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1. Approach
In the adiabatic approach energy balances are calculated under following assumptions: There is no heat exchange through the walls of the column The gas and liquid stream leaving a stage are at the same temperature
Therefore two new concepts become important: 1. 2. Energy balances Changes of L and G within the column
Calculating changes of L and G within the column are important when dealing with large solute fractions. This is often the case when calculating non-isothermal columns.
Once, pressure and initial composition and temperature of the solvent are set we can consider them as data. This is a list of known variables: TG1 Data and set values Pressure, p Gas flow rate, Gin Gas initial composition, yn+1 Equilibrium data, y=f(x,T) Specifications Gas final composition, y1 Unknowns Solvent flow rate at inlet, L2 Number of stages, n Solvent final composition, xn Solvent flow rate outlet, L1 G1 y1 TL0 L0 x0
y = f(x,T)
xn Ln TLn
2. Balances
Material Balance of column:
Hs
cp
J/(mol K)
HS represents the molar enthalpy of mixing or the integral heat of solution, at the prevailing concentration and at the base temperature T0 The amount of liquid increases from the bottom to the top of the column. It is calculated by adding up the amount of solvent and the amount of absorbed solute. The same way the amount of gas is calculated. It deacreases from the top to the bottom of the column as the solute absorbs to the liquid.