MANAV BHARTI UNIVERSITY, EXAMINATION 2010-11

Chemistry M. Sc. Ist year Paper- I (Inorganic chemistry)

Time: 3.00 hours M.M. - 100

Section- A (Short answer type question) Note. Attempt all question. Each question carries 2 marks.

(10 X 2 = 20)

1. (a) Give an account of bent rule. (b) Write short note on bent effect. (c) What is redox reaction? (d) Give the limitations of crystal field theory. (e) What is metalloboranes? Write their structure. (f) What is effective atomic rule for metal carbonyl? (g) Give bonding and structure of metaborane. (h) What are heteropoly acids? Discuss their properties. (i) What are electron transfer reactions? Give mechanism with example. (j) Give spectrophotometry method for determining stability constant of complexes. Section- B (Descriptive answer type question) Note. Attempt any 5 question. Each question carries 16 marks.

(5 X 16 = 80)

2. What are Orgel diagrams? Discuss their utility and draw their energy level orgel diagram for d1 and d6 configurations in octahedral environment. 3. Write short note on the following: (a) Tertiary phosphene as legend. (b) Metal only clusters. (c) Cotton effect 4. Explain the following with suitable example: (a) Mechanism of Acid hydrolysis reaction. (b) Mechanism of substitution reactions in square planer complex. 5. Discuss Leporte selection rule and spin selection rule of electron absorption spectroscopy. 6. Discuss the hydrolysis reactions in complex compounds. Explain their mechanism and kinetics of acid hydrolysis of six Co(III) Ammine complexes. 7. (a) Discuss the application of molecular orbital theory to tetrahedral complexes showing distribution of electrons to molecular orbitals of complex in [CoCl4]-2. (b) Discuss different rule of VSEPR theory and their limitation. 8. Write notes on following. (a) Structure of heteropolycyclic acid. (b) Vibrational spectra of metal carbonyls for bonding and structural elucidation. 9. Write notes on following. (a) Chemistry of metal nitrosyls. (b) Spin crossover (c) Wade rule.

MANAV BHARTI UNIVERSITY, EXAMINATION 2010-11

Chemistry M. Sc. Ist year Paper- II (Organic chemistry)
Time: 3.00 hours M.M. - 100

Section- A (Short answer type question) Note. Attempt all question. Each question carries 2 marks.

(10 X 2 = 20)

1. (a) What is hyper conjugation? Explain the stability of carbonium ion. (b) Discuss the optical activity of a compound which has no chiral carbon atom. (c) What are hard and soft acids and bases? Give some example. (d) The SN2 substitution of an axial substituent is faster than of an equatorial substituent, explain. (e) Describe the mechanism of halogenation of carboxylic acids and acyl halides. (f) Write a short note on Reimer-Tiemann reaction. (g) Write a short note on Sommelet-Hauser rearrangement. (h) What is nucleophiles and free radical? (i) Differentiate the E2 and E1 reactions. (j) Write a Fischer projection, staggered sawhorse and Newman formulae of theo-2, 3dichloro-3-phenylpropanoic acid (PhCHCICHCICOOH) Section- B (Descriptive answer type question) Note. Attempt any 5 question. Each question carries 16 marks.

(5 X 16 = 80)

2. Discuss on the concept of aromatic character. Also explain the theoretical criteria for aromaticity. 3. Discuss SN1 mechanism and its evidence. 4. What is meant by Nucleophilic aromatic substitution? Explain with example. 5. Describe the free radical substitution mechanism in halogenation reaction. 6. Describe the following reactions with example (a) Perkin rection. (b) Reformatsky reaction. 7. Explain Woodward-Haffmann rules for electro-cyclic reaction. 8. What do you mean by Nucleophilic aromatic substitution? Give mechanism. 9. A hydrocarbon C9H10 (A) rapidly decolorizes cold aqueous permanganate and readily absorbs one molecule of bromine. Vigrorous hydrogenation of (A) gives a compound (B) of the formula C9H12 . Strong oxidation of (A) yields phthalic acid. Propose a structure for (A) and give the basis for your answer.

MANAV BHARTI UNIVERSITY, EXAMINATION 2010-11

Chemistry M. Sc. Ist year Paper- III (Physical chemistry)
Time: 3.00 hours M.M. - 100

Section- A (Short answer type question) Note. Attempt all question. Each question carries 2 marks.

(10 X 2 = 20)

1. (a) Explain the significance of for an electron when it is treated as wave. (b) Explain Perturbation theory by applying to helium atom. (c) Discus Hackle theory of conjugated systems. (d) Explain the law of photochemical hydrogen chlorine reaction. (e) Explain Isotactic and Atactic polymers. (f) What is over-voltage theory. (g) Discuss Zeeman splitting. (h) Write short note on any one theory of adsorption. (i) What is Collision theory of reaction rate. (j) Give some name of surface active agents. Section- B (Descriptive answer type question) Note. Attempt any 5 question. Each question carries 16 marks.

(5 X 16 = 80)

2. (a) Derive the Schrodinger wave equation. (b) Write applications of variation method and preparation theory to the helium atom. 3. What is thermodynamic probability? Explain its importance to statistically thermodynamics. 4. Explain Einstein equation for heat of solids at low temperature. Correlate it with Nernst equation. 5. Write Short notes on: (a) Gibbs Duhem equation. (b) Determination of activity coefficient. (c) Eigen function and Eigen Value. (d) Zeta potential. 6. Draw the phase diagram in case of ferric chloride water system in which all the compounds have congruent melting points. 7. Derive B.E.T. equation with one method for determining of surface area of adsorption. 8. (a) Give expression for E.M.F. of concentration cell. (b) Describe Laplace-Young equation. 9. How will you determine the molecular weight of macromolecules by light-scattering method?

MANAV BHARTI UNIVERSITY, EXAMINATION 2010-11

Chemistry M. Sc. Ist year Paper- IV (Group theory, Spectroscopy and Diffraction methods)
Time: 3.00 hours M.M. - 100

Section- A (Short answer type question) Note. Attempt all question. Each question carries 2 marks. 1. (a) What do you mean by group and sub group? (b) What are selection rule? (c) Calculate vibrational degree of freedoms for CO2 molecule. (d) Explain Raman shift. (e) Discuss the axis of symmetry with example. (f) What are basic differences between IR and Microwave spectra? (g) What is Wierl Equation? (h) Explain quantization of energy. (i) Describe rotating crystal method. (j) What is photoelectric effect? Section- B (Descriptive answer type question) Note. Attempt any 5 question. Each question carries 16 marks.

(10 X 2 = 20)

(5 X 16 = 80)

2. Discuss character table and their uses in spectroscopy. Derive character table for C2v and C3v point group symmetry aspect of molecular vibrational of H2O molecule. 3. Explain the origin of microwave spectra for rigid and non rigid rotator. How it is used to explain molecular parameter and structures? 4. Explain the following terms: (a) Stark effect. (b) Hot bands and overtones. (c) Morse potential. (d) Transition moment. 5. Discuss briefly the theory of NMR spectroscopy. What are various factors which affects the magnitude of the chemical shift and coupling constant? 6. Write short note on the following: (a) Basic principal of photocoustic spectroscopy. (b) Frank-Cordon principle. (c) Low energy electron diffraction (LEED). (d) Advantage of FT NMR. 7. What is moss Bauer spectroscopy? Give their applications. 8. Give the differences between the following: (a) X-ray diffraction and neutron diffraction. (b) Raman spectra and infrared spectra Hot bands and overtones.

9. What are advantages and disadvantages of prism and gratings for emission? spectroscopy?

MANAV BHARTI UNIVERSITY, EXAMINATION 2010-11

Chemistry M. Sc. Ist year Paper- V {CH-405 (a), Mathematic for chemists} (For students without mathematics in B.Sc.)
Time: 3.00 hours M.M. - 100

Section- A (Short answer type question) Note. Attempt all question. Each question carries 2 marks. 1. (a) What is vector space? Give the precise definition. (b) Explain the term Diagonal matrix. (c) What do you mean by most probable errors? (d) Define exact differential. (e) Evaluate: (f) Find the value of k from the following system of equations; x + 2y = 3 2x - y = 2 X+y=k (g) Integrate: exx2dx (h) Find the value of determinant:

(10 X 2 = 20)

(i) Solve:

(1 + x)2 dy = (1+y2) dx

(j) Evaluate: cot2x dx Section- B (Descriptive answer type question) Note. Attempt any 5 question. Each question carries 16 marks.

(5 X 16 = 80)

2. Find the sum of the vectors 4i + 2j + 3k, I 7j 2k, 5i + 4j 2k and 2i + j + k. Also calculate the module and direction cosine of each. 3. (a) A pair of dice is thrown. What is the probability of getting a each?

(b) Show the vector addition is commutative ie; a+b = b+a, where a and b are any two vectors? 4. Write short notes on the following: (a) Difference between symmetric and skew symmetric (b) Reaction formula (c) Exact differentia (d) Permutation 5. (a) Define state function. Are thermodynamic functions state functions? (b) If x and y is function of t, prove the relation between Cartesian and polar coordinates: 6. (a) Discuss the continuity of function y = [x-1] at x = 1. (b) From a pack of 52 cards two are drawn at random. Find the probability of being a king and a queen. 7. Solve: (1+ex)y dy = (Y+1) exdx. 8. From a class of 32 students, 4 are to be selected tom take part in competition. In how many ways this can be done? 9. (a) Find the differential coefficient w.r.t.x. of x3ex. (b) Evaluate e12x.

MANAV BHARTI UNIVERSITY, EXAMINATION 2010-11

Chemistry M. Sc. Ist year Paper- V {CH-405 (b), Biology for chemists} (For students without Biology in B.Sc.)
Time: 3.00 hours M.M. - 100

Section- A (Short answer type question) Note. Attempt all question. Each question carries 2 marks. 1. (a) Differentiate between prokaryotic and eukaryotic cells. (b) What is ATP? Is ATP the biological energy currency? (c) What do you mean by carbohydrate metabolism? (d) Draw the structural formula of polysaccharides? (e) How lipids are classified? (f) Discuss the importance of lipoprotein. (g) What is the chemical basis of heredity? (h) Explain -oxidation of fatty acids in lipid metabolism. (i) Mention the specific role of RNAs found in the cells. (j) Define genetic code. Section- B (Descriptive answer type question) Note. Attempt any 5 question. Each question carries 16 marks.

(10 X 2 = 20)

(5 X 16 = 80)

2. Describe the structure organization and biological importance of proteins. Write the structure of secondary protein. 3. Write short notes on the following: (a) Gluconeogenesis. (b) Lipids. (c) Fluid Mosaic model of membrane. 4. Discuss in brief the chemistry of oxytocin. Write its useful and harmful effect. 5. Give methods of amino acids sequence determination in polypeptides. Discuss any one of these methods in detail. 6. What is krebs cycle? Discuss its significance by giving its various steps.

7. Explain the following terms: (a) Translation (b) Replication (c) Transcription (d) Atherosclerosis 8. Write short notes on the following: (a) Mitrochondria (b) Endoplasmic reticulum (c) Metabolism (d) Glycogenesis 9. Explain mutation, Biological membrane and deoxy sugars.

MANAV BHARTI UNIVERSITY, EXAMINATION 2010-11

Chemistry M. Sc. Ist year Paper- VI {CH-406, Computers for chemists}
Time: 3.00 hours M.M. - 100

Section- A (Short answer type question) Note. Attempt all question. Each question carries 2 marks.

(10 X 2 = 20)

1. (a) What is computer? Give its classification. (b) Write full forms for the following: (i) RAM (ii) ROM (iii) PROM (iv) EPROM (c) What do you mean by computer memory? (d) Write the set of allowed characters in FORTRAN language. (e) In what ways the database may be useful in the field of chemistry. Explain with a suitable example. (f) Taking example of Ph-titration, write a precise computer program. (g) Define and explain BYTE. (h) Differentiate between input and output statements. (i) What are secondary storages? (j) Give the significance of flowchart. Section- B (Descriptive answer type question) Note. Attempt any 5 question. Each question carries 16 marks.

(5 X 16 = 80)

2. Write a pregame for calculating mean and finding the largest number out of any three given numbers. 3. The order of increasing energy of the orbitals as your known is 1s 2s 2p 3s 3p 4s 3d Suggest a small computer code to write electron designation of elements. 4. Define and write a computer program to calculate radioactive decay of any compound and calculate half life and average life.

5. Develop a computer program to determine constant of a and b for different gases in Vander walls equation. 6. Describe applications of EASYPLOT and LOTUS software in chemistry. 7. What data the program would require to develop a small computer code for calculation of bond lengths and bond energy? 8. (a) Name of various high level languages. Describe any two of them. (b) Why the UNIX operating system is so popular? Discuss. How it is useful in chemistry? 9. Develop a small computer codes on (C and BASIC) language involving simple formulae in chemical kinetics.