MATERIALSAFETYDATASHEET Iron(III)nitratenonahydrate,reagentACS

Section1ChemicalProductandCompanyIdentification MSDSName: CatalogNumbers: Synonyms: Iron(III)nitratenonahydrate,reagentACS 423710000,423710030,423710050,423715000 Iron(III)nitratenonahydrate,Nitricacidiron(3+)saltnonahydrate. AcrosOrganicsBVBA JanssenPharmaceuticalaan3a 2440Geel,Belgium AcrosOrganics OneReagentLane FairLawn,NJ07410 800ACROS01 +3214575211 +3214575299 2017967100 8004249300 7035273887

CompanyIdentification:

CompanyIdentification:(USA)

ForinformationintheUS,call: ForinformationinEurope,call: EmergencyNumber,Europe: EmergencyNumberUS: CHEMTRECPhoneNumber,US: CHEMTRECPhoneNumber,Europe:

Section2Composition,InformationonIngredients CAS# 7782618 ChemicalName: Iron(III)nitratenonahydrate,reagentACS % EINECS# unlisted

HazardSymbols: XIO

RiskPhrases:

36/37/388 Section3HazardsIdentification

EMERGENCYOVERVIEW Irritatingtoeyes,respiratorysystemandskin.Contactwithcombustiblematerialmaycause fire.Hygroscopic(absorbsmoisturefromtheair). PotentialHealthEffects Eye: Skin: Causeseyeirritation. Causesskinirritation.

Ingestion: Maycausecentralnervoussystemdepression,kidneydamage,andliverdamage.Maycause gastrointestinalirritationwithnausea,vomitinganddiarrhea.Maycausecardiac disturbances.Thetoxicologicalpropertiesofthissubstancehavenotbeenfullyinvestigated. Inhalation: Causesrespiratorytractirritation. Chronic: Maycausemethemoglobinemia,whichischaracterizedbychocolatebrowncoloredblood,

headache,weakness,dizziness,breathshortness,cyanosis(bluishskinduetodeficient oxygenationofblood),rapidheartrate,unconsciousnessandpossibledeath. Section4FirstAidMeasures Eyes: Skin: Ingestion: Inhalation: Immediatelyflusheyeswithplentyofwaterforatleast15minutes,occasionallylifting theupperandlowereyelids.Getmedicalaid. Getmedicalaid.Immediatelyflushskinwithplentyofwaterforatleast15minutes whileremovingcontaminatedclothingandshoes. Ifvictimisconsciousandalert,give24cupfulsofmilkorwater.Getmedicalaid immediately. Removefromexposureandmovetofreshairimmediately.Ifnotbreathing,giveartificial respiration.Ifbreathingisdifficult,giveoxygen.Getmedicalaidifcoughorother symptomsappear.

Notesto Physician: Section5FireFightingMeasures General Information: Asinanyfire,wearaselfcontainedbreathingapparatusinpressuredemand, MSHA/NIOSH(approvedorequivalent),andfullprotectivegear.Usewatersprayto keepfireexposedcontainerscool.Oxidizer.Greatlyincreasestheburningrateof combustiblematerials. Usewateronly!DoNOTusecarbondioxideordrychemical. Section6AccidentalReleaseMeasures General Information: Spills/Leaks: UseproperpersonalprotectiveequipmentasindicatedinSection8. Wearaselfcontainedbreathingapparatusandappropriatepersonalprotection.(See ExposureControls,PersonalProtectionsection).Sweepup,thenplaceintoasuitable containerfordisposal. Section7HandlingandStorage Handling: Washthoroughlyafterhandling.Removecontaminatedclothingandwashbeforereuse.Use withadequateventilation.Donotgetonskinorineyes.Donotingestorinhale. Storage: Donotstorenearcombustiblematerials.Storeinatightlyclosedcontainer.Storeinacool, dry,wellventilatedareaawayfromincompatiblesubstances. Section8ExposureControls,PersonalProtection EngineeringControls: Useadequategeneralorlocalexhaustventilationtokeepairborneconcentrationsbelow thepermissibleexposurelimits. Exposure Limits CAS#7782618: BelgiumTWA:(ironsalts(soluble)):1mg/m3VLE(asFe) Malaysia:(ironsalts(soluble)):1mg/m3TWA(asFe) Netherlands:(ironsalts(soluble)):1mg/m3MAC(asFe) Spain:(ironsalts(soluble)):1mg/m3VLAED(asFe) PersonalProtectiveEquipment Eyes: Skin: WearappropriateprotectiveeyeglassesorchemicalsafetygogglesasdescribedbyOSHA's eyeandfaceprotectionregulationsin29CFR1910.133orEuropeanStandardEN166. Wearappropriateprotectiveglovestopreventskinexposure.

Extinguishing Media:

Clothing:

Wearappropriateprotectiveclothingtopreventskinexposure.

Respirators: FollowtheOSHArespiratorregulationsfoundin29CFR1910.134orEuropeanStandardEN 149.UseaNIOSH/MSHAorEuropeanStandardEN149approvedrespiratorifexposure limitsareexceededorifirritationorothersymptomsareexperienced. Section9PhysicalandChemicalProperties PhysicalState: Crystallinepowder Color: lightpurplegrey Odor: Notavailable pH: Notavailable VaporPressure: Negligible. Viscosity: Notavailable BoilingPoint: Notavailable Freezing/MeltingPoint: 0degC(32.00F) AutoignitionTemperature: Notavailable FlashPoint: Notavailable ExplosionLimits:Lower: Notavailable ExplosionLimits:Upper: Notavailable DecompositionTemperature: Notavailable Solubilityinwater: solubleinwater SpecificGravity/Density: MolecularFormula: Fe(NO3)3.9H2O MolecularWeight: 404.00 Section10StabilityandReactivity ChemicalStability: ConditionstoAvoid: IncompatibilitieswithOther Materials HazardousDecomposition Products HazardousPolymerization Stable.However,maydecomposeifheated. Incompatiblematerials,light,combustiblematerials,temperatures above50C(122F). Strongoxidizingagents,reducingagents. Nitrogenoxides. Hasnotbeenreported. Section11ToxicologicalInformation RTECS#: LD50/LC50: CAS#7782618:NO7175000 RTECS: CAS#7782618:Oral,rat:LD50=3250mg/kg .

Carcinogenicity: Iron(III)nitratenonahydrate,reagentACSNotlistedasacarcinogenbyACGIH,IARC, NTP,orCAProp65. Other: SeeactualentryinRTECSforcompleteinformation. Section12EcologicalInformation Other: Noinformationavailable. Section13DisposalConsiderations Disposeofinamannerconsistentwithfederal,state,andlocalregulations. Section14TransportInformation

ShippingName: HazardClass: UNNumber: PackingGroup:

IATA FERRICNITRATE 5.1 1466 III

IMO FERRICNITRATE 5.1 1466 III

RID/ADR FERRICNITRATE 5.1 1466 III

Section15RegulatoryInformation European/InternationalRegulations EuropeanLabelinginAccordancewithECDirectives HazardSymbols:XIO RiskPhrases: R36/37/38Irritatingtoeyes,respiratorysystemandskin. R8Contactwithcombustiblematerialmaycausefire. SafetyPhrases: S17Keepawayfromcombustiblematerial. S24/25Avoidcontactwithskinandeyes. WGK(WaterDanger/Protection) CAS#7782618:1 Canada USFederal TSCA CAS#7782618isnotontheTSCAInventorybecauseitisahydrate.Itisconsideredtobe listediftheCASnumberfortheanhydrousforminontheInventory(40CFR720.3(u)(2)). Section16OtherInformation MSDSCreationDate: 7/16/1996 Revision#0Date Original.
Theinformationaboveisbelievedtobeaccurateandrepresentsthebestinformationcurrentlyavailableto us.However,wemakenowarrantyofmerchantibilityoranyotherwarranty,expressorimplied,with respecttosuchinformation,andweassumenoliabilityresultingfromitsuse.Usersshouldmaketheirown investigationstodeterminethesuitabilityoftheinformationfortheirparticularpurposes.Innoeventshall thecompanybeliableforanyclaims,losses,ordamagesofanythirdpartyorforlostprofitsorany special,indirect,incidental,consequential,orexemplarydamageshowsoeverarising,evenifthecompany hasbeenadvisedofthepossibilityofsuchdamages.