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Model exam of secondary stage 2010

By prof/ Saif Soliman

Question 1
A) Choose the best answer and give reason:
1- If the compound ionized according to the following equation MOH=== MO - +H+ So M for a) Li b) Al c) Br 2- Lithium react with moist atmospheric air and gas evolved is A) Oxygen b) Hydrogen c) Ammonia 3- An element its oxidation no often (+1) and also (-1) is A) Lithium b) Sodium c) Hydrogen 4- When copper react with diluted nitric acid the gas evolved is A) Hydrogen b) Nitrogen dioxide c) Nitric oxide 5- Ammonia gas react with ethyl benzoate and produce A) Benzene b) Benzamide c) benzoic acid
prof/Saif Soliman 2010 Secondary exam

6- The level (L) saturate by.. Electrons a) 32 b) 8 c) 18

B) Show by balanced chemical questions how can you get each of the following
a) Chloroform from sodium acetate b) Ammonium phosphate from ammonium chloride c) Acetone from 1-propanol d) Salicyliamide from phenol

C) Solve the following problem

When heated 6.72 g of sodium bicarbonate until thermal composition and constant weight. When dissolve the output of the anhydrous sodium carbonate in the water and complete the solution with water until he became 400 ml neutralize 5 ml with 30 ml of diluted hydrochloric acid calculate the molarity of acid (Cl=35.5, H=1, C=12, O=16, Na=23)

D) Prepare and State one use for the following: 1-Dacrone fiber 2-tri nitro glycerin 3-tri nitro phenol 4-water gas 5-washing soda

prof/Saif Soliman

2010

Secondary exam

Question 2
A) Write the scientific term
1-A bond formed between tow similar atoms to form gaseous molecule. 2-electron must fill the lowest sublevels in energy first then the highest 3-reaction of ethylene with alkaline solution of potassium permanganate to give ethylene glycol 4- The presence of solid non metal element in different forms, have the same chemical properties different in physical properties 5-equaql volumes of gas under the same pressure and temperature contains the same number of molecules B) Writ the structural formula of the following 1- Glycine 2- Citric acid 3- Pyrogaloll 4- Poly hydroxyl ketone 5- PCB 6- Apatite 7- Carnilite 8- Car iolite 9- Halothane 10- Hydrazine 11-Arsine 12-Phosphorus in vapor state

prof/Saif Soliman

2010

Secondary exam

C) By passing intensity of current 12 A for 2.3 minute in electrolytic solution of .25 L of AgNO3 and all ions are receipted ,calculate the concentration of AgNO3 before electrolysis ? Ag= 108

Question 3 A) Give reason for

1-titanium used in manufacture of rockets and airplane 2-poly nitro compounds are very explosives 3- Sodium carbonate solution used in cleaning cooking utensils' from fat and oil 4- Preparation of ammonia gas by Happer method need pressure while in preparation of nitric oxide not 5-alkaline effect of sodium carbonate solution on litmus paper solution B)5.36 gm of sodium carbonate and sodium bi carbonate mixture sample is strongly heated ,0.488 L of CO2 is evolved calculate the percentage of sodium carbonate in the sample

C) Compare between
1- Thomson atomic model-Rutherford atomic model 2-dry cell alkaline cadmium nickel cell (overall reaction)

Question 4 A) Discuss the role of the following:

1-oxygen blown and dolomite in oxygen converter 2- Concentrated sulfuric acid in estrification reaction 3-indicator in the volumetric analysis

prof/Saif Soliman

2010

Secondary exam

4- Hydrated copper sulfate in preparation of acetylene 5-Enzyme in the human body 13- Florid salts of sodium and aluminum in extraction of Al

(B) A- Increase temperature B--reduce the pressure C-increase the pressure D-addition of catalyst E-decrease the temperature

C) How can you practically distinguish between?

1-diluted nitric acid - and diluted sulfuric acid 2- Ethanoic acid and carbolic acid 3-sodium nitrate and nitrite 4- Iron (II) iron (III) chloride 5-irom metal and magnetic iron oxide 6-methyle salycilate and acetyl salicylic acid 7-aliquer and other not 8-absolute acetic acid and other diluted 9-lithium nitrate and sodium nitrate 10-ethanol and 2- propanol by using (KMnO4/H+& Ph.Ph)

prof/Saif Soliman

2010

Secondary exam

Question 5 A) (I)Compare between the PH values for sodium chloride solution: 1- Before electrolysis 2- After electrolysis (II) Which is highest and give reason? PH value for 1-sodium carbonate or sodium chloride 2-citric acid or oxalic acid 3-orthosiliconic acid and perchloric acid. 4-potassium hydroxide and sodium hydroxide 5-sodium acetate and sodium chloride 6-.001M sodium hydroxide and 0.5 gm of caustic soda dissolved in 100 ml of water B) 7.9 gm of hematite ore converted to 3.808 gm of iron metal calculate the % of iron(III) oxide in the ore sample C) What is meant by : 1- Hund,s rule 2- Substitution alloy 3- Coordinate bond 4- Photoelectric phenomena 5- Saponification. 6-0.9% of NaCl solution 7- 5Ppm of Na2CO3 mixture
prof/Saif Soliman 2010 Secondary exam

Question 6 A) Write the following graph in answer paper

1- Write the structural formula for A and B 2- State the reaction condition for steps 1&2 3- Start from (A) show by balanced chemical equation ,how you can get a) TNT b) p- chloro benzoic acid c) Salicylic acid d) Asprine. B) The following scientist share in progress of chemistry explains: 1- Ostwald 2-Davey 3-kosl &Lewis 4-brezilus 5-wohler 6-summer field 7-Faradays 8- Wagg and Goldberg

C) Draw the apparatus used in preparation of: ethene gas in lab and write down the balanced chemical equations with full conditions

prof/Saif Soliman

2010

Secondary exam