IITJEE PAPER 1 Solutions

Sr i Chai t anya I I T Ac ademy., A.P.
IIT-JEE 2012
Paper - 1 along with Key
& Solutions
Admin Off : Plot No : 304, Kasetty Heights.
Ayyappa Society - Madhapur , Pin : 500081
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C Question Paper Format
The questions paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part consist of three sections.
12. Section I contains 10 multiple choice questions. Each question has four choices. (A), (B), (C) and (D) out of
which ONLY ONE is correct.
13. Section II contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE or MORE are correct.
14. Section III contains 5 questions. The answer to each question is a single digit integer, ranging from 0 to 9 (both
inclusive).
D.Marking Scheme
15. For each question in Section I, you will be awarded 3 marks if you darken the bubble corresponding to the correct
answer ONLY and zero marks if no bubbles are darkened. In all ohter cases, minus one (1) mark will be awarded
in this section.
16. For each question in Section II, you will be awareded 4 marks if you darken ALL the bubble(s) corresponding to the
correct answer(s) ONLY. In all other cases zero (0) marks will be awarded. No negative marks will be awarded for
incorrect answers in this section.
17. For each question in Section III, you will be awarded 4 marks if you darken the bubble corresponding to the correct
answer ONLY. In all other cases zero (0) will be awarded. No negative marks will be awarded for incorrect answers
in this section.
Sri Chaitanya IIT Academy PAPER-1 KEY & SOLUTIONS
Sr i Chai t anya I I T Ac ademy
Admin Of f : Plot No : 304, Kasetty Heights.
# 3
PHYSICS
SECTION I
( SINGLE CORRECT CHOICE TYPE )
Thi s section cont ains 10 multi ple choicse questions. Each question has 4 choices (A), (B), (C) and (D) f or its
answer, out of which ONLY ONE is cor rect
1. A small block is connected to one end of massless spring of unstretched length 4.9 m. The
other end of the spring (see the figure) is fixed. The system lies on a horizontal frictionless
surface. The block is stretched by 0.2 m and released from rest at t= 0. It then executes
simple harmonic motion with angular frequency
/
3
rad s
t
e =
. Simultaneously at t = 0, a
small pebble is projected with speed v from point P at an angle of 45
0
as shown in the figure.
Point P is at a horizontal distance to 10 m from O. If the pebble hits the block at t = 1s, the
value of v is (take g = 10 m/s
2
)
a) 50 / m s b) 51 / m s c) 52 / m s d) 53 / m s
Ans : A
Equation of SHM cos y A t e =
At
1 t =

0.2cos (1) 0.2cos 0.1
3
y m
t
e = = =
Block is at a distance 5m
Range of pebble is R =5m

2
2
sin90
50
10
V
R V
= =
50 / V m s =
# 4
2. In the determination of Youngs modulus
2
4MLg
Y
ld t
| |
=
|
\ .
by using Searles method, a wire of
length L = 2 m and diameter d = 0.5 mm is used. For a load M = 2.5 kg, an extension
l = 0.25 mm in the length of the wire is observed. Quantities d and l are measured using a
screw gauge and a micrometer, respectively. They have the same pitch of 0.5 mm. The num-
ber of divisions on their circular scale is 100. The contributions to the maximum probable
error of the Y measurement.
a) due to the errors in the measurements of d and l are the same
b) due to the error in the measurement of d is twice that due to the error in the measurement of l.
c) due to the error in the measurement of l is twice that due to the error in the measurement of d.
d) due to the error in the measurement of d is four times that due to the error in the measure-
ment of l.
Ans :A
2
2 2 4
d d
d
d v
| | A A
| |
= = A
| |
\ .
\ .
4
0.25
l l
l
l
A A
= = A
3. A small mass m is attached to a massless string whose other end is fixed at P as shown in the
figure. The mass is undergoing circular motion in the xy plane with centre at O and constant
angular speed
e
. If the angular momentum of the system, calculated about O and P are de-
noted by
0
L
and
P
L
respectively, then
# 5
a)
0
L
and
P
L
do not vary with time

b)
0
L
varies with time while

P
L
remains constant
c)
0
L
remains constant while

P
L
varies with time

d)
0
L
and
P
L
both vary with time

Ans :C
Torque about O is zero angular momentum will be constant about O. Torque about P is non
zero. Angular momentum about P varies with time.
( )
0
L m r v =
( )
P
L m OP v =
direction of
P
L
changes with
OP
and
P
L OP
4. Youngs double slit experiment is carried out by using green, red and blue light, one color at
a time. The fringe widths recorded are ,
G R
| | and
B
| , respectively. Then
a)
G B R
| | | > > b)
B G R
| | | > > c)
R B G
| | | > > d)
R G B
| | | > >
Ans :D
D
d
| | =
R G B
> >
R G B
| | | > >
# 6
5. Consider a thin spherical shell of radius R with its centre at the origin, carrying uniform
positive surface charge density. The variation of the magnitude of the electric field ( ) E r
and the electric potential V(r) with the distance r from the centre, is best represented by
which graph ?
a) b)
c) d)
Ans : D
From centre to surface E = 0, then
1
E
r
From centre to surface V = k, then

1
V
r
6. A biconvex lens is formed with two thin planoconvex lenses as shown in the figure. Re-
fractive index n of the first lens is 1.5 and that of the second lens is 1.2. Both the curved
surfaces are of the same radius of curvature R = 14 cm. For this biconvex lens, for an object
distance of 40 cm, the image distance will be
a) 280. 0 cm b) 40.0 cm c) 21. 5 cm d) 13.3 cm
# 7
Ans :B
1 2
1 1 1
F f f
= +
=
( ) ( )
1 2
1 1
R
+
=
0.5 0.2 0.7 1
14 14 20
+
= =
20 F cm =
40 R cm =
1 1 1 1 1 1 1 1 1 2 1 1
20 40 20 40 40 40 F v u v v
= = + = = =
40 v cm =
7. Two large vertical and parallel metal plates having as separation of 1 cm are connected to a
DC voltage source of potential difference X. A proton is released at rest midway between the
two plates. It is found to move at 45
0
to the vertical JUST after release. Then X is nearly
a)
5
1 10 V
b)
7
1 10 V
c)
9
1 10 V
d)
10
1 10 V
Ans :C
mg Eq =
45
mg
Eq
p
Vq
d
=
( )
9
10
mgd
V V approx
q
= =
8. Three very large plates of same area are kept parallel and close to each other. They are con-
sidered as ideal black surfaces and have very high thermal conductivity. The first and third
plates are maintained at temperatures 2T and 3T respectively. The temperature of the middle
(i.e. second) plate under steady state condition is
a)
1
4
65
2
T
| |
|
\ .
b)
1
4
97
4
T
| |
|
\ .
c)
1
4
97
2
T
| |
|
\ .
d)
( )
1
4
97 T
Ans : C
( ) ( )
4 4 4 4
1 2 2 3
A T T A T T o o =
( ) ( )
1
4
4 4
4 4
2 2 2
97
2 3
2
T T T T T T
| |
= =
|
\ .
# 8
9. A thin uniform rod, pivoted at O, is rotating in the horizontal plane with constant angular
speed
e
, as shown in the figure. At time t = 0, a small insect starts from O and moves with
constant speed v with respect to the rod towards the other end. It reaches the end of the rod at
t = T and stops. The angular speed of the system remains
e
throughout. The magnitude of the
torque of the torque ( )
t
on the system about O, as a function of time is best represented by

which plot ?
a) b)
c) d)
Ans : B
| |
dL d dI
I
dt dt dt
t e e = = =
constant
rod
I =
2
red
d
I mr
dt
e ( +

=
0 2
dr
m r
dt
e
| |
+
|
\ .

v
r = vt
2
2 2 mr v m v t e e = =
t t
when the insect reaches the end it stops v = 0
0 t =
# 9
10. A mixture of 2 moles of helium gas (atomic mass = 4amu) and 1 mole of argon gas (atomic
mass = 40 amu) is kept at 300 K in a container. The ratio of the rms speeds
( )
( )
helium
argon
rms
rms
v
v
| |
|
|
\ .
is
a) 0.32 b) 0.45 c) 2.24 d) 3.16
Ans : D
rms
T
V
M
1 2
2 1
40
10
4
He
Ar
V V M
V V M
= = = =
SECTION II
( MULTIPLE CORRECT ANSWER TYPE)
This section contai ns 5 multiple choicse questions. Each questi on has 4 choi ces (A), (B), (C) and (D) f or its answer,
out of which ONE or More are corr ect.
11. A small block of mass of 0.1 kg lies on a fixed inclined plane PQ which makes an angle
u
with the horizontal. A horizontal force of 1 N acts on the block through its center of mass as
shown in the figure. The block remains stationary if (take
2
10 / g m s = )

a)
0
45 u =
b)
0
45 u >
and a frictional force acts on the block towards P.
c)
0
45 u >
and a frictional force acts on the block towards Q.
d)
0
45 u <
Ans : A (or) AC
# 10
1cos sin mg u u =
45 u =
when
45 u >
friction force is upwards
If friction force sufficient block will be in state of rest
12. Consider the motion of a positive point charge in a region where there are simulataneous
uniform electric and magnetic fields
0
E E j =
and
0
B B j =
. At time t = 0 , this charge has

velcoity
v
in the x y plane, making an angle

u
with the x axis. Which of the following
option(s) is(are) correct for time t > 0 ?
a) If
0
0 u =
, the charge moves in a circular path in the x z plane
b) If
0
0 u =
, the charge undergoes helical motion with constant pitch along the y axis.
c) If
0
10 u =
, the charge undergoes helical motion with its pitch increasing with time, along the y axis
d) If
0
90 u =
, the charge undergoes linear but accelerated motion along the yaxis
Ans :C,D
when
90 u =
0
m
F =
when
10 u =
path is helical and with increasing pitch.
# 11
13. For the resistance network shown in the figure, choose the correct option(s).
a) The current through PQ is zero b)
1
3 I A =
c) The potential at S is less than that at Q. d)
2
2 I A =
Ans : A,B,C,D
1
12
3
4
I = =
2
12
3
18
I =

2A =
P Q
V V =
S Q
alsoV V =
14. A person blows into open end of a long pipe. A s a result, a high pressure pulse of air
travels down the pipe.When this pulse reaches the other end of the pipe,
a) a high pressure pulse starts travelling up the pipe, if the other end of the pipe is open
b) a low pressure pulse starts travelling up the pipe, if the other end of the pipe is open
c) a low pressure pulse starts travelling up the pipe, if the other end of the pipe is closed
d) a high pressure pulse starts travelling up the pipe, if the other end of the pipe is closed
Ans : B, D
# 12
Reflected pressure pulse
Incident pressure pulse
Open end
At open end pressure should not change pressure wave will get phase change as t
Closed end
At enclosed end pressure wave will get reflected without phase change
15. A cubical region of side a has its centre at the origin. It encloses three fixed point charges,
q at ( ) 0, / 4, 0 , 3 a q + at (0, 0, 0) and q at ( ) 0, / 4, 0 a + . Choose the correct
option(s).
a) The net electric flux crossing the plane
/ 2 x a = +
is equal to the net electric flux crossing
the plane
/ 2 x a =
b) The net electric flux crossing the plane / 2 y a = + is more than the net electric flux crossing
the plane / 2 y a = .
c) The net electric flux crossing the entire region is
0
q
c
.
d) The net electric flux crossing the plane
/ 2 z a = +
the plane
/ 2 x a = +
# 13
Ans : ACD
Net flux passing the plane

2
a
x = +
and
2
a
x =
is same
Net flux through cube is

0
q
c
Flux through plane

2
a
z =
and
2
a
x =
is same
SECTION III
( INTEGER ANSWER TYPE)
This section conta ins 5 questions. The answer to ea ch question is a single digit integer, ranging f rom 0 to 9
(both i nclusive).
16. A lamina is made by removing a small disc of diameter 2R from a bigger disc of uniform
mass density and radius 2R, as shown in the figure. The moment of inertia of this lamina
about axes passing through O and P is
0
I and
P
I , respectively. Both these axes are perpen-
dicular to the plane of the lamina. The ratio
0
P
I
I
to the nearest integer is
Ans : 3
( ) ( ) ( ) ( )
2
2 2 2 2 2
0
1 1
2 2
2 2
I R R R R R R t t t
(
(
= +
(

4 4
3
8
2
R R t t =
4 2
13 13
2 2
R MR t = =
( ) ( )( )
2 2
2 2
1 1
4 2 4 2 5
2 2
P
I M R M R MR M R
( (
= + +
( (

2 2 2
11
8 16
2
MR MR MR
(
= +
(

2 2
11 37
24
2 2
MR MR
(
= =
(

# 14
17. A circular wire loop of radius R is placed in the x - y plane centered at the origin O. A square
loop of side ( ) a a R << having two turns is placed with its center at
3 z R =
along the axis of
the circular wire loop, as shown in figure. The plane of the square loop makes an angle of
45
with respect to the z - axis. If the mutual inductance between the loops is given by
2
0
/ 2
2
p
a
R
,
then the value of p is
Ans : 7
( )
2
2
0
3/ 2
2
2
2 1
4 2
3
iR
B a
i
R R
| t
t
= =
(
+
(

(n = 2)
2
2 2 0 0
9/2
1
2 2 2
a
M R a

= =
18. A cylindrical cavity of diameter a exists inside a cylinder of diameter 2a as shown in the
figure. Both the cylinder and the cavity are infinetely long. A uniform current density J flows
along the length. If the magnitude of the magnetic field at the point P is given by
0
12
N
aJ
,
then the value of N is
# 15
Ans : 5
0
1
2
ja
B

=
2
2 0
0
2
2
3 12
2
2
a
j
ja
B
a a
t
t
| |
|
\ .
= =
| |
|
\ .
1 2 0
1 1
2 12
B B ja
| |
=
|
\ .
0
5
12
ja
=
19. A proton is fired from very far away towards a nucleus with charge 120 Q e = , where e is the
electronic charge. It makes a closest approach of 10 fm to the nucleus. The de Broglie wave-
length (in units of fm) of the proton at its start is:
(take the proton mass, ( )
27
5 / 3 10 ;
p
m kg
=
15
/ 4.2 10 . / H e j S c
= ;
9
0
1
9 10 / ;
4
m F
tc
=

15
1 10 fm m
= )
Ans : 7
2 2
9
15
120
9 10
10 10 2
p
e P
m
9 2 27
2
15
5
9 10 120 2 10
3
10 10
e
P
| |

|
\ .
=
17
15
3 2 10 3 2
10 10
e e
P

= =
15
4.2 10
6
10
h
p
= =
# 16
20. An infinitely long solid cylinder of radius R has a uniform volume charge density . It has a
spherical cavity of radius R/2 with its centre on the axis on the cylinder, as shown in the
figure. The magnitude of the electric field at the point P, which is at the distance 2R from the
axis of the cylinder, is given by the expression
0
23
16
R
k
c
. The value of k is
Ans: 6
( )
3
2
2
4
2
3 8
2
2
p
R
K
k R
E
R
R
t
t
=
4 1
1
3 32
p
E k R t
(
=
(

0
1 1
1
4 24
R t
tc
(
=
(

0
23
4 24
p
R
E

c
| |
=
|
\ .
24 4
6
16
K

= =
# 17
CHEMISRY
SECTION I
This sect ion contai ns 1 0 multi ple choicse q uest ions. Each questi on has 4 choi ces (A), (B), (C) and (D) f or i ts
21. The number of aldol reaction(s) that occurs in the given transformation is
. .
3
4
conc aq NaOH
CH CHO CHO +
OH
OH
HO
OH
a) 1 b) 2 c) 3 d) 4
Ans : C
3 2
OH
CH CHO CH CHO
2 2 2
H C H CH CHO O CH CH CHO +
O
H
2 2
OH
CH CHO HO CH CH CHO H - C - H
O
H
' HCHO Cannizaro s
NaOH reaction
CH CH
CHO
OH
OH
CHO
HO
OH
OH OH OH
OH HO
Number of aldol reaction = 3
# 18
22. A compound M
P
X
P
has cubic close packing (ccp) arrangement of X. Its unit cell structure is
shown below. The empirical formula of the compound is
a) MX b) MX
2
c) M
2
X d) M
5
X
14
Ans : B
Corner
Face center
1
6 3
2
=
1
8 1
8
=
4
X :
Edge centre
Body center
1 1 1 =
1
4 1
4
=
2
M :
4 2
X M
4 2
X M
2
MX
23. The carbonyl functional group (COOH) is present in
a) picric acid b) barbituric acid c) ascorbic acid d) aspirin
Ans : D
Acetyle salicylic acid = Asprin
COOH
OCOCH
3
# 19
24. The colour of light absorbed by an aqueous solution of CuSO
4
is :
a) organe-red b) blue-green c) yellow d) violet
Ans : A
Orange - red is absorbed
Based up on Munshell wagon wheel
V
B
G
O
R
Y
25. The number of optically active products obtained from the complete ozonolysis of the
given compound is :
CH
3
- CH = CH - C - CH = CH - C - CH = CH - CH
3
H
CH
3
H CH
3
a) 0 b) 1 c) 2 d) 4
Ans : A
As the ozonolysis products do not have chiral centres, number of optically active products = 0
26. As per IUPAC nomenclautre, the name of the complex ( ) ( )
2 3 3
4 2
Co H O NH Cl (

is
a) Tetraaqudiaminecobalt (III) chloride b) Tetraaquadiamminecobalt (III) chloride
c) Diammineteraaquacobalt (III) chloride d) Diamminetetraaquacobalt (III) chloride
Ans : D
( ) ( )
2 3 3
4 2
Co H O NH Cl (

Diammineteraaquacobalt (III) chloride
27. Which ordering of compound is according to the decreasing order of the oxidation state of
nitrogen ?
a)
3 4 2
, , , HNO NO NH Cl N b)
3 2 4
, , , HNO NO N NH Cl
c)
3 4 2
, , , HNO NH Cl NO N d)
3 4 2
, , , NO HNO NH Cl N
# 20
Ans : B
3
5 HNO +
2 NO +
2
0 N
4
3 NH Cl
Decreasing order of
O -S =
3 2 4
28. For one mole of a van der Waals gas when b = 0 and T = 300 K, the PV vs. I/V plot is shown
below. The value of the van der Waals constant a (atm. liter
2
mol
2
) is
a) 1.0 b) 4.5 c) 1.5 d) 3.0
Ans : C
( )
2
2
n a
P v nb nRT
v
| |
+ =
|
\ .
n = 1, b = 0
( )
2
q
p v b RT
v
| |
+ =
|
\ .
a
pv RT
v
+ =
a
pv RT
v
=
( )
2 2
21.6 20.1
1.5 .
3 2
y c mx m a slop atm t mole
= + = = = =

# 21
29. In allene ( )
3 4
C H , the type(s) of hybridisation of the carbon atoms is (are)
a) sp and sp
3
b) sp and sp
2
c) only sp
2
d) sp
2
and sp
3
Ans : B
2 2
H C C CH = =
2 2
sp sp sp
30. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [a
0
is Bohr
radius]
a)
2
2 2
0
4
h
ma t
b)
2
2 2
0
16
h
ma t
c)
2
2 2
0
32
h
ma t
d)
2
2 2
0
64
h
ma t
Ans : C
mvr=
2
nh
t
v=
2
nh
mr t
for second Bohrs orbit
2
r =4
0
a
V=
0
4
h
ma t
2
2
2 2 2
0
16
h
V
m a t
=
K.E
2
2
2 2
0
1
2 32
h
mv
ma t
= =
# 22
SECTION II
31. Which of the following molecules, in prue form, is (are) unstable at room temperature ?
a) b) c)
O
d)
O
Ans : BC
cyclobutadiene and cyclopentadien are anti aromatic.
32. Which of the following hydrogen halides react(s) with ( )
3
AgNO aq to give a precipitate that
dissolves in ( )
2 2 3
Na S O aq ?
a) HCl b) HF c) HBr d) HI
Ans : ACD
3 3
AgNO HX AgX HNO + +
aq aq
( )
2 2 3 3 2 3
2
2 AgX Na S O Na Ag S O NaX ( + +

aq
aq
s
AgF is soluble
33. Choose the correct reason(s) for the stability of the lyophobic colloidal particles >
a) Preferential adsorption of ions on their surface from the solution
b) Preferential adsorption of solvent of their surface the solution
c) Attraction between different particles having opposite charges on their surface
d) Potential difference between the fixed layer and the diffused layer of opposite charges
around the coolidal particles
Ans : AD
# 23
34. For an ideal gas, consider only P-V work in going from an
i ni ti al state X to the f i nal state Z. The can be reached by
either of the two paths shown in the figure. Which of the
following choice(s) is (are) correct ? [Take
S A
as change
in entropy and w as work done]
a)
x z x y y z
S S S

A = A + A b)
x z x y y z
W w w

= +
c)
x y z x y
w w

= d)
x y z x y
S S

A = A
Ans : AC
Based up on the given graph
x y x y y z
S S S

A = A + A
x y z x y
W W

=
35. Identify the binary mixtrue(s) that can be separated into individual compounds, by differen-
tial extraction,a s shown in the given scheme.
a)
6 5 6 5
C H OH and C H COOH b)
6 5 6 5 2
C H COOH and C H CH OH
c)
6 5 2 6 5
C H CH OH and C H OH d)
6 5 2 6 5 2
C H CH OH and C H CH COOH
Ans : BD
Benzyl alcohol is insoluble in both NaOH and
3
NaHCO ,
# 24
SECTION III
(both i nclusive).
36. When the following aldohexose exists in its B-configuration, the total number
C
CH
2
CHOH
CHOH
CHO
CH
2
OH
OH H
of stereoisomrs in its pyranose form is :
Ans : 8
As the configration at C-5 is fixed, (D-configration), then only 4 stero isomers are possible
solution
37. 29.2% (w/w) HCl stock solution has a densityh of 1.25 g mL
1
. The molecular weight of HCl
is 36.5 g mol
1
. The volume (mL) of stock solution required to prepare a 200 mL solution of
0.4 M HCl is :
Ans : 8
Molarity of stock solution =
10 d x
GMW

=
10 1.25 29.2
36.5

=10M

1 1 2 2
1
1
10 200 0.4
8 ( )
V M V M
V
V ML approx
=
=
=
38. The periodic table consists of 18 groups. An isotope of copper, on bombardment with pro-
tons, undergoes a nuclear reaction yielding element X as shown below. To which
group,element X belongs int he periodic table ?
Ans : 8
63 1 1 4 1 52
29 1 0 2 1 26
6 2 CU H n He H X + + + +
26
Fe 8 th group
# 25
39. An organic compound undergoes first-order decomposition. The time taken for its decom-
position to 1/8 and 1/10 of its initial concentration are t
1/8
and t
1/10
respectively. What is the
Ans : 9
1
8
1
10
2.303
log
8
2.303
log
10
a
t
a
k
a
t
a
k
=
=
1
8
1
10
log8
log10
t
t
=
1
8
1
10
3log 2
t
t
=
1
8
1
10
10 9
t
t
=
40. The substituents R
1
and R
2
for nine peptides are listed in the table given below. How many of
these peptides are positively charged at pH = 7.0 ?
Ans : 4
At pH below pI(Isoelectric point) Aminoacid exist as Cation. As BasicAminoacids of pH
around 9-8, these are expected to exists as cation of pH=7IV,VI,VIII,IX.
# 26
MATHEMATICS
SECTION I
This sect ion cont a ins 1 0 mult ip le choice q uest ions. Ea ch q uest ion ha s 4 choices (A), (B), (C) a nd (D) f or it s
a nswer, out of which O NLY O NE is cor r ect
41. Let z be a complex number such that the imaginary part of z is nonzero and and
2
1 a z z = + +
is real. Then a connot take the value
a) 1 b)
1
3
c)
1
2
d)
3
4
Ans. D
Let Z x iy = + ( ) 0 y =
2
1 a z z = + +
becomes
( ) ( )
2
1 a x iy x iy = + + + +
( ) ( )
2 2
1 2 0 x y x i xy y a i + + + + = +
Comparing real & imaginary parts
2 2
1 x y x a + + = (1)
2 0 xy y + = (2)
From (2)
1
2
x

=
as 0 y =
Put value of x in (1)
2
2
1 1
1
2 2
y a
| |
+ =
|
\ .
2
1 1
4 2
y a + =
2
3
0
4
y a = >
3
4
a <
# 27
42. If
2
1
lim 4
1
x
x x
ax b
x
| | + +
=
|
+
\ .
, then
a) a = 1, b = 4 b) a = 1, b = 4 c) a = 2, b = 3 d) a = 2, b = 3
Ans. B
2
1
lim 4
1
x
x x
ax b
x
+ +
=
+
( ) ( )
2
1 1 1
4
1
x
x a x a b b
lim
x
+ +
=
+
For existense of limit coefficient of
2
0 x =
1 a = 0
a = 1
( ) 1 1
lim 4
1
x
x a b b
x
+
=
+
1 4 a b =
b = 4
43. Let
ij
P a ( =

be a
3 3
matrix and let
ij
Q b ( =

, where 2
i j
ij ij
b a
+
= for 1 , 3 i j s s . If the deter-
minant of P is 2, then the determinant of the matrix Q is
a) 2
10
b) 2
11
c) 2
12
d) 2
13
Ans. D
as 2
i j
ij ij
b a
+
=
11 11 12 12 13 13
4 , 8 , 16 b a b a b a = = =
21 2 22 22 23 23
8 , 16 , 32 b a b a b a = = =
31 31 32 32 33 33
16 , 32 , 64 b a b a b a = = =
11 12 13
21 22 23
31 32 33
2
a a a
A a a a
a a a
(
(
= =
(
(

# 28
11 12 13
21 22 23
31 32 33
4 8 16
8 16 32
16 32 64
a a a
B a a a
a a a
(
(
=
(
(

11 12 13
21 22 23
31 32 33
4 8 16 2 2 2
4 4 4
a a a
a a a
a a a
(
(
=
(
(

11 12 13
21 22 23
31 32 33
4 8 16 2 4
a a a
a a a
a a a
(
(
=
(
(

4 8 16 2 4 2 =
13
2 B =
44. The ellipse
2 2
1
: 1
9 4
x y
E + = is inscribed in a rectangle R whose sides are parallel to the coor-
dinates axes. Another ellipse E
2
passing through the point (0, 4) circumscribes the rectangle
R. The eccentricity of the ellipse E
2
is
a)
2
2
b)
3
2
c)
1
2
d)
3
4
Ans. C
Given Ellipse
2 2
1
9 4
x y
+ =
As ellipse is bounded by & x a y b = =
Sides of rectangle are
3 & 2 x y = =
( ) ( ) 3, 2 , 3, 2 C D
D
(0,2)
(3,0)
(0,-2)
(-3,0)
A
B
C
( ) ( ) 3, 2 , 3, 2 A B
As new ellipse
Circumscribe the rectangle & passes through (0 ,4).
# 29
Let new ellipse is
2 2
2 2
1
x y
a b
+ =
Passes through ( )
2
2
16
0,4 1 16 b
b
= =
Passes through ( ) 3, 2
2
9 4
1
16 a
+ =
2
12 a =
So, Vertical ellipse
2 2
1
12 16
x y
+ =
( )
2 2 2
1 a b e =
( )
2
12 16 1 e =
2
12 1
1
16 4
e = =
1
2
e =
45. The function | | | | : 0, 3 1, 29 f , defined by ( )
3 2
2 15 36 1 f x x x x = + + is
a) one-one and onto b) onto but not one-one
c) one-one but not onto d) neither one-one nor onto
Ans. B
| | | | : 0, 3 1, 29 f
( )
3 2
2 15 36 1 f x x x x = + +
( )
' 2
6 30 36 f x x x = +
( )( ) 6 2 3 x x =
( ) ( )
''
6 2 5 f x x =
2 x =
is pt of maxima.
# 30
3 x =
is pt of minima.
( ) & 2 29 0 f = >
( ) 3 0 f >
so curve is
n
f is not one one
2 3
Min value ( ) 0 1 f = =
Max value ( ) 2 29 f = =
so
n
f is Onto.
46. The locus of the mid-point of the chord of contact of tangents drawn from points lying on
the straight line 4 5 20 x y = to the circle
2 2
9 x y + = is
a) ( )
2 2
20 36 45 0 x y x y + + = b) ( )
2 2
20 36 45 0 x y x y + + =
c) ( )
2 2
36 20 45 0 x y x y + + = d) ( )
2 2
36 20 45 0 x y x y + + =
Ans. A
Let ( ) ( )
1 1
, & , P h k Q x y
As P lies of 4x-5y=20
4 20
,
5
h
P h
| |
|
\ .
P
A
B
Q
Equation of chord of contact
1
0 AB S =
4 20
9
5
h
xh y
| |
+ =
|
\ .
( ) 5 4 20 45 xh y h + = ------------------(1)
Equation of chord AB whose mid point is ( )
1 1
, Q x y
# 31
2 2
1 1 1 1
xx yy x y + = + ---------------(2)
Compare (1) & (2)
2 2
1 1 1 1
5 4 20 45 h h
x y x y
= =
+
1 1
2 2 2 2
1 1 1 1
9 45
&4 20
x y
h h
x y x y
= =
+ +
On eliminating h
1 1
2 2 2 2
1 1 1 1
49 45
20
x y
x y x y
=
+ +
( )
2 2
1 1 1 1
20 36 45 x y x y + =
Locus is
( )
2 2
20 36 45 0 x y x y + + =
47. The point P is the intersection of the straight line joining the points Q (2, 3, 5) and
R (1, 1, 4) with the plane 5 4 1 x y z = . If S is the foot of the perpendicular drawn from the
point T (2, 1, 4) to QR, then the length of the line segement PS is
a)
1
2
b)
2
c) 2 d)
2 2
Ans. A
Equation of
1 1 4
1 4 1
x y z
QR
+
= = =
Drs of ( ) 1, 4,1 QR
Co-ordinates of ( ) 1 , 1 4 , 4 P + + +
As P is point of Intersection of QR & given plane, so
( ) ( ) ( ) 5 1 4 1 4 4 1 + + + =
1
3
=
T(2,1,4)
Q
S R
# 32
4 1 13
, ,
3 3 3
P
| |
|
\ .
Let ( ) 1 , 1 4 , 4 S + + +
Drs of ( ) 1, 4 2, TS
TS QR So,
( ) ( ) 1 1 4 4 2 0 + + =
1
2
=
3 9
,1,
2 2
S
| |
|
\ .
2 2 2
4 3 1 13 9
1
3 2 3 3 2
PS
| | | | | |
= + +
| | |
\ . \ . \ .
1
2
=
48. Let
( )
2
cos , 0
0, 0
x x
f x x
x
t
=
,
x IR e
, then f is
a) differentiable both at x = 0 and at x = 2
b) differentiable at x = 0 but not differentiable at x = 2
c) not differentiable at x = 0 but differentiable at x = 2
d) differentiable neither at x = 0 nor at x = 2
Ans. B
( )
2
cos ; 0
0 ; 0
x x
f x x
x
t
=
At x=0
# 33
( ) ( )
2
0 0
cos 0
0 0
lim lim
h h
h
f h f
h
RHD
h h
t

+
=
0
lim cos 0
h
h
h
t
| |
= =
|
\ .
( ) ( )
2
0 0
cos 0
0 0
lim lim
h h
h
f h f h
LHD
h h
t

| |

|

\ .
=

0
lim cos 0
h
h
h
t
| | | |
= =
| |
\ . \ .
Differentiable at x=0
At x=2
( ) ( )
( )
2
0 0
2 cos 4 cos
2 2
2 2
lim lim
h h
h
f h f
h
RHD
h h
t t

+
+
+
= =
( ) ( )
( )
2
0 0
2 cos 4 cos
2 2
2 2
lim lim
h h
h
f h f
h
LHD
h h
t t

= =

Not Differentiable at x=2.

49. The total number of ways in which 5 balls of different colours can be distributed among 3
persons so that each person gets at least one ball is
a) 75 b) 150 c) 210 d) 243
Ans. B
5 Balls to 3 persons, so that all persons get atleast one ball.
Case-I
Total ways 2 2 1
2
1
2
1 2 2
( )
5 3 1
2 2 1
3 C C C =
# 34
10 3 1 3 90 = =
Case-II
Total ways
( )
5 2 1
3 1 1
3 C C C =
1
1
1
1
3
3
1
3
1
10 2 1 3 60 = =
Total ways = 90 + 60 = 150.

50. The integral
( )
2
9/ 2
sec
sec tan
x
dx
x x +
} equals (for some arbitrary constant K)
a)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ +
`
) +
b)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ +
`
) +
c)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ + +
`
) +
d)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ + +
`
) +
Ans. C
( )
9
2
sec
sec tan
x
dx
x x +
}
Let
sec tan x x t + =
-------------(1)
So, ( )
2
sec tan sec x x x dx dt + =
sec
dt
x dx
t
=
------------(2)
# 35
1
sec tan x x
t
=
----------(3)
From (1) & (3)
1 1
sec
2
x t
t
| |
= +
|
\ .
So, Integral becomes
( )
9
2
sec .sec
sec tan
x x
dx
x x +
}
9
2
1 1
2
dt
t
t
t
t
| |
+
|
\ .
}
2
13
2
1 1
2
t
dt
t
+
}
9 13
2 2
1
2
t dt t dt

(
= +
(

} }
7 11
2 2
1
7 11
2
2 2
t t
K

(
(
= + +
(

7 11
2 2
7 11
t t
K

= + +

( ) ( )
7 11
2 2
1 1
11 sec tan 7 sec tan x x x x
=
+ +
( )
( )
2
11
2
1 1 1
sec tan
11 7
sec tan
x x K
x x
| |
= + + +
|
\ .
+
# 36
SECTION II
( MULTIPLE CORRECT CHOICE TYPE )
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct
51. A ship is fitted with three engines E
1
, E
2
and E
3
. The engines function independently of each
other with respective probabilities
1 1
,
2 4
and
1
4
. For the ship to be operational at least two of
its engines must function. Let X denote the event that the ship is operational and let X
1
, X
2
and X
3

denote respectively the events that the engines E
1
, E
2
and E
3
are functioning. Which of
the following is (are) true ?
a)
1
3
|
16
c
P x X ( =

b) P [Exactly two engines of the ship are functioning | X]
7
8
=
c) | |
2
5
|
16
P X X =
d) | |
1
7
|
16
P X X =
Ans. B,D
A)
( )
( )
1
1 1 1
1
2 4 4
1
8
4
c
P X X
P X

= =
( )
1 1 3 1 1 1 1
2 2
2 4 4 2 4 4 4
P X
| | | |
= + =
| |
\ . \ .
B)
| |
1 1 3 1 1 1
2
7 2 4 4 2 4 4
/
1
8
4
P Exactly twoengines of the ship are functioning X
| |
+
|
\ .
= =
C)
( )
| |
( )
2
2
2
1 1 3 1 1 1
2
5 2 4 4 2 4 4
/
1
8
4
P X X
P X X
P X
| | | |
+
| |
\ . \ .
= = =
D)
( )
| |
( )
1
1
1
1 1 3 1 1 1
2
7 2 4 4 2 4 4
/
1
16
2
P X X
P X X
P X
| |
+
|
\ .
= = =
# 37
52. Tangents are drawn to the hyperbola
2 2
1
9 4
x y
= , parallel to the straight line 2 1 x y = . The
points of contact of the tangents on the hyperbola are
a)
9 1
,
2 2 2
| |
|
\ .
b)
9 1
,
2 2 2
| |

|
\ .
c)
( )
3 3, 2 2 d)
( )
3 3, 2 2
Ans. A, B
2 2
1
9 4
x y
=
Tangent to the hyperbola is of the form
2 y x = +
( )
2
9 4 4 36 4 32 = = =
4 2 =
Tangent is :
2 4 2 0 x y =
Point of contact is
2 2
9 1 9 1
, , , ,
2 2 2 2 2 2
a l b m
n n
| | | | | |
=
| | |
\ . \ . \ .
53. Let S be the area of the region enclosed by
2
x
y e
=
, y = 0, x = 0, and x = 1. Then
a)
1
S
e
>
b)
1
1 S
e
>
c)
1 1
1
4
S
e
| |
s +
|
\ .
d)
1 1 1
1
2 2
S
e
| |
s +
|
\ .
Ans. A, B, D
2
1 1
0 0
1
1
x x
I e dx e dx
e

= > =
} }
1
1 I
e
>
2
1
1
x
e e

s s
2
1 1 1
1
0 0 0
x
e dx e dx dx

s s
} } }
2
1
0
1
x
e dx
e
>
}
# 38
54. If y (x) satisfies the differential equation ' tan 2 sec y y x x x = and y (0) = 0, then
a)
2
4 8 2
y
t t | |
=
|
\ .
b)
2
'
4 18
y
t t | |
=
|
\ .
c)
2
3 9
y
t t | |
=
|
\ .
d)
2
4 2
'
3 3 3 3
y
t t t | |
= +
|
\ .
Ans. A,D
tan 2 sec
dy
y x x x
dx
=
tan
. cos
dx
I F e x
}
= =
General solution is ( ) ( ) cos 2 sec cos y x x x x dx
}
2
x c = +
2
sec sec y x x c x = +
( ) 0, 0
0 0 0 c c = + =
.
2
sec y x x =
( )
2
2
4 16
y
t t | |
=
|
\ .
2
8 2
t
=
2
2
3 9
y
t t | |
=
|
\ .
2
sec tan 2 sec
dy
x x x x x
dx
= +
.
( )
2
1
2 3 2 2
3 9 3
y
t t t | | | |
= +
| |
\ . \ .
2
2 4
3 3 3
t t
= +
# 39
55. Let
u
, | | 0, 2 | t e be such that
( )
2
2cos 1 sin sin tan cot cos 1
2 2
u u
u | u |
| |
= +
|
\ .
,
( ) tan 2 0 t u > and
3
1 sin
2
u < < .
Then | cannot satisfy
a)
0
2
t
| < <
b)
4
2 3
t t
| < <
c)
4 3
3 2
t t
| < <
d)
3
2
2
t
| t < <
Ans. A, C, D
( )
3
tan 2 0, 1 sin
2
t u u > < <
3 5 1
, 0 cos
2 3 2
t t
u u
| |
e < <
|
\ .
______ (1)
( ) ( )
2
2cos 1 sin sin tan / 2 cot / 2 cos 1 u | u u u | = +
( )
1
sin cos
2
u | u + = +
( )
1
sin 1
2
u | < + <
(from (1))
13 17
6 6
t t
u | < + <
2 7
3 6
t t
| < <
(from (1))
cannot satisfied by A, C, D
# 40
SECTION III
This section contains 5 questions . The answer to each of the questions is a single digit integer, ranging from 0 to
9. The appropriate bubbles below the respective question numbers in the ORS have to be darkened.
56. Let p (x) be a real polynomial of least degree which has a local maximum at x = 1 and a local
minimum at x =3. If p (1) = 6 and p (3) = 2, then
( ) ' 0 p
is
Ans. 9
( )
3 2
P x ax bx cx d = + + +
( ) 1 6 6 P a b c d = + + + =
( ) 3 2 27 9 3 2 P a b c d = + + + =
( )
1
1 0 3 2 0 P a b c = + + =
( )
1
3 0 27 6 0 P a b c = + + =
1, 6, 9 a b c = = =
( )
1 2
3 2 P x ax bx c = + +
( )
1
0 9 P c = =
57. If
, a b
and
c
are unit vectors satisfying

2 2
2
9 a b b c c a + + =

,then 2 5 5 a b c + +

is\
Ans. 3
sol. 1 a b c = = =

2 2
2
9 a b b c c a + + =

3
.
2
a b b c c a

+ + =
( )
3 2 . . 0 a b b c c a + + + =

2
2 2
2 . . . 0 a b c a b b c c a + + + + + =

2
0 a b c + + =
# 41

0 a b c + + =
(1)
Taking dot product with (1) by , & a b c
then
1 1 1
. , . , .
2 2 2
a b b c c a

= = =
2 5 5 3 a b c + + =
58. The value of
3
2
1 1 1 1
6 log 4 4 4 ...
3 2 3 2 3 2 3 2
| |
|
+
|
\ .
is
Ans. 4
sol.
1
4
3 2
x x =
3 2 4 x x =
squaring on both sides
2
18 4 x x =
2
18 4 0 x x + =
2
18 9 8 4 0 x x x + =
( ) ( ) 9 2 1 4 2 1 0 x x x + + = .
( )( ) 2 1 9 4 0 x x + =
1 4
,
2 9
x =
4
9
x =
( ) 0 x >
Required answer is
2
3/ 2
3
6 log
2
| |
+
|
\ .
= 6 2
= 4
59. Let S be the focus of the parabola
2
8 y x = and let PQ be the common chord of the circle
2 2
2 4 0 x y x y + = and the given parabola. The area of the triangle PQS is
Ans. 4
# 42
sol.
P
Q
S
(0, 0)
(2,4)
(2, 0)
2
(0,4)
2
8 2 4 2 0 x x x x + =
( ) ( ) 0, 2 0, 0 , 2, 4 x P Q = = =
area of SPQ A
=
1
2 4
2

= 4
60. Let : f IR IR be defined as ( )
2
1 f x x x = + . The total number of points at which f attains
either a local maximum or a local minimum is
Ans. 5
sol. ( )
2
1, 1 f x x x x = + s

2
1 , 1 0 x x x = + < <

2
1 , 0 1 x x x = + s <

2
1, 1 x x x = + >
( ) ' 2 1, 1 f x x x = <
2 1, 1 0 x x = < <
0
-1 1
x
y
1 2 , 0 1 x x = < <
1 2 , 1 x x = + >
differentiable at
1 1
,
2 2
x =
,
not differentiable at 1, 0, 1
The number of points = 5
IIT-JEE 2012
& Solutions
INSTRUCTIONS
A. General
invigilators.
of this booklet.
inclusive).
D.Marking Scheme
in this section.
in this section.
# 3
PHYSICS
SECTION I
/
3
rad s
t
e =
0
2
)
a) 50 / m s b) 51 / m s c) 52 / m s d) 53 / m s
Ans : A
At
1 t =

0.2cos (1) 0.2cos 0.1
3
y m
t
e = = =

2
2
sin90
50
10
V
R V
= =
50 / V m s =
# 4
2
4MLg
Y
ld t
| |
=
|
\ .
ment of l.
Ans :A
2
2 2 4
d d
d
d v
| | A A
| |
= = A
| |
\ .
\ .
4
0.25
l l
l
l
A A
= = A
angular speed
e
noted by
0
L
and
P
L
respectively, then
# 5
a)
0
L
and
P
L

b)
0
L

P
L
remains constant
c)
0
L

P
L
varies with time

d)
0
L
and
P
L
both vary with time

Ans :C
( )
0
L m r v =
( )
P
L m OP v =
direction of
P
L
changes with
OP
and
P
L OP
G R
| | and
B
a)
G B R
| | | > > b)
B G R
| | | > > c)
R B G
| | | > > d)
R G B
| | | > >
Ans :D
D
d
| | =
R G B
> >
R G B
| | | > >
# 6
which graph ?
a) b)
c) d)
Ans : D
1
E
r

1
V
r
a) 280. 0 cm b) 40.0 cm c) 21. 5 cm d) 13.3 cm
# 7
Ans :B
1 2
1 1 1
F f f
= +
=
( ) ( )
1 2
1 1
R
+
=
0.5 0.2 0.7 1
14 14 20
+
= =
20 F cm =
40 R cm =
1 1 1 1 1 1 1 1 1 2 1 1
20 40 20 40 40 40 F v u v v
= = + = = =
40 v cm =
0
a)
5
1 10 V
b)
7
1 10 V
c)
9
1 10 V
d)
10
1 10 V
Ans :C
mg Eq =
45
mg
Eq
p
Vq
d
=
( )
9
10
mgd
V V approx
q
= =
a)
1
4
65
2
T
| |
|
\ .
b)
1
4
97
4
T
| |
|
\ .
c)
1
4
97
2
T
| |
|
\ .
d)
( )
1
4
97 T
Ans : C
( ) ( )
4 4 4 4
1 2 2 3
A T T A T T o o =
( ) ( )
1
4
4 4
4 4
2 2 2
97
2 3
2
T T T T T T
| |
= =
|
\ .
# 8
speed
e
e
t

which plot ?
a) b)
c) d)
Ans : B
| |
dL d dI
I
dt dt dt
t e e = = =
constant
rod
I =
2
red
d
I mr
dt
e ( +

=
0 2
dr
m r
dt
e
| |
+
|
\ .

v
r = vt
2
2 2 mr v m v t e e = =
t t
0 t =
# 9
( )
( )
helium
argon
rms
rms
v
v
| |
|
|
\ .
is
a) 0.32 b) 0.45 c) 2.24 d) 3.16
Ans : D
rms
T
V
M
1 2
2 1
40
10
4
He
Ar
V V M
V V M
= = = =
SECTION II
u
2
10 / g m s = )

a)
0
45 u =
b)
0
45 u >
c)
0
45 u >
d)
0
45 u <
Ans : A (or) AC
# 10
1cos sin mg u u =
45 u =
when
45 u >
0
E E j =
and
0
B B j =

velcoity
v

u
a) If
0
0 u =
b) If
0
0 u =
c) If
0
10 u =
d) If
0
90 u =
Ans :C,D
when
90 u =
0
m
F =
when
10 u =
# 11
1
3 I A =
2
2 I A =
Ans : A,B,C,D
1
12
3
4
I = =
2
12
3
18
I =

2A =
P Q
V V =
S Q
alsoV V =
Ans : B, D
# 12
Open end
Closed end
option(s).
/ 2 x a = +
the plane
/ 2 x a =
0
q
c
.
/ 2 z a = +
the plane
/ 2 x a = +
# 13
Ans : ACD

2
a
x = +
and
2
a
x =
is same

0
q
c
Flux through plane

2
a
z =
and
2
a
x =
is same
SECTION III
(both i nclusive).
0
I and
P
0
P
I
I
Ans : 3
( ) ( ) ( ) ( )
2
2 2 2 2 2
0
1 1
2 2
2 2
I R R R R R R t t t
(
(
= +
(

4 4
3
8
2
R R t t =
4 2
13 13
2 2
R MR t = =
( ) ( )( )
2 2
2 2
1 1
4 2 4 2 5
2 2
P
I M R M R MR M R
( (
= + +
( (

2 2 2
11
8 16
2
MR MR MR
(
= +
(

2 2
11 37
24
2 2
MR MR
(
= =
(

# 14
3 z R =
along the axis of
45
2
0
/ 2
2
p
a
R
,
Ans : 7
( )
2
2
0
3/ 2
2
2
2 1
4 2
3
iR
B a
i
R R
| t
t
= =
(
+
(

(n = 2)
2
2 2 0 0
9/2
1
2 2 2
a
M R a

= =
0
12
N
aJ
,
# 15
Ans : 5
0
1
2
ja
B

=
2
2 0
0
2
2
3 12
2
2
a
j
ja
B
a a
t
t
| |
|
\ .
= =
| |
|
\ .
1 2 0
1 1
2 12
B B ja
| |
=
|
\ .
0
5
12
ja
=
27
5 / 3 10 ;
p
m kg
=
15
/ 4.2 10 . / H e j S c
= ;
9
0
1
9 10 / ;
4
m F
tc
=

15
1 10 fm m
= )
Ans : 7
2 2
9
15
120
9 10
10 10 2
p
e P
m
9 2 27
2
15
5
9 10 120 2 10
3
10 10
e
P
| |

|
\ .
=
17
15
3 2 10 3 2
10 10
e e
P

= =
15
4.2 10
6
10
h
p
= =
# 16
0
23
16
R
k
c
. The value of k is
Ans: 6
( )
3
2
2
4
2
3 8
2
2
p
R
K
k R
E
R
R
t
t
=
4 1
1
3 32
p
E k R t
(
=
(

0
1 1
1
4 24
R t
tc
(
=
(

0
23
4 24
p
R
E

c
| |
=
|
\ .
24 4
6
16
K

= =
# 17
CHEMISRY
SECTION I
. .
3
4
conc aq NaOH
CH CHO CHO +
OH
OH
HO
OH
a) 1 b) 2 c) 3 d) 4
Ans : C
3 2
OH
CH CHO CH CHO
2 2 2
O
H
2 2
OH
O
H
' HCHO Cannizaro s
NaOH reaction
CH CH
CHO
OH
OH
CHO
HO
OH
OH OH OH
OH HO
# 18
22. A compound M
P
X
P
a) MX b) MX
2
c) M
2
X d) M
5
X
14
Ans : B
Corner
Face center
1
6 3
2
=
1
8 1
8
=
4
X :
Edge centre
Body center
1 1 1 =
1
4 1
4
=
2
M :
4 2
X M
4 2
X M
2
MX
Ans : D
COOH
OCOCH
3
# 19
4
is :
Ans : A
V
B
G
O
R
Y
given compound is :
CH
3
3
H
CH
3
H CH
3
a) 0 b) 1 c) 2 d) 4
Ans : A
2 3 3
4 2
Co H O NH Cl (

is
Ans : D
( ) ( )
2 3 3
4 2
Co H O NH Cl (

nitrogen ?
a)
3 4 2
3 2 4
c)
3 4 2
3 4 2
# 20
Ans : B
3
5 HNO +
2 NO +
2
0 N
4
3 NH Cl
Decreasing order of
O -S =
3 2 4
2
mol
2
) is
a) 1.0 b) 4.5 c) 1.5 d) 3.0
Ans : C
( )
2
2
n a
P v nb nRT
v
| |
+ =
|
\ .
n = 1, b = 0
( )
2
q
p v b RT
v
| |
+ =
|
\ .
a
pv RT
v
+ =
a
pv RT
v
=
( )
2 2
21.6 20.1
1.5 .
3 2
= + = = = =

# 21
29. In allene ( )
3 4
a) sp and sp
3
b) sp and sp
2
c) only sp
2
d) sp
2
and sp
3
Ans : B
2 2
H C C CH = =
2 2
sp sp sp
0
is Bohr
radius]
a)
2
2 2
0
4
h
ma t
b)
2
2 2
0
16
h
ma t
c)
2
2 2
0
32
h
ma t
d)
2
2 2
0
64
h
ma t
Ans : C
mvr=
2
nh
t
v=
2
nh
mr t
2
r =4
0
a
V=
0
4
h
ma t
2
2
2 2 2
0
16
h
V
m a t
=
K.E
2
2
2 2
0
1
2 32
h
mv
ma t
= =
# 22
SECTION II
a) b) c)
O
d)
O
Ans : BC
3
dissolves in ( )
2 2 3
Na S O aq ?
Ans : ACD
3 3
AgNO HX AgX HNO + +
aq aq
( )
2 2 3 3 2 3
2

aq
aq
s
AgF is soluble
Ans : AD
# 23
S A
as change
a)
x z x y y z
S S S

A = A + A b)
x z x y y z
W w w

= +
c)
x y z x y
w w

= d)
x y z x y
S S

A = A
Ans : AC
x y x y y z
S S S

A = A + A
x y z x y
W W

=
a)
6 5 6 5
6 5 6 5 2
c)
6 5 2 6 5
6 5 2 6 5 2
Ans : BD
3
NaHCO ,
# 24
SECTION III
(both i nclusive).
C
CH
2
CHOH
CHOH
CHO
CH
2
OH
OH H
Ans : 8
solution
1
is 36.5 g mol
1
0.4 M HCl is :
Ans : 8
10 d x
GMW

=
10 1.25 29.2
36.5

=10M

1 1 2 2
1
1
10 200 0.4
8 ( )
V M V M
V
V ML approx
=
=
=
Ans : 8
63 1 1 4 1 52
29 1 0 2 1 26
6 2 CU H n He H X + + + +
26
Fe 8 th group
# 25
1/8
and t
1/10
Ans : 9
1
8
1
10
2.303
log
8
2.303
log
10
a
t
a
k
a
t
a
k
=
=
1
8
1
10
log8
log10
t
t
=
1
8
1
10
3log 2
t
t
=
1
8
1
10
10 9
t
t
=
1
and R
2
Ans : 4
# 26
MATHEMATICS
SECTION I
2
1 a z z = + +
a) 1 b)
1
3
c)
1
2
d)
3
4
Ans. D
Let Z x iy = + ( ) 0 y =
2
1 a z z = + +
becomes
( ) ( )
2
1 a x iy x iy = + + + +
( ) ( )
2 2
1 2 0 x y x i xy y a i + + + + = +
2 2
1 x y x a + + = (1)
2 0 xy y + = (2)
From (2)
1
2
x

=
as 0 y =
2
2
1 1
1
2 2
y a
| |
+ =
|
\ .
2
1 1
4 2
y a + =
2
3
0
4
y a = >
3
4
a <
# 27
42. If
2
1
lim 4
1
x
x x
ax b
x
| | + +
=
|
+
\ .
, then
a) a = 1, b = 4 b) a = 1, b = 4 c) a = 2, b = 3 d) a = 2, b = 3
Ans. B
2
1
lim 4
1
x
x x
ax b
x
+ +
=
+
( ) ( )
2
1 1 1
4
1
x
x a x a b b
lim
x
+ +
=
+
2
0 x =
1 a = 0
a = 1
( ) 1 1
lim 4
1
x
x a b b
x
+
=
+
1 4 a b =
b = 4
43. Let
ij
P a ( =

be a
3 3
matrix and let
ij
Q b ( =

, where 2
i j
ij ij
b a
+
a) 2
10
b) 2
11
c) 2
12
d) 2
13
Ans. D
as 2
i j
ij ij
b a
+
=
11 11 12 12 13 13
4 , 8 , 16 b a b a b a = = =
21 2 22 22 23 23
8 , 16 , 32 b a b a b a = = =
31 31 32 32 33 33
16 , 32 , 64 b a b a b a = = =
11 12 13
21 22 23
31 32 33
2
a a a
A a a a
a a a
(
(
= =
(
(

# 28
11 12 13
21 22 23
31 32 33
4 8 16
8 16 32
16 32 64
a a a
B a a a
a a a
(
(
=
(
(

11 12 13
21 22 23
31 32 33
4 8 16 2 2 2
4 4 4
a a a
a a a
a a a
(
(
=
(
(

11 12 13
21 22 23
31 32 33
4 8 16 2 4
a a a
a a a
a a a
(
(
=
(
(

4 8 16 2 4 2 =
13
2 B =
44. The ellipse
2 2
1
: 1
9 4
x y
2
2
is
a)
2
2
b)
3
2
c)
1
2
d)
3
4
Ans. C
Given Ellipse
2 2
1
9 4
x y
+ =
3 & 2 x y = =
( ) ( ) 3, 2 , 3, 2 C D
D
(0,2)
(3,0)
(0,-2)
(-3,0)
A
B
C
( ) ( ) 3, 2 , 3, 2 A B
As new ellipse
# 29
Let new ellipse is
2 2
2 2
1
x y
a b
+ =
Passes through ( )
2
2
16
0,4 1 16 b
b
= =
2
9 4
1
16 a
+ =
2
12 a =
2 2
1
12 16
x y
+ =
( )
2 2 2
1 a b e =
( )
2
12 16 1 e =
2
12 1
1
16 4
e = =
1
2
e =
3 2
2 15 36 1 f x x x x = + + is
Ans. B
| | | | : 0, 3 1, 29 f
( )
3 2
2 15 36 1 f x x x x = + +
( )
' 2
6 30 36 f x x x = +
( )( ) 6 2 3 x x =
( ) ( )
''
6 2 5 f x x =
2 x =
is pt of maxima.
# 30
3 x =
is pt of minima.
( ) & 2 29 0 f = >
( ) 3 0 f >
so curve is
n
f is not one one
2 3
Min value ( ) 0 1 f = =
Max value ( ) 2 29 f = =
so
n
f is Onto.
2 2
9 x y + = is
a) ( )
2 2
20 36 45 0 x y x y + + = b) ( )
2 2
20 36 45 0 x y x y + + =
c) ( )
2 2
36 20 45 0 x y x y + + = d) ( )
2 2
36 20 45 0 x y x y + + =
Ans. A
Let ( ) ( )
1 1
, & , P h k Q x y
4 20
,
5
h
P h
| |
|
\ .
P
A
B
Q
1
0 AB S =
4 20
9
5
h
xh y
| |
+ =
|
\ .
( ) 5 4 20 45 xh y h + = ------------------(1)
1 1
, Q x y
# 31
2 2
1 1 1 1
xx yy x y + = + ---------------(2)
Compare (1) & (2)
2 2
1 1 1 1
5 4 20 45 h h
x y x y
= =
+
1 1
2 2 2 2
1 1 1 1
9 45
&4 20
x y
h h
x y x y
= =
+ +
On eliminating h
1 1
2 2 2 2
1 1 1 1
49 45
20
x y
x y x y
=
+ +
( )
2 2
1 1 1 1
20 36 45 x y x y + =
Locus is
( )
2 2
20 36 45 0 x y x y + + =
a)
1
2
b)
2
c) 2 d)
2 2
Ans. A
Equation of
1 1 4
1 4 1
x y z
QR
+
= = =
Drs of ( ) 1, 4,1 QR
Co-ordinates of ( ) 1 , 1 4 , 4 P + + +
( ) ( ) ( ) 5 1 4 1 4 4 1 + + + =
1
3
=
T(2,1,4)
Q
S R
# 32
4 1 13
, ,
3 3 3
P
| |
|
\ .
Let ( ) 1 , 1 4 , 4 S + + +
Drs of ( ) 1, 4 2, TS
TS QR So,
( ) ( ) 1 1 4 4 2 0 + + =
1
2
=
3 9
,1,
2 2
S
| |
|
\ .
2 2 2
4 3 1 13 9
1
3 2 3 3 2
PS
| | | | | |
= + +
| | |
\ . \ . \ .
1
2
=
48. Let
( )
2
cos , 0
0, 0
x x
f x x
x
t
=
,
x IR e
, then f is
Ans. B
( )
2
cos ; 0
0 ; 0
x x
f x x
x
t
=
At x=0
# 33
( ) ( )
2
0 0
cos 0
0 0
lim lim
h h
h
f h f
h
RHD
h h
t

+
=
0
lim cos 0
h
h
h
t
| |
= =
|
\ .
( ) ( )
2
0 0
cos 0
0 0
lim lim
h h
h
f h f h
LHD
h h
t

| |

|

\ .
=

0
lim cos 0
h
h
h
t
| | | |
= =
| |
\ . \ .
At x=2
( ) ( )
( )
2
0 0
2 cos 4 cos
2 2
2 2
lim lim
h h
h
f h f
h
RHD
h h
t t

+
+
+
= =
( ) ( )
( )
2
0 0
2 cos 4 cos
2 2
2 2
lim lim
h h
h
f h f
h
LHD
h h
t t

= =


a) 75 b) 150 c) 210 d) 243
Ans. B
Case-I
Total ways 2 2 1
2
1
2
1 2 2
( )
5 3 1
2 2 1
3 C C C =
# 34
10 3 1 3 90 = =
Case-II
Total ways
( )
5 2 1
3 1 1
3 C C C =
1
1
1
1
3
3
1
3
1
10 2 1 3 60 = =
Total ways = 90 + 60 = 150.

50. The integral
( )
2
9/ 2
sec
sec tan
x
dx
x x +
a)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ +
`
) +
b)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ +
`
) +
c)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ + +
`
) +
d)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ + +
`
) +
Ans. C
( )
9
2
sec
sec tan
x
dx
x x +
}
Let
sec tan x x t + =
-------------(1)
So, ( )
2
sec
dt
x dx
t
=
------------(2)
# 35
1
sec tan x x
t
=
----------(3)
From (1) & (3)
1 1
sec
2
x t
t
| |
= +
|
\ .
( )
9
2
sec .sec
sec tan
x x
dx
x x +
}
9
2
1 1
2
dt
t
t
t
t
| |
+
|
\ .
}
2
13
2
1 1
2
t
dt
t
+
}
9 13
2 2
1
2
t dt t dt

(
= +
(

} }
7 11
2 2
1
7 11
2
2 2
t t
K

(
(
= + +
(

7 11
2 2
7 11
t t
K

= + +

( ) ( )
7 11
2 2
1 1
=
+ +
( )
( )
2
11
2
1 1 1
sec tan
11 7
sec tan
x x K
x x
| |
= + + +
|
\ .
+
# 36
SECTION II
1
, E
2
and E
3
1 1
,
2 4
and
1
4
1
, X
2
and X
3

1
, E
2
and E
3
a)
1
3
|
16
c
P x X ( =

7
8
=
c) | |
2
5
|
16
P X X =
d) | |
1
7
|
16
P X X =
Ans. B,D
A)
( )
( )
1
1 1 1
1
2 4 4
1
8
4
c
P X X
P X

= =
( )
1 1 3 1 1 1 1
2 2
2 4 4 2 4 4 4
P X
| | | |
= + =
| |
\ . \ .
B)
| |
1 1 3 1 1 1
2
7 2 4 4 2 4 4
/
1
8
4
| |
+
|
\ .
= =
C)
( )
| |
( )
2
2
2
1 1 3 1 1 1
2
5 2 4 4 2 4 4
/
1
8
4
P X X
P X X
P X
| | | |
+
| |
\ . \ .
= = =
D)
( )
| |
( )
1
1
1
1 1 3 1 1 1
2
7 2 4 4 2 4 4
/
1
16
2
P X X
P X X
P X
| |
+
|
\ .
= = =
# 37
2 2
1
9 4
x y
a)
9 1
,
2 2 2
| |
|
\ .
b)
9 1
,
2 2 2
| |

|
\ .
c)
( )
3 3, 2 2 d)
( )
3 3, 2 2
Ans. A, B
2 2
1
9 4
x y
=
2 y x = +
( )
2
9 4 4 36 4 32 = = =
4 2 =
Tangent is :
2 4 2 0 x y =
Point of contact is
2 2
9 1 9 1
, , , ,
2 2 2 2 2 2
a l b m
n n
| | | | | |
=
| | |
\ . \ . \ .
2
x
y e
=
, y = 0, x = 0, and x = 1. Then
a)
1
S
e
>
b)
1
1 S
e
>
c)
1 1
1
4
S
e
| |
s +
|
\ .
d)
1 1 1
1
2 2
S
e
| |
s +
|
\ .
Ans. A, B, D
2
1 1
0 0
1
1
x x
I e dx e dx
e

= > =
} }
1
1 I
e
>
2
1
1
x
e e

s s
2
1 1 1
1
0 0 0
x
e dx e dx dx

s s
} } }
2
1
0
1
x
e dx
e
>
}
# 38
a)
2
4 8 2
y
t t | |
=
|
\ .
b)
2
'
4 18
y
t t | |
=
|
\ .
c)
2
3 9
y
t t | |
=
|
\ .
d)
2
4 2
'
3 3 3 3
y
t t t | |
= +
|
\ .
Ans. A,D
tan 2 sec
dy
y x x x
dx
=
tan
. cos
dx
I F e x
}
= =
}
2
x c = +
2
( ) 0, 0
0 0 0 c c = + =
.
2
sec y x x =
( )
2
2
4 16
y
t t | |
=
|
\ .
2
8 2
t
=
2
2
3 9
y
t t | |
=
|
\ .
2
sec tan 2 sec
dy
x x x x x
dx
= +
.
( )
2
1
2 3 2 2
3 9 3
y
t t t | | | |
= +
| |
\ . \ .
2
2 4
3 3 3
t t
= +
# 39
55. Let
u
( )
2
2 2
u u
u | u |
| |
= +
|
\ .
,
( ) tan 2 0 t u > and
3
1 sin
2
u < < .
a)
0
2
t
| < <
b)
4
2 3
t t
| < <
c)
4 3
3 2
t t
| < <
d)
3
2
2
t
| t < <
Ans. A, C, D
( )
3
tan 2 0, 1 sin
2
t u u > < <
3 5 1
, 0 cos
2 3 2
t t
u u
| |
e < <
|
\ .
______ (1)
( ) ( )
2
( )
1
sin cos
2
u | u + = +
( )
1
sin 1
2
u | < + <
(from (1))
13 17
6 6
t t
u | < + <
2 7
3 6
t t
| < <
(from (1))
# 40
SECTION III
( ) ' 0 p
is
Ans. 9
( )
3 2
( ) 1 6 6 P a b c d = + + + =
( ) 3 2 27 9 3 2 P a b c d = + + + =
( )
1
1 0 3 2 0 P a b c = + + =
( )
1
3 0 27 6 0 P a b c = + + =
1, 6, 9 a b c = = =
( )
1 2
3 2 P x ax bx c = + +
( )
1
0 9 P c = =
57. If
, a b
and
c

2 2
2
9 a b b c c a + + =

,then 2 5 5 a b c + +

is\
Ans. 3
sol. 1 a b c = = =

2 2
2
9 a b b c c a + + =

3
.
2
a b b c c a

+ + =
( )
3 2 . . 0 a b b c c a + + + =

2
2 2
2 . . . 0 a b c a b b c c a + + + + + =

2
0 a b c + + =
# 41

0 a b c + + =
(1)
then
1 1 1
. , . , .
2 2 2
a b b c c a

= = =
2 5 5 3 a b c + + =
58. The value of
3
2
1 1 1 1
6 log 4 4 4 ...
3 2 3 2 3 2 3 2
| |
|
+
|
\ .
is
Ans. 4
sol.
1
4
3 2
x x =
3 2 4 x x =
2
18 4 x x =
2
18 4 0 x x + =
2
18 9 8 4 0 x x x + =
( ) ( ) 9 2 1 4 2 1 0 x x x + + = .
( )( ) 2 1 9 4 0 x x + =
1 4
,
2 9
x =
4
9
x =
( ) 0 x >
Required answer is
2
3/ 2
3
6 log
2
| |
+
|
\ .
= 6 2
= 4
2
2 2
Ans. 4
# 42
sol.
P
Q
S
(0, 0)
(2,4)
(2, 0)
2
(0,4)
2
8 2 4 2 0 x x x x + =
( ) ( ) 0, 2 0, 0 , 2, 4 x P Q = = =
area of SPQ A
=
1
2 4
2

= 4
2
Ans. 5
sol. ( )
2
1, 1 f x x x x = + s

2
1 , 1 0 x x x = + < <

2
1 , 0 1 x x x = + s <

2
1, 1 x x x = + >
( ) ' 2 1, 1 f x x x = <
2 1, 1 0 x x = < <
0
-1 1
x
y
1 2 , 0 1 x x = < <
1 2 , 1 x x = + >
differentiable at
1 1
,
2 2
x =
,
IIT-JEE 2012
& Solutions
INSTRUCTIONS
A. General
invigilators.
of this booklet.
inclusive).
D.Marking Scheme
in this section.
in this section.
# 3
PHYSICS
SECTION I
/
3
rad s
t
e =
0
2
)
a) 50 / m s b) 51 / m s c) 52 / m s d) 53 / m s
Ans : A
At
1 t =

0.2cos (1) 0.2cos 0.1
3
y m
t
e = = =

2
2
sin90
50
10
V
R V
= =
50 / V m s =
# 4
2
4MLg
Y
ld t
| |
=
|
\ .
ment of l.
Ans :A
2
2 2 4
d d
d
d v
| | A A
| |
= = A
| |
\ .
\ .
4
0.25
l l
l
l
A A
= = A
angular speed
e
noted by
0
L
and
P
L
respectively, then
# 5
a)
0
L
and
P
L

b)
0
L

P
L
remains constant
c)
0
L

P
L
varies with time

d)
0
L
and
P
L
both vary with time

Ans :C
( )
0
L m r v =
( )
P
L m OP v =
direction of
P
L
changes with
OP
and
P
L OP
G R
| | and
B
a)
G B R
| | | > > b)
B G R
| | | > > c)
R B G
| | | > > d)
R G B
| | | > >
Ans :D
D
d
| | =
R G B
> >
R G B
| | | > >
# 6
which graph ?
a) b)
c) d)
Ans : D
1
E
r

1
V
r
a) 280. 0 cm b) 40.0 cm c) 21. 5 cm d) 13.3 cm
# 7
Ans :B
1 2
1 1 1
F f f
= +
=
( ) ( )
1 2
1 1
R
+
=
0.5 0.2 0.7 1
14 14 20
+
= =
20 F cm =
40 R cm =
1 1 1 1 1 1 1 1 1 2 1 1
20 40 20 40 40 40 F v u v v
= = + = = =
40 v cm =
0
a)
5
1 10 V
b)
7
1 10 V
c)
9
1 10 V
d)
10
1 10 V
Ans :C
mg Eq =
45
mg
Eq
p
Vq
d
=
( )
9
10
mgd
V V approx
q
= =
a)
1
4
65
2
T
| |
|
\ .
b)
1
4
97
4
T
| |
|
\ .
c)
1
4
97
2
T
| |
|
\ .
d)
( )
1
4
97 T
Ans : C
( ) ( )
4 4 4 4
1 2 2 3
A T T A T T o o =
( ) ( )
1
4
4 4
4 4
2 2 2
97
2 3
2
T T T T T T
| |
= =
|
\ .
# 8
speed
e
e
t

which plot ?
a) b)
c) d)
Ans : B
| |
dL d dI
I
dt dt dt
t e e = = =
constant
rod
I =
2
red
d
I mr
dt
e ( +

=
0 2
dr
m r
dt
e
| |
+
|
\ .

v
r = vt
2
2 2 mr v m v t e e = =
t t
0 t =
# 9
( )
( )
helium
argon
rms
rms
v
v
| |
|
|
\ .
is
a) 0.32 b) 0.45 c) 2.24 d) 3.16
Ans : D
rms
T
V
M
1 2
2 1
40
10
4
He
Ar
V V M
V V M
= = = =
SECTION II
u
2
10 / g m s = )

a)
0
45 u =
b)
0
45 u >
c)
0
45 u >
d)
0
45 u <
Ans : A (or) AC
# 10
1cos sin mg u u =
45 u =
when
45 u >
0
E E j =
and
0
B B j =

velcoity
v

u
a) If
0
0 u =
b) If
0
0 u =
c) If
0
10 u =
d) If
0
90 u =
Ans :C,D
when
90 u =
0
m
F =
when
10 u =
# 11
1
3 I A =
2
2 I A =
Ans : A,B,C,D
1
12
3
4
I = =
2
12
3
18
I =

2A =
P Q
V V =
S Q
alsoV V =
Ans : B, D
# 12
Open end
Closed end
option(s).
/ 2 x a = +
the plane
/ 2 x a =
0
q
c
.
/ 2 z a = +
the plane
/ 2 x a = +
# 13
Ans : ACD

2
a
x = +
and
2
a
x =
is same

0
q
c
Flux through plane

2
a
z =
and
2
a
x =
is same
SECTION III
(both i nclusive).
0
I and
P
0
P
I
I
Ans : 3
( ) ( ) ( ) ( )
2
2 2 2 2 2
0
1 1
2 2
2 2
I R R R R R R t t t
(
(
= +
(

4 4
3
8
2
R R t t =
4 2
13 13
2 2
R MR t = =
( ) ( )( )
2 2
2 2
1 1
4 2 4 2 5
2 2
P
I M R M R MR M R
( (
= + +
( (

2 2 2
11
8 16
2
MR MR MR
(
= +
(

2 2
11 37
24
2 2
MR MR
(
= =
(

# 14
3 z R =
along the axis of
45
2
0
/ 2
2
p
a
R
,
Ans : 7
( )
2
2
0
3/ 2
2
2
2 1
4 2
3
iR
B a
i
R R
| t
t
= =
(
+
(

(n = 2)
2
2 2 0 0
9/2
1
2 2 2
a
M R a

= =
0
12
N
aJ
,
# 15
Ans : 5
0
1
2
ja
B

=
2
2 0
0
2
2
3 12
2
2
a
j
ja
B
a a
t
t
| |
|
\ .
= =
| |
|
\ .
1 2 0
1 1
2 12
B B ja
| |
=
|
\ .
0
5
12
ja
=
27
5 / 3 10 ;
p
m kg
=
15
/ 4.2 10 . / H e j S c
= ;
9
0
1
9 10 / ;
4
m F
tc
=

15
1 10 fm m
= )
Ans : 7
2 2
9
15
120
9 10
10 10 2
p
e P
m
9 2 27
2
15
5
9 10 120 2 10
3
10 10
e
P
| |

|
\ .
=
17
15
3 2 10 3 2
10 10
e e
P

= =
15
4.2 10
6
10
h
p
= =
# 16
0
23
16
R
k
c
. The value of k is
Ans: 6
( )
3
2
2
4
2
3 8
2
2
p
R
K
k R
E
R
R
t
t
=
4 1
1
3 32
p
E k R t
(
=
(

0
1 1
1
4 24
R t
tc
(
=
(

0
23
4 24
p
R
E

c
| |
=
|
\ .
24 4
6
16
K

= =
# 17
CHEMISRY
SECTION I
. .
3
4
conc aq NaOH
CH CHO CHO +
OH
OH
HO
OH
a) 1 b) 2 c) 3 d) 4
Ans : C
3 2
OH
CH CHO CH CHO
2 2 2
O
H
2 2
OH
O
H
' HCHO Cannizaro s
NaOH reaction
CH CH
CHO
OH
OH
CHO
HO
OH
OH OH OH
OH HO
# 18
22. A compound M
P
X
P
a) MX b) MX
2
c) M
2
X d) M
5
X
14
Ans : B
Corner
Face center
1
6 3
2
=
1
8 1
8
=
4
X :
Edge centre
Body center
1 1 1 =
1
4 1
4
=
2
M :
4 2
X M
4 2
X M
2
MX
Ans : D
COOH
OCOCH
3
# 19
4
is :
Ans : A
V
B
G
O
R
Y
given compound is :
CH
3
3
H
CH
3
H CH
3
a) 0 b) 1 c) 2 d) 4
Ans : A
2 3 3
4 2
Co H O NH Cl (

is
Ans : D
( ) ( )
2 3 3
4 2
Co H O NH Cl (

nitrogen ?
a)
3 4 2
3 2 4
c)
3 4 2
3 4 2
# 20
Ans : B
3
5 HNO +
2 NO +
2
0 N
4
3 NH Cl
Decreasing order of
O -S =
3 2 4
2
mol
2
) is
a) 1.0 b) 4.5 c) 1.5 d) 3.0
Ans : C
( )
2
2
n a
P v nb nRT
v
| |
+ =
|
\ .
n = 1, b = 0
( )
2
q
p v b RT
v
| |
+ =
|
\ .
a
pv RT
v
+ =
a
pv RT
v
=
( )
2 2
21.6 20.1
1.5 .
3 2
= + = = = =

# 21
29. In allene ( )
3 4
a) sp and sp
3
b) sp and sp
2
c) only sp
2
d) sp
2
and sp
3
Ans : B
2 2
H C C CH = =
2 2
sp sp sp
0
is Bohr
radius]
a)
2
2 2
0
4
h
ma t
b)
2
2 2
0
16
h
ma t
c)
2
2 2
0
32
h
ma t
d)
2
2 2
0
64
h
ma t
Ans : C
mvr=
2
nh
t
v=
2
nh
mr t
2
r =4
0
a
V=
0
4
h
ma t
2
2
2 2 2
0
16
h
V
m a t
=
K.E
2
2
2 2
0
1
2 32
h
mv
ma t
= =
# 22
SECTION II
a) b) c)
O
d)
O
Ans : BC
3
dissolves in ( )
2 2 3
Na S O aq ?
Ans : ACD
3 3
AgNO HX AgX HNO + +
aq aq
( )
2 2 3 3 2 3
2

aq
aq
s
AgF is soluble
Ans : AD
# 23
S A
as change
a)
x z x y y z
S S S

A = A + A b)
x z x y y z
W w w

= +
c)
x y z x y
w w

= d)
x y z x y
S S

A = A
Ans : AC
x y x y y z
S S S

A = A + A
x y z x y
W W

=
a)
6 5 6 5
6 5 6 5 2
c)
6 5 2 6 5
6 5 2 6 5 2
Ans : BD
3
NaHCO ,
# 24
SECTION III
(both i nclusive).
C
CH
2
CHOH
CHOH
CHO
CH
2
OH
OH H
Ans : 8
solution
1
is 36.5 g mol
1
0.4 M HCl is :
Ans : 8
10 d x
GMW

=
10 1.25 29.2
36.5

=10M

1 1 2 2
1
1
10 200 0.4
8 ( )
V M V M
V
V ML approx
=
=
=
Ans : 8
63 1 1 4 1 52
29 1 0 2 1 26
6 2 CU H n He H X + + + +
26
Fe 8 th group
# 25
1/8
and t
1/10
Ans : 9
1
8
1
10
2.303
log
8
2.303
log
10
a
t
a
k
a
t
a
k
=
=
1
8
1
10
log8
log10
t
t
=
1
8
1
10
3log 2
t
t
=
1
8
1
10
10 9
t
t
=
1
and R
2
Ans : 4
# 26
MATHEMATICS
SECTION I
2
1 a z z = + +
a) 1 b)
1
3
c)
1
2
d)
3
4
Ans. D
Let Z x iy = + ( ) 0 y =
2
1 a z z = + +
becomes
( ) ( )
2
1 a x iy x iy = + + + +
( ) ( )
2 2
1 2 0 x y x i xy y a i + + + + = +
2 2
1 x y x a + + = (1)
2 0 xy y + = (2)
From (2)
1
2
x

=
as 0 y =
2
2
1 1
1
2 2
y a
| |
+ =
|
\ .
2
1 1
4 2
y a + =
2
3
0
4
y a = >
3
4
a <
# 27
42. If
2
1
lim 4
1
x
x x
ax b
x
| | + +
=
|
+
\ .
, then
a) a = 1, b = 4 b) a = 1, b = 4 c) a = 2, b = 3 d) a = 2, b = 3
Ans. B
2
1
lim 4
1
x
x x
ax b
x
+ +
=
+
( ) ( )
2
1 1 1
4
1
x
x a x a b b
lim
x
+ +
=
+
2
0 x =
1 a = 0
a = 1
( ) 1 1
lim 4
1
x
x a b b
x
+
=
+
1 4 a b =
b = 4
43. Let
ij
P a ( =

be a
3 3
matrix and let
ij
Q b ( =

, where 2
i j
ij ij
b a
+
a) 2
10
b) 2
11
c) 2
12
d) 2
13
Ans. D
as 2
i j
ij ij
b a
+
=
11 11 12 12 13 13
4 , 8 , 16 b a b a b a = = =
21 2 22 22 23 23
8 , 16 , 32 b a b a b a = = =
31 31 32 32 33 33
16 , 32 , 64 b a b a b a = = =
11 12 13
21 22 23
31 32 33
2
a a a
A a a a
a a a
(
(
= =
(
(

# 28
11 12 13
21 22 23
31 32 33
4 8 16
8 16 32
16 32 64
a a a
B a a a
a a a
(
(
=
(
(

11 12 13
21 22 23
31 32 33
4 8 16 2 2 2
4 4 4
a a a
a a a
a a a
(
(
=
(
(

11 12 13
21 22 23
31 32 33
4 8 16 2 4
a a a
a a a
a a a
(
(
=
(
(

4 8 16 2 4 2 =
13
2 B =
44. The ellipse
2 2
1
: 1
9 4
x y
2
2
is
a)
2
2
b)
3
2
c)
1
2
d)
3
4
Ans. C
Given Ellipse
2 2
1
9 4
x y
+ =
3 & 2 x y = =
( ) ( ) 3, 2 , 3, 2 C D
D
(0,2)
(3,0)
(0,-2)
(-3,0)
A
B
C
( ) ( ) 3, 2 , 3, 2 A B
As new ellipse
# 29
Let new ellipse is
2 2
2 2
1
x y
a b
+ =
Passes through ( )
2
2
16
0,4 1 16 b
b
= =
2
9 4
1
16 a
+ =
2
12 a =
2 2
1
12 16
x y
+ =
( )
2 2 2
1 a b e =
( )
2
12 16 1 e =
2
12 1
1
16 4
e = =
1
2
e =
3 2
2 15 36 1 f x x x x = + + is
Ans. B
| | | | : 0, 3 1, 29 f
( )
3 2
2 15 36 1 f x x x x = + +
( )
' 2
6 30 36 f x x x = +
( )( ) 6 2 3 x x =
( ) ( )
''
6 2 5 f x x =
2 x =
is pt of maxima.
# 30
3 x =
is pt of minima.
( ) & 2 29 0 f = >
( ) 3 0 f >
so curve is
n
f is not one one
2 3
Min value ( ) 0 1 f = =
Max value ( ) 2 29 f = =
so
n
f is Onto.
2 2
9 x y + = is
a) ( )
2 2
20 36 45 0 x y x y + + = b) ( )
2 2
20 36 45 0 x y x y + + =
c) ( )
2 2
36 20 45 0 x y x y + + = d) ( )
2 2
36 20 45 0 x y x y + + =
Ans. A
Let ( ) ( )
1 1
, & , P h k Q x y
4 20
,
5
h
P h
| |
|
\ .
P
A
B
Q
1
0 AB S =
4 20
9
5
h
xh y
| |
+ =
|
\ .
( ) 5 4 20 45 xh y h + = ------------------(1)
1 1
, Q x y
# 31
2 2
1 1 1 1
xx yy x y + = + ---------------(2)
Compare (1) & (2)
2 2
1 1 1 1
5 4 20 45 h h
x y x y
= =
+
1 1
2 2 2 2
1 1 1 1
9 45
&4 20
x y
h h
x y x y
= =
+ +
On eliminating h
1 1
2 2 2 2
1 1 1 1
49 45
20
x y
x y x y
=
+ +
( )
2 2
1 1 1 1
20 36 45 x y x y + =
Locus is
( )
2 2
20 36 45 0 x y x y + + =
a)
1
2
b)
2
c) 2 d)
2 2
Ans. A
Equation of
1 1 4
1 4 1
x y z
QR
+
= = =
Drs of ( ) 1, 4,1 QR
Co-ordinates of ( ) 1 , 1 4 , 4 P + + +
( ) ( ) ( ) 5 1 4 1 4 4 1 + + + =
1
3
=
T(2,1,4)
Q
S R
# 32
4 1 13
, ,
3 3 3
P
| |
|
\ .
Let ( ) 1 , 1 4 , 4 S + + +
Drs of ( ) 1, 4 2, TS
TS QR So,
( ) ( ) 1 1 4 4 2 0 + + =
1
2
=
3 9
,1,
2 2
S
| |
|
\ .
2 2 2
4 3 1 13 9
1
3 2 3 3 2
PS
| | | | | |
= + +
| | |
\ . \ . \ .
1
2
=
48. Let
( )
2
cos , 0
0, 0
x x
f x x
x
t
=
,
x IR e
, then f is
Ans. B
( )
2
cos ; 0
0 ; 0
x x
f x x
x
t
=
At x=0
# 33
( ) ( )
2
0 0
cos 0
0 0
lim lim
h h
h
f h f
h
RHD
h h
t

+
=
0
lim cos 0
h
h
h
t
| |
= =
|
\ .
( ) ( )
2
0 0
cos 0
0 0
lim lim
h h
h
f h f h
LHD
h h
t

| |

|

\ .
=

0
lim cos 0
h
h
h
t
| | | |
= =
| |
\ . \ .
At x=2
( ) ( )
( )
2
0 0
2 cos 4 cos
2 2
2 2
lim lim
h h
h
f h f
h
RHD
h h
t t

+
+
+
= =
( ) ( )
( )
2
0 0
2 cos 4 cos
2 2
2 2
lim lim
h h
h
f h f
h
LHD
h h
t t

= =


a) 75 b) 150 c) 210 d) 243
Ans. B
Case-I
Total ways 2 2 1
2
1
2
1 2 2
( )
5 3 1
2 2 1
3 C C C =
# 34
10 3 1 3 90 = =
Case-II
Total ways
( )
5 2 1
3 1 1
3 C C C =
1
1
1
1
3
3
1
3
1
10 2 1 3 60 = =
Total ways = 90 + 60 = 150.

50. The integral
( )
2
9/ 2
sec
sec tan
x
dx
x x +
a)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ +
`
) +
b)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ +
`
) +
c)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ + +
`
) +
d)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ + +
`
) +
Ans. C
( )
9
2
sec
sec tan
x
dx
x x +
}
Let
sec tan x x t + =
-------------(1)
So, ( )
2
sec
dt
x dx
t
=
------------(2)
# 35
1
sec tan x x
t
=
----------(3)
From (1) & (3)
1 1
sec
2
x t
t
| |
= +
|
\ .
( )
9
2
sec .sec
sec tan
x x
dx
x x +
}
9
2
1 1
2
dt
t
t
t
t
| |
+
|
\ .
}
2
13
2
1 1
2
t
dt
t
+
}
9 13
2 2
1
2
t dt t dt

(
= +
(

} }
7 11
2 2
1
7 11
2
2 2
t t
K

(
(
= + +
(

7 11
2 2
7 11
t t
K

= + +

( ) ( )
7 11
2 2
1 1
=
+ +
( )
( )
2
11
2
1 1 1
sec tan
11 7
sec tan
x x K
x x
| |
= + + +
|
\ .
+
# 36
SECTION II
1
, E
2
and E
3
1 1
,
2 4
and
1
4
1
, X
2
and X
3

1
, E
2
and E
3
a)
1
3
|
16
c
P x X ( =

7
8
=
c) | |
2
5
|
16
P X X =
d) | |
1
7
|
16
P X X =
Ans. B,D
A)
( )
( )
1
1 1 1
1
2 4 4
1
8
4
c
P X X
P X

= =
( )
1 1 3 1 1 1 1
2 2
2 4 4 2 4 4 4
P X
| | | |
= + =
| |
\ . \ .
B)
| |
1 1 3 1 1 1
2
7 2 4 4 2 4 4
/
1
8
4
| |
+
|
\ .
= =
C)
( )
| |
( )
2
2
2
1 1 3 1 1 1
2
5 2 4 4 2 4 4
/
1
8
4
P X X
P X X
P X
| | | |
+
| |
\ . \ .
= = =
D)
( )
| |
( )
1
1
1
1 1 3 1 1 1
2
7 2 4 4 2 4 4
/
1
16
2
P X X
P X X
P X
| |
+
|
\ .
= = =
# 37
2 2
1
9 4
x y
a)
9 1
,
2 2 2
| |
|
\ .
b)
9 1
,
2 2 2
| |

|
\ .
c)
( )
3 3, 2 2 d)
( )
3 3, 2 2
Ans. A, B
2 2
1
9 4
x y
=
2 y x = +
( )
2
9 4 4 36 4 32 = = =
4 2 =
Tangent is :
2 4 2 0 x y =
Point of contact is
2 2
9 1 9 1
, , , ,
2 2 2 2 2 2
a l b m
n n
| | | | | |
=
| | |
\ . \ . \ .
2
x
y e
=
, y = 0, x = 0, and x = 1. Then
a)
1
S
e
>
b)
1
1 S
e
>
c)
1 1
1
4
S
e
| |
s +
|
\ .
d)
1 1 1
1
2 2
S
e
| |
s +
|
\ .
Ans. A, B, D
2
1 1
0 0
1
1
x x
I e dx e dx
e

= > =
} }
1
1 I
e
>
2
1
1
x
e e

s s
2
1 1 1
1
0 0 0
x
e dx e dx dx

s s
} } }
2
1
0
1
x
e dx
e
>
}
# 38
a)
2
4 8 2
y
t t | |
=
|
\ .
b)
2
'
4 18
y
t t | |
=
|
\ .
c)
2
3 9
y
t t | |
=
|
\ .
d)
2
4 2
'
3 3 3 3
y
t t t | |
= +
|
\ .
Ans. A,D
tan 2 sec
dy
y x x x
dx
=
tan
. cos
dx
I F e x
}
= =
}
2
x c = +
2
( ) 0, 0
0 0 0 c c = + =
.
2
sec y x x =
( )
2
2
4 16
y
t t | |
=
|
\ .
2
8 2
t
=
2
2
3 9
y
t t | |
=
|
\ .
2
sec tan 2 sec
dy
x x x x x
dx
= +
.
( )
2
1
2 3 2 2
3 9 3
y
t t t | | | |
= +
| |
\ . \ .
2
2 4
3 3 3
t t
= +
# 39
55. Let
u
( )
2
2 2
u u
u | u |
| |
= +
|
\ .
,
( ) tan 2 0 t u > and
3
1 sin
2
u < < .
a)
0
2
t
| < <
b)
4
2 3
t t
| < <
c)
4 3
3 2
t t
| < <
d)
3
2
2
t
| t < <
Ans. A, C, D
( )
3
tan 2 0, 1 sin
2
t u u > < <
3 5 1
, 0 cos
2 3 2
t t
u u
| |
e < <
|
\ .
______ (1)
( ) ( )
2
( )
1
sin cos
2
u | u + = +
( )
1
sin 1
2
u | < + <
(from (1))
13 17
6 6
t t
u | < + <
2 7
3 6
t t
| < <
(from (1))
# 40
SECTION III
( ) ' 0 p
is
Ans. 9
( )
3 2
( ) 1 6 6 P a b c d = + + + =
( ) 3 2 27 9 3 2 P a b c d = + + + =
( )
1
1 0 3 2 0 P a b c = + + =
( )
1
3 0 27 6 0 P a b c = + + =
1, 6, 9 a b c = = =
( )
1 2
3 2 P x ax bx c = + +
( )
1
0 9 P c = =
57. If
, a b
and
c

2 2
2
9 a b b c c a + + =

,then 2 5 5 a b c + +

is\
Ans. 3
sol. 1 a b c = = =

2 2
2
9 a b b c c a + + =

3
.
2
a b b c c a

+ + =
( )
3 2 . . 0 a b b c c a + + + =

2
2 2
2 . . . 0 a b c a b b c c a + + + + + =

2
0 a b c + + =
# 41

0 a b c + + =
(1)
then
1 1 1
. , . , .
2 2 2
a b b c c a

= = =
2 5 5 3 a b c + + =
58. The value of
3
2
1 1 1 1
6 log 4 4 4 ...
3 2 3 2 3 2 3 2
| |
|
+
|
\ .
is
Ans. 4
sol.
1
4
3 2
x x =
3 2 4 x x =
2
18 4 x x =
2
18 4 0 x x + =
2
18 9 8 4 0 x x x + =
( ) ( ) 9 2 1 4 2 1 0 x x x + + = .
( )( ) 2 1 9 4 0 x x + =
1 4
,
2 9
x =
4
9
x =
( ) 0 x >
Required answer is
2
3/ 2
3
6 log
2
| |
+
|
\ .
= 6 2
= 4
2
2 2
Ans. 4
# 42
sol.
P
Q
S
(0, 0)
(2,4)
(2, 0)
2
(0,4)
2
8 2 4 2 0 x x x x + =
( ) ( ) 0, 2 0, 0 , 2, 4 x P Q = = =
area of SPQ A
=
1
2 4
2

= 4
2
Ans. 5
sol. ( )
2
1, 1 f x x x x = + s

2
1 , 1 0 x x x = + < <

2
1 , 0 1 x x x = + s <

2
1, 1 x x x = + >
( ) ' 2 1, 1 f x x x = <
2 1, 1 0 x x = < <
0
-1 1
x
y
1 2 , 0 1 x x = < <
1 2 , 1 x x = + >
differentiable at
1 1
,
2 2
x =
,
IIT-JEE 2012
& Solutions
INSTRUCTIONS
A. General
invigilators.
of this booklet.
inclusive).
D.Marking Scheme
in this section.
in this section.
# 3
PHYSICS
SECTION I
/
3
rad s
t
e =
0
2
)
a) 50 / m s b) 51 / m s c) 52 / m s d) 53 / m s
Ans : A
At
1 t =

0.2cos (1) 0.2cos 0.1
3
y m
t
e = = =

2
2
sin90
50
10
V
R V
= =
50 / V m s =
# 4
2
4MLg
Y
ld t
| |
=
|
\ .
ment of l.
Ans :A
2
2 2 4
d d
d
d v
| | A A
| |
= = A
| |
\ .
\ .
4
0.25
l l
l
l
A A
= = A
angular speed
e
noted by
0
L
and
P
L
respectively, then
# 5
a)
0
L
and
P
L

b)
0
L

P
L
remains constant
c)
0
L

P
L
varies with time

d)
0
L
and
P
L
both vary with time

Ans :C
( )
0
L m r v =
( )
P
L m OP v =
direction of
P
L
changes with
OP
and
P
L OP
G R
| | and
B
a)
G B R
| | | > > b)
B G R
| | | > > c)
R B G
| | | > > d)
R G B
| | | > >
Ans :D
D
d
| | =
R G B
> >
R G B
| | | > >
# 6
which graph ?
a) b)
c) d)
Ans : D
1
E
r

1
V
r
a) 280. 0 cm b) 40.0 cm c) 21. 5 cm d) 13.3 cm
# 7
Ans :B
1 2
1 1 1
F f f
= +
=
( ) ( )
1 2
1 1
R
+
=
0.5 0.2 0.7 1
14 14 20
+
= =
20 F cm =
40 R cm =
1 1 1 1 1 1 1 1 1 2 1 1
20 40 20 40 40 40 F v u v v
= = + = = =
40 v cm =
0
a)
5
1 10 V
b)
7
1 10 V
c)
9
1 10 V
d)
10
1 10 V
Ans :C
mg Eq =
45
mg
Eq
p
Vq
d
=
( )
9
10
mgd
V V approx
q
= =
a)
1
4
65
2
T
| |
|
\ .
b)
1
4
97
4
T
| |
|
\ .
c)
1
4
97
2
T
| |
|
\ .
d)
( )
1
4
97 T
Ans : C
( ) ( )
4 4 4 4
1 2 2 3
A T T A T T o o =
( ) ( )
1
4
4 4
4 4
2 2 2
97
2 3
2
T T T T T T
| |
= =
|
\ .
# 8
speed
e
e
t

which plot ?
a) b)
c) d)
Ans : B
| |
dL d dI
I
dt dt dt
t e e = = =
constant
rod
I =
2
red
d
I mr
dt
e ( +

=
0 2
dr
m r
dt
e
| |
+
|
\ .

v
r = vt
2
2 2 mr v m v t e e = =
t t
0 t =
# 9
( )
( )
helium
argon
rms
rms
v
v
| |
|
|
\ .
is
a) 0.32 b) 0.45 c) 2.24 d) 3.16
Ans : D
rms
T
V
M
1 2
2 1
40
10
4
He
Ar
V V M
V V M
= = = =
SECTION II
u
2
10 / g m s = )

a)
0
45 u =
b)
0
45 u >
c)
0
45 u >
d)
0
45 u <
Ans : A (or) AC
# 10
1cos sin mg u u =
45 u =
when
45 u >
0
E E j =
and
0
B B j =

velcoity
v

u
a) If
0
0 u =
b) If
0
0 u =
c) If
0
10 u =
d) If
0
90 u =
Ans :C,D
when
90 u =
0
m
F =
when
10 u =
# 11
1
3 I A =
2
2 I A =
Ans : A,B,C,D
1
12
3
4
I = =
2
12
3
18
I =

2A =
P Q
V V =
S Q
alsoV V =
Ans : B, D
# 12
Open end
Closed end
option(s).
/ 2 x a = +
the plane
/ 2 x a =
0
q
c
.
/ 2 z a = +
the plane
/ 2 x a = +
# 13
Ans : ACD

2
a
x = +
and
2
a
x =
is same

0
q
c
Flux through plane

2
a
z =
and
2
a
x =
is same
SECTION III
(both i nclusive).
0
I and
P
0
P
I
I
Ans : 3
( ) ( ) ( ) ( )
2
2 2 2 2 2
0
1 1
2 2
2 2
I R R R R R R t t t
(
(
= +
(

4 4
3
8
2
R R t t =
4 2
13 13
2 2
R MR t = =
( ) ( )( )
2 2
2 2
1 1
4 2 4 2 5
2 2
P
I M R M R MR M R
( (
= + +
( (

2 2 2
11
8 16
2
MR MR MR
(
= +
(

2 2
11 37
24
2 2
MR MR
(
= =
(

# 14
3 z R =
along the axis of
45
2
0
/ 2
2
p
a
R
,
Ans : 7
( )
2
2
0
3/ 2
2
2
2 1
4 2
3
iR
B a
i
R R
| t
t
= =
(
+
(

(n = 2)
2
2 2 0 0
9/2
1
2 2 2
a
M R a

= =
0
12
N
aJ
,
# 15
Ans : 5
0
1
2
ja
B

=
2
2 0
0
2
2
3 12
2
2
a
j
ja
B
a a
t
t
| |
|
\ .
= =
| |
|
\ .
1 2 0
1 1
2 12
B B ja
| |
=
|
\ .
0
5
12
ja
=
27
5 / 3 10 ;
p
m kg
=
15
/ 4.2 10 . / H e j S c
= ;
9
0
1
9 10 / ;
4
m F
tc
=

15
1 10 fm m
= )
Ans : 7
2 2
9
15
120
9 10
10 10 2
p
e P
m
9 2 27
2
15
5
9 10 120 2 10
3
10 10
e
P
| |

|
\ .
=
17
15
3 2 10 3 2
10 10
e e
P

= =
15
4.2 10
6
10
h
p
= =
# 16
0
23
16
R
k
c
. The value of k is
Ans: 6
( )
3
2
2
4
2
3 8
2
2
p
R
K
k R
E
R
R
t
t
=
4 1
1
3 32
p
E k R t
(
=
(

0
1 1
1
4 24
R t
tc
(
=
(

0
23
4 24
p
R
E

c
| |
=
|
\ .
24 4
6
16
K

= =
# 17
CHEMISRY
SECTION I
. .
3
4
conc aq NaOH
CH CHO CHO +
OH
OH
HO
OH
a) 1 b) 2 c) 3 d) 4
Ans : C
3 2
OH
CH CHO CH CHO
2 2 2
O
H
2 2
OH
O
H
' HCHO Cannizaro s
NaOH reaction
CH CH
CHO
OH
OH
CHO
HO
OH
OH OH OH
OH HO
# 18
22. A compound M
P
X
P
a) MX b) MX
2
c) M
2
X d) M
5
X
14
Ans : B
Corner
Face center
1
6 3
2
=
1
8 1
8
=
4
X :
Edge centre
Body center
1 1 1 =
1
4 1
4
=
2
M :
4 2
X M
4 2
X M
2
MX
Ans : D
COOH
OCOCH
3
# 19
4
is :
Ans : A
V
B
G
O
R
Y
given compound is :
CH
3
3
H
CH
3
H CH
3
a) 0 b) 1 c) 2 d) 4
Ans : A
2 3 3
4 2
Co H O NH Cl (

is
Ans : D
( ) ( )
2 3 3
4 2
Co H O NH Cl (

nitrogen ?
a)
3 4 2
3 2 4
c)
3 4 2
3 4 2
# 20
Ans : B
3
5 HNO +
2 NO +
2
0 N
4
3 NH Cl
Decreasing order of
O -S =
3 2 4
2
mol
2
) is
a) 1.0 b) 4.5 c) 1.5 d) 3.0
Ans : C
( )
2
2
n a
P v nb nRT
v
| |
+ =
|
\ .
n = 1, b = 0
( )
2
q
p v b RT
v
| |
+ =
|
\ .
a
pv RT
v
+ =
a
pv RT
v
=
( )
2 2
21.6 20.1
1.5 .
3 2
= + = = = =

# 21
29. In allene ( )
3 4
a) sp and sp
3
b) sp and sp
2
c) only sp
2
d) sp
2
and sp
3
Ans : B
2 2
H C C CH = =
2 2
sp sp sp
0
is Bohr
radius]
a)
2
2 2
0
4
h
ma t
b)
2
2 2
0
16
h
ma t
c)
2
2 2
0
32
h
ma t
d)
2
2 2
0
64
h
ma t
Ans : C
mvr=
2
nh
t
v=
2
nh
mr t
2
r =4
0
a
V=
0
4
h
ma t
2
2
2 2 2
0
16
h
V
m a t
=
K.E
2
2
2 2
0
1
2 32
h
mv
ma t
= =
# 22
SECTION II
a) b) c)
O
d)
O
Ans : BC
3
dissolves in ( )
2 2 3
Na S O aq ?
Ans : ACD
3 3
AgNO HX AgX HNO + +
aq aq
( )
2 2 3 3 2 3
2

aq
aq
s
AgF is soluble
Ans : AD
# 23
S A
as change
a)
x z x y y z
S S S

A = A + A b)
x z x y y z
W w w

= +
c)
x y z x y
w w

= d)
x y z x y
S S

A = A
Ans : AC
x y x y y z
S S S

A = A + A
x y z x y
W W

=
a)
6 5 6 5
6 5 6 5 2
c)
6 5 2 6 5
6 5 2 6 5 2
Ans : BD
3
NaHCO ,
# 24
SECTION III
(both i nclusive).
C
CH
2
CHOH
CHOH
CHO
CH
2
OH
OH H
Ans : 8
solution
1
is 36.5 g mol
1
0.4 M HCl is :
Ans : 8
10 d x
GMW

=
10 1.25 29.2
36.5

=10M

1 1 2 2
1
1
10 200 0.4
8 ( )
V M V M
V
V ML approx
=
=
=
Ans : 8
63 1 1 4 1 52
29 1 0 2 1 26
6 2 CU H n He H X + + + +
26
Fe 8 th group
# 25
1/8
and t
1/10
Ans : 9
1
8
1
10
2.303
log
8
2.303
log
10
a
t
a
k
a
t
a
k
=
=
1
8
1
10
log8
log10
t
t
=
1
8
1
10
3log 2
t
t
=
1
8
1
10
10 9
t
t
=
1
and R
2
Ans : 4
# 26
MATHEMATICS
SECTION I
2
1 a z z = + +
a) 1 b)
1
3
c)
1
2
d)
3
4
Ans. D
Let Z x iy = + ( ) 0 y =
2
1 a z z = + +
becomes
( ) ( )
2
1 a x iy x iy = + + + +
( ) ( )
2 2
1 2 0 x y x i xy y a i + + + + = +
2 2
1 x y x a + + = (1)
2 0 xy y + = (2)
From (2)
1
2
x

=
as 0 y =
2
2
1 1
1
2 2
y a
| |
+ =
|
\ .
2
1 1
4 2
y a + =
2
3
0
4
y a = >
3
4
a <
# 27
42. If
2
1
lim 4
1
x
x x
ax b
x
| | + +
=
|
+
\ .
, then
a) a = 1, b = 4 b) a = 1, b = 4 c) a = 2, b = 3 d) a = 2, b = 3
Ans. B
2
1
lim 4
1
x
x x
ax b
x
+ +
=
+
( ) ( )
2
1 1 1
4
1
x
x a x a b b
lim
x
+ +
=
+
2
0 x =
1 a = 0
a = 1
( ) 1 1
lim 4
1
x
x a b b
x
+
=
+
1 4 a b =
b = 4
43. Let
ij
P a ( =

be a
3 3
matrix and let
ij
Q b ( =

, where 2
i j
ij ij
b a
+
a) 2
10
b) 2
11
c) 2
12
d) 2
13
Ans. D
as 2
i j
ij ij
b a
+
=
11 11 12 12 13 13
4 , 8 , 16 b a b a b a = = =
21 2 22 22 23 23
8 , 16 , 32 b a b a b a = = =
31 31 32 32 33 33
16 , 32 , 64 b a b a b a = = =
11 12 13
21 22 23
31 32 33
2
a a a
A a a a
a a a
(
(
= =
(
(

# 28
11 12 13
21 22 23
31 32 33
4 8 16
8 16 32
16 32 64
a a a
B a a a
a a a
(
(
=
(
(

11 12 13
21 22 23
31 32 33
4 8 16 2 2 2
4 4 4
a a a
a a a
a a a
(
(
=
(
(

11 12 13
21 22 23
31 32 33
4 8 16 2 4
a a a
a a a
a a a
(
(
=
(
(

4 8 16 2 4 2 =
13
2 B =
44. The ellipse
2 2
1
: 1
9 4
x y
2
2
is
a)
2
2
b)
3
2
c)
1
2
d)
3
4
Ans. C
Given Ellipse
2 2
1
9 4
x y
+ =
3 & 2 x y = =
( ) ( ) 3, 2 , 3, 2 C D
D
(0,2)
(3,0)
(0,-2)
(-3,0)
A
B
C
( ) ( ) 3, 2 , 3, 2 A B
As new ellipse
# 29
Let new ellipse is
2 2
2 2
1
x y
a b
+ =
Passes through ( )
2
2
16
0,4 1 16 b
b
= =
2
9 4
1
16 a
+ =
2
12 a =
2 2
1
12 16
x y
+ =
( )
2 2 2
1 a b e =
( )
2
12 16 1 e =
2
12 1
1
16 4
e = =
1
2
e =
3 2
2 15 36 1 f x x x x = + + is
Ans. B
| | | | : 0, 3 1, 29 f
( )
3 2
2 15 36 1 f x x x x = + +
( )
' 2
6 30 36 f x x x = +
( )( ) 6 2 3 x x =
( ) ( )
''
6 2 5 f x x =
2 x =
is pt of maxima.
# 30
3 x =
is pt of minima.
( ) & 2 29 0 f = >
( ) 3 0 f >
so curve is
n
f is not one one
2 3
Min value ( ) 0 1 f = =
Max value ( ) 2 29 f = =
so
n
f is Onto.
2 2
9 x y + = is
a) ( )
2 2
20 36 45 0 x y x y + + = b) ( )
2 2
20 36 45 0 x y x y + + =
c) ( )
2 2
36 20 45 0 x y x y + + = d) ( )
2 2
36 20 45 0 x y x y + + =
Ans. A
Let ( ) ( )
1 1
, & , P h k Q x y
4 20
,
5
h
P h
| |
|
\ .
P
A
B
Q
1
0 AB S =
4 20
9
5
h
xh y
| |
+ =
|
\ .
( ) 5 4 20 45 xh y h + = ------------------(1)
1 1
, Q x y
# 31
2 2
1 1 1 1
xx yy x y + = + ---------------(2)
Compare (1) & (2)
2 2
1 1 1 1
5 4 20 45 h h
x y x y
= =
+
1 1
2 2 2 2
1 1 1 1
9 45
&4 20
x y
h h
x y x y
= =
+ +
On eliminating h
1 1
2 2 2 2
1 1 1 1
49 45
20
x y
x y x y
=
+ +
( )
2 2
1 1 1 1
20 36 45 x y x y + =
Locus is
( )
2 2
20 36 45 0 x y x y + + =
a)
1
2
b)
2
c) 2 d)
2 2
Ans. A
Equation of
1 1 4
1 4 1
x y z
QR
+
= = =
Drs of ( ) 1, 4,1 QR
Co-ordinates of ( ) 1 , 1 4 , 4 P + + +
( ) ( ) ( ) 5 1 4 1 4 4 1 + + + =
1
3
=
T(2,1,4)
Q
S R
# 32
4 1 13
, ,
3 3 3
P
| |
|
\ .
Let ( ) 1 , 1 4 , 4 S + + +
Drs of ( ) 1, 4 2, TS
TS QR So,
( ) ( ) 1 1 4 4 2 0 + + =
1
2
=
3 9
,1,
2 2
S
| |
|
\ .
2 2 2
4 3 1 13 9
1
3 2 3 3 2
PS
| | | | | |
= + +
| | |
\ . \ . \ .
1
2
=
48. Let
( )
2
cos , 0
0, 0
x x
f x x
x
t
=
,
x IR e
, then f is
Ans. B
( )
2
cos ; 0
0 ; 0
x x
f x x
x
t
=
At x=0
# 33
( ) ( )
2
0 0
cos 0
0 0
lim lim
h h
h
f h f
h
RHD
h h
t

+
=
0
lim cos 0
h
h
h
t
| |
= =
|
\ .
( ) ( )
2
0 0
cos 0
0 0
lim lim
h h
h
f h f h
LHD
h h
t

| |

|

\ .
=

0
lim cos 0
h
h
h
t
| | | |
= =
| |
\ . \ .
At x=2
( ) ( )
( )
2
0 0
2 cos 4 cos
2 2
2 2
lim lim
h h
h
f h f
h
RHD
h h
t t

+
+
+
= =
( ) ( )
( )
2
0 0
2 cos 4 cos
2 2
2 2
lim lim
h h
h
f h f
h
LHD
h h
t t

= =


a) 75 b) 150 c) 210 d) 243
Ans. B
Case-I
Total ways 2 2 1
2
1
2
1 2 2
( )
5 3 1
2 2 1
3 C C C =
# 34
10 3 1 3 90 = =
Case-II
Total ways
( )
5 2 1
3 1 1
3 C C C =
1
1
1
1
3
3
1
3
1
10 2 1 3 60 = =
Total ways = 90 + 60 = 150.

50. The integral
( )
2
9/ 2
sec
sec tan
x
dx
x x +
a)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ +
`
) +
b)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ +
`
) +
c)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ + +
`
) +
d)
( )
( )
2
11/ 2
1 1 1
sec tan
11 7
sec tan
x x K
x x

+ + +
`
) +
Ans. C
( )
9
2
sec
sec tan
x
dx
x x +
}
Let
sec tan x x t + =
-------------(1)
So, ( )
2
sec
dt
x dx
t
=
------------(2)
# 35
1
sec tan x x
t
=
----------(3)
From (1) & (3)
1 1
sec
2
x t
t
| |
= +
|
\ .
( )
9
2
sec .sec
sec tan
x x
dx
x x +
}
9
2
1 1
2
dt
t
t
t
t
| |
+
|
\ .
}
2
13
2
1 1
2
t
dt
t
+
}
9 13
2 2
1
2
t dt t dt

(
= +
(

} }
7 11
2 2
1
7 11
2
2 2
t t
K

(
(
= + +
(

7 11
2 2
7 11
t t
K

= + +

( ) ( )
7 11
2 2
1 1
=
+ +
( )
( )
2
11
2
1 1 1
sec tan
11 7
sec tan
x x K
x x
| |
= + + +
|
\ .
+
# 36
SECTION II
1
, E
2
and E
3
1 1
,
2 4
and
1
4
1
, X
2
and X
3

1
, E
2
and E
3
a)
1
3
|
16
c
P x X ( =

7
8
=
c) | |
2
5
|
16
P X X =
d) | |
1
7
|
16
P X X =
Ans. B,D
A)
( )
( )
1
1 1 1
1
2 4 4
1
8
4
c
P X X
P X

= =
( )
1 1 3 1 1 1 1
2 2
2 4 4 2 4 4 4
P X
| | | |
= + =
| |
\ . \ .
B)
| |
1 1 3 1 1 1
2
7 2 4 4 2 4 4
/
1
8
4
| |
+
|
\ .
= =
C)
( )
| |
( )
2
2
2
1 1 3 1 1 1
2
5 2 4 4 2 4 4
/
1
8
4
P X X
P X X
P X
| | | |
+
| |
\ . \ .
= = =
D)
( )
| |
( )
1
1
1
1 1 3 1 1 1
2
7 2 4 4 2 4 4
/
1
16
2
P X X
P X X
P X
| |
+
|
\ .
= = =
# 37
2 2
1
9 4
x y
a)
9 1
,
2 2 2
| |
|
\ .
b)
9 1
,
2 2 2
| |

|
\ .
c)
( )
3 3, 2 2 d)
( )
3 3, 2 2
Ans. A, B
2 2
1
9 4
x y
=
2 y x = +
( )
2
9 4 4 36 4 32 = = =
4 2 =
Tangent is :
2 4 2 0 x y =
Point of contact is
2 2
9 1 9 1
, , , ,
2 2 2 2 2 2
a l b m
n n
| | | | | |
=
| | |
\ . \ . \ .
2
x
y e
=
, y = 0, x = 0, and x = 1. Then
a)
1
S
e
>
b)
1
1 S
e
>
c)
1 1
1
4
S
e
| |
s +
|
\ .
d)
1 1 1
1
2 2
S
e
| |
s +
|
\ .
Ans. A, B, D
2
1 1
0 0
1
1
x x
I e dx e dx
e

= > =
} }
1
1 I
e
>
2
1
1
x
e e

s s
2
1 1 1
1
0 0 0
x
e dx e dx dx

s s
} } }
2
1
0
1
x
e dx
e
>
}
# 38
a)
2
4 8 2
y
t t | |
=
|
\ .
b)
2
'
4 18
y
t t | |
=
|
\ .
c)
2
3 9
y
t t | |
=
|
\ .
d)
2
4 2
'
3 3 3 3
y
t t t | |
= +
|
\ .
Ans. A,D
tan 2 sec
dy
y x x x
dx
=
tan
. cos
dx
I F e x
}
= =
}
2
x c = +
2
( ) 0, 0
0 0 0 c c = + =
.
2
sec y x x =
( )
2
2
4 16
y
t t | |
=
|
\ .
2
8 2
t
=
2
2
3 9
y
t t | |
=
|
\ .
2
sec tan 2 sec
dy
x x x x x
dx
= +
.
( )
2
1
2 3 2 2
3 9 3
y
t t t | | | |
= +
| |
\ . \ .
2
2 4
3 3 3
t t
= +
# 39
55. Let
u
( )
2
2 2
u u
u | u |
| |
= +
|
\ .
,
( ) tan 2 0 t u > and
3
1 sin
2
u < < .
a)
0
2
t
| < <
b)
4
2 3
t t
| < <
c)
4 3
3 2
t t
| < <
d)
3
2
2
t
| t < <
Ans. A, C, D
( )
3
tan 2 0, 1 sin
2
t u u > < <
3 5 1
, 0 cos
2 3 2
t t
u u
| |
e < <
|
\ .
______ (1)
( ) ( )
2
( )
1
sin cos
2
u | u + = +
( )
1
sin 1
2
u | < + <
(from (1))
13 17
6 6
t t
u | < + <
2 7
3 6
t t
| < <
(from (1))
# 40
SECTION III
( ) ' 0 p
is
Ans. 9
( )
3 2
( ) 1 6 6 P a b c d = + + + =
( ) 3 2 27 9 3 2 P a b c d = + + + =
( )
1
1 0 3 2 0 P a b c = + + =
( )
1
3 0 27 6 0 P a b c = + + =
1, 6, 9 a b c = = =
( )
1 2
3 2 P x ax bx c = + +
( )
1
0 9 P c = =
57. If
, a b
and
c

2 2
2
9 a b b c c a + + =

,then 2 5 5 a b c + +

is\
Ans. 3
sol. 1 a b c = = =

2 2
2
9 a b b c c a + + =

3
.
2
a b b c c a

+ + =
( )
3 2 . . 0 a b b c c a + + + =

2
2 2
2 . . . 0 a b c a b b c c a + + + + + =

2
0 a b c + + =
# 41

0 a b c + + =
(1)
then
1 1 1
. , . , .
2 2 2
a b b c c a

= = =
2 5 5 3 a b c + + =
58. The value of
3
2
1 1 1 1
6 log 4 4 4 ...
3 2 3 2 3 2 3 2
| |
|
+
|
\ .
is
Ans. 4
sol.
1
4
3 2
x x =
3 2 4 x x =
2
18 4 x x =
2
18 4 0 x x + =
2
18 9 8 4 0 x x x + =
( ) ( ) 9 2 1 4 2 1 0 x x x + + = .
( )( ) 2 1 9 4 0 x x + =
1 4
,
2 9
x =
4
9
x =
( ) 0 x >
Required answer is
2
3/ 2
3
6 log
2
| |
+
|
\ .
= 6 2
= 4
2
2 2
Ans. 4
# 42
sol.
P
Q
S
(0, 0)
(2,4)
(2, 0)
2
(0,4)
2
8 2 4 2 0 x x x x + =
( ) ( ) 0, 2 0, 0 , 2, 4 x P Q = = =
area of SPQ A
=
1
2 4
2

= 4
2
Ans. 5
sol. ( )
2
1, 1 f x x x x = + s

2
1 , 1 0 x x x = + < <

2
1 , 0 1 x x x = + s <

2
1, 1 x x x = + >
( ) ' 2 1, 1 f x x x = <
2 1, 1 0 x x = < <
0
-1 1
x
y
1 2 , 0 1 x x = < <
1 2 , 1 x x = + >
differentiable at
1 1
,
2 2
x =
,

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Sr i Chai t anya I I T Ac ademy., A.P.

Range of pebble is R =5m

do not vary with time

varies with time while

remains constant while

varies with time

both vary with time

From centre to surface V = k, then

on the system about O, as a function of time is best represented by

. At time t = 0 , this charge has

in the x y plane, making an angle

Net flux passing the plane

Net flux through cube is

Flux through plane

Sri Chaitanya IIT Academy PAPER-1 KEY & SOLUTIONS

Not Differentiable at x=2.

Total ways = 90 + 60 = 150.

are unit vectors satisfying

Range of pebble is R =5m

do not vary with time

varies with time while

remains constant while

varies with time

both vary with time

From centre to surface V = k, then

on the system about O, as a function of time is best represented by

. At time t = 0 , this charge has

in the x y plane, making an angle

Net flux passing the plane

Net flux through cube is

Flux through plane

Sri Chaitanya IIT Academy PAPER-1 KEY & SOLUTIONS

Not Differentiable at x=2.

Total ways = 90 + 60 = 150.

are unit vectors satisfying

Range of pebble is R =5m

do not vary with time

varies with time while

remains constant while

varies with time

both vary with time

From centre to surface V = k, then

on the system about O, as a function of time is best represented by

. At time t = 0 , this charge has

in the x y plane, making an angle

Net flux passing the plane

Net flux through cube is

Flux through plane

Sri Chaitanya IIT Academy PAPER-1 KEY & SOLUTIONS

Not Differentiable at x=2.

Total ways = 90 + 60 = 150.

are unit vectors satisfying

Range of pebble is R =5m

do not vary with time

varies with time while

remains constant while

varies with time

both vary with time

From centre to surface V = k, then

on the system about O, as a function of time is best represented by

. At time t = 0 , this charge has

in the x y plane, making an angle

Net flux passing the plane