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I. INTRODUCTION
N2(g) + 3H2(g)
2NH3(g)
OSMIUM OR MAGNETITE
PLATINUM
PETROLEUM CRACKING
ZEOLITE
A. DEFINITION OF CATALYST
SMALL AMOUNTS RELATIVE TO THE REACTANTS, THAT MODIFIES AND INCREASES THE RATE OF A REACTION WITHOUT BEING CONSUMED IN THE PROCESS
B. DEFINITION OF CATALYSIS
CHANGE IN RATE OF A CHEMICAL REACTION DUE TO THE PARTICIPATION OF A SUBSTANCE CALLED A CATALYST
A CATALYST THAT EXISTS IN THE SAME PHASE AS THE REACTANTS AND PRODUCTS USUALLY LIQUID PHASE REACTIONS, SOMETIMES GAS PHASE
III. THEORIES
Theories in Catalyst
Chemical Kinetics Also known as Reaction Kinetics. It is the study of rates of chemical processes. It includes investigations of how different experimental conditions can influence the speed of a chemical reaction. Yield information about the reaction's mechanism and transition states. The construction of mathematical models that can describe the characteristics of a chemical reaction.
Theories in Catalyst
Peter Waage and Cato Guldberg pioneered
the development of chemical kinetics by formulating the law of mass action. Law of Mass Action states that the speed of a chemical reaction is proportional to the quantity of the reacting substances. Chemical kinetics deals with the experimental determination of reaction rates from which rate laws and rate constants are derived.
Rate Law Rate Law = Law of mass action For the reaction: A B For Liquids: -rA = kCA^n For Gases: -rA = kPA^n Where: n is the order of the reaction.
Homogeneous Catalyst
Homogeneous Catalyst
Catalyst and Reactants are in the same phase.
Example of Homogeneous Catalyst : Oxidation of sulfur dioxide to form sulfur trioxide in presence of nitric oxide. Here, nitric oxide acts as a catalyst and reactants and catalyst are in same phase. (gaseous phase) 2SO2 + O2 + NO SO3 + NO
Homogeneous Catalyst
Another examples of Homogeneous Catalyst:
Acid Catalysis Base Catalysis Acylation Aldol Reaction Alkylation Oxidation Hydrolysis Nitration
LAND AIR
WATER
CONTAMINATION