MODEL SOLUTIONS TO IIT JEE 2012

Paper I Code-0

1 2 3 4 5 6 7 8 9 10
C D D C B C D B A A
11 12 13 14 15
A, B, C,
D
B, D C, D A, C, D
A, C

16 17 18 19 20
5 7 7 6 3

Section I

1. (3T)
4
T0
4
= T0
4
(2T)
4

81T
4
T0
4
= T0
4
16T
4

97T
4
= 2T0
4


4
0
4
T T
2
97
= |

\
|

T0 = T
2
97
4 / 1
|

\
|


2. ( ) r E for 0 r < R = 0
V(r) for 0 r R is constant
graph given in (D)

3. =
d
D

R > G > B
R > G > B

4.







qE = mg
= E =
19
27
10 6 . 1
10 10 6 . 1
q
mg

=
= 10
7
N C
1

V = Ed = 10
7
10
2
m
= 10
9
V

5. ( ) cm
28
1 1
14
1
1 5 . 1
f
1
1
=
(

=
( ) cm
70
1 1
14
1
1 2 . 1
f
1
2
=
(

=
cm
20
1
70
1
28
1
f
1
f
1
F
1
2 1
= + = + =
F = +20 cm
u = 40 cm

F
1
v
1
u
1
= +
v = 2F = 2 10 = 40 cm

6. p r L
0
=

0
L = mr
2
along OP = constant
( ) Pm r p r L
p
= =
p
L is perpendicular to Pm, which is varying with
time.

7. At a given T,
M
1
v
rms

10
4
40
M
M
v
v
He
Ar
Ar
He
= = =
= 3.16

8. L =
=
dt
d
dt
dL
=
= ( )
(

+
2
0
mr
dt
d

=
dt
dr
r 2 . m . = 2mrv
= r t (Q r = vt)
1 cm
+
qE
mg

9. d(l) = d(d) (data) Q LC is same

( ) ( )
d
d d 2 d
Y
dY
+ =
l
l
=
5 . 0
) d ( d 2
25 . 0
) ( d
+
l

-
( ) ( )
25 . 0
d d
25 . 0
d
+
l

% error in Y, contribution from
( )
d
d d
is same as
the contribution from
( )
l
l d


10. x = x0 + A cost
= 1
3
cos 2 . 0 9 . 4

+
= 4.9 + 0.1 = 5 m
x = (10 x) = 5 m
x = v cos45 1 second
v =
1
s m 50 2 5
45 cos
' x

= =

Aliter
Time of flight T = 1 s
T =
g
45 sin v 2

v =
1
s m 50
45 sin 2
gT

=

Section II

11. PQ and ST can be removed due to symmetry
Current through PQ = zero
P.D across each resistor is 4 V
2 = A 2
2
V 4
=

; 3 = =

1
4
V 4

1 = 2 + 3 = 2 + 1 = 3 A
VS = 4 V, VQ = 8 V VQ > VS

12. When other end is open, the reflected wave is of
least intensity low pressure.
When the other is closed, the reflected wave is of
maximum intensity high pressure.

13. Path will be helical if 90, pitch will be
non-uniform (increasing). If = 90, path will be
straight, accelerated motion along Y-axis.

14. All surfaces of the cube are symmetrically placed
w.r.t charge distribution. Total charge enclosed is
q0.
Net flux =
0
0
q

15. F = 1 N, mg = 0.1 1 = 1 N
If no friction, Fcos = mgsin
tan =
mg
F
= 1 = 45, friction zero
If > 45, mgsin increases
friction should be up the plane (towards Q)
If < 45, Fcos increases
friction should be down the plane (towards P).

Section III

16. B1 = ( ) J a
a
2
.
4
2 0

=
2
aJ
0

+
B2 = J
2
a
.
2
a 3
2
.
4
2
0
|

\
|

\
|

=
2 1
0
B B B
12
aJ
+ =

=
12
aJ 5
12
aJ
2
aJ
0 0 0

=

N = 5

17. KE =
d 4
Qq
0

(From energy conservation)

=
mKE 2
h
p
h
=
=
d 4
Qq
. m 2
h
0

= 7 fm

18. B at loop =
[ ]
2 / 3
2 2
2
0
R R 3
R 2
.
4
+

=
R 16
0


Flux linked with loop = BNAcos
=
R 2 8
a
2
1
a 2
R 16
2
0 2 0

=


= 7 p
R 2
a
R 128
a
2 / 7
2
0
2
0
= =

=



19. Q = R
2
L
=
L
Q
= R
2

E1 =
0 0
4
R
d 2

Q1 =
8
R
3
4
3

E2 =
0
2
0
1
96
R
d 4
Q

E = E1 + E2 =
0 0
96
R
4
R

=
0
6 16
R 23

k = 6
20. Mass of full disc MF = (2R)
2
= 4R
2
= 4 m
Mass of cut disc MC = R
2
= R
2
= m
0 =
( )
(
(

+
2
2 2
mR
2
mR
2
R 2 m 4

=
2
mR
2
13

P =
( )
( )
(
(

+
(
(

+
2
2
2
2
R 5 m
2
mR
R 2 m 4
2
R 2 m 4

=
2
mR
2
37

3
13
37
0
P
=

PART II


21 22 23 24 25 26 27 28 29 30
C A A B D D C B B C

31 32 33 34 35
A, D A, C A, C, D B, D B, C

36 37 38 39 40
8 9 8 4 8

Section I

21. When b = 0
PV = RT
V
a

PV = 21.6 L atm

V
1
= 2 mol L
1

a = 1.5

22. The products of ozonolysis are CH3CHO and
C CHO
H
CH
3
OHC
Both are optically inactive

23. CuSO4 solution is blue. The complimentary
colour of blue which is absorbed is orange red.

24. Oxidation states of N in
HNO3 is + 5
NO is + 2
N2 is 0
NH4Cl is 3

25. Diamminetetraaquacobalt(III) chloride

26. Aspirin is acetyl salicylic acid
COOH
OCOCH
3


27. a0 =
2 2
2
Ze m 4
h

Ze
2
=
0
2
2
a m 4
h

KE =
n
2
r 2
Ze

But r2 = 4a0
KE =
2
0
2
2
a m 32
h

28.
CH
2
C CH
2
sp
2
sp sp
2
(allene)


29. M from edge centres = 4
4
1
= 1
M from body centre = 1
X from corners = 8
8
1
= 1
X from face centres = 6
2
1
= 3
Empirical formula = MX2

30.
CHO CH
3
NaOH
HCHO
(aldol)
H
2
C
CHO
CH
2
OH

NaOH
HCHO
(aldol)
HC CH
2
OH
CH
2
OH
CHO
NaOH
HCHO
(aldol)


C CH
2
OH
CH
2
OH
CHO
NaOH
HCHO
(Cannizzaro
reaction)
HOH
2
C



C CH
2
OH + HCOONa
CH
2
OH
CH
2
OH
HOH
2
C
(pentaerythritol)



Section II

31. Stability of lyophobic colloids is due to
(i) Preferential adsorption of ions on the
surface of the colloidal particles

(ii) Potential difference between the fixed layer
and the diffused layer

32. Sxz = Sxy + Syz
Since S is a state property

Wxyz = Wxy
Since Wyz = 0 as there is no volume change

33. AgCl, AgBr & AgI are soluble in Na2S2O3 solution
forming the complex Na3[Ag(S2O3)2]

34. (B) & (D) are mixtures of carboxylic acid and
alcohol. They can be separated by using
NaOH(aq) or NaHCO3(aq)

35. Cyclobutadiene (B) is antiaromatic and hence
unstable. Since cyclopentadienyl cation is
antiaromatic, cyclopentadienone is highly
reactive and unstable in the pure form.

Section III

36. X H 2 He n 6 H Cu
52
26
1
1
4
2
1
0
1
1
63
29
+ + + +
X is Iron, it belongs to group 8

37. k =
R
R
log
t
303 . 2
0

8 log
t
303 . 2
10 log
t
303 . 2
8
1
10
1
=

8
1
10
1 t
3 . 0 3 303 . 2
t
303 . 2
=
9 10
t
t
10
1
8
1
=

38. 29.2 g HCl in 100 g or 80 mL solution
(or)
395 g HCl in 1000 mL solution
i.e., 10 M solution
8 mL of the stock solution contains 80 millimoles

39. Peptides IV, VI, VIII & IX are basic amino acids
and hence exist as cations at pH = 7

40. Since the aldohexose exists in its
D-configuration, the configuration on C5 is
fixed. There are 3 other chiral carbon atoms in
the pyranose form. Hence the total number of
stereo isomers = 2
3
= 8






PART III


41 42 43 44 45 46 47 48 49 50
B B C A A D C B B D

51 52 53 54 55
A, B, D A, D A, B A, C, D B, D

56 57 58 59 60
4 4 3 5 9

Section I

41. f(x)

0 x , 0
0 x ,
x
x cos x
2

0 x lim ) x ( f lim
2
0 x 0 x
= <



f is continuous at x = 0, 2
f(0) =
h
0
h
cos h
lim
2
0 h

= 0
f(2) =
( )
( )
h
0
h 2
cos h 2
lim
2
0 h

=
( )
h
h 2
lim
2
0 h
+

does not exist

Choice (B)

42. f (x) = 6 x
2
5x + 6)
fx = 6 (x 3) (x 2)
f(x) = 0 at x = 2, 3
f(x) is not one one
But f (x) is bonded between 1 to 29
f (x) is onto
choice (B)

43. E1 : 1
4
y
9
x
2 2
= +
E2 passes through (0, 4) and hence b = 4









E2 = 1
16
y
a
x
2
2
2
= + a
2
= 12 (Since E2 passes
through (3, 2))
e =
2
1
16
12
1 =
Choice (C)

44. Line QR is

1
5 z
4
3 y
1
2 x
=

Any point on QR
(r +2, 4r+3, r+5)
5(r +2) 4(4r+30 ( r+5) = 1
12r = 8 r =
3
2

P is |

\
|
3
13
,
3
1
,
3
4
-------(1)
Let S be (r +2, 4r+3, r+5)
PS is r to QR
r+16r +8+r+1 = 0
18r+9 = 0 , r =
2
1

S is |

\
|
2
9
, 1 ,
2
3

PS
2
=
2 2 2
3
13
2
9
3
1
1
3
4
2
3
|

\
|
+ |

\
|
+ |

\
|

=
2
1

PS =
2
1

Choice (A)

45. (x1, y1) midpoint point of chord of contact of
tangents from points having on the straight line
4x 5y = 20 to the circle x
2
+ y
2
= 9
xx1 + yy1 =
2
1
2
1
y x + -----------(1)
5y + 4x 20
E1
E2


x = t
y =
5
20 t 4







p |

\
|
5
20 t 4
, t chord of contact of tangents shown
from P
( )
9
5
20 t 4 y
xt =

+ --------(2)
From (1) and (2)

2
1
2
1
1 1 y x
9
y
4
4
t
4
x
t
+
=

=
t =
2
1
2
1
1
y x
x 9
+


2
1
2
1
1
y x
y 9
4
5
t 4
+
=
t =
4
5
4
y x
y 9
2
1
2
1
1
|
|

\
|
+
+

Locus of (x1, y1) is

2
1
2
1
1
y x
x 9
+
= 5+
) y x ( 4
y 45
2
1
2
1
1
+
=
9x1 = 5 ( )
4
y 45
y x
1 2
1
2
1
+ +
36x1 = 20 ( )
2
1
2
1
y x + +45y1
20 (x
2
+ y
2
) 36x +45y = 0
Choice (A)

46. Let P
(
(
(

33 32 31
23 22 21
13 12 11
a a a
a a a
a a a

then Q =
(
(
(
(

33
6
32
5
31
4
23
5
22
4
21
3
13
4
12
3
11
2
a 2 a 2 a 2
a 2 a 2 a 2
a 2 a 2 a 2

= 2
2
2
3
2
4

(
(
(

33
2
32
2
31
2
23 22 21
13 12 11
a 2 a 2 a 2
a 2 a 2 a 2
a a a

= 2
9
2 2
2
[P]
= 2
13
[ ] ( ) 2 P = Q
Choice (D)

47.
( )
dx
tan x sec
x sec
2
x
2

+

t = secx + tanx

t
1
= secx tanx
t +
t
1
= 2 secx
|

\
|
+
t
1
t
2
1
= sec x
dt = secx ( secx + tanx) dt

t
dt
= secx dx

\
|
+
2
9
t
t
dt
t
1
t
2
1

= dt
t
1
t
1
2
1
dt
t t
1 t
2
1
2
13
2
9
2
9
2
2
|
|

\
|
+ =
+

=

|
|
|
|

2
11
t
2
1
t
2
1
2
11
2
3

=
|
|
|
|

\
|
+
2
11
2
7
t 11
1
t 7
1

=
(

+
11
1
t
7
1
t
1
2
2
11

=
( )
( ) c x tan x sec
7
1
11
1
x tan x sec
1
2
2
11
+
(

+ +
+

Choice (C)

48. 1 1 3 20 C C
1
4
1
5
=
2 2 1 30 C C
2
3
2
5
=
20 3+30 3 = 150

49. 4
1 x
) 1 x )( b ax ( 1 x x
lim
2
x
=
|
|

\
|
+
+ + + +



( )
4
1 x
b 1 x ) b a 1 ( x a 1
lim
2
x
=
+
+ +


4
x
1
1 x
x
b 1
x
b a 1
a 1
x lim
2
x
=
|

\
|

|
|

\
|
+

+
2


1 a b = 4 a + b = 3
True only (B)

50. z
2
+ z + 1 = a
z
2
+ z + 1 a = 0
D= 1 4 ( 1 a) = 1 4 + 4a < 0
3 + 4a < 0 a <
4
3

a
4
3

M
N
(0, 0)
P


Section II

51. m (b a) < S < m ( b a)
e
1
S < 1

e
1
S S
e
1
(A) true
x
2
> x in x (0, 1)

1
0
1
0
x x
dx e dx e
2

S ( )
1
0
x
e

e
1
+ 1 = 1
e
1

(B) is true

1
0
x
dx e
2









= dx e dx e
1
2
1
x
2
1
0
x
2 2


+
=

+
|
|

\
|

2 / 1
0
x
dx e
e
1
2
1
1
2

=

+
|
|

\
|

2 / 1
0
dx 1
e
1
2
1
1
=
|
|

\
|
+
|
|

\
|
0
2
1
e
1
2
1
1
D is true

52. y
1
y tanx = 2x xsecx
cosx y sinx y = 2x
y cox = x
2
+ C
y(0) = 0 C = 0
y cos x = x
2
\
y
2 8
2
16 4
2 2

= |

\
|
(a) is false

2 8
8
4
' y
2
+
= |

\
|
(b) is true

9
2
3
y
9 2
1
3
y
2 2

= |

\
|

= |

\
|
(c) is false
2
3
2
3
9
2
3
' y
2

|

\
|


3 3
2
3
4
3
' y
2

= |

\
|
(d) is true

53. Slope of tangent = 2

9
x 2
9 0
2
' yy
9
x
0
4
' yy
9
x
= = =
x =
2
1
y ,
2 2
9
= so (a) & (b)

54. 2cos 2sin( + ) = 2sincos 1
2
tan
2

( )
( )( ) ( ) 1 cos
sin
2
sin sin 1 cos 2
2
tan
cos sin 2 sin 2 1 cos 2
2
2

+ + = +

= 2sincos 1
2cos + 1 = 2sin ( + )
L. H. S is > 0
Since lines in the 4
th
quadrant
sin ( +) > 0
( + ) must be in (0, 180)
A is true
C is true
D is true
Section III

55. Angels
E1 E2 E3
Possible cases
E1 E2 E3
32
1
4
1
8
1
=
E1 E2
32
3
4
3
8
1
E =
E1
32
3
4
1
4
3
2
1
E E
3 2
=

32
1
4
1
4
1
2
1
E E E
3 2 1
=

32
3
4
1
4
3
2
1
E E E
3 2 1
=

32
3
4
3
4
1
2
1
E E E
3 2 1
=

32
9
4
3
4
3
2
1
E E E
3 2 1
=

1
32
9
4
3
4
3
2
1
E E E
3 2 1
=
P(X) =
4
1
32
1
32
3
32
3
3
1
= + + +
P(X1) =
2
1
32
1
32
3
32
3
32
1
= + + +
P(X2) =
4
1
32
3
32
1
32
3
32
1
= + + +
P(X3) =
4
1
32
3
32
1
32
3
32
1
= + + +
P ( )
8
1
4
1
32
1
) X ( p
) XX ( P
X X
c
1 c
1
= = = A is false
0
y
x
1
2
1



P (two tangents functioning |x)
=
8
7
1
4
32
7
4
1
32
1
32
3
32
3
= =
+ +

B is true
P (X|X2) =
8
5
4
32
5
4
1
32
1
32
3
32
1
= =
|

\
|
+ +
C is false
P(X|X1) =
16
7
2
1
32
3
32
3
32
1
=
+ +
D is true

56. Let x
2 3
1
4
2 3
1
4 =
4 x
2 3
1
= x
2


2
x 2 3 x 2 12 =
0 2 12 x x 2 3
2
= +
x =
2 6
2 12 2 12 1 1 +

=
2 3
8
2 6
16
2 6
17 1
= =


(As x cannot be <0)
6+
)
`

2 3
8
2 3
1
log
2
3

= 6+
2
2
3
3
2
log
)
`

= 6 2 = 4

57. A point on the parabola is (2t
2
, 4t)
4t
4
+ 16t
2
4t
2
16t = 0
4t
4
+ 12t
2
16t = 0
4t (t
3
+3t 4) = 0
t = 0, 1
Point of intersection are (0,0) and (2, 4)
Equation of the common chord is y 2x = 0
Area of PQS =
5
4
20
2
1

= 2 2 = 4

58. ( )


= =
2
3
c . b 9 c b
2

But for unit vectors c , b , a
0 c b a
2
3
c a = + +

a 3 c 5 b 5 a 2 = + + = 3

59. f(x) = |x| + |x
2
1|



x < 1 f(x) = x + x
2
1
1 < x < 0 f(x) = x + 1 x
2

0 < x < 1 f(x) = x + 1 x
2

x > 1 f(x) = x + x
2
1
f(1 0) = 1 + 1 1 = 1
f(1 + 0) = 1 + 1 1 = 1
f(0

) = 1
f(0
+
) = 1
f(1

) = 1
f(1
+
) = 1
f(x) is continuous in R
f(x) = 1 +2x, x < 1
= 1 2x , 1 < x < 0
= 1 2x, 0 < x < 1
= 1 + 2x, x > 1
f(x) is discontinuous at x = 1, 0, 1
f(x) = 0 gives x =
2
1
,
2
1

f(1

) = 3 1 minimum point
f(1
+
) =1 0 minimum point
f(0

) = 1 1 minimum point
f(0
+
) = 1
f (1
+
) = 1
f(1

) = + 1


2
1
,
2
1
max. points

Total = 5


60. p(x) is a centric
p(x) = ax
3
+ bx
2
+ cx + d
p (3x) = 3ax
2
+2bx + c
p (1) = 0 3a +2b + c = 0 -------(1)
p(3) = 0 27a + 6b + c = 0 -----(2)
p(1) = 6 a + b + c + d = 6}
p(3) = 2 27a + 9b + 3c + d = 2}
26a+ 87b + 2c = 4-----(3)
Using equation (1) (2) and (3)
=
2 8 26
1 6 27
1 2 3
=
0 4 20
0 4 24
1 2 3
= 96 80 = 16
c =
4 8 26
0 6 27
0 2 3

= 4 (18 54) = 144

C =
16
144
=

= 9

1 0 1
2
1

+
2
1

+