FIITJEE Ltd.

, FIITJEE House, 29 A, Kalu Sarai, Sarvapriya Vihar, New Delhi - 110016, Ph : 26515949 , 26569493, Fax :011- 26513942.
FACULTY RECRUITMENT TEST
CAT-A (APT & SAT-II)
CHEMISTRY (PAPER-II)


Time: 60 Minutes. Maximum Marks: 40

Name:....................................................................................................
Subject: ................................................................................................

Marks:



Instructions:
Attempt all questions.
This question paper has two Parts, I and II. Each question of Part I carries 2 marks and of
Part II carries 5 marks.
Calculators and log tables are not permitted

PART I
1. A vessel of volume 5 litre contains 1.4 gm of nitrogen at a temperature 1800K. Find the pressure of
the gas if 30% its molecules are dissociated into atoms at this temperature.

2. 1.0 gm of Mg atoms (atomic mass = 24.0 amu) in the vapour phase absorb 50.0 kJ of energy. Find
the composition of the final mixture, if the first and 2
nd
ionization energy of Mg are 740 and 1450 kJ
mol
1
respectively.

3. Show that time required for 99.9% change of a first order reaction is about 10 times than that for 50%
completion of the reaction at a given temperature.

4. 5.95g sample of barium dichromate ore after fusion with regular way is treated with 75 ml of 2 M
Mohrs salt and excess of Fe
+2
requires 15 ml of 0.1 M dichromate of Al salt then find out the % of
Cr in the sample of dichromate.

5. A sample of AgCl was treated with 5.0 M Na
2
CO
3
solution to give Ag
2
CO
3
. The remaining solution
contained 0.0026 gm of Cl

per liter. Calculate solubility product of AgCl ( )

12
CO spAg
10 2 . 8 K
3 2

=

FIITJEE Ltd., FIITJEE House, 29 A, Kalu Sarai, Sarvapriya Vihar, New Delhi - 110016, Ph : 26515949 , 26569493, Fax :011- 26513942.
FACREC-04-(APT & SAT-II-P-2-09-10)CH2

6. Compare the basic strength of the following
NH
3
, CH
3
NH
2
(CH
3
)
2
NH (CF
3
)
3
N
7. Why allylic free radical CH
2
= CH
2
H C
-
is more stable than CH
3
CH
2

2
H C
-
while both are
primary free radicals.

8. A solution of ferric chloride acidified with HCl is unaffected when hydrogen is bubbled through it, but
gets reduced when Zn is added to same acidified solution - why?

9. Explain the following:
(a) Ice is lighter than water.
(b) PH
5
is not possible whereas PF
5
is possible.

10. Acetic acid (CH
3
COOH) associates in benzene to form double molecules. 1.65 g of acetic acid when
dissolved in 100g of benzene raised the boiling point by 0.36C. Calculate the Van't Hoff Factor and the
degree of association of acetic acid in benzene (Molal elevation constant of benzene is 2.57).

PART II

1. Alkenes (A) and (B) yield the same alcohol (C) on hydration. On vigorous oxidation with KMnO
4
(A)
gives a carbonyl compound (D) and an acid (E) each containing four carbon atoms. On the other
hand (B) gives an acid (E) and a carbonyl compound (G). In (G) no two identical groups are attached
to the same carbon atom. Give the structures if (A) to (G).

2. (a) For the reaction CaCO
3(s)


CaO
(s)
+ CO
2(g)
; K = 0.059 atm at 1000K. 10g of CaCO
3
is placed
in a 10 litre container at 100K to reach the equilibrium. Calculate the mass of CaCO
3
left of
equilibrium.
(b) Solid NH
4
I on rapid heating in a closed vessel at 357C develops a constant pressure at 275 mm
of Hg owing to the partial decomposition of NH
4
I into NH
3
and HI but the pressure gradually
increases further (when excess solid residually remains in the vessel) owing to the dissociation of
HI. Calculate the final pressure developed under conditions.
NH
4
I
(s)


NH
3(g)
+ HI
(g)

2HI
(g)


H
2(g)
+ I
2(g)
K
c
= 0.15 at 357C

3. The half-life of first order decomposition of nitramide is 2.1 hours at 15C.
NH
2
NO
2
(aq) N
2
O(g) + H
2
O(l)
If 6.2 g of NH
2
NO
2
is allowed to decompose calculate (I) time taken for NH
2
NO
2
to decompose 99%
and (ii) the volume of dry N
2
O produced at this point, measured at STP.

4. The gas liberated on heating a mixture of two salts with NaOH gives a raddish brown precipitate with
an alkaline solution of K
2
HgI
4
. The aqueous solution of the mixture on treatment with BaCl
2
gives a
white precipitate which is sparingly soluble in concentrated HCl. On heating the mixture with K
2
Cr
2
O
7

and conc. H
2
SO
4
, red vapours (A) are produced. The aqueous solution of the mixture gives a deep
blue colouration (B) with K
3
[Fe(CN)
6
] solution. Identify the radicals in the given mixture and write the
balanced equations for the formation of (A) and (B).


+++++