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HOCHSCHULE ZITTAU/GRLITZ

( FH) - Univer sit y of Appl ied Sciences

Faculty of MECHANICAL ENGINEERING Department of TECHNICAL THERMODYNAMICS

Property Software for Ideal Gases and Gas Mixtures

FluidTI for TI 89 and TI 92 TI Voyage 200

Prof. Hans-Joachim Kretzschmar Dr. Ines Stoecker Dipl.-Ing. (FH) L. Kleemann R. Krause

Property Functions for Ideal Gases and Gas Mixtures from the VDI-Guideline 4670

IDGAS FluidTI

Contents
1. Property Functions 1.1 Range of Validity and Structure of Program Library 1.2 Property Functions for Ideal Gases and Mixtures 2. Using "FluidTI - Ideal Gases and Mixtures" 2.1 Installation on the calculators TI 89, TI 92, TI 92Plus, and TI Voyage 200 2.2 Example: Calculation of the Enthalpy h = f(p,t) of a Gas 2.3 Example: Calculation of the Enthalpy h = f(t,1... 10) of the Gas Mixture 2.4 Example: Calculation of the Mass Fraction i = f(i, 1...10) of a Gas 2.5 Removing FluidTI 3. Software Documentation 4. References

_____________________________________________________ Zittau/Goerlitz University of Applied Sciences (FH) Faculty of Mechanical Engineering Department of Technical Thermodynamics Prof. Dr.-Ing. habil. H.-J. Kretzschmar Dr.-Ing. I. Stoecker Tel.: +49 3583-61-1846 or -1881 Fax: 03583-61-1847 E-mail: hj.kretzschmar@hs-zigr.de Internet: www.thermodynamics-zittau.de

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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1. Property Functions
1.1 Range of Validity and Program Library Structure
Calculation of thermodynamic properties of gases and mixtures of gases in ideal gas state is carried out with the algorithms of the VDI-Guideline 4670 [1] while transport properties are calculated according to Brandt [2] . Important properties were taken from the Blanke [4] compendium. It is possible to calculate mixtures of the following gases, which are in the following referred to as mixtures of gases: Gas-No. 1 2 3 4 5 6 7 8 9 10 Mixture gas Argon Neon Nitrogen Oxygen Carbon monoxide Carbon dioxide Steam Sulfur dioxide Air (dry) Atmospheric Nitrogen Ar Ne N2 O2 CO CO2 H2O SO2

Calculation programs are valid in the temperature range: from - 73.15 C to 1,726.85 C Pressure range is restricted to the range in which the gas mixtures can be considered as ideal gases and thus ranges from from above 0 MPa to 1 (3) MPa, maximum 5 MPa The assumption of ideal gas applies to a good approximation to 1 MPa, while above and to 5 MPa at temperatures below 500 C you have to accept substantial inaccuracies of the properties calculated. These inaccuracies have only few effects on the calculation of the efficiency of gas turbines. Available subprograms and functions in "FluidTI - Ideal Gases and Mixtures" are specified in the following subsection.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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1.2 Property Functions for Ideal Gases and Mixtures "Ideal Gases and Mixtures"
Functional Dependence v = f(p, t,1...10 or 1...10) h = f(t,1...10 or 1...10 s = f(p,t,1...10 or 1...10) cp = f(t,1...10 or 1...10) Function Name Property or Function Unit of the Function Value m/kg kJ/kg kJ/kg K kJ/kg K W/m K
. . . . .

Source or Algorithm

Information on page

v_pt_ig h_t_ig s_pt_ig cp_t_ig Kappa_t_ig _t_ig Eta_t_ig t_h_ig t_ps_ig M_ig R_ig

Specific volume of the mixture Specific enthalpy of the mixture Specific entropy of the mixture Specific isobaric heat capacity of the mixture Isentropic exponent of the mixture Thermal conductivity of the mixture Dynamic viscosity of the mixture Backward function: Temperature from the enthalpy of the mixture Backward function: Temperature from pressure and entropy of the mixture Molar mass of the mixture Specific gas constant of the mixture

ideal gas equation [1] [1] [1] [1] [2], [3]

3/13 3/4 3/10 3/2 3/5 3/6 3/3 3/11 3/12 3/7 3/9 3/14 3/8

= f(t,1...10 or 1...10)

= f(t,1...10 or 1...10) = f(t,1...10 or 1...10)


t = f(h,1...10 or 1...10) t = f(p,s,1...10 or 1...10) M = f(1...10 or 1...10) R = f(1...10 or 1...10)

Pa s = kg/m s [2], [3] K K kg/kmol kJ/kg K kg/kg kmol/kmol


.

[1] [1] [4] [4] Conversion with the rule of mixture Conversion with the rule of mixture

i = f(i,1...10) i = f(i,1...10)

Xsi_igas_Psi_ig Mass fraction of the gas mixture i from mole fractions of all gas mixtures Psi_igas_Xsi_ig Mole fraction of the gas mixture i from mass fractions of all gas mixtures

Hochschule Zittau/Grlitz (FH), Fachgebiet Technische Thermodynamik, Prof. Dr.-Ing. habil. H.-J. Kretzschmar, Dr.-Ing. I. Stcker

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Mixture gases
Gas-No. Mixture gas 1 2 3 4 5 6 7 8 9 Argon Neon Nitrogen Oxygen Carbon monoxide Carbon dioxide Steam Sulfur dioxide Ar Ne N2 O2 CO CO2 H 2O SO2

Air (dry) Composition in mole fractions: 78.1109 % N2 20.9548 % O2 0.9343 % Ar from VDI4670 [1] Composition in mass fractions: 75.5577 % N 23.1535 % O2, 1.2888 % Ar 2 Atmospheric Composition in mole fractions: 98.7750 % N2, 0.0400 % CO2, 1.1820 % Ar, 0.0030 % Ne Nitrogen Composition in mass fractions: 98.2586 % N2, 0.0625 % CO2, 1.6768 % Ar 0.0021 % Ne corresponding to Brandt [2]

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Hochschule Zittau/Grlitz (FH), Fachgebiet Technische Thermodynamik, Prof. Dr.-Ing. habil. H.-J. Kretzschmar, Dr.-Ing. I. Stcker

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Units
Formula Symbol t p 1 ... 10 1... 10 art Description Temperature Pressure Mass fractions of gas mixtures Mole fractions or volume fractions of gas mixtures Input parameters: art = 1 for input of composition in mass fractions 1, ... 10 art = 0 for input of composition in mole fractions 1, ... 10 zu1 ... zu10 for art =1 zu1 ... zu10 for art =0 Composition as mass fractions 1, ... 10 Composition as mole fractions 1, ... 10 kg/kg kmol/kmol Unit C MPa kg/kg kmol/kmol

Range of validity:
Temperature range: Pressure: Specific volume: Specific enthalpy: Specific entropy:

Reference states:
t = -73.15 C to 1726.85 C p = 1 kPa ... 5 MPa v = 5.1 m3/kg ... 2,9 109 m3/kg h = -136 kJ/kg ... 4100 kJ/kg s = 2.8 KJ/kg K ... 9.7 KJ/kg K Thermodyn. Factor Pressure Temperature Enthalpy Entropy for single component 1.01325 bar 273.15 K 0 kJ/kg 0 kJ/kg

Note:
If the calculation results in -1 or -1000, this indicates that the values entered are located outside the range of validity or the sum of the values entered 1, 10 or. 1, ... 10 entered does not result in 1.
Hochschule Zittau/Grlitz (FH), Fachgebiet Technische Thermodynamik, Prof. Dr.-Ing. habil. H.-J. Kretzschmar, Dr.-Ing. I. Stcker

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2. Using "FluidTI - Ideal Gases and Mixtures"


2.1 Installation on the calculators TI 89, TI 92, TI 92Plus, and TI Voyage 200

The "FluidTI - Ideal Gases and Mixtures" program will be copied onto the pocket calculator with the help of a link program and the appropriate link cord. You can acquire the software needed on buying the TI calculator or in the Internet at the address http://www.ti.com/calc/docs/link.htm. The link cord necessary can be bought as accessory e. g. from Bttcher Datentechnik GmbH http://www.boettcher-datentechnik.de/. The following description applies to the link programs TI-Graph-Link and TI-Connect, whereas the particular program must be installed. If you are using other link programs you have to take the steps for data transfer from the appropriate instructions manual or online help. 1. Insert the FluidTI floppy disk in the floppy drive of your computer. It contains the group files listed in the following table: TI-Model File TI 89 IdGas89.89g TI 92 IdGas92E.92g TI 92Plus, IdGas92P.9xg TI Voyage 200 IdGasVoyage200.9xg

2. For the installation and working with the program it is necessary that the language of the TI-calculator is set to English. If this is not the case, you can change the language corresponding to the following description: - Press the <MODE> key - Press the <F3> key The language currently set is displayed next to "Language". - Open the "Language" menu by pressing the right direction key You will now see all available languages on your TI-calculator - Select the language "English" with the help of the direction keys - Confirm your selected language by pressing the <ENTER> key - Confirm your selection again by pressing the <ENTER> key 3. Connect your TI-calculator to your computer by plugging the link cord in a free serial interface (mostly COM2 or USB) and the phono connector in the pocket calculator. If you wish to use the TI-Connect link program for data transfer, please follow subsection 5.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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4. Data Transfer using the TI-Graph-Link Program


a) Run the TI-Graph-Link program on your computer. Click on "Link" in the upper menu bar and then select "Send". Search and click the letter of your floppy disk drive in the "Drives:" window. The group file belonging to your TI model appears in the "File name:" window. Considering the table above click on the file belonging to your model and afterwards click the "Add" button. The group file and the drive letter will be shown in the "Selected files:" window. Highlight the square "Retain folder" by clicking on it. Click the "OK" button. Now, the data transfer from the computer to your pocket calculator begins. You will now see the files which have been copied. The directory FLUIDTI will be created on your TI and afterwards the appropriate program files of the group file will be copied into it. b) Click the "OK" button to confirm the "Finished" notification which appears on your computer screen. You have now finished installation of FluidTI on your pocket calculator. If the copying process has failed, the following errors are possible: - TI has not been connected or switched on when the TI-Graph-Link program had been started - The TI cursor was not placed in the command line - A wrong cord has been used - The connectors are not plugged in properly - A wrong interface is set (menu item "Link") c) In order to run the program, navigate into the "fluidti" directory by pressing <MODE> and select the entry "fluidti" in the field "Current Folder" by pressing the right direction key. Confirm your selection by pressing the <ENTER> key. Now, "fluidti" flashes in the "Current Folder" field. Confirm again by pressing <ENTER>. In the lower left edge of the screen you will now see "FLUIDTI". Type "idgas()" and confirm your entry by pressing the <ENTER> key. Now, proceed as described in section 2.3.

5. Data Transfer Using the TI-Connect Program


a) Run the TI-Connect program on your computer.

Click on "DeviceExplorer". In some cases, the "TI Communication Settings" menu will be opened. You will see the name of your TI calculator, the name of the cord and the port which will be used for the cord. Check if everything is correct and confirm by clicking the "OK" button. In the following window you will see the directory tree with the programs of the connected TI calculator.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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Click on "Tools" in the upper menu bar and then select "GroupExplorer". Search the letter of your floppy drive in the main window and click on the "+" next to the drive name. Below the name of the floppy drive you will now see the group files. Considering the table above, left click the file belonging to your model. Now, right click the item in order to open the pop-up menu. Within the menu click on "Send To Device". Now, the data transfer from the computer to your pocket calculator begins. You will now see the files which have been copied on your computer screen. The directory FLUIDTI will be created on your TI and afterwards the appropriate program files of the group file will be copied into it. You have now finished installation of FluidTI on your TI-pocket calculator. b) If the copying process has failed, the following errors are possible: - TI has not been connected or switched on when the TI-Connect program had been started - The TI cursor was not placed in the command line - A wrong cord has been used - The connectors are not plugged in properly c) In order to run the program, navigate into the "fluidti" directory by pressing <MODE> and select the entry "fluidti" in the field "Current Folder" by pressing the right direction key. Confirm your selection by pressing the <ENTER> key. Now, "fluidti" flashes in the "Current Folder" field. Confirm again by pressing <ENTER>. In the lower left edge of the screen you will now see "FLUIDTI". Now, type "idgas()" and confirm your entry by pressing the <ENTER> key. Now, proceed as described in section 2.2.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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2.2 Calculation of the Entropy s = f(p, t) of a Gas


We will now calculate, step by step, the specific entropy s as a function of temperature t = 250 C, and pressure p = 1 MPa. The result of the specific entropy calculated is to be saved within the variable "s1". Please carry out the following instructions: 1. Run the "FluidTI - Ideal Gases and Mixtures" program as described in section 2.1. 2. After leaving the start screen by pressing <ENTER>, you will see the menu with which you can choose to calculate either individual gases or gas mixtures.

Select "individual gas" and confirm by pressing <ENTER> twice. 3. In the main menu, select the gas "oxygen" next to "Choose a gas" and confirm by pressing <ENTER> twice.

4. In the next menu "Function input" choose the function "s_pt_ig" and confirm by pressing <ENTER> twice.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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5. In the "Input" menu, you now have to enter the values of the given state variables. According to our example, type the values "1" for p in MPa and the value "250" for t in C. Confirm your input by pressing the <ENTER> key twice. Now, the calculation will be carried out. Note: Please make sure that the input values are located within the range of validity of the chosen function (cp. section 1.2).

While the calculation is carried out, you will see the "Busy" symbol in the lower right edge of your screen. 6. After the calculation has been carried out successfully the "Output" menu appears.

Next to "save as :" enter the name "s1" for the variable in which the result is going to be saved. You can now use the result in further calculations within or outside "FluidTI - Ideal Gases and Mixtures". An example would be the input of the entropy calculated before when calculating the function "t_ps_ig". Go back to the main menu by pressing the <ENTER> key. Note: You can arbitrarily choose the name of the variable. It should merely not begin with the sign (omega) and it should not bear the name of a system variable (cp. TI manual). Generally, variables used within the FLUIDTI directory should not begin with the sign .

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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2.3 Calculation of the Enthalpy h = f(t,1... 10) of a Gas Mixture


We will now calculate, step by step, the specific enthalpy h of a flue gas as a function of temperature t = 100 C, and a mixture consisting of the following mass fractions: 13 % carbon monoxide, 11 % steam, and 76 % air nitrogen. Please carry out the following instructions: 1. Run the "FluidTI - Ideal Gas and Mixture" program as described in section 2.1. 2. After leaving the start screen by pressing <ENTER>, you will see the menu with which you can choose to calculate either individual gases or gas mixtures. Select "gas mixture" and confirm by pressing <ENTER> twice.

3. In the main menu, select the entry "mass fraction i" next to "Input in" because we need to enter the gas fractions in mass fractions in our sample calculation. You must confirm your input by pressing the <ENTER> key.

4. The input of the gas fractions will be carried out within two separate screens. It is not necessary to enter a value for the gases whose percentage of the mixture is 0. You may also enter the value "0" for these gases. In the first screen you have to enter the fractions of argon, neon, nitrogen, oxygen, and carbon monoxide. Corresponding to our example you have enter the value "0.13" for carbon monoxide. Confirm by pressing <ENTER>. Note: Use the point on your keypad as decimal point. The sum of the fractions of the individual gases must result in 1.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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In the second screen you have to enter the fractions of carbon dioxide, steam, sulfur dioxide, air (dry), and air nitrogen. Enter the value "0.11" for steam and "0.76" for air nitrogen. Confirm your input by pressing the <ENTER> key. Note: Use the point on your keypad as decimal point. The sum of the fractions of the individual gases must result in 1.

5. Chose the function "h_t_ig" in the function input menu and confirm by pressing <ENTER>.

6. Now the parameter input window pops up. Here you have to enter the appropriate state variables of the function such as temperature, pressure, enthalpy, and entropy. The function "h_t_ig" only depends on the temperature. Now, type "100" for t in C and confirm your entry by pressing the <ENTER> key. Now, the calculation will be carried out automatically. Note: Please make sure that the input values are located within the range of validity of the chosen function (see section 1.2).

7. While the calculation is carried out, you will see the "Busy" symbol in the lower right edge of your screen. After the calculation of the chosen function has been carried out successfully the "Output" menu appears. It is now possible to save the calculated result in a variable and to use it in another calculation. Go back to the main menu by pressing the <ENTER> key.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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2.4 Calculation of the Mass Fraction i = f(i, 1...10) of a Gas


We will now calculate, step by step, the mass fraction i of argon as a function of the given mixture consisting of the following mole fractions: 20 % argon and 80 % carbon monoxide Please carry out the following instructions: 1. Run the "FluidTI - Ideal Gas and Mixture" program as described in section 2.1. 2. After leaving the start screen by pressing <ENTER>, you will see the menu with which you can choose to calculate either individual gases or gas mixtures. Select "gas mixture" and confirm by pressing <ENTER> twice.

3. In the main menu, select the entry "mol fraction i" next to "Input in" because we need to enter the gas fractions in mole fractions in our sample calculation. You must confirm your input by pressing the <ENTER> key.

4. Enter the values "0.2" for argon and "0.8" for carbon monoxide. It is not necessary to enter a value for the gases whose percentage of the mixture is 0. You may also enter the value "0" for these gases. Confirm by pressing <ENTER>.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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5. Chose the function "_igas__ig" in the function input menu and confirm by pressing <ENTER>.

6. Now the input window for selecting the gases pops up. Chose the gas "argon" in the input menu and confirm by pressing <ENTER>.

7. While the calculation is carried out, you will see the "Busy" symbol in the lower right edge of your screen. After the calculation of the chosen function has been carried out successfully the "Output" menu appears. It is now possible to save the calculated result in a variable and to use it in another calculation. Go back to the main menu by pressing the <ENTER> key.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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2.5 Removing FluidTI


Please carry out the following instructions for the pocket calculators TI 89, TI 92, TI 92 Plus, and TI Voyage 200. 1. Open the "Var-Link" menu by pressing the <2nd> key and then the < - > key (but not <(-)> ). You will see the following menu:

2. Search the FLUIDTI directory with the cursor and highlight it by pressing the <F4> key. In front of the FluidTI directory and the appropriate files appears a checkmark.

If you have other FluidTI programs installed on your TI (e. g. Water and Steam from IAPWS-IF97 or Humid Air (cp=const)), you will find them in the FLUIDTI directory as well. If you do not wish to remove them, please make sure that they are not checkmarked. If necessary you have to move the cursor on these files and remove the checkmark by pressing the <F4> key. Checkmark only those files which should really be deleted. The program package "FluidTI - Ideal Gas and Mixture" contains the following files: igasdat1, igasdat2, igasdat3, igasdat4, and idgas. 3. Press the <F1> key. The "Manage" menu appears. Select "UnLock Variable" with the cursor and confirm this selection by pressing <ENTER>.

4. Deletion is carried out by opening the "Manage" menu again pressing <F1>, then select the option "Delete" with the cursor and confirm by pressing <ENTER>. Confirm the following query by pressing <ENTER> again. Now FluidTI has been removed.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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3.

Software Documentation

Specific Isobaric Heat Capacity cp = f(t, 1...10 or 1...10) Name in "FluidTI - Ideal Gas and Mixture" cp_t_ig Input Values: t art - Temperature t in C - Type of composition: art=1 for composition in mass fractions art=0 for composition in mole fractions

zu1...zu10 - composition in mass fractions 1...10 in kg/kg - composition in mole fractions 1... 10 in kmol/kmol Result: cp_t_ig or cp - specific isobaric heat capacity in kJ/(kg K) Range of validity: Temperature t: Comments: Model of an ideal mixture Results for wrong input values: cp_t_ig or cp = -1 References: cp from VDI 4670 [1] from -73.15 C to 1,726.85 C

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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Dynamic Viscosity = f(t, 1...10 or 1...10) Name in "FluidTI - Ideal Gas and Mixture" Eta_t_ig Input Values: t art - Temperature t in C - Type of composition: art=1 for composition in mass fractions art=0 for composition in mole fractions

zu1...zu10 - composition in mass fractions 1...10 in kg/kg - composition in mole fractions 1... 10 in kmol/kmol Result: Eta_t_ig or eta - dynamic viscosity in Pa s Range of validity: Temperature t: from -73.15 C to 1,726.85 C

Comments: Calculations corresponding to Brandt Model of ideal mixture Results for wrong input values: Eta_t_ig or Eta = -1 References: Unsaturated and saturated humid air: corresponding to Brandt [2]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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Specific Enthalpy h = f(t, 1...10 or 1...10) Name in FluidTI- Ideal Gas and Mixture: h_t_ig Input Values: t art - Temperature t in C - Type of composition: art=1 for composition in mass fractions art=0 for composition in mole fractions

zu1...zu10 - composition in mass fractions 1...10 in kg/kg - composition in mole fractions 1... 10 in kmol/kmol Result: h_t_ig or h - specific enthalpy in kJ/kg Range of validity: Temperature t: Comments: Model of an ideal mixture Results for wrong input values: h_t_ig or h = -1000 References: h from VDI 4670 [1] from -73.15 C to 1,726.85 C

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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Isentropic Exponent = f(t, 1...10 or 1...10) Name in FluidTI- Ideal Gas and Mixture: Kappa_t_ig Input Values: t art - Temperature t in C - Type of composition: art=1 for composition in mass fractions art=0 for composition in mole fractions

zu1...zu10 - composition in mass fractions 1...10 in kg/kg - composition in mole fractions 1... 10 in kmol/kmol Result: Kappa _t_ig or Kappa Isentropic exponent Range of validity: Temperature t: Comments: Kappa
=
cp cp R

from -73.15 C to 1,726.85 C

Results for wrong input values: Kappa _t_ig or Kappa = -1 References: Unsaturated and saturated humid air: cp from VDI 4670 [1]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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Thermal Conductivity = f(t, 1...10 or 1...10) Name in FluidTI- Ideal Gas and Mixture: _t_ig Input Values: t art - Temperature t in C - Type of composition: art=1 for composition in mass fractions art=0 for composition in mole fractions

zu1...zu10 - composition in mass fractions 1...10 in kg/kg - composition in mole fractions 1... 10 in kmol/kmol Result: _t_ig or - Thermal conductivity in W/(m K) Range of validity: Temperature T: Temperature t: Comments: Calculations corresponding to Brandt Model of ideal mixture Results for wrong input values: _t_ig or Lambda = -1 References: Unsaturated and saturated humid air: corresponding to Brandt [2] from -73.15 C to 1,726.85 C

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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Molar Mass M = f(t, 1...10 or 1...10) Name in "FluidTI - Ideal Gas and Mixture" M_ig Input Values: art - Type of composition: art=1 for composition in mass fractions art=0 for composition in mole fractions zu1...zu10 - composition in mass fractions 1...10 in kg/kg - composition in mole fractions 1... 10 in kmol/kmol Result: M_ig or M - Molar mass in kg/kmol Comments: Calculations according to Blanke Results for wrong input values: M_ig or M = -1 References: M corresponding to Blanke [4]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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Mole Fraction i = f(i, 1...10)

Name in "FluidTI - Ideal Gas and Mixture" Psi_igas_Xsi_ig Input Values: i - Description of the gas zu1...zu10 - composition in mass fractions 1...10 in kg/kg Result: Psi_igas_Xsi_ig or Psi - Mole fraction in kmol/kmol Comments: Mole fraction:
i =

(i Ri )

Ri

Results for wrong input values: Psi_igas_Xsi_ig or Psi = -1

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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Specific Gas Constant R = f(1...10 or 1...10)

Name in "FluidTI - Ideal Gas and Mixture" R_ig Input Values: art - Type of composition: art=1 for composition in mass fractions art=0 for composition in mole fractions zu1...zu10 - composition in mass fractions 1...10 in kg/kg - composition in mole fractions 1... 10 in kmol/kmol Result: R_ig or R - Specific gas constant in kJ/(kg K) Comments: Specific gas constant: R = ( i Ri )
i

or:

R=

1
i

( Ri )
i

Results for wrong input values: R_ig or R = -1

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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Specific Entropy s = f(p,t,1...10 or 1...10)

Name in "FluidTI - Ideal Gas and Mixture" s_pt_ig Input Values: p t art - Overall pressure p in MPa - Temperature t in C - Type of composition: art=1 for composition in mass fractions art=0 for composition in mole fractions

zu1...zu10 - composition in mass fractions 1...10 in kg/kg - composition in mole fractions 1... 10 in kmol/kmol Result: s_pt_ig or s - Entropy in kJ/(kg K) Range of validity: Pressure p: from 1 Pa to 5 MPa Temperature t: Comments: Model of an ideal mixture Results for wrong input values: s_pt_ig or s = -1000 References: s from VDI 4670 [1] from -73.15 C to 1,726.85 C

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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Backward Function t = f(h, 1...10 or 1...10)

Name in FluidTI- Ideal Gas and Mixture: t_h_ig Input Values: h art - Enthalpy h in kJ/kg - Type of composition: art=1 for composition in mass fractions art=0 for composition in mole fractions

zu1...zu10 - composition in mass fractions 1...10 in kg/kg - composition in mole fractions 1... 10 in kmol/kmol Result: t_h_ig or t - Temperature in C Range of validity: Enthalpy h: Comments: Iteration of t from h = f(t, zu1...zu10) Results for wrong input values: t_h_ig or t = -1 References: h from VDI 4670 [1]

from -135.6 kJ/kg to 4100 kJ/kg

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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Backward function t = f(p, s, 1...10 or 1...10)

Name in FluidTI- Ideal Gas and Mixture: t_ps_ig Input Values: p s art - Overall pressure p in MPa - Entropy s in kJ/(kg K) - Type of composition: art=1 for composition in mass fractions art=0 for composition in mole fractions

zu1...zu10 - composition in mass fractions 1...10 in kg/kg - composition in mole fractions 1... 10 in kmol/kmol Result: t_ps_ig or t - Temperature in C Range of validity: Pressure p: from 1 Pa to 5 MPa Enthalpy s: Comments: Iteration of T from s (p, t, zu1...zu10) Results for wrong input values: t_ps_ig or t = -1 References: s from VDI 4670 [1] from -2.377 kJ/(kg K) to 9.706 kJ/(kg K)

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

3/12

Specific Volume v = f(p, t, 1...10 or 1...10)

Name in FluidTI- Ideal Gas and Mixture: v_pt_ig Input Values: p t art - Overall pressure p in MPa - Temperature t in C - Type of composition: art=1 for composition in mass fractions art=0 for composition in mole fractions

zu1...zu10 - composition in mass fractions 1...10 in kg/kg - composition in mole fractions 1... 10 in kmol/kmol Result: v_pt_ig or v - Specific volume in m3/kg Range of validity: Pressure p: Temperature t: Comments: Specific volume v from: v= Rm T p from 1 Pa to 5 MPa from -73.15 C to 1,726.85 C

Results for wrong input values: v_pt_ig or v = -1

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

3/13

Mass Fraction i = f(i, 1... 10)

Name in FluidTI- Ideal Gas and Mixture: Xsi_igas_Psi_ig Input Values: i - Description of the gas zu1...zu10 - composition in mole fractions 1... 10 in kmol/kmol Result: Xsi_igas_Psi_ig or Xsi - Mass fraction in kg/kg Comments: Mass fraction:
i =
Mi i ( i M i )

Results for wrong input values: Xsi_igas_Psi_ig or Xsi = -1

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

4/1

4. References
[1] [2] VDI Richtlinie 4670 u. Thermodynamische Stoffwerte von feuchter Luft und Verbrennungsgasen Brandt, F.: Wrmebertragung in Dampferzeugern und Wrmetauschern. FDBR-Fachbuchreihe, Bd. 2, Vulkan Verlag Essen (1985) VDI-Wrmeatlas, 7. Auflage. VDI-Verlag, Dsseldorf (1995) Blanke, W.: Thermophysikalische Stoffgren. Springer-Verlag, Berlin (1989) Release on the IAPWS Industrial Formulation 1997 for the Thermodynamic Properties of Water and Steam IAPWS-IF97. IAPWS Sekretariat, Dooley, B, EPRI, Palo Alto CA (1997) Wagner, W.; Kruse, A.: Zustandsgren von Wasser und Wasserdampf. Springer-Verlag, Berlin (1998) Wagner, W.; Cooper, J.R.; Dittmann, A.; Kijima, J.; Kretzschmar, H.-J.; Kruse, A.; Mares, R.; Oguchi, K.; Sato, H.; Stcker, I.; Sifner, O.; Takaishi, Y.; Tanishita, I.; Trbenbach, J.; Willkommen, Th.: The IAPWS Industrial Formulation 1997 for the Thermodynamic Properties of Water and Steam. ASME Journal of Eng. for Gasturbines and Power 122 (2000) Nr. 1, S. 150-182 Revised Release on the IAPS Formulation 1985 for the Thermal Conductivity of Ordinary Water Substance. IAPWS Sekretariat, Dooley, B., EPRI, Palo Alto CA, (1997) Revised Release on the IAPS Formulation 1985 for the Viscosity of Ordinary Water Substance. IAPWS Secretariat, Dooley, B., EPRI, Palo Alto CA, (1997)

[3] [4]

[5]

[6]

[7]

[8]

[9]

[10] IAPWS Release on Surface Tension of Ordinary Water Substance 1994. IAPWS Sekretariat, Dooley, B., EPRI, Palo Alto CA, (1994) [11] Release on the IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use. IAPWS Sekretariat, Dooley, B., EPRI, Palo Alto CA, (1995) [12] Grigull, U.: Properties of Water and Steam in SI Units. Springer-Verlag, Berlin (1989) [13] Kretzschmar, H.-J.: Zur Aufbereitung und Darbietung thermophysikalischer Stoffdaten fr die Energietechnik. Habilitation, TU Dresden, Fakultt Maschinenwesen (1990)

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

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