atomic structure 1.

In Balmer series of lines of hydrogen spectrum, the third line from the red--end corresponds to which one of the following inter-orbit jumps of the electrons for Bohr's orbits in an atom of hydrogen? (a) 3 2 (b) 5 2 (c) 4 1 (d) 2 5 2. The orbital angular momentum of revolving in an orbit is given by This momentum for an s-electron will be3. The de Broglie wavelength of a tennis ball of (At mass 60 g moving with a velocity of 10 m/s, is approximately(h = 6.63 x 10-34 Js) (a) 10-33 m (b) 10-31 (c) 10-16m (d) 10-25 m 5. Which one of the following groupings represents a collection of isoelectronic species? (At. Nos. Cs= 55, Br= 35) + 2+ 2+ 33+ + 3+ 2+ + (a) Na , Ca , Mg (b) N , Al , Na (c) Be,AI , Cr (d) Ca , Cs , Br 6. Which of the following sets of quantum numbers is correct for an electron in 4f orbital? (a) n=4 /=3 m=+4 s=- (b) n = 3, / = 2, m = -2, S = + (c) n=4 l =3 m=+l s=+- (d) n = 4, l = 4, m = -4, s = - 7. Consider the ground state of Cr atom (Z = 24), the number of electrons, with azimuthal quantum numbers l = 1 and l = 2 are respectively: 10. In a multielectron atom, which of the following orbitals described by Three quantum numbers will have same energy in the absence of magnetic field and electric field: (I) n = 1, l = 0, m = 0 (II) n = 2, l = 0, m = 0 (III) n = 3, I = 1, m = 1 (IV) n = 3, I = 2, m = 1 (V) n=3, l=2, m=0 (a) I and II (b) II and III (c) III and IV (d) IV and V 11. Which of the following statements in relation to the hydrogen atom is correct? (a) 3s-orbital is lower in energy than 3p-orbital t8 (b) 3p-orbital is lower in energy than 3d-orbital (c) 3s and 3p-orbitals are of lower energy than 3d-orbital (d) 3s, 3p and 3d.arbitals all have the same energy 12. According to Bohr's theory the angular momentum of electron in 5th orbit is : 13. Uncertainty in the position of an electron (mass= 9.1 x 10-31 kg) moving with a velocity of 300 ms-1 accurate upto 0.001 %, will be: -2 -2 -2 -2 (a) 5.76x10 m (b) 1.92x10 m (c) 3.84x10 m (d) 19.2x10 m 14. Which of the following sets of quantum numbers represents the highest energy of an atom? (a) 4 I I 0 0 +- (b) 3 0 0 +- (cl3 I I +- . (d) 3 2 I +15. Calculate the wavelength (in nanometer) associated with a proton moving at1.0 x 103 ms-1 ,mass of proton =1.67 x 10-27 kg and ( h = 6.63x10-34 Js) (a) 0.05 nm (b) 2.5nm (c) 14.0.nm (d) 0.032nm 16. In an atom, an electron is moving with a speed of 600 m/s with an accuracy of 005%. Certainty with which the position of the electron can be located is: ( h=6.6x10-34 kgm2s-1, mass of electron em = 9.1 x 10-31 kg) (a) 5.10x10-3 m . (b) 1.92 x 10-3 m . (c) 3.84x10-3 m (d) 1.52 x 10-4 m 17. lonisation energy of He+ is 19.6 x10-19 Jatom-I. The energy of the first stationary state (n = I) of Li2+ is : (a) 8.82x10-17 J atom-l (b) 4.41x10-16 J atom-1 (c) -4.41 x I0-17 Jatom-1 (d) - 2.2 x 10-I5 J atom-1 18. N3- , O2-, F- are related to one another as : (a) isotones (b) isodiaphers (c) isoelectronics (d) nuclear isomers 19. What is the ratio of specific charge of -particle to proton? (a) 1: 1 (b) 4 : 1 (c) : 1 (d) 1 : 20. The wavelength of limiting line (i.e., of shortest wavelength) in Balmer series of H-atom is : (a) 4758 A (b) 3644 A (c) 2435 A (d) 4634 A 21. Bohr's radius of H-atom is 0.529 A. What is the radius of 2nd shell of He+1 (a) 0.529 A (b) 10.58 A (c) 1.058 A (d) 0.2645 A 22. The wavelength of the first spectral line in Balmer series of spectrum of H-atom is: 23. If two particles A .and B having masses in the ratio 1 : 4 . are moving with same velocity, the ratio of wavelengths associated with them will be in the ratio: (a) 1: 4 (b) 4: 1 (c) 2 : -1 (d) 1 : 2 24. If an electron, a proton and an -particle have same de Broglie wavelengths, their kinetic energies are related to one another as : (a) electron'> proton> - particle (b) proton> electron> - particle (c) - particle> proton> electron (d) electron = proton = - particle 25. An electron in 3d-subshell has orbital angular momentum: 26. For l= 2, the type and number of orbitals are: (a) f ,7 (b) d,5 (c) p,3 (d) s,1 + 27. The number of electrons in d-subshell of Cr (Z= 24) is not equal to: (a) s-electrons in Ne(Z= 10) (b) unpaired electrons in Fe (Z= 26) (c) p-electrons in O (Z= 8) (d) d-electrons in Fe3+ (Z=26 28. The energy of a subshell in H-atom depends upon: (a) n value (b) (n+ 1) value (c) 1 value only (d) n, 1 and m values 29. When an electron jumps from 6th to 3rd shell the number of lines produced is : (a) 3 (b) 4 (c) 6 (d) 9 30. The quantum numbers of 9th electron in electronic configuration of fluorine (Z = 9), (a) n = 2, l = 0, m = 0, S = 0 (b) n=2 l=0 m=0 s=+ (c) n = 2 l=1 m = 0 s = + (d) n = 2 I = 1 m = 1 s = +,- 31. For C-atom, 1s22s22p2 two unpaired electrons are in l= 1, the spin angular momentum will be : 36. The energy of second Bohr's orbitin hydrogen [@ ... ohr iSb~~::kJ. mol-I. The. energy of the third (a) 14 .78 kJ /mol (b) 154.87 kJ /mol (c) 7.5 kJ/ mol (d) 87.54 kJ/ mol -19 18. The wavelength of aphot9n that is associated with 1 e V energy is : (h = 6.6 X 10-34 Js, IeV=1.6x10 J, 8 c=3x10 ms-I) (a) 1.2375A (b) 12.375A (c) 123.75 A (d) 12375 A

19. The dimensions of Planck's constant are the same as that of: (a) energy (b) angular momentum (c) work (d) power 10. The ratio of ionisation energies of Li2+ and Be3+ is: 2 . (a) 3" 3 (Of P2 . 9 (c) 16 16 (d) 9

1. Rate constant k of a flfst order reaction is related. to initial concentration Co and C, at time t by the equation let = log e Co-log eC, . The graph is straight line if we plot: (2002) (a) t vs loge Co (b) t vsloge C, (c)t-1 vs'loge C, (d) log e Co vs log c,l . 2. Consider following two re t~ A~products; _ d(A) / dt B ~ products; - d(B)/dt = k2[Bl k1 and k2 are expressed in terms of molar (mol L-1 )andtime(s)as : ( (a) s-1;Ms-:1 (b) Ms-1;M -I (c) s-1;M-1s (d) Ms~l;s3. For a reaction A + 2B ~ C, rate is given + d[Cl / dt = [Al(B]. ~ The ord~rofreaction is: . .~~ (a) 3. . (b) 2 ~ ~ (c) 1 (d) 0 4. Half-life of a substance A following firs order kinetics is 5 days. Starting with 100 g of A, amount left after 15 days is:. (2002) (a) 25 g (b) 50 g (c) 12.5 g (d) 6.25 g 5. The differential rate law fot H2 + 12---+ 2HI,is: (2002) (a) -d[H21 = -d[I2l = -d[HI] dt dt dt (d)" 2(n-m) Thehalf~liftf of a radioisotope is 3 hr. If the initial mass of the isotopeis256g,the mass of . remaining undecayed after 18 hr would be : (2003) -Ea In res cf of the equation k == AeRY in chemic I kinetics, which one of the following statem t is correct? (2003) ~~@, equnibrium const.ant ~ ~ . s adsorption factor (ill . (c Ed r~'energy of activation (d) R is Rydberg's constant 9. For the reaction system 2NO(g)+02(g~ 2N02(g) Vol\lme is suddenly reduced to half its value by increasing the pressure on it. If the reaction is of fIrst order w.r.t. O2 and second order w.r.t. NO, the rate of -reaction will: (2003) (a) diminish to one-fourth ofits initial value (b) diminish to one-eights of its initial value (c) increase to eight times of its initial value . (d) increase to four times of its initial value 4.0 g(b) 8.0 g 1.20 g (d) 16.0g 10. Ina flfstorder reaction, the conc. of reactant decreasesfromO.8MtoOAM in 15minutes. The times taken for the conc. to change from 0.1 M to 0.025 Mis: (2004) (a) 30 min (b) 60 min (c) 7.5 min (d) IS min 11. The rate equation for the reaction 2A + B ~ C, is/found to be r= k[A][Bl The correct stateme\1t in relation to this reaction is that the : (2004) '(a) unit ofk must besec-1 (b) value of ki~. independe.nt of the .i~l (. concentrations of A and ~ (c) rate. offonnation of C is ~ ate disappearance of A . (d) 11/2 is a constant 12. A reac. ti. 011 involving two different reactants( can never be : (2005). . (a) bimolecular

(b) second order reaction @ (c) first order reaction (d) unimolecular reaction 13. 11/4 call be taken as the time taken for concentration of reactant to drop to 3/4 of its initial value. If the rate constantor a frrst orderreaction is k. the 11/4 can be ~tten as: (a) 0.75 (b) 0.69 ~reU kkf (c) 0.29 (d) 0.10 kk 14. Consider an endothermic reaction x ~ y with the activation energies E b and E f for the backward and forward reaction, respectively. In general: (2005) (a) Eb < E f. (b) Eb> E I (c) Eb = Ef (d) there is no defmite relation between E b andEf ;,.' ct.. 15. A schematiC plot of In keq versus inverse of temperature for a reaction is shown infigure. 2.0 1.5x10-3 --+: 117(K-1) r: .... e reaction mu.st be: (a) ermic ) d rmic with negligible enthalpy change (d) highly spontaneous at ordinary temperature The following mechanism has been @ .. proosedforthereactionofNOWithBr2to .. .form NOBr : CXg)+Br2(g) ~ NOBr2(g) NOBr2 (g)+ NO(g) ~ 2NOBr (g) fthe second step is rate determining step, the order of reaction W.r.t. NO (g ) is: (2006) @I ~;~~In was found t~ s~cond order w.r.! (g1~~entration of carbon monoxide. If the concentration of carbon monoxide is doubled, with 'everything else kept the same, the rate of reaction will : (2006) (a) remain unchanged (b) triple . (c) increase by a factor of 4 (d) double 18. Rate of reaction can be expressed by Arrhenius equation as : _!E..

k = A e RT In this equation E a represents : (a) energy below which colliding molecules will not react (b) the total energy of reacting molecules at a temperature T (c) the fraction of molecules with energy

PERIODIC PROPERTIES CLASSIFICATION OF PERIODICITY I]

l. The reduction in atomic size with increase in atomic number is characteristic' of elements of: (a) d-block (b) I-block. (c) radioactive series (d) high atomic masses 2. According to the periodic law the variation in properties related to their : (a) nuclear neutron-proton number r (b) atomic masses (c) nuclear masses (d) atomic numbers 3. The atomic' numbers of vanadium ( V), chromium (Cr), manganese (Mn)& Iron (Fe) are respectively 23, 24, 25 and 26. Which of these may be expected to have highest second ionisation enthalpy? (a) Fe (b) V (c) Cr (d) Mn 4. Which one of the following are species? (At. Nos. : Cs == 55, Br == 35) (a) Ca2+,Cs+,Br (b) Na+,Ca2+,Mg2+ (c) N3- ,F- ,Na+ (d) Be,AI3+ ,CI5. Which of the following ion has the highest value of ionic radius? (2004) (a) Li+ (b) B3+ (c) O2- (d) F6. Among Al2O3,SiO2,P2O3 and SO2 , the correct order of acid strength is : (a) SO2 < P2O3 < SiO2 < Al2O3, (b) Al2O3, < SiO2 < SO2 < P2O3 (c) Al2O3, < SiO2< P2O3< SO2 (d) SiO2< SO2 < Al2O3,< P2O3 7. Which of the following sets of ions represents the collection of isoelectronic speCies? (2004) (At. Nos. :-F = 9, Cl = 17, Na == 11, Mg == 12, Al = 13, K = 19, Ca = 20, Sc == 21) (a) K+ ,Ca2+ ,Sc3+ ,CI- (b) Na + Ca 2+ Sc3+ F- (c) K+ ,Cl- ,Mg2+ ,Sc3+ (d)Na+ ,Mg2+ ,AI3+ ,Cl9. Which of the .fOllOWing arrangement.is the not according to the property @ against it? (a) Li < Na < K < Rb, increasing metallic character (b) B < C < N < O, increasing first ionisation energy (c) I < Br < F < Cl, increasing electron gain enthalpy (with negative sign) (d) Al3+ < Mg 2+ < Na + < F- , increasing ionic size 10. Of the following sets which one does not contain isoelectronic species? (a) BO~- ,CO~- ,NO; (b) SO~- ,CO~- ,NO; (c) CN- ,N2'C~- (d) pot ,SO~- ,CIO. 11. Which of the following oxides is amphoteric in character? (a) SnO2 (b) SiO2 (c) CO2 (d) CaO 12. Following statements regarding the periodic trends .of chemical reactivity of alkali metals and the halogens are given. Which of these statements give the correct picture? (a) E~~~m=;i~. i~;as. de~s I w~~ halogens. ~ ~ (b) In alkali metals the reacti . reas in the halogens it decreases' creasein: atomic number down the group. (c) The reactivity decreases iti the . metals but iliereases in halogens with the increase in atomic number. . . (d) In both the alkali metals and the h og ns, the reactivity decreases with increase m atomic number 'down the group. 13. The increasing order of first ionisation enthalpies of the elements B, P, S and(lowest first) is : . (a) F < S < P < B (b) P <B<S< F (c) B < P < S < F (d) B<P <F<S 14. Which one of the following se ~ s represents a collection of isoelectronic species? (a) K+ ,CI- ,Ca2+ ,Sc3+ (b) Ba2+ ,Sr2+ ,K+ ,Ca2+ (e) N3- ,O2- ,F- ,S2- (d) Li+ ,Na + ,Mg2+ ,Ca2+ 15. Which one of the following constitutes a group of the isoelectronic species? (2008) (a) N2,O2 ,NO+ ,CO (b) CO2 ,O2 , CO, NO (c) NO+ ,CO ,CN- ,N2 (d) CN- ,N2O,NH3,CO 16. Which one of the following arrangements does not give the correct picture of the trend indicated against it? (a) F2> Cl2> Br2 > I2 : Electron gain enthalpy (b) F2 > Cl2 > Br2 > I2: Bond dissociation energy (c) F2> Cl2 > Br2> I2: Electronegativity (d) F2 > Cl2 > Br2 > I2: Oxidising power . 17. The correct sequence which shows decreasing f the ionic radii of the elements is : (a) F- > Na+ > Mg2+ > Al3+ (b) Al3+ > Mg2+ > Na+ > F- > O2+ +2 3+ 2(c) Na > Mg > Al > O >F- (d) Na+ > F- > Mg2+ > O2- > AI3+ 18. Atomic number is more fundamental than atomic mass. This-idea was given by: (a) Mendeleef (b) Bohr (c) W mer (d) Moseley 19. Moseley plotted: (a) frequencies of X -rays versus atomic numbers (b) frequencies of X-rays versus atomic masses (c) frequencies of X-rays versus square roots of atomic numbers (d) square roots of frequencies of X -rays versus atomic numbers 20. Which of the following electronic configuration is wrong? (a) s-block : nsl-2 (b). p-block : ns2npl-6 (c) d-block : (n_l)dl-l0 n1-2. (d) [f-block: (n-2)f1-14(n-1)d0-1ns2 21. Most of the work on transuranic elements was done by: (a) Bohr (b) Seaborg (c) Me Millan (d) Slater 22. The element with electronic configuration [Ne] 3323 p 6 3d 1 4s2, belongs to : (a) 11th group, 4 th period (b) 2nd group, 3 rd period (c) 3 rd group, 4 th period (d) 4 th group, 3 rd period 23. Atomic number 34 belongs to: (a) 3rd period, 15th group, P-block . (b) 4 th period, 16th group, p-block . (c) 4 th period, 2nd group, s-block (d) 5th period, 12th group,d-block 24. Bond length of A-A for single bond is 154.1 pm ..The bondlength of A= A for double bond is likely to be : (a) 77.05 pm (b) 308.2 pm (c) 132.5 pm (d) 118.7 pm 25. Bond length of A = A for double bond is 1132.5 pm. The bond length for A A triple bond is likely to be:

(a) 118.6 pm (b) 198.75 P (c) 44.17 pm (d) none of these 26. What is the length of Be-Cl bond (i) electronegativities of Be and CI are 1.5 and 3.0 respectively, (ii) covalent radii are 112 pm and 99 pm respectively, (iii) slight ionic character exists? (a) 211 pm (b) 211.135 pm (c) 210.865 pm (d) 155.5 pm 27. Using the following data decide the bond length of Cl bond. Atomic radii of carbon and chlorine atoms are 77.1 pm and 99 pm respectively while their electronegativities are 2.5 and 3.0 respectively: (a) 176.1 pm (b) 176.6 pm (c) 176.145 pm (d) 176.055 pm 28. The next element in the same group to the element . having electronic (configuration 1s22s22p63s23p4 ) is: (a) Ge (b) As (c) Se (d) Br 29. Which of the following order is correctw.r.t. the radius? (a) O2- > F- > Na+ > Mg2+ .(b) Mg2+ > Na + > F- > O2(c) F- >O2- > Mg2+ > Na+ (d) Na + > Mg 2+ > O2- > F30. Out of these radii, which of the following is right : (a) A+ > A> A- (b) A+>A->A . (c) A->A>A+ (d) A>A->A+ 31. Which of the following is correct, if for the same element three separate radii 105 nm,100nm & 90 nm reported? (a) 105 is van der Waals' radius, 100 nm is metallic radius and 90 nm is covalent radius (b) These are metallic, covalent and van der Waals' radii respectively (c) These are covalent, metallic and van der Waals radii respectively (d) These are metallic, van der Waals' and covalent radii. 32. bolh have approXimate ionic radii 5 pm each. Atomic radii (covalent) for these respectively are given by the set: (a) 196 pm and 68 pm (b) 68 pm and 196 pm (c) 196 pm each (d) 68 pm each 33. Which is the correct order w.r.t. ionisation energies of Be, B, C, N and O? (a) Be < C < N < O < B (b) B<N<C<O<Be (c) B < Be < C < O < N (d) O < N < C < B < Be