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Chemistry 112 is the second course in a two-course sequence in General Chemistry. The object of this course is to introduce you to some of the basic principles of chemistry with an emphasis on the relationships between the microscopic structure and macroscopic properties of matter. We will also illustrate the use of these principles in a wide variety of examples from the life sciences, from engineering and technology, and from everyday life. While it is a continuation of Chemistry 110, using the same text and building on the subject matter of Chemistry 110, it differs from Chemistry 110 in two important respects: 1. There are no required recitation classes. All of the class meetings will be of lecture size and there are only 3 meetings per week. 2. You will find much less carry-over of material from your high school chemistry course in Chem 112 than you did in Chem 110. The format of Chem 112 places a larger responsibility on you to master the subject material of the course. INSTRUCTORS: Lecturer
Dr. David Boehr Dr. Ayusman Sen Dr. Ayusman Sen Dr. Alan Benesi
Time
8:00am 9:05am 10:10am 3:35pm
Office
240 Chemistry 440 Chemistry 440 Chemistry 8 Chemistry
E-mail
ddb12@psu.edu axs20@psu.edu axs20@psu.edu alan@chem.psu.edu
Office hours
By appt. By appt. By appt. By appt.
Meetings with your instructor may be arranged at the end of lecture or by e-mail. Simple questions or comments can also be sent via e-mail. For administrative questions and questions concerning exam scores contact the administrative assistant in 210 Whitmore. WEB PAGE: http://courses.chem.psu.edu/chem112/Spring The course syllabus, past exams, supplementary lecture notes, exam locations, handouts, TA information, and other interesting chemistry sites are available at this location. TEACHING ASSISTANTS: Name E-mail Joshua Wrubel Kaitlin Haas Matt Langston Angela Jovanovich jmw5758@psu.edu kwh5231@psu.edu mcl17@psu.edu amj5318@psu.edu
Experienced instructors will provide free help to Chemistry 112 students in Room 211 Whitmore Laboratory. Tutors will be available during the following hours throughout the semester except during spring break and finals week. SUNDAY - THURSDAY, 6:30-10:30 P.M. LOCATION- 211 Whitmore. However, we suggest that you see the regular course TAs as much as possible.
TEXTBOOK AND OTHER MATERIALS: 1. Required Textbook: T.L. Brown, H.E. LeMay, B.E. Bursten, and C. J. Murphy, Chemistry, The Central Science, 11th Edition, Prentice-Hall, 2009. 2. Chem 112 Student Packet (required). Available at the Penn State Bookstore on campus. This packet has the syllabus, General Course Information, Supplemental Homework Problems and Practice exams. 3. The Chem 112 web site contains a syllabus, links to lecture notes, supplementary reading assignments, and multiple choice homework problems. You will be responsible for printing out these materials as needed. You are strongly advise to bring copies of notes to lecture, so you can listen, think, and ask questions rather than spend all your time copying down what is written on the overheads. In addition to these required materials, sample exams from previous years are also available on the course Web page. Please note that because of changes in the course, old exams may not contain precisely the same collection of materials as this years exams. 4. A suitable scientific calculator (one that handles numbers in scientific notation and provides log/antilog functions) is essential. Calculators with text-storage capabilities (such as the TI-81 used in Math 140) will not be permitted for use on exams and quizzes. 5. Optional Materials: Hill, Students Guide to Brown, LeMay & Bursten, and Wilson, Bursten & LeMay, Solutions to Black Exercises are optional; they are available in the bookstores if you wish to use them. LECTURES: Chem 112 meets for three lectures each week. You should attend every lecture even if you think you already know the material. You are responsible for all course material and administrative announcements covered in lecture, including problem assignments, syllabus changes, and exam locations. Always read the material covered in a lecture before the lecture. Reading both the textbook and trying problems assigned from the text prior to the lecture is essential. HOMEWORK: Homework assignments are given in the syllabus. The end of the Chapter homework problems should be done before lecture. The supplemental multiple choice homework problems can be done after lecture. These homework problems will prepare you for the graded on-line quizzes. Doing all assigned problems is essential to success in this course. If you have questions about the homework you can raise them during class or seek help in the Resource Room 211 Whitmore. WEB BASED SKILL CHECK TESTS and QUIZZES (Detailed Instructions after Schedule): 1. Skill Check Tests. There are 8 Skill Check Tests (SCTs) available on line. Detailed instructions for taking are also posted on the course Web page. You will be allowed to take these tests as many times as you like; however, you must achieve 100% on these tests in order to receive credit. Deadlines for each of the Skill Check Tests are given on the Web Based instruction page. NOTE: there is an early deadline for these! You can earn extra credit by getting 100% by the early deadline. If you do not complete the Skill Check Test by the FINAL deadline of APRIL 25, you will get a zero. There are no make-up opportunities for these. 2. Unit Quizzes. There will be 13 sets of quizzes that you will be expected to do on-line. These on-line quizzes will be graded. Each quiz will have about 5-7 questions. After doing the assigned homework in the syllabus, you should be able to do these problems. You will have a limited number of attempts for each quiz so it is important that you do the assigned homework BEFORE attempting the quizzes. (Note: each quiz will be unique.) Your grade for each quiz will be the highest score of your total attempts. There will be a deadline for each problem set as well. Once the deadline has passed, you will not be able to access the quizzes and there will be no make-up opportunities if you miss the quiz altogether or do not use all of your available submissions.
EXAMINATIONS: There will be three evening examinations during the semester and a comprehensive final examination during the final exam period. The dates and times for the mid-semester exams are fixed; you must work out any conflicts that arise.
Three evening midterm examinations will be held: Exam 1: Wednesday 2/2 at 6:30 pm Exam 2: Wednesday 3/2 at 6:30 pm Exam 3: Wednesday 4/6 at 6:30 pm
We will make provisions for conflicts between these evening exams and other scheduled University activities; you must register for such conflicts in class when the request is made. The final exam will be given at the time and place set by the University in its final exam schedule. Do not make plans to leave the University before you know the final exam date for Chem 112. Locations for all exams will be announced in class, and posted on the web; please do not phone or e-mail for exam locations! You should bring to each exam your calculator, some #2 pencils, an eraser, and your student I.D. card. A periodic table and data sheet will be provided with each exam. Be sure you know your correct section number and student I.D. number and that you enter these correctly on your exam answer sheet. MAKE-UP EXAM: A student having a legitimate excuse for missing any of the three scheduled midterm exams will be provided with a single make-up opportunity near the end of the semester. This make-up exam will cover the material for all three midterm exams. It is your responsibility to obtain permission from your lecturer to take this exam and to respond to the in-class request to sign up for this exam; this will be made shortly after the third exam. GRADING: Your course grade will be completely determined by your on-line quiz scores, three midsemester exam grades and your final exam grade. These will be weighted as follows: Basic Skills Unit quizzes Three evening mid-semester examinations Final examination (comprehensive) 5% 15% 17% each 29% 100% 10 points 30 points 34 points each 58 points 200 points
The exact course point requirements for each letter grade will be decided at the end of the course. A typical distribution for this course is as follows: A/ AB+/ B/ BC+/ C D 89% 78% 67% 56% 178 course points 156 course points 134 course points 112 course points
There is no assurance that this distribution will be the same this session; however, you may assume that it will not be greatly different. There is no predetermined grade distribution for this course; if, at the end of the course everyone has a final point grade in the A range, then everyone will earn an A! CHEMISTRY RESOURCE ROOM: The Department operates a Resource Room, 211 Whitmore Lab, which provides free help to Chemistry 112 students. It will open early in the semester and its hours of operation will be announced in class. The Chem 112 TAs will be available in the Resource Room on a regular basis. You are strongly encouraged to make use of this service as soon as you discover any need for help. Delay may put you too far behind to catch up.
GENERAL CHEMISTRY LABORATORY: Chem 113 is a 1-credit laboratory course that complements Chem 112. If you need the laboratory component (not all majors require it), we recommend that you take it concurrently with Chem 112. The first day of Chem 113 lab will begin with an introductory lecture. Signs will be posted on the first floor of Whitmore giving the location of the lecture. Please bring the following items with you on the first day: (1) Lab Manual, "Penn State Version of Chemtrek,"; (2) Chem 113 Packet (analogous to the Chem 112 Packet); (3) Lab Kit (this zip lock bag contains a variety of lab related items from pH paper to a blank lab notebook, it is sold only in the Penn State Bookstore); (4) Eye Protection (regular eyeglasses are not sufficient). If you took Chem 111 recently, then you only need to purchase the Chem 113 packet, and a new notebook. Get additional information by calling the Undergraduate Chemistry Office at 865-9391. ACADEMIC INTEGRITY: All Penn State policies regarding ethics and honorable behavior apply to this course. (http://www.psu.edu/ufs/policies) Academic dishonesty, including any form of cheating, is regarded as a very serious offense and will result in a failing grade in the course. In an examination or quiz setting, unless the instructor gives explicit prior instructions to the contrary, violations of academic integrity shall consist of any attempt to receive assistance from written or printed aids, from any person or papers or electronic devices, or of any attempt to give assistance, whether the student doing so has completed his or her own work or not. Other violations include, but are not limited to, any attempt to gain an unfair advantage in regard to an examination, such as tampering with a graded exam or claiming another's work to be one's own. Failure to comply will lead to sanctions against the student in accordance with the Policy on Academic Dishonesty in the Eberly College of Science. (http://www.science.psu.edu/academic/integrity/)
Code of Mutual Respect and Cooperation for Faculty, Staff and Students in The Eberly College of Science: As members of the Eberly College of science community, we should be respectful of
others at all times whether we are students, staff, or faculty. We can create an environment that fosters mutual and dignity for everyone if we as individuals act upon the following 12 Principles of the Code of Mutual Respect and Cooperation. These principles remind us to conduct ourselves in a professional manner at all times and to promote a positive climate for everyone. The 12 Principles of the code are: 1. Treat everyone equally and with respect. 2. Be courteous and tactful. 3. Be ready to communicate. 4. Encourage others and share your expertise with them. 5. Give and accept constructive criticism. 6. Be receptive to change. 7. Be a team player. 8. Get involved. 9. Have a positive attitude. 10. Be honest and accept responsibility. 11. Recognize other peoples priorities. 12. Strive to do your best. For more information on the Code of Mutual Respect and Cooperation, please check the website at http://courses.chem.psu.edu/chem112/General Materials//Respect.html
1. Mole concept Mole/gram conversions; reactions 2. Equilibrium principles Meaning of Keq Distinction between Keq and the mass action expression (reaction quotient) Principle of LeChatelier Simple calculations using Keq 3. Solution concentrationsmolarity Definitions of strong and weak electrolytes Definition of saturated solution Definitions of oxidation- reduction 4. Meaning of enthalpy; H 5. Lewis formulae; Shapes of molecules
3.27,31,33,35
15.13-16,27-28,37-40
Ch. 16-17
Ch. 16-17
These are exercises from the 11th edition of Chemistry: The Central Science. The useful exercises in the 10th edition are not necessarily the same.
Schedule - Spring 2011 See Schedule on the Course Web page for updates http://courses.chem.psu.edu/chem112/Spring
Date
Topic
Supplemental
Kinetics 1-3 Rate Laws 14.3 14.23, 25, 27, 29, 32, (33) Skill Check Test 1: Nomenclature Bonus Deadline: Thurs Jan. 13 (midnight) F Jan. 14 Kin. II: Time Dependence 14.4 14. 35, 37, 41, 45 Kinetics 4-7
M Jan. 17 Martin Luther King Day Holiday No classes 14. 5 14. 5, 47, 49, 51,55, 57 W Jan. 19 Temp. Dependence Kinetics 8-13 14. 10, 63, 65, 67, 69, 99 Kinetics III: Mechanisms 14. 6 Skill Check Test 2: Ions in Solution Bonus Deadline: Thurs Jan. 20 (midnight) Kinetics 14-17 F Jan. 21 Catalysis 14.7 14. 73, 75 M Jan. 24 Enzymes Enzyme 14.79-81, 92, 95 Suppleme Unit Quiz 1 Kinetics START DATE: Tue Jan. 25 Final Due Date: Thurs. Jan. 27 (midnight) Equilibrium 1-16 15. 1-7 15.1,11,13, 15,21a,b,23,29 Review Gas Phase 15. 35, 37, 45, 51,53 Equilibrium W Jan. 26 Nuclear Reactions 21.1-3 21.1,2, 7, 9, 11,13,17,19,27, 65 Nuclear 1-6
Skill Check Test 3: Equilibrium Bonus Deadline: Thurs. Jan. 27 (midnight) Nuclear 7-13 Half Life Mass21.4-6 21.4, 32, 33, 37,39, 41, 42 21. 43,45,47,51 Energy Conversion Nuclear 14-15 M Jan. 31 Fission/Fusion 21.7-9 21.6, 35,53,57 p. 236, Med. Nuclear Nuclear 16-18 p. 910, 922 Unit Quiz 2 Nuclear START DATE: Sat Jan. 29. Final Due Date: Tue Feb. 1 (midnight) W Feb. 2 Review F Jan. 28
FIRST MIDTERM EXAM Wednesday, Feb. 2 - 6:30-7:45 PM Covers Chapter 14 and 21, Basic Skills 1 and 2
Syllabus
Schedule - Spring 2011 See Schedule on the Course Web page for updates http://courses.chem.psu.edu/chem112/Spring
Date
F Feb. 4
Topic
Dissociation, pH
Supplemental
Acid-Base 1
M Feb. 7 W Feb. 9
Acid-Base 2-8
Acid Base 9-26 16.6, 51, 53, 57, 61, 65 16. 73,75,77 Basic Skill Test 4: Basic Acid-Base chemistry (pH) Bonus Deadline Thurs Feb. 10 (midnight) F Feb. 11 Ka, Kb, Salt Solutions 16.8-9 16.79, 81, 83, 85 ,87 Acid Base 27- 32
Unit Quiz 3 Acid Base Part 1 Chapt 16.1-8 START DATE: Fri Feb. 11 Final Due Date: Mon Feb. 14 (midnight) M Feb. 14 Chemical Structure 16.10-11 16.9, 93, 95, 97, 101, 103 Acid Base 33-36 Lewis Theory 7.5, 23,25,27,29,31, 49, 57, 61,63 Periodic Trends 17.1-6 W Feb. 16 Periodicity 22.1 22.1, 7, 8a, b, c , 11, 13, 15, 45 Unit Quiz 4 Acid Base II START DATE: Tue Feb. 15 Final Due Date: Thur Feb. 17 (midnight) Skill Check Test 5 Concentration Dilution Bonus Deadline Thurs Feb. 17 (midnight) 17.13, 15 Common Ion Effect 17.1 Buffers 1-4
F Feb. 18
Unit Quiz 5 Buffers and Titration START DATE: Tue Feb. 22 Final Due Date: Thurs. Feb. 24 (midnight) Buffers 5-14 M Feb. 21 Buffer Solutions/ 17.4, 19,21, 23, 25, 27, 29 17.2-3 17. 7, 33, 35, 37, 39, 41, 43, 45 Titrations, Indicators 19.1-2 19.1, 9,11, 13, 23, 25 W Feb. 23 Spontaneity, Enthalpy F Feb. 25 Entropy 19.3-4 19.4, 31,33, 39,41, 43, 47, 49 Thermo 1-6
Unit Quiz 6 Thermodynamics Part 6 Entropy START DATE: Sat Feb. 26 Final Due Date: Tue Mar. 1 (midnight) M Feb. 28 Free Energy 19.5-6 19.6, 51, 53, 55, 57,65 Thermo 7-18 W Mar. 2 Review
SECOND MIDTERM EXAM Wednesday, Mar. 2- 6:30-7:45 PM Chapter 16.1-11, 17.1-3, and 19.1-4, Basic Skills 3, 4, and 5
Syllabus
Schedule - Spring 2011 See Schedule on the Course Web page for updates http://courses.chem.psu.edu/chem112/Spring
Date
F Mar. 4
Topic
Free Energy , Keq
Supplemental
Thermo 19-22
Unit Quiz 7 Thermodynamics Part 2 Free Energy START DATE: Mon Mar. 7 Final Due Date: Mon Mar. 14 (midnight) Mar. 7-11 Spring Break 4.2,17.4-5 17.47,49,51, 53, 55, 57 M Mar. 14 Solubility Equilibria W Mar. 16 Precipitation/Dissolution Complex Ions F Mar. 18 Finish Chapter 17 Oxidation Numbers 17.6-7 17.10, 59, 61,63,67 17.82, 85, 88, 101
#101 use Kf = 4.6 10+17
Solubility 1- 14
4.4 4.49, 51, 53 Unit Quiz 8 Solubility START DATE: Fri. Mar. 18 Final Due Date: Tue Mar. 22 (midnight) 20.11, 13, 15,19, 21, 93 M Mar. 21 Balancing Redox reactions 20.1-2 W Mar. 23 Voltaic Cells, EMF 20.3-4 20.4, 25,33,35, 37, 39, 42,43,45
Electrochem. 1-4
Electrochem 5-10
F Mar. 25
Skill Check Test 6 Oxidation Reduction Bonus Deadline Thurs Mar. 24 (midnight) 20.7,49,51,53a,55 Electrochem.11-19 20.5-6 Spontaneity, effect of concentration 20. 59, 61, 63, 65, 96 Electrochem. 20-21 Batteries, Corrosion 20.71,73, 75, 81, 83 20.7-8
F Apr. 1
M Apr. 4 W Apr. 6
Quantitative electrochem Metallurgy 1-12 23.1-4 23.2, 10,14,17, 19 Metallurgy Unit Quiz 9 Electrochemistry START DATE: Fri Apr. 1 Final Due Date: Mon Apr. 4 (midnight) Transition Metals 6.8-9 6.67b,d, 70 23.7 23.43, 45, 47 Review
Syllabus
Schedule - Spring 2011 See Schedule on the Course Web page for updates http://courses.chem.psu.edu/chem112/Spring
Date
Review F Apr. 8 F Apr. 8 M Apr. 11
Topic
Intermolecular Forces, Phase diagrams, Covalent bonding Transition Metals
Supplemental
Transition Metals 1-11 Unit Quiz 10 Metallurgy, Transition Metals, Chemistry of Elements START DATE: Tue Apr. 12 Final Due Date: Thurs. Apr.14 (midnight) Molecular Orbital W Apr. 13 Bonding in Solids: 9.7-8 9.59, 65,67,69,71 Theory 1-6 Molecular Orbital Theory Skill Check Test 7: Periodicity Bonus Deadline: Thurs Apr. 14 (midnight) Bonding in 11.7c, 57,69, 71,73,75,77 F Apr. 15 Bonding and Structure of 11.7, 8 Materials 1-10 Solids: C, ceramics 12.4,22.1,10 12.32 b,c Transition Metals
p. 515-516
M Apr. 18
22.1-11
12.1, 2, 13, 15, 17, 23, 87 W Apr. 20 Bonding in Metals Metal Properties 12.1-3, Electrical Properties 12.5, 23.5 23.25, 29, 31 1-5 Skill Check Test 8: Forces and Bonding in Solids Bonus Deadline: Thurs Apr. 21 (midnight) 23.6, 11.7 23. 33, 34 F Apr. 22 Metal properties Metal Properties Mechanical 6 to 11 Metal Suppl. Unit Quiz 11 Chemistry of the Elements, and MO Theory, Metal Properties START DATE: Sat Apr. 23 Final Due Date: Tue Apr. 26 (midnight) Final Deadline for Skill Check Test 1-8 Monday Apr. 25 (midnight) M Apr. 25 Modern Materials Polymer Synthesis 12.6 Polymer suppl. 12.5ab, 39, 40, 41, 43, 45 Polymers 1,2
W Apr. 27 Modern Materials 12.3, 47, 48, 49, 51, 52 12.6, 7 Polymers 3-8 Polymer Properties and Polymer Biomaterials suppl. Unit Quiz 12 Review Part 1 START DATE: Thurs Apr. 7 Final Due Date: Apr. Thurs 28 (midnight) Unit Quiz 13 Review Part 2 START DATE: Thurs Apr. 7 Final Due Date: Thurs Apr. 28 (midnight) F Apr. 29 Review
Syllabus
Mon. Apr. 25
11. MO theory, Chemistry of the Apr. 23 Tues. Apr. 26 Chapter 12, 22 Elements, properties of metals 12. Review 1 Apr. 7 Thurs. Apr. 28 Chapters 14,15,16,17 13. Review 2 Apr. 7 Thurs. Apr. 28 Chapters 19, 20, 21 Final Exam May 3-7 Date and Time TBA: Comprehensive
Deadlines