SAFETY DATA SHEET according to 91/155/EWG

POLYMITB D.O.O
Company: Branimira Cosica 6 Srbija, 15000 Sabac POLYSAN PS 050 Page 1 of 7 Date:15.09.2009

Trade Name:

1.

Identification of the substance/preparation and the company/undertaking

1.1 1.2

Identification of the substance:

Impact Polystyrene (I-PS) Sheets

Supplier: POLYMITB D.O.O Branimira Cosica 6 Srbija, 15000 Sabac Emergency telephone number: (+381 15) 360 300 Composition/Information on ingredients: rubber containing polystyrene, if applicable with lubricant and colour, UV stabilisation polystyrene + polybutadiene + colour Solid, foils and sheets if applicable granules or regrind opac, transparent or various colours odourless

1.3 2.

Chemical Characterisation: Composition: Physical State: Colour: Odour: 3. Hazardous ingredients:

This product is not hazardous according to EC criteria. 3.1 Hazardous identification Products: In case of thermal decomposition, traces of hydrocarbons (ethylbenzene, styrebe). Thermal decomposition products are carbonmonoxide, carbon-dioxide and water. Hazardous reactions With oxidising agents.

3.2 3.3

Avoid excessive temperatures. At temperatures above 300C, Other data: decomposition of the polymer starts under releasing of decomposition products.

POLYMIT-B d.o.o Srbija, 15000 Sabac ; Branimira Cosica 6 tel: (+381 15) 360 300 ; fax: (+381 15) 360 309 www.polymit.com

SAFETY DATA SHEET according to 91/155/EWG

POLYMITB D.O.O
Company: Branimira Cosica 6 Srbija, 15000 Sabac POLYSAN PS 050 Page 2 of 7 Date:15.09.2009

Trade Name:

4.First aid measures: 4.1 After spilling, leakage, leaving of gas: First aid: Other data: Inhalation: in a solid state are no noxious effects through a appropriate handling. After inhalation of decomposition products: rest, fresh-air, medical attention Wash off in the shower or keep under running water; no noxious effects on this way of intake, After contact with molten material keep under cold running water. Do not peel off. Irrigate immediately with water for at least 5 minutes. Mechanical irritation of the cornea only. Material is not expected to be absorbed from the digestive system. No noxious effects on this way of intake Sweep up and deposit properly. Never give fluids or induce vomiting if patient is unconscious or is having convulsions.

4.2

Skin contact:

Eye contact:

Swallowing

Specific features at place of work: 5. Fire-fighting measures: water, dry powder, foam, carbon dioxide, alcoholic foam hard water spray

Suitable extinguishing media: Unsuitable extinguishing media: Releasing products: Specific hazards:

Carbon dioxide, steam Thermal composition and burning release oxides of carbon and steam. In small quantities, the emission of carbon monoxide, monomers and traces of cyanhydrogen are possible. If irritations through fumes in thermal processing: rest, fresh air, symptomatic First aid: medical treatment Specific protective equipment: In case of burning use a self- contained breathing apparatus, fire prevention POLYMIT-B d.o.o Srbija, 15000 Sabac ; Branimira Cosica 6 tel: (+381 15) 360 300 ; fax: (+381 15) 360 309 www.polymit.com

SAFETY DATA SHEET according to 91/155/EWG

POLYMITB D.O.O
Company: Branimira Cosica 6 Srbija, 15000 Sabac POLYSAN PS 050 Page 3 of 7 Date:15.09.2009

Trade Name:

Other data:

Burned material and contaminated extinguishing media is to be deposited properly. Soak carefully with water to avoid a renewed ignition.

6.

Accidental release measures: Methods for cleaning up (granules/regrind): On cause of slid danger pick running off granules on solid ground immediately mechanically up. Or guard against with a cordon. Handling and Storage: Storage: Store in a cool, dry place away from direct sunlight. Avoid heat and wetness, also extreme temperature differences (because of condensed moisture). Avoid solar radiation. Storage silos must be grounded to prevent static charge. Use suitable dust filter to avoid emission. Avoid dust formation. Avoid breathing dust. Sensible and careful handling of the product is advisable. With some procedures, local extraction may be required, e.g. to avoid irritation caused by dust, resulting from grinding and swarf. Follow industrial practice as far as organisation and hygiene at the workplace is concerned. From handling and/or storage developed dust can become explosive. Make sure that machines are ventilated enough. Reduce dust concentration to a minimum When dust formation use admitted particle filter (DIN 3181) Use safety goggles Wear overall with long sleeves Wash hands before breaks or end of the workday

7. 7.1

Handling:

Inhalation protection:

Breathing protection: Eye protection: Skin protection: Hand protection: Others:

POLYMIT-B d.o.o Srbija, 15000 Sabac ; Branimira Cosica 6 tel: (+381 15) 360 300 ; fax: (+381 15) 360 309 www.polymit.com

SAFETY DATA SHEET according to 91/155/EWG

POLYMITB D.O.O
Company: Branimira Cosica 6 Srbija, 15000 Sabac POLYSAN PS 050 Page 4 of 7 Date:15.09.2009

Trade Name:

8. 8.1

Exposure controls/Personal protection Other data for the organisation of technical constructions:

8.2

Ingredients with workplace exposure limits: During processing of the sheets, the following ingredients can be released Styrene: CAS-Nr. 100-42-5 MAK: 20ml/m = 85 mg/m (Austria) 1,3-Butadien: CAS-Nr. 106-99-0 compare part III A2 of MAC- Listing (Austria) Personal protection equipment Use ventilation in case of mechanical dust generation. Ventilation : Inhalation protection: Eye protection: Skin protection: Hand protection: Other data: In case of dust generation use approved particle filters (DIN 3181) Use safety goggles. Wear overall with long sleeves. Wear gloves to prevent mechanical injuries

POLYMIT-B d.o.o Srbija, 15000 Sabac ; Branimira Cosica 6 tel: (+381 15) 360 300 ; fax: (+381 15) 360 309 www.polymit.com

SAFETY DATA SHEET according to 91/155/EWG

POLYMITB D.O.O
Company: Branimira Cosica 6 Srbija, 15000 Sabac POLYSAN PS 050 Page 5 of 7 Date:15.09.2009

Trade Name:

9.

Physical and protective information:

Figure: ABS/PMMA foils or sheets (regrinds) Colour: depends on specific coloration Odour: none Melting point/range: Boiling point: Density: Steam pressure: Viscosity: Water solubility: pH-Factor: Flash Point: Ignition temperature: Explosion Limits: Thermal Decomposition: 10. 10.1 10.2 Stability and Reactivity Chemical stability: Conditions to avoid: Avoid excessive heating. Thermal decomposition starts at 300C. Processe dat high temperatures, the material may generate vapour levels sufficient to cause eye and respiratory irritation. 10.3 10.4 Products to avoid: strong oxidising agents Stable under normal storage and handling conditions. > 80C n. a. appr. 1,05 -1,07 (at 25C) g/cm n. a. n. a. not soluble n. a. n.a. > 400 C n.a. > 300 C

Hazardous decomposition products: Monomers, other products. Releasing fumes could contain traces of hydrocarbons

POLYMIT-B d.o.o Srbija, 15000 Sabac ; Branimira Cosica 6 tel: (+381 15) 360 300 ; fax: (+381 15) 360 309 www.polymit.com

SAFETY DATA SHEET according to 91/155/EWG

POLYMITB D.O.O
Company: Branimira Cosica 6 Srbija, 15000 Sabac POLYSAN PS 050 Page 6 of 7 Date:15.09.2009

Trade Name:

11.

Toxicological information: Swallowing: Oral toxicology is probably very less, physiological inactive Swallowing in form of pellets can cause constipation Eye contact: Solid matter or dust cause injuries of the cornea on account of mechanical effects Skin contact: Injuries only on account of mechanical effects. Absorption on account of physical properties not possible Inhalation: On account of physical properties is an exposition of fumes at room temperature improbable. In higher temperatures fume concentrations can conduct. Those can cause irritations and other effects. Dust can cause irritations of the respiratory tract. At handling with high temperatures keep to the legal MAC-figures for styrene

12.

Ecological information: Elimination information: No information available: the product is water-insoluble Behaviourism in environment On account of the consistence and the water-insolubility of the product Mobility: On account of the products consistence is an environmental distribution improbably Biodegradability: The product is potentially hard biodegradable in ground The product is practically nonsoluble in water and solid. Therefore, under environmental conditions, no detrimental effect on plants, animals and micro-organism are to expect

POLYMIT-B d.o.o Srbija, 15000 Sabac ; Branimira Cosica 6 tel: (+381 15) 360 300 ; fax: (+381 15) 360 309 www.polymit.com

SAFETY DATA SHEET according to 91/155/EWG

POLYMITB D.O.O
Company: Branimira Cosica 6 Srbija, 15000 Sabac POLYSAN PS 050 Page 7 of 7 Date:15.09.2009

Trade Name:

13.

Disposal considerations: Disposal of product: All efforts should be made to recycle the product. The guidelines of this data sheet should therefore be followed. Clean, unused materiel can be disposed or be sent to a reuser. By-products and intermediateproducts can be recycled. Production waste is to be deposited properly e.g on an approved waste site, or it can be burned in approved site according to local regulations. Waste code number: 57202

14.

Transport information: Labelling according to EEC regulations is not required.

15. 15.1 15.2

Regulatory information: EG classification: National regulations - Germany: Water Endangering Class: not water endangering WGK 0 VwVws, addendum 1, number: 766

Labelling according to EEC regulations not required 16. Other information: Telephonic further enquiry when claim: (+381 15) 360 300 This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulations. The information contained herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It should therefore not be construed as guaranteeing specific properties.

POLYMIT-B d.o.o Srbija, 15000 Sabac ; Branimira Cosica 6 tel: (+381 15) 360 300 ; fax: (+381 15) 360 309 www.polymit.com