LIMITS: Not flammable pH: 8 - 9.5 SOLUBILITY IN WATER: Completely soluble INGREDIENTS Ammonia Ammonia thiogly olate Hydrogen Peroxide Sodium bromate Other ingredients determined not to HEALTH EFFECTS ACUTE EFFECTS: Swallow: Eye: Skin: Inhaled: CHRONIC EFFECTS: FIRST AID: Swallowed: Eyes: Skin: Inhaled: Advice to Doctor: CAS No. 7664 - 41 - 7 5421 - 46 - 5 7722 - 84 - 1 7789 - 38 - 0 be hazardous % w/w Content <2 < 12 <3 < 10.5 to 100

HEALTH HAZARD INFORMATION Irritant. Avoid contact with eyes. Harmful if swallowed. May cause irritation of the gastrointestinal tract. Avoid contact. Corrosive in concentrate form. Avoid contact. May cause skin irritation. Inhalation of vapours may cause irritation of nose and throat. Long term or repeated exposure may result in skin irritation in some individuals. If swallowed do not induce vomiting, give a glass of water. Contact a doctor or the National Poison Information centre. Phone 0800-764766 If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor. Do not rub. Rinse with water. Remove contaminated clothing. Remove person to fresh air. Treat symptomatically. If in eyes, recheck after one week.

21

PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA* CHEMICAL NAME: Ammonia 17mg/m 3(25ppm) Hydrogen peroxide 1.4mg/m 3(1ppm) *New Zealand workplace Exposure Standards ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this product. Disposable gloves must not be latex Eyes: Safety glasses must be worn to avoid product contacting the eyes. Flammability:Product is not flammable. SAFE HANDLING INFORMATION STORAGE AND TRANSPORT SPILL AND DISPOSAL: FIRE / EXPLOSION HAZARD: Store product in a cool place away from foodstuffs and oxidising materials. Dilute small spills with water. Contain and absorb larger spill in inert materials (sand or other absorbent material). Dispose of in accordance with local regulations. Product is not flammable. May release toxic hydrogen sulphide fumes if heated to decomposition. In case of fire, water, water fog, dry chemical, CO2 or foam can be used. OTHER INFORMATION Do not mix with hydrogen peroxide (3% 6%, 9% or 12%) solutions or bleach powders.

22

HAIR COLOUR (Flammable liquid) MATERIAL SAFETY DATA SHEET NO 8 v Hazardous according to criteria of Occupational Safety & Health. Date of Issue: 1.7.2002 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing UN No: 1170 HAZCHEM CODE:25 DANGEROUS GOODS CLASS: 3 POISION SCHEDULE: 4 SUBSIDIARY RISK: Not applicable PRODUCT USE: Hair Colour PACKAGING GROUP No: lll PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Coloured Liquid BOILING POINT: > 35oC FLASH POINT: 23-61 oC VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY: 0.85 - 1.0g/mL FLAMMABILITY LIMITS: Flammable pH: 5.0 - 11.7 SOLUBILIT Y IN WATER: Completely soluble INGREDIENTS Ethyl alcohol or Isopropyl alcohol Ammonia Ethanolamine Toluene -2, 5-Diamine Sulfate Resorcinol Phenylenediamines Other ingredients determined not to CAS No. 64 - 17 - 5 67 - 63 - 0 7664 - 41 - 7 141 - 43 - 5 615-50-9 108-46-3 --be hazardous % w/w Content < 60 <2 < 10 <2 <2 <2 to 100

23

HEALTH EFFECTS

HEALTH HAZARD INFORMATION This product contains ingredients which may cause skin irritation and sensitisation to certain individuals (ie. phenylendiamines). A preliminary skin test must be carried out before use. (For test details see product pack copy). Product must not be used for dyeing the eyelashes or eyebrows. Harmful if swallowed. May cause irritation of the gastrointestinal tract. Splash in the eyes may cause immediate stinging sensation and tears. Transient reddening of the eye may also occur. Avoid contact. Prolonged skin contact may cause skin irritation. At relatively high vapour concentrations ethyl or isopropyl alcohol are irritants to the nose and throat and may cause central nervous system depression. Long term exposure to ethyl and isopropyl alcohol may result in irritation of the lining of the nose and mouth, headache, lack of concentration and drowsiness. Repeated skin contact may lead to dermatitis. Some aromatic amine dyes may cause dermatitis and allergic reactions in some individuals. If swallowed do not induce vomiting, give a glass of water. Contact a doctor or the National Poison Information centre. Phone 0800-764766 If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor if pain persists. Wash affected area with water. If irritation develops seek medical advice. Remove person to fresh air. Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE

ACUTE EFFECTS: Swallow: Eye: Skin: Inhaled: CHRONIC EFFECTS:

FIRST AID: Swallowed: Eyes: Skin: Inhaled: Advice to Doctor:

EXPOSURE LIMITS: TWA* CHEMICAL NAME: Ethyl alcohol 1880mg/m 3(1000ppm) or Isopropyl alcohol 983mg/m 3(400ppm) Ammonia 17mg/ m 3(25ppm) Etholamine 7.5mmg/ m3(3ppm) *New Zealand workplace Exposure Standards ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this product. Disposable gloves must not be latex Eyes: Eye protection should be worn (safety glasses) to avoid product contacting the eyes. Flammability:Flammable. Keep away from heat, flame or ignition source.

24

SAFE HANDLING INFORMATION STORAGE AND TRANSPORT: Store product in a cool place out of direct sunlight. Store away from corrosive and oxidising products. Store in accordance with Dangerous Goods Regulations and transport in accordance with the NZDG Code for Dangerous Goods Class 3. Remove possible leaking containers. Remove all ignition sources and ventilate area. Dilute small spills with water. For larger spills, dilute with water and absorb in inert material (sand or vermiculate). Dispose of in accordance with local regulations. Flammable. If spilled or ruptured will increase the intensity of fire. In case of fire water, water fog, dry chemical, CO2 or foam can be used. OTHER INFORMATION

SPILL AND DISPOSAL:

FIRE / EXPLOSION HAZARD:

25

HAIR COLOUR (Permanent/Semi-permanent, Cream/Liquid) MATERIAL SAFETY DATA SHEET NO 9 v Hazardous according to criteria of Occupational Safety & Health. Date of Issue: 1.7.2002 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual company listing UN No: Not applicable HAZCHEM CODE: Not applicable DANGEROUS GOODS CLASS: Not applicable POISON SCHEDULE: 4 SUBSIDIARY RISK: Not applicable PRODUCT USE: Hair Colour PACKAGING GROUP No: Not applicable PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Creamy soft mass with ammonia odour BOILING POINT: Not Determined FLASH POINT: Not flammable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY: 0.98 - 1.0g/mL FLAMMABILITY LIMITS: Not Applicable pH: 7.0 - 11.0 SOLUBILITY IN WATER: Completely soluble INGREDIENTS Ammonia Toluene-2,5-Dianmine Sulfate Resorcinol Phenylendiamines Ethanolamine Other ingredients determined not to HEALTH EFFECTS CAS No. 7664 - 41 - 7 615 - 50 - 9 108 - 46 - 3 141 - 43 - 5 be hazardous % w/w Content <5 <5 <2 <2 < 10 to 100

ACUTE EFFECTS: Swallow: Eye: Skin: Inhaled: CHRONIC EFFECTS:

HEALTH HAZARD INFORMATION This product contains ingredients which may cause skin irritation and sensitisation to certain individuals (ie. phenylendiamines). A preliminary skin test must be carried out before use. (For test details see product pack copy). Product must not be used for dyeing the eyelashes or eyebrows. Harmful if swallowed. Product may cause irritation of the gastrointestinal tract. Corrosive to the eye. Avoid contact. Prolonged skin contact may cause skin irritation. Ammonia vapours may cause irritation of the nose and throat. Long term or repeated skin contact may lead to dermatitis. Some aromatic amine dyes may cause contact dermatitis and allergic reactions in some individuals.

26

FIRST AID: Swallowed: Eyes: Skin: Inhaled: Advice to Doctor:

If swallowed do not induce vomiting. Give a glass of water. Contact a doctor or the National Poison Information centre. Phone 0800-764766 If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor if pain persists. Wash affected area with water. If irritation develops seek medical advice. Remove person to fresh air. Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA* CHEMICAL NAME: Ammonia 17mg/m 3(25ppm) Resorcinol 45mg/m 3(10ppm) Phenylendiamines (refer to pack copy 0.1mg/ m 3 for specific ingredients) Ethanolamine 7.5mmg/ m3(3ppm) *New Zealand workplace Exposure Standards ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this product or the mixture between products and solutions containing hydrogen peroxide. Disposable gloves must not be latex Eyes: Eye protection should be worn (safety glasses) to avoid product contacting the eyes. Flammability: Product is not flammable. SAFE HANDLING INFORMATION STORAGE AND TRANSPORT: SPILL AND DISPOSAL: FIRE / EXPLOSION HAZARD: Store product in a cool place out of sun and away from food stuffs. Dilute small spills with water. Contain and absorb in inert material (ie. sand or vermiculate). Dispose of in accordance with local regulations. The material is not flammable. In case of fire water, water fog, dry chemical, CO2 or foam can be used.

OTHER INFORMATION

27

HAIR COLOURS (AEROSOL) MATERIAL SAFETY DATA SHEET NO 10 v Hazardous according to criteria of Occupational Safety & Health. Date of Issue: 1.7.2002 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual UN No: 1950 DANGEROUS GOODS CLASS: 2 SUBSIDIARY RISK: Not applicable PACKAGING GROUP No: Not applicable company listing HAZCHEM CODE: Not applicable POISON SCHEDULE: 4 PRODUCT USE: Hair Colour

PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Coloured foam BOILING POINT: Not Determined FLASH POINT: -87oC VAPOUR PRESSURE: 448 - 517KPa SPECIFIC GRAVITY: 0.90 - 1.0g/mL FLAMMABILITY LIMITS: 1.9 - 9.5% pH: 6.0 - 11.0 SOLUBILITY IN WATER: Completely Soluble INGREDIENTS Hydrocarbon propellant LPG (Butane - Propane) Ammonia Toluene 2,5-diamine sulphate Resorcinol Phenylendiamines Ethanolamine Ethyl alcohol Other ingredients determined not to HEALTH EFFECTS CAS No. { 106 - 97 - 8 { 74 - 98 - 6 7664 - 41 7 615 - 50 - 9 108 - 46 - 3 141 - 43 - 5 64 - 17 - 5 be hazardous % w/w Content < 10 <5 <5 <2 <2 < 10 < 11 to 100

ACUTE EFFECTS: Swallow: Eye: Skin: Inhaled: CHRONIC EFFECTS:

HEALTH HAZARD INFORMATION This product contains ingredients which may cause skin irritation and sensitisation to certain individuals (ie. phenylendiamines). A preliminary skin test must be carried out before use. (For test details see product pack copy). Product must not be used for dyeing the eyelashes or eyebrows. Harmful if swallowed. Product may cause irritation of the gastrointestinal tract. Irritant to the eye. Avoid contact. Prolonged skin contact may cause skin irritation. Inhalation of aerosol products may cause irritation to the nose and throat. Long term or repeated skin contact may lead to dermatitis. Some aromatic amine dyes may cause contact dermatitis and allergic reactions in some individuals.

28

FIRST AID: Swallowed: Eyes: Skin: Inhaled: Advice to Doctor:

If swallowed do not induce vomiting. Give a glass of water. Contact a doctor or the National Poison Information centre. Phone 0800-764766 If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor if pain persists. Wash affected area with water. If irritation develops seek medical advice. Remove person to fresh air. Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA* CHEMICAL NAME: Hydrocarbon Propellant LPG 1800mg/ m 3(1000ppm) (Propane-Butane) Ammonia 17mg/m 3(25ppm) Resorcinol 45mg/m 3(10ppm) Phenylendiamines 0.1mg/ m 3 Ethanolamine 7.5mmg/ m3(3ppm) Ethyl alcohol 1880mg/ m 3(1000ppm) *New Zealand workplace Exposure Standards ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this product or the mixtures. Disposable gloves must not be latex Eyes: Eye protection must be worn (safety glasses) to avoid product contacting the eyes. Flammability: Flammable, keep away from heat, flame or ignition source. SAFE HANDLING INFORMATION STORAGE AND TRANSPORT: Store product in a cool place out of direct sunlight. Store away from food stuffs and corrosive materials. Store in accordance with Dangerous Good Regulations and transport in accordance with the NZDG Code for Dangerous Goods Class 2. Remove possible leaking containers. Remove all ignition sources. Ventilate area. Dilute spills with water. Do not puncture or incinerate cans even when empty. Dispose of in accordance with local regulations. Flammable. Closed containers may rupture when exposed to heat greater than 50oC. May produce toxic vapours. Fog, fine water spray, CO2 foam or dry chemical can be used to extinguish fire. OTHER INFORMATION These products may be supplied in bi-compartmental containers in which the propellant is not mixed with the product (bag in the can type). 29

SPILL AND DISPOSAL:

FIRE / EXPLOSION HAZARD:

HAIRSPRAYS/LACQUERS (AEROSOLS) MATERIAL SAFETY DATA SHEET NO 11 v Non-hazardous according to criteria of Occupational Safety & Health. Date of Issue: 1.7.2002 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: Refer to individual UN No: 1950 DANGEROUS GOODS CLASS: 2 SUBSIDIARY RISK: Not applicable PACKAGING GROUP No: Not applicable company listing HAZCHEM CODE: 2Y POISON SCHEDULE: Not Applicable PRODUCT USE: Hair Styling preparation.

PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Clear liquid BOILING POINT: Not Determined FLASH POINT: - 87oC VAPOUR PRESSURE: 275 - 345KPa SPECIFIC GRAVITY: 0.86 - 0.90g/mL FLAMMABILITY LIMITS: 1.9 - 9.5% pH: 6.0 - 8.5 SOLUBILITY IN WATER: Completely Soluble INGREDIENTS Hydrocarbon propellant (LPG) - Propane - Butane Difluoro ethane Dimethyl ether Ethyl alcohol Other ingredients HEALTH EFFECTS ACUTE EFFECTS: Swallow: Eye: Skin: Inhaled: CHRONIC EFFECTS: CAS No. 74 - 98 - 6 106 - 97 - 8 75 - 37 - 6 115 - 10 - 6 64 - 17 - 5 % w/w Content } } 30 - 50 10 30 - 40 40 - 65 to 100

HEALTH HAZARD INFORMATION Warning intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. Low toxicity by the oral route. May cause irritation of the gastrointestinal tract. Depression of the central nervous system may result in headache and dizziness. Splashes in the eye may cause immediate stinging sensation and tears. Transient reddening of the eye may also occur. No appreciable irritation of the skin is expected. At relatively high vapour concentrations ethyl and isopropyl alcohol are irritants to the nose and throat and may cause central nervous system depression. Long term exposure to ethyl and isopropyl alcohol may result in irritation of the nose and mouth, headaches, lack of concentration and drowsiness. Prolonged or repeated skin contact may lead to dermatitis.

30

FIRST AID: Swallowed: Eyes: Skin: Inhaled: Advice to Doctor:

If swallowed do not induce vomiting. Give a glass of water. If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor if pain persists. Wash affected area with water. Remove person to fresh air. Treat symptomatically. If in eyes, recheck after one week. PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA* CHEMICAL NAME: Hydrocarbon Propellant LPG 1800mg/ m 3(1000ppm) Ethyl alcohol 1880mg/ m 3(1000ppm) *New Zealand workplace Exposure Standards ENGINEERING CONTROLS: Use in well ventilated areas and away from ignition sources. PERSONAL PROTECTION: Skin: Avoid prolonged skin contact with the product. Eyes: Protect eyes when using. Flammability: Highly flammable, keep away from heat, flame or ignition source. SAFE HANDLING INFORMATION STORAGE AND TRANSPORT: Store product in a cool place out of direct sunlight. Store away from corrosive products. Store in accordance with Dangerous Good Regulations and transport in accordance with the NZDG Code for Dangerous Goods Class 2. Remove all ignition sources and ventilate area. Remove possible leaking containers. Dilute spills with water. Do not puncture or incinerate cans even when empty. Dispose of in accordance with local regulations. Highly flammable. Vapours are heavier than air, distant ignition source possible. Closed containers may rupture when exposed to heat greater than 50oC. May react with oxidising agents. May produce toxic vapours on decomposition. Fog, fine water spray, carbon dioxide, foam or dry chemical can be used to extinguish fires. OTHER INFORMATION

SPILL AND DISPOSAL:

FIRE / EXPLOSION HAZARD:

31

AEROSOL MOUSSES (STYLING & CONDITIONING) MATERIAL SAFETY DATA SHEET NO 12 v Non-hazardous according to criteria of Occupational Safety & Health. Date of Issue: 1.7.2002 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: UN No: 1950 DANGEROUS GOODS CLASS: 9 SUBSIDIARY RISK: Not applicable PACKAGING GROUP No: Not applicable Refer to individual company listing HAZCHEM CODE: Not applicable POISON SCHEDULE: Not Applicable PRODUCT USE: Hair Styling/conditioning preparation.

PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: White foam BOILING POINT: Not Determined FLASH POINT: - 87oC VAPOUR PRESSURE: 448 - 517KPa SPECIFIC GRAVITY: 0.88 - 0.74g/mL FLAMMABILITY LIMITS: 1.9 - 9.5% pH: 4.0 -7.0 SOLUBILITY IN WATER: Completely Soluble INGREDIENTS Hydrocarbon propellant (LPG) - Propane - Butane Ethyl alcohol Other ingredients HEALTH EFFECTS ACUTE EFFECTS: Swallowed: Eye: Skin: Inhaled: CHRONIC EFFECTS: FIRST AID: Swallowed: Eyes: Skin: Inhaled: Advice to Doctor: CAS No. 74 - 98 - 6 106 - 97 - 8 64 - 17 - 5 % w/w Content } < 15 } < 20 to 100

HEALTH HAZARD INFORMATION Low toxicity by the oral route. May cause irritation of the gastrointestinal tract. Depression of the central nervous system may result in headache and dizziness. Contact may irritate eye. Prolonged and repeated skin contact should be avoided. Inhalation of aerosol products may cause irritation to the nose and throat. Prolonged or repeated exposure may lead to skin dryness. If swallowed do not induce vomiting. Give one glass of water. If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor if pain persists. Wash affected area with water. Remove person to fresh air. Treat symptomatically.

32

PRECAUTIONS FOR USE EXPOSURE LIMITS: TWA* CHEMICAL NAME: Hydrocarbon Propellant LPG 1800mg/ m 3(1000ppm) Ethyl alcohol 1880mg/ m 3(1000ppm) *New Zealand workplace Exposure Standards ENGINEERING CONTROLS: Use in well ventilated areas and away from ignition sources. PERSONAL PROTECTION: Skin: Avoid prolonged and repeated skin contact with the product. Eyes: Avoid contact with eyes. Flammability: Flammable. Keep away from heat, flame or ignition source. SAFE HANDLING INFORMATION STORAGE AND TRANSPORT: Store product in a cool place out of direct sunlight. Store away from corrosive materials. Store in accordance with Dangerous Good Regulations and transport in accordance with the NZDG Code for Dangerous Goods Class 2. Remove all ignition sources and ventilate area. Remove possible leaking containers. Do not puncture or incinerate cans even when empty. Dispose of in accordance with local regulations. Flammable. Closed containers may rupture when exposed to heat greater than 50oC. Fog, fine water spray, carbon dioxide, foam or dry chemical can be used. OTHER INFORMATION

SPILL AND DISPOSAL: FIRE / EXPLOSION HAZARD:

33

SHAMPOOS MATERIAL SAFETY DATA SHEET NO 13 v Non-hazardous according to criteria of Occupational Safety & Health. Date of Issue: 1.7.2002 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: UN No: DANGEROUS GOODS CLASS: SUBSIDIARY RISK: PACKAGING GROUP No: Refer to individual company listing Not Applicable HAZCHEM CODE: Not applicable POISON SCHEDULE: Not applicable Not applicable PRODUCT USE: Not applicable Not Applicable To cleanse hair and scalp.

PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Viscous liquid BOILING POINT: Approx. 100oC FLASH POINT: Not Applicable VAPOUR PRESSURE: Not determined SPECIFIC GRAVITY: 1.0 - 1.10 FLAMMABILITY LIMITS: Not combustible pH: 4.5 - 7.5 SOLUBILITY IN WATER: Completely Soluble INGREDIENTS Anionic & amphoteric surfactants such as: Sodium laureth sulphate Sodium lauryl sulphate Ammonium lauryl sulphate Cocamido propyl betain Other ingredients HEALTH EFFECTS ACUTE EFFECTS: Swallow: Eye: Skin: Inhaled: CHRONIC EFFECTS: CAS No. { 3088 - 31 - 1 { 13150 - 00 -0 151 - 21 - 3 2235 - 54 - 3 { 61789 - 40 - 0 { 831138 - 08 -3 { 80438 - 79 - 1 % w/w Content < 20 < 10 < 15 < 15 to 100

HEALTH HAZARD INFORMATION Low toxicity by the oral route. Splashes in the eye may cause stinging sensation and tears. Transient reddening of the eye may also occur. Prolonged and repeated skin contact should be avoided No appreciable irritation is expected by this route. May produce dermatitis on repeated or prolonged contact with skin.

34

FIRST AID: Swallowed: Eyes: Skin: Skin: Inhaled: Advice to Doctor:

If swallowed DO NOT induce vomiting. Give one or two glasses of water and seek medical attention. If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor if pain persists. Wash affected area with water. Remove contaminated clothing and wash affected area with water. Remove from further exposure. Treat symptomatically. PRECAUTIONS FOR USE

EXPOSURE LIMITS: CHEMICAL NAME:

TWA*

*New Zealand workplace Exposure Standards ENGINEERING CONTROLS: None required. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) are recommended if prolonged contact with the product is envisaged. Eyes: Protect eyes when using. Flammability: Product is not flammable. SAFE HANDLING INFORMATION STORAGE AND TRANSPORT: SPILL AND DISPOSAL: FIRE / EXPLOSION HAZARD: Store product in a cool place. Spills are slippery. Remove possible leaking containers. Mop up small spills. For larger spills absorb in inert material (sand or vermiculate). Dispose of in accordance with local regulations. Will not burn. Not considered a significant risk. OTHER INFORMATION

35

CONDITIONERS & TREATMENTS MATERIAL SAFETY DATA SHEET NO 14 v Non-hazardous according to criteria of Occupational Safety & Health. Date of Issue: 1.7.2002 PRODUCT IDENTIFICATION PRODUCT NAME/CODE: UN No: DANGEROUS GOODS CLASS: SUBSIDIARY RISK: PACKAGING GROUP No: Refer to individual company listing Not Applicable HAZCHEM CODE: Not applicable Not applicable POISON Not Applicable SCHEDULE: Not applicable PRODUCT USE: To condition and beautify hair after cleansing. Not applicable

PHYSICAL / CHEMICAL PROPERTIES APPEARANCE: Viscous liquid BOILING POINT: Approx. 100oC VAPOUR PRESSURE: Not determined FLAMMABILITY LIMITS: Not combustible SOLUBILITY IN WATER: Miscible INGREDIENTS Cationic surfactants such as: Certrimonium chloride Cetrimonium bromide Stearalkonium chloride Other ingredients HEALTH EFFECTS ACUTE EFFECTS: Swallow: Eye: Skin: Inhaled: CHRONIC EFFECTS: CAS No. 112 - 02 - 7 57 - 09 - 0 - 1 122 - 19 - 0 FLASH POINT: Not Applicable SPECIFIC GRAVITY: 0.95 - 1.0 pH: 2.5 - 5.5 % w/w Content < 2.5 < 2.5 < 3.0 to 100

HEALTH HAZARD INFORMATION Low toxicity by the oral route. Eye contact may cause some stinging and tears. Transient reddening of the eye may also occur. Prolonged and repeated skin contact should be avoided No appreciable irritation is expected by this route however, prolonged repeated skin contact should be avoided. No appreciable irritation is expected by this route.

36

FIRST AID: Swallowed: Eyes: Skin: Inhaled: Advice to Doctor:

If swallowed DO NOT induce vomiting. Give one or two glasses of water and seek medical attention. If in eyes, hold eyes open, flood with water for at least 15 minutes and see a Doctor if pain persists. Remove contaminated clothing and wash affected area with water. If affected, remove from further exposure. Treat symptomatically. PRECAUTIONS FOR USE

EXPOSURE LIMITS: CHEMICAL NAME:

TWA*

*New Zealand workplace Exposure Standards ENGINEERING CONTROLS: None required. PERSONAL PROTECTION: Skin: Not normally required. For prolonged use gloves are advised. Eyes: Protect eyes when using. Flammability: Product is not flammable. SAFE HANDLING INFORMATION STORAGE AND TRANSPORT: SPILL AND DISPOSAL: Store product in a cool place. Spills are slippery. Remove possible leaking containers. Mop up small spills. For larger spills absorb in inert material (sand or vermiculate). Dispose of in accordance with local regulations. Will not burn. Not considered a significant risk. OTHER INFORMATION

FIRE / EXPLOSION HAZARD:

37