JOURNAL

Title of Experiment Name of apprentice Class/Group Reg.Number Partners Assistant : Preparation Complex Salt and Double Salt : Andi Fildah Yakub : ICP of Chemistry / I : 101304151 : 1. Ria Natalia dianty 2. Andi Sri Ansyari : Andriana Poppy

A. The Aim of Experiment To learn preparation and kharacteristic of double salt sulphate ammonium cupri and complex of salt tetrammincopper (II) sulphate monohydrate sulphate. B. Apparatus and Chemical 1. Apparatus a. Analytical Balance (1 piece) b. Wristwatch Glass (2 piece) c. Beaker Glass 100 mL (1 piece) d. Beaker Glass 250 mL (2 piece) e. Stir Bar (1 piece) f. Funnel (1 piece) g. Steaming Bowl (1 piece) h. Drop Pipette (5 drop) i. Spiritus Burner (1 piece) j. Asbestos Screen (1 piece) k. Tripod (1 piece) l. Measure Glass 10 mL (1 piece) m. Big reaction tube (2 piece) n. Small reaction tube (2 piece) o. Wood Clamp (2 piece) p. Vacuum pump (1 piece)

q. Stem erlenmeyer flask 500 mL (1 piece) r. Spatula (1 buah) s. Tweerzers (1 piece) t. Water bath (1 piece) u. Buchner funnel (1 piece) v. Spray flask (1 piece) 2. Chemicals a. Crystal of pentahydrate sulphate cupri (CuSO4. 5H2O) b. Crystal of sulphate ammonium (NH4)2SO4 c. Sulphate copper (CuSO4) anhydrate d. Ammonia solution (NH3) 6 M and 15 M e. Alcohol etyl solution (CH3CH2OH) f. Aquadest g. Filter Paper h. Whatman filter paper i. Tissue j. matches C. Work Procedure 1. Preparation of double salt of sulphate ammonium cupri, CuSO4. (NH4)2SO4. 6H2O a
5 g ra m of
4.C

5 H2O

u S O 5 g ra m 5 H2O

of

4.C

uSO

10 mL aquadest d ilu te d of h e a te d

of a ll s a lt is p e r fe c t s o lu te

2 ,6 4 ( N H 4S) O 2 4

g ra m

o2f ,6 4 ( N H 4S) O 2 4

g ra m

b.

let it be solution to be cool at room temperature until form crystal

let it be during one night so, more than crystal which produce

c.
continued cooled with water bath dekantire filter its crystal

d.

d r ie d c r y s ta l in filte r p a p e r

its c r y s ta l fo r m e d m o n o k lin

e.

balance the crystal

2. Preparation of complex salt tetraamincopper (II) monohydrate sulphate, Cu(NH3)4SO4. H2O a.

8 mL of NH3 dilute

5 mL of aquadest

b.

5 gram of CuSO4. 5H2O

5 gram of CuSO4. 5H2O

solution of NH3
c.
8 mL of etil alkohol closed with arloji glass

not stirr / shaked

let it be during one night

d.
3-5 mL of mixture solution of NH3 15 M with stir by carrefull CH3CH2OH

dekantire

filtered

washed

e.

5 mL of alcohol etyl

f.

balace its crystal

3. The compare some's of characterictic by single salt, double salt, and complex salt. a.

0,5 gram anhydrate

of

CuSO 4

1 or 2 mL of aquadest

4 mL of NH3 6 M drop by drop

b.

3 mL of aquadest crystal of CuSO . (NH4)2SO4. 6H2O 4

10 mL of aquadest

diluted

c.

noted gas which formed

noted gas which formed

crystal of CuSO4. (NH4)2SO4. noted its color changes 6H2O noted its color changes

crystal H2O

Cu(NH3)4SO4.

Makassar, May 14th 2012 Assistant Apprentice

( Andriana Poppy )

(Andi Fildah Yakub)