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Honeycomb Ceramic Used in Vehicle, VOC & RTO System

Beihai Huihuang Langjie Environmental Protection Technology Co.,Ltd.


E-mail : huihuang @huihuang-packing.com Tel : +0086-779-2228238 Fax : +0086-779-2228278

Directory of Honeycomb Ceramics


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I. Sample picture--------------------------------------------------------------------------------------------1
II.

1.

Directory--------------------------------------------------------------------------------------------------2

Honeycomb ceramic series----------------------------------------------------------------3


1.1

Honeycomb ceramic substrate (used in vehicle)------------------------------------------------3


Product Readme------------------------------------------------------------------------------------3
Specifications---------------------------------------------------------------------------------------4
Honeycomb ceramic substrate (used in diesel vehicle)---------------------------------------6
1.2 Honeycomb ceramic and heat accumulation substance for RTO ect.------------------------7
Product Readme------------------------------------------------------------------------------------7
Dimension and physicochemical capability----------------------------------------------------8
Physics performance-------------------------------------------------------------------------------8
Chemical composition-----------------------------------------------------------------------------9
Features & Sizes------------------------------------------------------------------------------------9
Honeycomb ceramics(substrate) products technological functions------------------------10
1.3 Honeycomb ceramic filtering (used in industry)-----------------------------------------------11
Product Readme-----------------------------------------------------------------------------------11
Characteristic--------------------------------------------------------------------------------------11
Material: mullite, cordieri, high alumina, nicalon etc.---------------------------------------12
Chemical high aluminium honeycomb ceramic catalyst substrate-------------------------13

2.

Car/Motorcycle catalyst Series----------------------------------------------------------14


2.1

Car/motorcycle three-way catalyst--------------------------------------------------------------14


Product Readme-----------------------------------------------------------------------------------14
Substrate-------------------------------------------------------------------------------------------14
Coating---------------------------------------------------------------------------------------------14
Geometrical features------------------------------------------------------------------------------15
Purificant-------------------------------------------------------------------------------------------15
Operating principle-------------------------------------------------------------------------------16
Good characteristics------------------------------------------------------------------------------16
The main chemical reaction formula as follows----------------------------------------------17
Emission pollution and European emission standard for car--------------------------------17
Notices---------------------------------------------------------------------------------------------17

2.2

Diesel soot particulate filter----------------------------------------------------------------------18


Product Readme-----------------------------------------------------------------------------------18
Dimension-----------------------------------------------------------------------------------------19
Physico-chemical performance-----------------------------------------------------------------20
Physical performance----------------------------------------------------------------------------20

2.3

Insulating mat BHLJ-------------------------------------------------------------------------21


Product Readme-----------------------------------------------------------------------------------21
Physical property---------------------------------------------------------------------------------24
The influence of overhigh temperature to the catalytic converter-------------------------24

Beihai Huihuang Langjie Environmental Protection Technology Co.,Ltd.


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Honeycomb Ceramics Series


Honeycomb ceramic substrate (used in vehicle)

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1. Honeycomb ceramic series


1.1 Honeycomb ceramic substrate (used in vehicle)

Product Readme
The ceramic substrate is made of cordierite, and it is used for car catalytic converter. The cells
density can be 100 cpsi, 300 cpsi, 400 cpsi or 600 cpsi. The BHLJape will be round, oval or
racetrack. We can supply both ceramic element coated with noble metals of Pt, Pd, Rh and ceramic
element without noble metals.

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Beihai Huihuang Langjie Environmental Protection Technology Co.,Ltd.
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Honeycomb Ceramics Series


Honeycomb ceramic substrate (used in vehicle)

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Specifications

Racetrack BHLJape(ellipse)
169185.711271
14818211271

R30
R38

144.8181.3176.21

R37

Rotundity
150100
15075
125130

144.8181.31751

R37

144152

1271611120.71

R23

118152

1458080
931611901
120.6180150.81

106150
R30
R39.6

1208075
1471951701

106100
103100
101.6100

R36.6

100100

10010075

93130

505025

9349.85
8388
80100
8075
10075
125100
125130

Remarks: The channel density is within 400Holes/square inch, the BHLJape dimension within
150mmX150mm, and we can customize the product according to the users requires.

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Honeycomb Ceramics Series


Honeycomb ceramic substrate (used in vehicle)

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Index
Item
CFT-02(260 )

CFT-03(300 CFT-04(400
)

Volume kg/cm3

0.70

Water absorption %

20-27

Resistance to

CFT-06(600 )

X (Vertical
50

to

normal

50

65

channels)

atmospheric
temperature

Y (Vertical

KN/cm2

to

160

180

200

channels)
Coefficient of thermal

1.5010-6

expansion -1(20-800)
0.1MPa soften temperature

1450

Thermal stability 800

Specific surface area

20

CM2/CM3
Chemical composition range

Al2O3

Si2O

MgO

K.Na2O

Fe2O3

Others

3134

4851

1214

0.5

800-1200

750-800

1.5-2.5

1.3-1.5

Specific heat20-100 J/Kg.K 800-900 800-950


Thermal conductivity20-100
W/m.k

1.5-2.5

1.4-2.0

850-1100 840-920
1.5-2.3

1.0-1.2

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Honeycomb Ceramics Series


Honeycomb ceramic substrate (used in vehicle)

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Honeycomb ceramic substrate (used in diesel vehicle)

Channel
density

Dimension(mm)

Picture

144150
144152.4
150150
190200
190203

100

240240

channels/

240305

square

260305

inch
267305
286305
286355
Composite
racetrack
BHLJape
374270317
144150

200
channels/
square

144152.4
190200
228305

inch
260305
267305

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Honeycomb Ceramics Series


Honeycomb ceramic and heat accumulation substance for RTO ect.

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1.2 Honeycomb ceramic and heat accumulation substance for RTO ect.

Product Readme
Honeycomb ceramic and heat accumulation substance is one kind of porous ceramic. It has
advantages of large surface area, big caloric receptivity, good heat stability, low heat expansion
coefficient, good corrosion resistance and light weight. Recently, HTAC has been widely used in all
kinds of burning furnace, heating furnace, steel burner and heat treater in metallurgy industry.
The heat accumulating burning technique by using the honeycomb ceramic as heat accumulator
has following advantages

1. It can use blast furnace gas of low calorific value.


2. It can save 40-60% energy.
3. It can reduce more than 50% pollutant emission.

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Honeycomb Ceramics Series


Honeycomb ceramic and heat accumulation substance for RTO ect.

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Dimension and physicochemical capability

Number
LWH

150150300 150150300 150150300 150150300 150150300

Channels

2525

3434

4040

4343

5050

4.9

3.9

3.0

3.0

2.26mm

1.0

0.45

0.7

0.5

0.7/0.55

540

805

825

1000

1005

67

80

65

72

57/64

Width of
Channels(mm)
Wall
thickness(mm)
Specific Surface
Area(m2/m3)
Void(%)

Physics performance

Alumina

Cordierite

Cordierite

Dense

Porous

2.1

2.47

1.9

2.3-2.4

6.20

1.3-1.4

2.5-5

4-7

750-800

840-920

250

300

250

1300

1300

1200

Performance

Units

Density

g/cm3

2.7

10-6/k-1

5-7

Heat capacity 20-1000

J/kg

800-900

Heat resisting assaulting

150

350

1300

1600

The hot coefficient of


expansion 20-1000

The highest
using emperature

Porcelain

Mullite

850-1050 800-1200

Stoneware

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Honeycomb Ceramics Series


Honeycomb ceramic and heat accumulation substance for RTO ect.

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Chemical composition

Alumina

Composition

Mullite

Porcelain

Cordierite

Cordierite

Dense

Porous

Stoneware

SiO2

42.8

27.8

47.8

47.9

70.2

Al2O3

50.5

70.1

35.1

33.7

19.4

MgO

--

--

6.7

8.5

0.18

Fe2O3

0.6

0.8

0.78

1.6

0.7

Na2O+K2O+CaO

4.8

1.0

2.8

1.3

3.3

TiO2+BaO

--

--

0.39

0.78

0.25

High aluminum

Al2O390%

SiO298%

SiO298%

Al2O390% High Silicon

Features & Sizes

Channel
Number of Channels

density
Cells/in2
(cm2)

Width of
channel
(mm)

Specific surface area


2

Hole fraction

(m m )

(%)

55

26.3

117

77

1313

5(1)

9.2

278

64

2020

11(2)

6.4

455

73

2525

18(3)

4.9

540

67

4040

46(7)

3.0

825

65

5050

72(11)

2.3

1005

57

Standard dimension 150150300mm


Standard materials: alumina-porcelain/compacted cordierite/porous mullite

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Honeycomb Ceramics Series


Honeycomb ceramic and heat accumulation substance for RTO ect.

======================================================================
Honeycomb ceramics(substrate) products technological functions

155100,Different specifications of honeycombs can be


BHLJape dimensions

produced in the range of 155100 as per custoners


requests.

Square check hole

Density 150-400 holes/square inch, holes separating the


board thickness (0,3mm)

Compressive strength

Axial 12 Mpa, Radial 4 MPa

Thermal energy coefficient

1-210-6

Highest working temperature

Within 1500

Anti-heat &vibration

900

Anti-acid & alkali

Strong

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Honeycomb Ceramics Series


Honeycomb ceramic filtering (used in industry)

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1.3 Honeycomb ceramic filtering (used in industry)

Product Readme
The product is widely used to filter casting and melting metal liquid in foundry industry. It is the
best filter for the foundry manufacturer because of its good practicability, reliability, quality and
low price.
Characteristic

Good heat BHLJock resistance, high temperature casting resistance and high mechanical
strength.
Straight-hole meBHLJ with good quality and high density, low porosity, good effect of filter and
wipe off impurity and slag charge etc.

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Beihai Huihuang Langjie Environmental Protection Technology Co.,Ltd.
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Honeycomb Ceramics Series


Honeycomb ceramic filtering (used in industry)

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Material: mullite, cordieri, high alumina, nicalon etc.

Type
Name

(hole/square

Specification(mm)

Application

Material

inch)
666612.5

Cordierite

300

818112.5

Cordierite

100

555512.5

Cordierite

7012.5

Cordierite

100

6012.5

Cordierite

100-300

505012.5

Cordierite

818112.5

Cordierite

300

666612.5

Cordierite

100

666612.5

Cordierite

110

818112.5

300

filter

Cordierite

755021

Cordierite

50

37379.5

Cordierite

300

404014.5

Cordierite

150

505012.5

Rutile

755012.5

Rutile

757512.5

Rutile

1007512.5

Rutile

10010012.5

Rutile

12512515

Cordierite

12510015

Cordierite

150

15010

Cordierite

300

(middle hole 4O)14510

400

8010

Honeycomb
ceramic filter

555512.5

Cordierite
Iron casting

100-300

Gas stove

Cordierite
Rutile

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Honeycomb Ceramics Series


Honeycomb ceramic filtering (used in industry)

======================================================================

Chemical high aluminium honeycomb ceramic catalyst substrate

Number

Specification

Pass

4712.5

Triangular hole

4712.5

Triangular hole

4712.5

Triangular hole

4712.5

Triangular hole

2512.5

Triangular hole

Type
100 holes / square
inch
200 holes / square
inch
300 holes / square
inch
400 holes / square
inch
800 holes / square
inch

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Car / Motorcycle Catalyst Series


Car/motorcycle three-way catalyst

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2.

Car/Motorcycle catalyst Series

2.1 Car/motorcycle three-way catalyst

Product Readme
Our company has successfully developed many types of three-way Catalytic Converter, which are
suitable for cars in all types and meet the emission standard. As customers requests, all kind of
three-way Catalytic Converter can be explored and produced.

The three-way Catalytic Converter can eliminate 90% amount of the three main pollutants
(hydrocarbon, carbon monoxide and nitrogen oxide). A complete catalyzing reaction depends on
the preserving degree of the mixed fuel on the small side of A/F (rate of air and fuel). And only the
normal system of oxide sensor exerts its function, this A/F can be realized.
Substrate:
The basic material is ceramic(MgO2, AL2O3SiO2). The aim is to offer inert physical structure for
carrying catalyst coating. In order to make a biggiBHLJ catalytic coating in a lesser volume, we
make the surface of the substrate alveolate.
Coating:
There is a loose layer in the surface of substrate which is mainly made of metal oxides -AL2O3. As
a very rough surface, the actual wall area has increased about 7000 times, which greatly increase
the activated surface and the capacity of oxygen storage of the car/ motorcycle three-way catalyst.
Assistant catalyst which contains Zr, Ce and other elements and the main catalyst which contains
Rh, Pd, Pt and other precious metals are coated in the external activated surface.

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Car / Motorcycle Catalyst Series


Car/motorcycle three-way catalyst

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Geometrical features

Type

Cpsi/foot
(CPSI)

Wall
thickness
(mm)

Width

Area
2)

(mm) (mm

Interstitial
rate
(%)

Internal
specific

Weight

area

(g/liter)

(m /liter)

BHLJ-23

600

0.17

0.87

0.752

70

3.225

580

BHLJ-24

600

0.20

0.84

0.700

65

3.114

580

BHLJ-25

600

0.23

0.81

0.651

61

3.002

580

BHLJ-26

400

0.17

1.10

1.210

75

2.728

480

BHLJ-27

400

0.20

1.07

1.745

71

2.654

480

BHLJ-28

400

0.23

1.04

1.082

67

2.579

480

BHLJ-29

300

0.19

1.28

1.625

74

2.310

500

BHLJ-30

300

0.22

1.25

1.550

70

2.260

500

BHLJ-31

300

0.25

1.22

1.476

67

2.200

500

BHLJ-32

200

0.21

1.58

2.490

77

1.957

435

BHLJ-33

200

0.24

1.55

2.396

74

1.920

435

BHLJ-34

200

0.26

1.53

2.335

72

1.895

435

BHLJ-35

100

0.35

2.18

4.766

74

1.354

465

BHLJ-36

100

0.38

2.15

4.635

72

1.334

465

BHLJ-37

100

0.40

2.13

4.550

71

1.323

465

BHLJ-38

50

0.64

3.00

9.000

67

0.672

565

BHLJ-39

50

0.67

2.97

8.821

66

0.659

565

BHLJ-40

50

0.69

2.95

8.703

65

0.650

565

Purificant
Our catalyst is coated with noble metals of Pt, Pd and Rh. When the exhaust is passing through the
three-way catalyst, CO, HC and NOx, the activity of the gas is enhanced under high temperature.
As a result, the CO would be oxidized into CO2, the HC is turned into H2O and CO2 , and the NOx
is deoxidized into nitrogen.

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Car / Motorcycle Catalyst Series


Car/motorcycle three-way catalyst

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Operating principle
When the exhaust is passing through the exhaust pipe, CO, HC, and Nox ---the three types of gas
are passing through the clarifier of the reactor in the three-way Catalytic Converter, the activity of
the gas would be enhanced, they would be under an oxidation and deoxidization reaction. Under
such a high temperature, the CO would be oxidated into a gas without color and poison--CO2; the
HC compound would be turned into H2O and CO2; and the Nox would be deoxidated into Nitrogen.
The three nocuous gases would be turned into the non-harmful gas to purify the exhaust.
Good characteristics
Using honeycomb ceramics carrier that has many advantages, such as low cost, strong adhesive
and active ingredient, long life etc.; adopting late-model of rare earths (material Zirconium and
Titanium) to advance the heat resistance and activity of catalyst; introducing transitional metal,
alkaline earth metal and active material of little precious metal that has plenty of excellences, such
as high purification rate, and low burning temperature etc.; making use of new-style of oxygen
storing stuff that reduces the burning temperature of catalyst and complete transformation.
The catalytic converter applied and produced by this technique has past the test of BHLJanghai
national exhaust gas test center and Tianjin university burning internal-combustion engine lab, the
result indicates: using this cat that can make the emission standard reach European no.3 and meet
the technique requirements the converter product demands. The special exhaust gas catalytic
converter for CNG engine is composed of two parts, that are catalyst of honeycomb ceramics and
metal BHLJell, the main elements is: The exhaust gas pass through the catalyst of honeycomb
ceramics, the active ingredient of catalyst (mostly are metal oxide of rare earths, precious metal
and transitional metal) is able to carry out the catalysed reaction fully under the temperature
condition of 200 to 300 above converting the harmful element such as CO, HC, NOX etc. to
innocuous water, carbon dioxide and nitrogen. A key technique is the core of this program is the
exhaust

gas

decontamination

technique

of

CNG

engine,

which

belongs

to

three-way

decontamination catalyst technique, and is the main means of dealing with exhaust gas of CNG.

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Car / Motorcycle Catalyst Series


Car/motorcycle three-way catalyst

======================================================================
The main chemical reaction formula as follows
Oxidation reaction HC+O2=H2O+CO2
Deoxidization reaction Nox+HC+CO=N2+H2O+CO2
Emission pollution and European emission standard for car
The main pollution exhaust from car: HC, Nox, CO, PM. They are mainly let off through exhaust
pipe, in which, there are nearly 45% HC and little other pollution substance emitted by crankcase
and fuel system.
In the above pollution exhaust, CO, the half burned production of fuel, is worse for health. HC,
constituted by 200 types of elements, is the production, mostly made by half burned and fuel
vaporized action, which contain cancerous substance. Nox, composed by chemical combination of
N2 and O2 under high temperature and pressure condition in firebox, becomes NO2 in the air, which
with strong poisonousness is terrible for human being and plant, and one of main substance that
form acid rain and actinic fog. PM ,its main ingredient is carbonic smoke ,which with a great deal of
chemical substance comprises cancerous substance ,will stay long in the lung of human after
having absorbed.
As the quantity of car increasing, the harm and danger of pollution exhaust of car brought to the
environment will be heavy increasingly, thereby, every nation and area around the world
establiBHLJ the emission limit value of car exhaust one after another, thereinto, the European
standard , EU constituted, is the reference for most of countries and areas.
Notices
1. Let the engine maintain the good working status---the ideal A/F and safe combustion.
2. Avoid suddenly jump-starting the car using the largest accelerograph.
3. The best working temperature of Catalyzer is 400-800 , it BHLJould not exceed 1000.
Otherwise it would accelerate the aging and BHLJorten the life-span of the Catalyzer.
4. If the piston is damaged, the oil would flee into the engine, which would reduce the activity of
the Catalyzer.

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Car / Motorcycle Catalyst Series


Diesel soot particulate filter

======================================================================
2.2 Diesel soot particulate filter

Product Readme
The product is one kind of wall flowed honeycomb ceramic filter with special structure and material.
It is applied in the tail gas clean-up plant of diesel. It utilizes the pore of wall flowed filter to cut-off
and catch the soot particulate in the tail gas of diesel and then purifies the tail gas. It is made by
two materials: cordierite and carborundum.

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Car / Motorcycle Catalyst Series


Diesel soot particulate filter

======================================================================

Dimension

Channel
density

Specification(mm)

Picture

144150
144152.4
150150
190200
190203
100
channels/
square
inch

240240
240305
260305
267305
286305
286355
Combined
racetrack
374270317
144150

200
channels/
square
inch

144152.4
190200
228305
260305
267305

characteristic
1Large and compact area per unit volume;2Small pressure loss and excellent capturing
performance3Excellent heat resistance and heat BHLJock resistance.

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Car / Motorcycle Catalyst Series


Diesel soot particulate filter

======================================================================
Physico-chemical performance

Component

Unit

Numeric value

Component

Unit

Numeric value

SiO2

wt%

48-51

Fe2O3

wt%

<0.5

Al2O3

wt%

31-34

Na2O

wt%

<0.5

MgO

wt%

14-16

K2O

wt%

<0.5

Physical performance

Item

Unit

Numeric value

g/cm3

1.9-2.0

10-6/k-1

<2

Specific heat

KJ/Kg

830-900

Circle-resistant temperature

300

Bulk specific gravity of


bluestone
Average Linear Expansion

(20-1000 C)

Maximum operating

1300

800

Acid resistance

>99

Alkali resistance

>85

Water absorption

Wt%

22+(-)5

temperature
Heat resistance

If the DPF is coated with noble metal (such as Pt, Pd and Rh), the particulate of emission is
captured inside thin gas hole or entrance. As it lasts, the cumulated layer become thick, and
pressure loss increase. To ensure the performance of engine, when pressure loss reaches some
value, it is a must to recycle the filter. The recycle is making the particulate burning, by raising the
gas temperature of filter. The particulate condition is related to the oxygen concentration.
Normally, it is burning at 550-650. Usually we raise emission temperature by adjusting throttle,
and increase gas temperature with burner. The particulate burning temperature can be decreased
by catelyzer, making cumulative particulate burning as soon as possible, thus recover the pressure
loss and fitters performance, then the filter is recycled.

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Car / Motorcycle Catalyst Series


Insulating mat BHLJ

======================================================================
2.3 Insulating mat BHLJ

Product Readme
Product density

Average thickness

Clearance applicable

(g/m )

(mm)

(mm)

2600

4.15

2.36-2.60

3100

4.90

2.82-3.10

4070

6.02

3.70-4.70

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Car / Motorcycle Catalyst Series


Insulating mat BHLJ

======================================================================

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Beihai Huihuang Langjie Environmental Protection Technology Co.,Ltd.
E-mail : huihuang@huihuang-packing.com Tel : +0086-779-2228238 Fax : +0086-779-2228278

Car / Motorcycle Catalyst Series


Insulating mat BHLJ

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Physical property

The influence of overhigh temperature to the catalytic converter


1.Reduce the pressure to the cuBHLJion
2.Reduce the intensity and rigidity of metal BHLJell
3.Increase the clearance between metal BHLJell and ceramic substrate, aggravate the distortion of
metal BHLJell
4.Increase the damage of the cuBHLJion, BHLJorten the working life

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Beihai Huihuang Langjie Environmental Protection Technology Co.,Ltd.
E-mail : huihuang@huihuang-packing.com Tel : +0086-779-2228238 Fax : +0086-779-2228278

Car / Motorcycle Catalyst Series


Insulating mat BHLJ

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Designing of the substrate of catalytic converter


Designing principle of the substrate BHLJ ape:
1.Exert the highest efficiency of catalyst
2.Transverse temperature of the substrate is minimum
3.Make hermetic pressure distribute evenly
Length of the substrate is usually 76mm-152mm.
Honeycomb wall thickness of the substrate is 0.1-0.2mm

weight of original insulating mat


Density after canning = ------------------------------------------------clearance between BHLJell and substrate

Usually the density after canning is controlled about lg/cm3

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Beihai Huihuang Langjie Environmental Protection Technology Co.,Ltd.
E-mail : huihuang@huihuang-packing.com Tel : +0086-779-2228238 Fax : +0086-779-2228278

Car / Motorcycle Catalyst Series


Insulating mat BHLJ

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,the density can not above 1.2g/cm 3and also can not below:

4.70g/cm2

0.4070g/cm2

-------------- = ----------------- lg/cm3


4.1mm

0.41cm

Function of insulating mat


1.Fixation of crispy ceramic substrate, Protecting ceramic carrier away from effecting by the out
force and BHLJ ock
2.Airproof and preventing waste gas leak
3.Heatproof and avoiding overheating of the BHL Jell
4.Sound insulation and noise reduction

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Beihai Huihuang Langjie Environmental Protection Technology Co.,Ltd.
E-mail :huihuang@huihuang-packing.com Tel : +0086-779-2228238 Fax : +0086-779-2228278

Car / Motorcycle Catalyst Series


Insulating mat BHLJ

======================================================================

Click here back to Directory


Beihai Huihuang Langjie Environmental Protection Technology Co.,Ltd.
E-mail : huihuang@huihuang-packing.com Tel : +0086-779-2228238 Fax : +0086-779-2228278