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SUSTAINABILITY IN GEOPOLYMER
BATCH MEMBERS
OBJECTIVE
Study & evaluation of chemical composition & effects
Mix Design Casting of Concrete Testing of Concrete Results Scope of the Future References
INTRODUCTION
Geopolymers are cementitious
materials that do not require the presence of OPC to harden or gain strength. Geopolymers are formed by a 3D network of Si & Al mineral molecules linked through covalent bonds with oxygen molecules. A positive ion must be provided to allow aluminum to become tetravalent.
INTRODUCTION
The source of Si & Al for geopolymers
can be any mineral (e.g. metakaolin) or by-product (e.g. fly ash) The positive ion is usually provided by a hydroxide solution of Na or K, etc. Water glass provides the monomers from which the polymeric chains grow. In most cases a slightly elevated temperature is required to kick start the geopolymerization reaction
Geopolymer
paste
Aggregate
Geopolymer Concrete
SUSTAINABILITY
Actual production of Ordinary Portland cement
contributes 13.5 billion tons of CO2 per year. Approximately 5% of the total global emission of CO2 to the atmosphere. Geopolymer made out of waste materials like fly ash, bottom ash and not only have a smaller footprint but help to reduce the footprint of other industries namely, coal-fired power plants.
Literature Review
Limited literatures on the rheological behaviour of slag
based geopolymer mortar and fly ash based geopolymer paste are only available. No information is available on the rheological behaviour of fly ash geopolymer concrete. An attempt has made to study the rheological behaviour of fly ash based geopolymer concrete with a rate controlled concrete rheometer. Rheological parameters in terms of yield stress and plastic viscosity can be estimated from the down curve of torquespeed plot (Rajan Bhattacharjee, et.al.,2010).
Literature Review
The strength of fly ash geopolymer concrete was
improved to a certain extent by decreasing the water/solids ratio, the aggregate/solids ratio, and the alkaline to fly ash ratio. Aggregate grading showed a marginal influence in the strength development of fly ash geopolymer concrete. (Monita Olivia, et.al.,2011)
Literature Review
Fly ash-based geopolymer is better than normal
concrete in many aspects such as compressive strength, exposure to aggressive environment, workability and exposure to high temperature.(Mohd Mustafa Al Bakri, et.al., 2010)
Literature Review
The mechanism of activation of a fly ash (no other
solid material was used) with highly alkaline solutions is described. The result showed that the geopolymer paste with NaOH concentration, compressive strength increase with molarities increases. (Prof.M.A.Bhosale, et.al., 2012)
MATERIALS COLLECTED
Sodium hydroxide (98% purity in pure form)
Sodium silicate solutions Coarse Aggregate
Bottom ash
Engineered
REFERENCES
Rajan Bhattacharjee ,
Rajan Bhattacharjee Aminul Islam Laskar. Review on
RHEOLOGICAL BEHAVIOR OF FLY ASH BASED GEOPOLYMER CONCRETE, 2010. National Institute of Technology, Silchar, India Monita Olivia, Hamid R. Nikraz. Review on Strength and water penetrability of Fly ash Geopolymer concrete, 2011. Australia. Mohd Mustafa Al Bakri, H. Mohammed, H. Kamarudin, I. Khairul Niza And Y. Zarina. 2010. Review On Fly Ash-Based Geopolymer Concrete Without Portland Cement. Geopolymer Concrete by Using Fly Ash in Construction (By Prof.M.A.Bhosale, Prof.N.N.Shinde)