Iit Jee 2012 Paper 2 Solutions

MAHESH JANMANCHI IIT JEE 2012 PAPER 2
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PAPER-2
Maximum Marks: 66

Question paper format and Marking scheme:

1. In Section I ( Total Marks: 24), for each question you will be awarded 3 marks if you darken ONLY the
bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases,
minus one (1) mark will be awarded.

2. In Section II (Total Marks: 18), for each question you will be awarded 3 marks if you darken ALL the
bubble(s) corresponding to the correct answer(s) ONLY and zero marks other wise. In all other cases,
minus one (1) mark will be awarded.

3. In Section III (Total Marks: 24), for each question you will be awarded 4 marks if you darken ONLY the
bubble corresponding to the correct answer and zero marks if no bubble is darkened. There are no negative
marks in this section.



SECTION - I
(Single Correct Answer Type)

This section contains 8multiple choice questions, Each question has four choices, (A), (B), (C) and (D) out
of which ONLY ONE is correct.

21. The Shape of
2 2
XeO F molecule is
(A) trigonal bypyramidal (B) square planar
(C) tetrahedral (D) see-saw

Sol. (D)

XeO
2
F
2
has trigonal bipyramidal geometry due to sp
3
d hybridisation of the central atom Xe but due to
the presence of lone pair at equatorial position, its shape is distorted and becomes see-saw.

22. For a dilute solution containing 2.5 g of a non-volatile non-electrolyte solute in 100 g of water, the
elevation in boiling point at 1 atm pressure is 2
0
C. Assuming concentration of solute is much
lower than the concentration of solvent, the vapour pressure (mm of Hg) of the solution is (take

1
0.76Kkg mol
b
K

= )
(A) 724 (B) 740 (C) 736 (D) 718

Sol. (A)

b b
T K m =
2 0.76 m =
m 2.63 =
o
0
P P 1000
molality
P ''
x
M
= ( where M is the mol wt of solvent)

760 P 1000
2.63
760 18
x
=
P 724torr =



23. The compound that undergoes decarboxylation most readily under mild condition is

(A)
COOH
CH COOH
2
(B)
COOH
O

(C)
COOH
COOH
(D)
CH COOH
2
O

Sol. (B)
In decarboxylation, -carbon acquires partial ve charge. Whenever partial ve charge is stabilized,
decarboxylation becomes easy.
In option (B), it is stabilized by - M & - I of C = O group

24. Using the data provided, calculate the multiple bond energy
( )
1
kJ mol
of a C = C bond in C
2
H
2
.
That energy is (take the bond energy of a C-H bond as 350
1
kJ mol
)
( ) ( ) ( )
2 2 2
2C +H g C H g s
1
H 225kJ mol
=
( ) ( ) 2C 2C g s
1
H 1410kJ mol
=
( ) ( )
2
H g 2H g
1
H 330 kJ mol
=
(A) 1165 (B) 837 (C) 865 (D) 815

Sol. (D)
( ) ( ) ( )
2 2 2
2C +H g C H g s
1
H 225kJ mol
=
( )
C C
225 [1410 330] [ 350 2 ]

+ = + +

C C
815 KJ/mol

= +



25. The major product H of the given reaction sequence is

95%H SO
CN
2 4
CH CH CO CH G H
3 2 3
Heat

(A)
CH CH C COOH
3
=
CH
3
(B)
CH CH C CN
3
=
CH
3

(C)
CH CH C COOH
3 2

CH
3
OH
(D)
CH CH C CO NH
3 2
=
CH
3

Sol. (A)

26.
( ) { } 6 5 2
2
NiCl P C H ( )
2 2 5
2
C H exhibits temperature dependent magnetic behavior
(paramagnetic/diamagnetic). The coordination geometries of
2
Ni
+
in the paramagnetic and
diamagnetic states are respectively
(A) tetrahedral and tetrahedral (B) square planar and square planar
(C) tetrahedral and square planar (D) square planar and tetrahedral

Sol. (C)

( ) { } 6 5 2
2
NiCl P C H ( )
2 2 5
2
C H contains
2+
Ni

In high spin state, it is paramagnetic, sp
3
hybridized, tetrahedral.

In low spin state, it is diamagnetic, dsp
2
, square planar.


27. In the cyanide extraction process of silver from argentite ore, the oxidizing and reducing agents
used are
(A) O
2
and CO respectively (B) O
2
and Zn dust respectively
(C) HNO
3
and Zn dust respectively (D) HNO
3
and CO respectively

Sol. (B)

In extraction of silver, Ag
2
S is leached with KCN in presence of air:
( )
2 2 2 2 3
2
Ag S+NaCN+O Na Ag CN +Na S O (

Thus, O
2
is oxidizing agent.

( ) ( )
2
2 4
2Ag CN +Zn Zn CN +2Ag
(

So, Zn is reducing agent

28. The reaction of white phosphorus with aqueous NaOH gives phosphine along with another
phosphorus containing compound. The reaction type; the oxidation states of phosphorus in
phosphine and the other product are respectively
(A) redox reaction -3 and -5 (B) redox reaction; +3 and +5
(C) disproportion reaction; -3 and +5 (D) disproportion reaction; -3 and +3

Sol. (None of the above Zero marks to all )

( ) ( ) P S +NaOH PH NaH PO aq
4 3 2 2
+
(-3) (+1)
Na PO +PH
3 4 3
(+5)

Oxidation states of P in Na PO &PH
3 4 3
are +5 & -3 respectively.
It is a disproportionation reaction.



SECTION . II
(Paragraph Type)

This section contains 6 multiple choice questions relating to three paragraphs with two questions on each
paragraph. Each question has four choices (A), (B) (C) and (D) out of which ONLY ONE is correct.

Paragraph for Questions 29 and 30

The electrochemical cell shown below is a concentration cell.

2+
M| M (saturated solution of a sparingly soluble salt, MX
2
)
( )
3 2+
|| M 0.01mol dm
| M
The emf of the cell depends on the difference in concentration of
2
M
+
ions at the two electrodes. The
emf of the cell is 298 K is 0.05 V.

29. The solubility product
3 9
K mol dm
, sp
| |
|
\
of MX
2
at 298 K based on the information available for
the given concentration cell is (take 2.303 R 298 / F=0.059V )
(A)
15
1 10
(B)
15
4 10
(C)
12
1 10
(D)
12
4 10

Sol. (B)
( ) ( )
2+ 2+
M| M aq || M aq | M
0.001 M
Anode : ( )
2+
M M aq 2e
+
Cathode: ( )
2+
M aq 2e M
+
( ) ( )
2+ 2
c a
M aq M aq
+

( )
2+
a
cell 3
M aq
0.059
E 0 log
2 10

=
`

)

( )
2+
a
3
M aq
0.059
0.059 log
2 10

=
`

)

( )
2+
a
3
M aq
2 log
10

=
`

)

( )
2 3 2+
a
10 10 M aq Solubility = S

= =
For MX
3
,
( )
3
3 5 15
sp
K 4S 4 10 4 10

= = =



30. The value of
( )
1
G kJ mol
for the given cell is (take 1 F = 96500

1
Cmol
)
(A) -5.7 (B) 5.7 (C) 11.4 (D) -11.4

Sol. (D)

3
cell
G nFE 2 96500 0.059 10 kJ/mole
= =
= -11.4 kJ/mole


In the following reaction sequence, the compound J is an intermediate.

( ) ( )

CH CO O
i H , Pd / C
3
2 2
I J K
CH COONa
3
( ) ii SOCl
2
( ) iii anhyd. AlCl
3

( )
J C H O
9 8 2
gives effervescence on treatment with NaHCO
3
and a positive Baeyers test.
31. The compound I is
(A) (B) (C) (D)

Sol. (A)

32. The compound K is
(A) (B)

(C) (D)


Sol. (C)

Sol. (31 and 32)

Step 1 is perkin reaction.


Bleaching powder and bleach solution are produced on a large scale and used in several household products.
The effectiveness of bleach solution is often measured by iodometry.

33. 25 mL of household bleach solution was mixed with 30 mL of 0.50 M KI and 10 mL of 4 N acetic
acid. In the titration of the liberated iodine, 48 mL of 0.25 N
2 3
Na SO was used to reach the end
point. The molarity of the household bleach solution is
(A) 0.48 M (B) 0.96 M (C) 0.24 M (D) 0.024 M

Sol. (C)

Milli mole Hypo 0.25 48 =

2
2 milli mole of Cl =

Milli mole of Cl
2

0.25 48
6milli mole
2
= =
= Milli mole of Cl
2
= milli mole of CaOCl
2

So, molarity =
6
M=0.24M
25



34. Bleaching powder contains a salt of an oxoacid as one of its components. The anhydride of
that oxoacid is
(A)
2
Cl O (B)
2 7
Cl O (C)
2
ClO (D)
2 6
Cl O
Sol. (A)
( )
2
CaOCl =Ca OCl Cl
OCl
- Hydrochlorite ion, anion of HOCl

Anhydride of HOCl = Cl
2
O
SECTION - III
(Multiple Correct Answer(s) Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE orMORE are correct.

35. With respect to graphite and diamond, which of the statement(s) given below is (are) correct?
(A) Graphite is harder than diamond.
(B) Graphite has higher electrical conductivity than diamond.
(C) Graphite has higher thermal conductivity than diamond.
(D) Graphite has higher C C bond order than diamond.

Sol. (B, D)
(A) Diamond is harder than graphite.
(B) Graphite is a better conductor of electricity than diamond.
(C) Diamond is a better conductor of heat than graphite.
(D) Bond order of graphite ( ) 1.5 > Bond order of diamond ( = 1)

36. With reference to the scheme given, which of the given statement(s) about T, U, V and W is
(are) correct ?

(A) T is soluble in hot aqueous NaOH
(B) U is optically active
(C) Molecular formula of W is
10 18 4
C H O
(D) V gives effervescence on treatment with aqueous
3
NaHCO


Sol. (A, C, D)

37. Which of the given statement(s) about N, O, P and Q with respect to M is (are) correct?

(A) M and N are nonmirror image stereoisomers
(B) M and O are identical
(C) M and P are enantiomers
(D) M and Q are identical

Sol. (A, B, C)

HO
HO HO HO
HO
OH
CH
3
CH
3
CH
3
Cl
Cl
H
H H
H
H
H
M N O
Cl



38. The reversible expansion of an ideal gas under adiabatic and isothermal conditions is shown
in the figure. Which of the following statement(s) is (are) correct?

(A) T
1
= T
2
(B) T
3
> T
1

(B)
isothermal adiabatic
w >w (D)
isothermal adiabatic
U > U

Sol. (A, D)

(A) T
1
= T
2
(due to isothermal)
(B) T
3
> T
1
(incorrect) cooling occurs in adiabatic expansion)
(C) W
isothermal
> W
adiabatic
{ with sign, this is incorrect}
(D) U
isothermal
= 0 > U
adiabatic
= - ve



39. The given graphs / data I, II, III and IV represent general trend observed for different
physisorption and chemisorption processes under mild conditions of temperature and pressure.
Which of the following choice(s) about I, II, III and IV is (are) correct ?

(A) I is physisorption and II is chemisorption
(B) I is physisorption and III is chemisorption
(C) IV is chemisorption and II is chemisorption
(D) IV is chemisorption and III is chemisorptions

Sol. (A, C)
I is physisorption because in physisorption on increasing temperature at constant pressure, adsorption
decreases
II is chemisorptions, because on increasing temperature adsorption increases at same pressure due to
activation energy
III is physical adsorption because , extent of adsorption is decreasing on increasing temperature,.
IV is representing high enthalpy change during chemical adsorption (due to bond formation)
So, it is chemical adsorption.



40. For the given aqueous reactions, which of the statement(s) is (are) true?

excess KI + ( )
3
6
K Fe CN (

2 4
dilute H SO
brownish-yellow solution
4
ZnSO
White precipitate + brownish-yellow filtrate
colourless solution
2 2 3
Na S O

(A) The first reaction is a redox reaction.
(B) White precipitate is ( )
3
6
2
Zn Fe CN (

(C) Addition of filtrate to starch solution gives blue colour.
(D) White precipitate is soluble in NaOH solution.

Sol. (A, C, D)

KI(aq) +
( ) ( )
3
6
K Fe CN aq (

brownish-yellow
( )
4
+ZnSO aq
White ppt
colourless
2 2 3
Na S O
( ) ( ) ( ) Kl aq K Fe CN aq
6 3 4
(
+

( ) ( ) K Zn Fe CN Kl aq
6 2 3 3
2
(
+

( ) ( )
2
I aq S O aq
4 6

+
OR
( )
{ }
K Zn Fe CN
6 2
(

(D) with NaOH
( ) ( ) ( ) ( ) ( )
4 2
4 6
K Zn Fe CN NaOH Zn OH aq Fe CN aq
6
2

(
( ( + + +

Iit Jee 2012 Paper 2 Solutions

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MAHESH JANMANCHI IIT JEE 2012 PAPER 2

Visit us at http://www.chemistrycrest.com/ Page 1

= ( where M is the mol wt of solvent)

for the given cell is (take 1 F = 96500

- Hydrochlorite ion, anion of HOCl

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