Hall-Yarborough (1973) z-factor calculation

Hall, K.R. & Yarborough, L. (1973): A New Euation of State for Z-factor Calculations,
The Oil and Gas Journal, June 18, 82-92
Molecular weight oxygen, MO 15.9994 g/mole
Molecular weight sulfur, MS 32.07 g/mole
Molecular weight, carbon, MC 12.01 g/mole
Molecular weight, hydrogen, MH 1.01 g/mole
Molecular weight air, MA 28.97 g/mole
Components Molecular weight Mole fraction Tci Tci Pci Pci
g/mole yi oR K psia Mpa
Methan, CH4 16.042 0 343 190 667.8 4.61
Ethan, C2H6 30.07 0 549.8 305 708 4.88
Propan, C3H8 44.10 0 665.7 370 616 4.25
i-Butane, C4H10 58.12 0 734.7 408 529 3.65
n-Butane, C4H10 58.12 0 765 425 551 3.80
i-Pentane C5H12 72.15 0 829 460 491 3.39
n-Pentane C5H12 72.15 0 845 469 489 3.37
Hexane C6H14 86.18 0 913 507 437 3.01
Heptane C7H16 100.21 0 972 540 397 2.74
Hydogen, H2 2.02 0 60 33 187 1.29
Nitrogen, N2 28.01 0 227.4 126 492 3.39
Oxygen, O2 32.00 0 277.8 154 731 5.04
Carbon dioxid, CO2 44.01 0 547.6 304 1071 7.38
Hydrogensulfid, H2S 34.08 0 672.4 373 1306 9.01
Dihydrogenoksid, H2O 18.02 0 1165 647 3199 22.06
Mole fraction 0.0000
Total molecular weight gas 0.00 g/mole
Spesific gravity 0.00
Temperature 0.00
o
C 273.15 K
Pressure 0.000E+00 Pa
Method used (1, 2 or 3) 1
Compressebility factor, z #DIV/0!
Method 1 (Properties from composition, Key's rule)
Pseudo critical temperature
TPc (oil field units) 0.00 oR
TPc (SI units) 0.00 K
Pseudo critical pressure
PPc (oil field units) 0.00 psia
Methods for finding pseudo critical pressure and
pseudo critical temperature

=
i i
y P PPc

=
i i
y T TPc
PPc (SI units) 000.0E+0 Pa
Method 2 (Sutton's correlations)
Pseudo critical temperature
TPc (oil field units) 169.20 oR
TPc (SI units) 93.67 K
Pseudo critical pressure
PPc (oil field units) 756.80 psia
PPc (SI units) 5.2E+6 Pa
Method 3 (Standing's correlation)
Pseudo critical temperature If we have a "dry" gas, SG < 0,75
TPc (oil field units) 168.00 oR
TPc (SI units) 93.00 K
Pseudo critical pressure
PPc (oil field units) 667.00 psia
PPc (SI units) 4.6E+6 Pa
Pseudo reduced properties
TPR #DIV/0!
PPR #DIV/0!
Hall-Yarborough
t #DIV/0!
a #DIV/0!
Reduced-density parameter, y
0
0.01
Continue until f(y) < 1x10^(-5)
Iteration 1
f(y) #DIV/0!
Derivated of f(y), df(y) #DIV/0!
Newton Rapson: Reduced- density parameter, y
1
#DIV/0!
Compressebility factor, z #DIV/0!
Iteration 2
( )
( ) y f
y f
y y
i i
'
1
=
+
( )
( )
( ) ( )( )
t
y t t t t y t t t
y
y y y y
dy
y df
82 , 2 18 , 1 3 2 3 2
4
4 3 2
4 , 42 2 , 242 7 , 90 82 , 2 18 , 2 16 , 9 52 , 19 52 , 29
1
4 4 4 1
+
+ + + +

+ + +
=
( )
( )
( ) ( )
t
pr
y t t t y t t t
y
y y y y
ap y f
82 , 2 18 , 2 3 2 2 3 2
3
4 3 2
4 , 42 2 , 242 7 , 90 58 , 4 76 , 9 76 , 14
1
0
+
+ + +

+ +
+ = =
pr
T
t
1
=
pc
pr
p
p
P =
pc
pr
T
T
T =
2
g
3.6 - 131,0 - 756.8 = PPc
g
2
g g
74,0 - 349.5 + 169.2 = TPc
2
5 , 12 325 168
gHC gHC pcHC
T + =
2
5 , 37 0 , 15 667
gHC gHC pcHC
p + =
y
p
Z
pr
o
=
( ) ( )
2
1 2 , 1
06125 , 0
t
e t a

=
f(y) #DIV/0!
Derivated of f(y), df(y) #DIV/0!
Newton Rapson: Reduced-density parameter y
2
#DIV/0!
Compressebility factor, z #DIV/0!
Iteration 3
fy #DIV/0!
Derivated of f(y), df(y) #DIV/0!
Newton Rapson: Reduced-desity parameter y
3
#DIV/0!
Compressebility factor, z #DIV/0!
Iteration 4
f(y) #DIV/0!
Derivated of f(y), df(y) #DIV/0!
Newton Rapson: Reduced-density parameter y
4
#DIV/0!
Compressebility factor, z #DIV/0!
Iteration 5
f(y) #DIV/0!
Derivated of f(y), df(y) #DIV/0!
Newton Rapson: Reduced-density parameter y
4
#DIV/0!
Compressebility factor, z #DIV/0!
( )
( ) y f
y f
y y
i i
'
1
=
+
Convertion
oC -> K 273.15
atm -> bar 1.01325
cp -> Pas 1.00E-03
bar -> Pa 1.00E+05
m m -> m 1.00E-03
oR -> K 0.56
psig -> bar 0.07
oF -> oR 460
Instructions

1. Insert mole fractions.
2. Insert temperature [C] and pressure [Pa].
3. Choose which pseudo method you will use.
4. Read your z-factor beneath.

(Insert values in cells where the font color is red)
Methods for finding pseudo critical pressure and
pseudo critical temperature

1. Properties from composition, Key's rule (Preferred choice).
Newton-Rapson iteration.
2. Sutton's correlations
3. Standing's correlations
If we have a "dry" gas, SG < 0,75 If we have a "wet" gas, SG 0,75
( )
( )
( ) ( )( )
t
y t t t t y t t t
y
y y y y
dy
y df
82 , 2 18 , 1 3 2 3 2
4
4 3 2
4 , 42 2 , 242 7 , 90 82 , 2 18 , 2 16 , 9 52 , 19 52 , 29
1
4 4 4 1
+
+ + + +

+ + +
=
( )
( )
( ) ( )
t
pr
y t t t y t t t
y
y y y y
ap y f
82 , 2 18 , 2 3 2 2 3 2
3
4 3 2
4 , 42 2 , 242 7 , 90 58 , 4 76 , 9 76 , 14
1
0
+
+ + +

+ +
+ = =
2
g
3.6 - 131,0 - 756.8 = PPc
g
2
g g
74,0 - 349.5 + 169.2 = TPc
2
5 , 12 325 168
gHC gHC pcHC
T + =
2
5 , 37 0 , 15 667
gHC gHC pcHC
p + =
2
5 , 71 330 187
gHC gHC pcHC
T + =
2
1 , 11 7 , 51 706
gHC gHC pcHC
p + =
( ) ( )
2
1 2 , 1
06125 , 0
t
e t a

=
( )
( )
( ) ( )( )
t
y t t t t y t t t
y
y y y y
dy
y df
82 , 2 18 , 1 3 2 3 2
4
4 3 2
4 , 42 2 , 242 7 , 90 82 , 2 18 , 2 16 , 9 52 , 19 52 , 29
1
4 4 4 1
+
+ + + +

+ + +
=
( )
( )
( ) ( )
t
pr
y t t t y t t t
y
y y y y
ap y f
82 , 2 18 , 2 3 2 2 3 2
3
4 3 2
4 , 42 2 , 242 7 , 90 58 , 4 76 , 9 76 , 14
1
0
+
+ + +

+ +
+ = =