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Lecture 15
October 14, 2009
Introduction to Crystallography
electronic structure Bohr atom Bohr-Sommerfeld quantum numbers Aufbau principle multielectron atoms Periodic Table patterns
octet stability bonding state of aggregation gas liquid solid 3.091
primary: ionic covalent metallic van der Waals secondary: dipole-dipole London dispersion hydrogen
solid: that which is dimensionally stable, i.e., has a volume of its own
Sn
1.40 1.62 16.31 3.67/7.7 11.50 C
o
white
Tetragonal
a = b = c, = = =90o
7.03 290.4
301.25
0.228 0.668
4 Lattice Types
Bravais Lattice
Parameters
Simple (P)
Triclinic
Monoclinic
7 Crystal Classes
Orthorhombic
Tetragonal
a1 = a2 = a3 12 = 23 = 31 = 900
Trigonal
Cubic
Hexagonal
a2 a1
Courtesy of National Academy of Sciences, U. S. A. Used with permission. Source: Caspar, Donald L. D., and Eric Fontano. "Five-fold Symmetry in Crystalline Quasicrystal Lattices." PNAS 93 (December 1996): 14271-14278. Copyright 1996 National Academy of Sciences, U.S.A.
Figure 12.5
Pearson. All rights reserved. This content is excluded from our Creative Commons license. For more information, see http://ocw.mit.edu/fairuse.
Source: Fig. 12.5 in Averill, Bruce, and Patricia Eldredge. Chemistry: Principles, Patterns, and Applications. San Francisco, CA: Pearson/Benjamin Cummings, 2007. ISBN: 080538039.
Figure 12.5c
Pearson. All rights reserved. This content is excluded from our Creative Commons license. For more information, see http://ocw.mit.edu/fairuse. Source: Fig. 12.5 in Averill, Bruce, and Patricia Eldredge. Chemistry: Principles, Patterns, and Applications. San Francisco, CA: Pearson/Benjamin Cummings, 2007. ISBN: 080538039.
Figure 12.10
Pearson. All rights reserved. This content is excluded from our Creative Commons license. For more information, see http://ocw.mit.edu/fairuse. Source: Fig. 10.24 in McMurry, John, and Robert C. Fay. Chemistry. 4th ed. Upper Saddle River, NJ: Pearson/Prentice-Hall, 2004. ISBN: 0131402218.
Pearson. All rights reserved. This content is excluded from our Creative Commons license. For more information, see http://ocw.mit.edu/fairuse. Source: Fig. 10.24 in McMurry, John, and Robert C. Fay. Chemistry. 4th ed. Upper Saddle River, NJ: Pearson/Prentice-Hall, 2004. ISBN: 0131402218.
Pearson. All rights reserved. This content is excluded from our Creative Commons license. For more information, see http://ocw.mit.edu/fairuse. Source: Fig. 10.24 in McMurry, John, and Robert C. Fay. Chemistry. 4th ed. Upper Saddle River, NJ: Pearson/Prentice-Hall, 2004. ISBN: 0131402218.
Pearson. All rights reserved. This content is excluded from our Creative Commons license. For more information, see http://ocw.mit.edu/fairuse. Source: Fig. 10.24 in McMurry, John, and Robert C. Fay. Chemistry. 4th ed. Upper Saddle River, NJ: Pearson/Prentice-Hall, 2004. ISBN: 0131402218.
All M. C. Escher works 2010 The M. C. Escher Company The Netherlands. All rights reserved. www.mcescher.com.
All M. C. Escher works 2010 The M. C. Escher Company The Netherlands. All rights reserved. www.mcescher.com.
All M. C. Escher works 2010 The M. C. Escher Company The Netherlands. All rights reserved. www.mcescher.com.
Figure 12.5a
Pearson. All rights reserved. This content is excluded from our Creative Commons license. For more information, see http://ocw.mit.edu/fairuse. Source: Fig. 12.5 in Averill, Bruce, and Patricia Eldredge. Chemistry: Principles, Patterns, and Applications. San Francisco, CA: Pearson/Benjamin Cummings, 2007. ISBN: 080538039.
All M. C. Escher works 2010 The M. C. Escher Company The Netherlands. All rights reserved. www.mcescher.com.
All M. C. Escher works 2010 The M. C. Escher Company The Netherlands. All rights reserved. www.mcescher.com
All M. C. Escher works 2010 The M. C. Escher Company The Netherlands. All rights reserved. www.mcescher.com
2r 4 a 3 a 0.5
4r/3 2 a 0.68
22r
0.74
3 1 1 4 3 2 2
1 8 x = 1
8 1 6 x = 3
2 = 4 lattice
points/unit cell
FCC
Pearson. All rights reserved. This content is excluded from our Creative Commons license. For more information, see http://ocw.mit.edu/fairuse.
Source: Fig. 12.5 in Averill, Bruce, and Patricia Eldredge. Chemistry: Principles, Patterns, and Applications.
San Francisco, CA: Pearson/Benjamin Cummings, 2007. ISBN: 080538039.
a = 407 pm
4r
a
Image by MIT OpenCourseWare. Adapted from Fig. 5 in Aquaro, Donato. "Thermal Mechanical Analysis of a Solid Breeding Blanket."
Fusion Engineering and Design 69 (2003): 511-518. Courtesy of Elsevier, Inc., http://www.sciencedirect.com. Used with permission.
Houses at LEstaque
Georges Braque
1908
Colored Golds:
FCC with zest
pure Au
Cu(low)
Cu(high)
Ni Al In Cr yellow
yellow
pink white purple
blue green
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