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2. Which of the following statements are incorrect about canonical structure? All canonical structures of
a molecule
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(a) must have same number of unpaired electron
(b) must have different number of unpaired electrons
(c) need not be always equivalent but they should not differ much in stability
(d) must have electrons in different orbital
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3. Which of the following statements are true about resonance ?
(a) Resonance involves delocolisation of & elements
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(b) Resonance involves delocolisation of electrons only
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(c) Resonance has no effect on potential energy of the molecule.
(d) Resonance hybrid explains all feature of molecule
4. em
A canonical structure will be more stable if
(a) If has more number of bonds than if it has less number of bonds.
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(b) the octet of all atoms are complete than if octet of all atoms are not complete.
(c) it has charge separation than it has no charge separation
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(d) - ve charge is on more electronegative atom than if +ve charge in on less electronegative atom
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(I) and
CH3 –– C == N(CH3)2
H3C –– C –– N(CH3)2
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OH OH
(II)
HO OH HO OH
and
(III) O
OH
N and
N
H
O OH
(IV) (C6H5)2 CH –– N – and (C6H5)2 C = N –
O O
(a) I and IV (b) II and III (c) I and II (d) All
SCHOOL OF CHEMISTRY 1-D-10 Talwandi Commerce College Main Road Kota Ph -0744-2407906 1
SINHA IIT CHEMISTRY TEST- G.O.C.
– + + –
CH2 == CH –– CH == O CH2 == CH –– CH == O
(c) (d)
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N
H
8. In which of the following lone pair indicated is not involved is resonance
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(b) CH2 = CH – CH = O
(a) CH2 = CH – N H – CH3
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CH2 = CH – O – CH = CH2
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(c) (d)
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O
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9. Identify electron withdrawing groups in resonance among the following
(a) –CO2H (b) —C —NH —CH3 (c) —C —Cl (d) CN
O O
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10. Identify electron donating groups in resonance among the following
(a) —C —NH2 (b) – NO2 (c) —O — C —CH3 (d) —C —OCH3
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O O O
11. Which of the following groups cannot participate in resonance with other suitable groups?
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O
12. Which of the following groups can participate in resonance with other suitable groups?
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CH2 = O — –CH2 – C H 2 (c) –CH2 – C H 2
+ +
CH2
(a) (b) (d)
13. Which of the following groups can either donate or withdraw a pair of electrons in resonance
depending upon situation?
(a) – NO2 (b) –NO (c) –CH = CH2 (d) –CHO
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SINHA IIT CHEMISTRY TEST- G.O.C.
18. C1 – C2 bond is shortest in
2
1 C ≡ CH 1 CH = CH2 1 CH2–CH3 1 C ≡ CH
(a) 2 (b) 2 (c) 2 (d)
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CH2
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20. Which is the correct order +I effect of the following groups/atoms
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(a) tbutyl > isopropyl > ethyl > methyl (b) D > H
(c) –O– > – CO 2
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(d) All
21. Which is the correct order of – I effect of the following groups/atoms ?
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(a) F > Cl > Br > I (b) N H 3 > NO2 > CN > –CO2H
(c) em
–CO2 R > – SH > – OH > – C CR > – CH = CR2 (d) All
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22. Which of the following statement is correct :
(a) Inductive effect is distance independent (b) Inductive effective is temporary effect
(c) Inductive effect occurs in saturated system (d) If effect stability of the molecule
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(c) at low temp towards – OH group & at high temp towards –CO2H group
(d) neither –OH nor towards –CO2H group.
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24. Heat of hydrogenation of cyclohexene to cyclohexane is –28.6 Kcals/mole. The observed heat of
hydrogenation of benzene to cydohexane is – 49.8 Kcals/mole. The resonance energy of benzene is
(a) 48 Kcals/mole (b) 36 Kcals/mole (c) 24 Kcals/mole (d) 12 Kcals/mole
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SINHA IIT CHEMISTRY TEST- G.O.C.
28. Acyl cation has two resonating structures (I) and (II):
R –– C O R –– C O
(I) (II) Which statements is correct for (I) and (II) :
(a) (I) is more stable than (II)
(b) (II) is more stable than (I)
(c) Stability of (I) and (II) will be the same
(d) For some time (I) will be more stable and for remaining time (II) will be more stable.
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29. In pyridine; Number of conjugated electrons are:
.c
N
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(a) 6 (b) 8 (c) zero (d) 5
CH3 CH3
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H H H H
30.
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H3 C CH3 H3 C H
H CH3
(a)
(c)
I
Conformational isomers
Constitutional isomers
are II
em (b) Stereoisomers
(d) Identical
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CH2
31. H H
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H H
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Me Me
Me Me Me H MeMe MeH
(a) (b) (c) (d)
H H H Me
Me Me H H Me
H Me Me
Me Me
34 Which of the following statements regarding the projections shown below is true.
H Cl
H3C Cl
H
Cl H CH3
CH3 Cl
H CH3
‘a’ ‘b’
(a) ‘a’ and ‘b’ both represent the same configuration (b) Both ‘a’ and ‘b’ are optically active
(c) ‘b’ alone is optically active (d) ‘a’ alone is optically active
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SINHA IIT CHEMISTRY TEST- G.O.C.
H OH HO H
H OH H OH
O and HO H O are :
35. HO H
H OH H OH
H H
CH2OH CH2OH
(a) Diastereomers (b) Enantiomers (c) Tautomers (d) Conformers
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CH3 CH3 CH3 COOH
H3C Cl Br H H OH H OH
(a) (b) (c) (d)
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H H Cl H3C H H OH
Cl
H CH3 CH3 COOH
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tr
37.. Which of the following compounds will show geometrical isomerism :
(a) 2-butene (b) propene
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(c) 1-phenylpropene (d) 2-methyl-2-butene
38.
CH3
41. The number of isomer for the compound with molecular formula C2BrCl I F
(a) 3 (b) 4 (c) 5 (d) 6
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SINHA IIT CHEMISTRY TEST- G.O.C.
(c) An equimolar mixture of enantiomers is called racemic mixture.
(d) Mirror image of an optical active isomer will have opposite configurations on all respective
asymmetric centre.
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CH2OH CH2OH CH2OH CH2OH
47. An enantiomerically pure acid is treated with racemic mixture of an alchol having one chiral carbon.
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The ester formed will be :
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(a) Optically active mixture (b) Pure enantiomer
(c) Meso compound (d) Reacemic mixture
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Me H Me
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48. Hydrogenation of the adjoining compound
in the presence of poisoned palladium
catalyst gives :
(a) an optically active compound
(b) an optically inactive compound
em H
H
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(c) a racemic mixture Me
(d) a diastereomeric mixture.
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49 The optically active tartaric acid is named as D–(+)– tartaric acid because:
(a) optical rotation and is derived from D–glucose
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50.. The no.of possible enantiomeric pair that can be produced during monochlorination of 2–methyl-
butane is
(a) 2 (b) 3 (c) 4 (d) 1
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