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*
*Dental Amalgam is a metal like restorative
material composed of a mixture of silver/tin/copper alloy and mercury.
*
Dimensional change Strength Corrosion Creep
Ideally, an amalgam should have:
No change in dimensions Remain stable for the life of the restoration.
The specimen size should be essentially equivalent to the bulk used in large 7 restorations
The leading causes for failures include Secondary caries Marginal fracture Bulk fracture Tooth fracture At microstructural level Corrosion & tarnish Transformation Stress associated with mastication forces
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*
*Under triturition Restoration in the mouth has contracted or As
expanded within the required 20micrometers limit of such dimensional change . average human hair is 40micrometer it is virtually impossible to detect margins that may be open a a few micrometers either wit a eye or dental instrument
*
*Early surveys 16.6% of a large group of
defective restoration failed because of excessive expansion.
*1.Delayed expansion
*2.Insufficient triturition or condensation
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magnitude occurs ,the restoration may become wedged so tightly against the cavity walls that a pressure towards the pulp chamber results and finally protrusion of restoration. 11
*
oPrimary requisite- sufficiently high strength to
resist fracture.
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*
Compressive strength of a satisfactory amalgam should be 310MPa compressive strength tensile strength
(MPa)
Amalgam Low copper Admix 137 1hour 145 7days 343 431 24hour 60 48
(MPa)
Single
composition
262
510
64
14
Lathe cut alloy- high condensation pressure. Spherical alloy- light pressure. Good condensation techniques express mercury result in a
smaller volume fraction of matrix phases .
15
increase in time
undertrituration & delayed condensation
restorations that fractures do shortly after insertion. Clinical manifestation may not be evident but an initial crack may occur within few hours. the 1- wk strength .
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*
*Any exccess mercury left in the restoration can produce a
marked reduction in strength.
17
*
*Amalgam restorations often tarnish &corrode in the oral
environment.
greatly on the individuals oral environment & to a certain extent to the alloy employed. metal surface along the interface between the tooth and the restorations .
*Active corrosion of a newly placed restoration occurs on the *Self sealing restorations . *Presence of 2
Most common products oxides &chlorides of tin
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*
* DEFINITION:-time dependent plastic strain of a material under a static load or
constant stress.
* Creep has been found to correlate with the marginal breakdown of traditional low
copper amalgams. Higher the creep of marginal deterioration. It is prudent to select a commercial alloy that has a creep rate below the level of 3% specified in ANSI/ADA specification no. 1 . Greater degree magnitude
19
2.0% 0.4 %
0.13%
20
*Creep rates - higher 1volume fractions . *Creep rate - larger 1grain sizes. Presence of 2 - higher creep rates Very low creep rates in single composition high copper alloys
which may be associated with rods .
Mercury alloy ratio should be minimized . Condensation pressure maximized for lathe cut & admixed
alloys .
21
1. 2. 3. 4.
The proportioning of mercury and alloy Trituration Condensation Contouring and finishing
22
*
*Historically only way to achieve smooth & plastic *Because of deleterious effects mercury contents
are reduced
amalgam mix is by considerable amount of mercury .
2. During condensation
But there is considerable chance of error . So the most obvious method is to reduce the mercury
content by reducing mercury alloy ratio.
23
Minimal mercury technique or Eames technique- designed for manipulation with reduced mercury/alloy ratios .
be comparable of that of the original mercury alloy ,usually about 50% with lesser amounts (~42wt%)being used with spherical alloys.
*
*Amount of alloy & mercury *Acc. to ratio
mercury/alloy ratio Mercury /alloy ratio 6 parts of mercury of 6/5 indicates 5 parts of alloy by wt. * According to percentage a mix of amalgam prepared with a mercury / alloy ratio of 6:5 contains 54. 5% of mercury . Recommended mercury/alloy ratios :Lathe cut alloys - 1:1 or 50% mercury Spherical alloys 42% If Mercury content low Mix can be dry and grainy . - Corrosion resistance is reduced .
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Disposable capsules
* Pre-proportioned aliquots of
alloy.
mercury &
*
Glass mortar
& pestle are used. Glass mortar inner surface roughened to increase the friction between amalgam and the glass surface . Pestle is a glass rod with a round end.
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29
*
*Mechanical amalgamators are more
commonly used to triturate amalgam alloy & mercury.
top of the machines . When put on, the arms holding the capsule oscillate at high speed , thus triturating the amalgam . confine mercury spray & prevent accidents .
30
*
Mixing time
refer to manufacturer
recommendation.
amalgamation time than do lathe alloys. mixing time than a smaller one .
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32
*
NORMAL MIX
Shiny surface & a smooth & soft consistency. Warm but not hot when removed from the capsule . Best compressive strength & tensile strength . Have increase resistance to tarnish and corrosion.
OVERTRITURATION
Hot mix. Mix is soupy & sticks to capsule. Decreases working / setting time. Slight increase in setting contraction. Creep is increased.
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UNDERTRITURATION
Grainy,
crumbly mix. Rough surface after carving . Strength is less . Mix hardens too rapidly.
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*
*Actually a continuation of triturition .
-Improve the homogenecity of the mass. -To assure a consistent mix
1. Mix is enveloped in a dry piece of rubber dam & vigrously rubbed between the 1st finger & the thumb ; or the thumb of one hand &palm of the other hand . The process should not exceed 2 to 5 seconds . 2. After trituration the pestle can be removed from the capsule , & the mix can be triturated in the pestlefree capsule for an additional 2 to 3 seconds .
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*
GOAL- To compact the alloy into the prepared cavity so that the greatest possible density is attained , with sufficient mercury present to ensure complete continuity of the matrix phase between the alloy particles. It is of two types :-
1. Hand condensation.
2. Mechanical condensation.
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*
Increments should be carried to &inserted into the
prepared cavity by means of instruments such as an amalgam carrier.
the condenser point is stepped little by little towards the cavity walls.
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*
The procedure of adding an Increment ,condensing it
, adding another increment & so forth is continued until the cavity is overfilled .
increment carried into the cavity . Larger the piece ,more difficult to reduce the voids & adapt it to the cavity walls.
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*
The condensation pressure is
governed by
1. 2.
The area of the condenser point, or face. The force exerted on it by the operator .
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Increased
amalgam
Thrust of 44(N)(10lb)
Circular Condenser 2mm 13.8mpa
(2000psi)
Circular Condenser 3.5mm 4.6mpa (667 psi)
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Force recommended
66.7N
For condensation
(15lb)
13.3N-17.8N (3-4lb)
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Oval
Crescent Trapezoidal
Square
Round condenser Triangular Rectangular point
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*
*The procedures and principles of mechanical
condensation are the same as those for hand condensation.
* Various mechanisms are employed for these instruments. Impact type of force Rapid vibration.
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Advantages:
1.
Whichever device , less energy is needed than for hand condensation 2. The operation may be less fatiguing to the dentist .
*
* After condensation , the restoration is carved to
reproduce the proper tooth anatomy. OBJECTIVE-
* Carving is too deep Bulk at marginal areas are reduced. Thinning will leads to its fracture under
masticatory forces .
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*
After the carving is completed the surface should
be smoothed .This may be accomplished by judiciously burnishing the surface &margins of the restoration.
* A rigid, flat bladed instrument is best used on smooth * Pre-burnish * removes excess mercury
*
* Post-burnish
*
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*
Final smoothing Done b y rubbing The surface Moist cotton pellet or Rubber polishing cup with prophylactic paste
It should be delayed for 24hr after condensation. The use of dry polishing powders can raise the surface
temperature above the 60deg c (danger point).
Thus a wet
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*
* Mercury * Mercury
toxicity from dental restorations is the cause for certain undiagnosed illness, and a real hazard may exist for dentist when mercury vapor is inhaled during mixing, placement and removal. penetrates from the restoration into tooth structure leading to discoloration of the tooth.
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Mercury release from amalgam fillings is phasic and consists of a very low release, and an increased stimulated release results due to tooth brushing or chewing. Mercury emitted from amalgam may be in one or two forms. Mercury vapor(hg0) which passes into intra oral air and from here may be either inspired into the lungs or expired into the outside air. Mercuric ions (hg2+)which passes into the saliva and from there to the gastro intestinal tract.
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* * *
*Dentists
are exposed daily to the risk of mercury intoxication,through skin,or by inhalation. readily detected by simple means.
* Maximum
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*
AUTHOR NO. OF SURFACES 12.6 MERCURY(g/ DAY) 19.8
VIMY & LORSEHEIDER (1985) LANGWORTH (1988) SNAPP (1989) SKARE & ENGQVIST (1994)
25 14
3 1.3
39
12
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*
*VAPOR
METALLIC hg CAN BE INHALED AND ABSORBED THROUGH THE ALVEOLI IN THE LUNGS AT 80% EFFICIENCY, AND THUS CONSIDERED AS THE MAJOR ROUTE FOR ENTRY INTO HUMAN BODY.
*Eventually
all are excreted but rate is dependent upon bodys ability to convert it to other forms.
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INVESTIGATOR
AFTER
UNITS
*
EFFECT NO EFFECT DECREASE INCREASE AVERAGE STIMULATION FACTORS FOOD AND DRINK HOT AND COLD DRINK,APPLE MIXED LUNCH,EGGS BRITTLE BISCUITS
GUM CHEWING
MIXED FOOD CHEWING TOOTH BRUSHING
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X 5.3
X 3.7 X 1.9
SUBJECTS
PITUITARY n
BRAIN n
DENTISTS (3)
CONTROL (12)
1533
273
56
1599
107
61
11
*
*CLINICAL MERCURISM THRESHOLD -100g per cubic
meter.(Loael low observed adverse effect level)
*General public threshold -5g per cubic meter.(Noael) *Children,pregnant,sick threshold -1g per cubic
meter.(Noael)
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*
* Vimy/lorscheider
*
(am physio 1990/258/939-945) j
5 adult ewes autopsied after amalgam placement. fetal lambs exposed in utero after mothers amalgam placement.
* 3-5
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and
TO hgo RATS REVEALED HYPEREXCITEMENT SOMETIMES FOLLOWED BY ATAXIA AND TREMOR WHILE THE RATS EXPOSED TO BOTH SHOWED MILD DYSPNOEA,COUGH AND DIARRHOEA. * After 8 wks 10 out of40 rats died in 1st group and 4 out 40 died in 2nd group.
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Pink Disease: the iatrogenic poisoning of babies with mercury-containing teething powders & worming medicines
* Warkany
( am j dis child 1966/112/147-156) estImated that 1 in 500 exposed infants developed the disease.
of children were killed by accidental poisoning and many suffered in misery. disappeared after the Hg containing medicine were with drawn. Adult survivors of pink disease tend to have aspergers syndrome.
* Disease
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millionaire in Lewis Carroll's classic children's book, Alice in Wonderland. relates to a disease peculiar to the hat making industry in the 1800s. turning fur into felt, which caused the hatters to breathe in the fumes of this highly toxic metal.
* But few actually know that the true origin of the saying
* A mercury solution was commonly used during the process of * Resulting in symptoms such as trembling (known as "hatters'
shakes"), loss of coordination, slurred speech, loosening of teeth, memory loss, depression, irritability and anxiety -"The Mad Hatter Syndrome." The phrase is still used today to describe the effects of mercury poisoning.
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* Exposed
persons experience feelings of fatigue and restlessness; they lose interest in their surroundings and in their own life; they withdraw more and more from social contacts; they become increasingly irritable and sensitive, reacting strongly to relatively innocent remarks uttered by family or friends; and they have a tendency for sweating and blushing. In this blushing - or reddening the classical term "erethism finds its origin. * In very severe cases, the depression may reach suicidal proportions. * A deterioration of intelligence gradually emerges during chronic exposure to elemental mercury. Previously bright persons become dull and slow in thinking.
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*
*This
at times been claimed as potential hazard. This is an immune system response to very low level of mercury.
*The
antigen antibody reaction marks by itching, rashes, sneezing, difficulty in breathing, swelling, or other symptoms.
hypersensitivity to mercury results in a contact eczematous reaction on the skin and possibly the 64 oral mucosa.
* Delayed
* Its
prevalance is low in population. Only 41 published cases of allergy to amalgam restoration from 1905-1986. Oral manifestations were present in only 17 cases. such a reaction has been documented, an alternative material, such as composite, ceramic or cast metal alloy must be used.
* When
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vapor?
*
*Mercury is the most toxic non-radioactive element on
earth. *A silver-coloured mercury amalgam filling normally contains 52 percent mercury. *On average, amalgam fillings weigh 1 gram and contain gram of mercury. *Half a gram of mercury in a 10-acre lake would warrant issuance of a fish advisory for the lake. *1 OUT OF EVERY 10 DENTAL OFFICE CROSSES THE MAX. EXPOSURE LEVEL OF MERCURY.
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HARDMAN J G,LIMBIRD L E THE PHARMACOLOGICAL BASIS OF THERAPEUTICS,10TH EDITION,MC GRAW HILL 2001 68
*
* Chelation was first used in the 1940s by the U.S. Navy to treat lead
poisoning and was subsequently approved by the FDA as a safe method of treating heavy metal toxicity. Chelation therapy is a medical treatment that improves metabolic and circulatory function by removing toxic metals and abnormally located nutritional metallic ions (such as iron) from the body. This is accomplished by administering an amino acid, ethylene-di- amine-tetra-acetic acid (EDTA), by either an oral or intravenous infusion.
on to the heavy metal particles, binding tightly and pulling them out of the membrane or body tissue in which they are embedded. Since EDTA is an artificial amino acid, the body regards it as a foreign substance and delivers it to the kidneys to be excreted in the urine.
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*
MAIN AREAS THAT BEEN INVESTIGATED ARE
* BIRTH DEFECTS
* GENERAL HEALTH
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*
* THE
MINIMUM URINARY LEVEL TO SHOW ANY SIGN OF NEUROTOXICITY IS 25/g CREATININE AND THIS IS 6 TIMES HIGHER THAN HIGHEST URINE LEVEL ATTRIBUTABLE TO PRESENCE OF DENTAL RESTORATION.
*A
recent study in greenland (tulinus -arctic medical research 1995/54) showed intellectual ability of school children with dental amalgam restoration in their mouth.
* No
corelation found in marks in any shool subjects and no.Of amalgam restoration.
* So
*
* Studies
of industrial workers exposed to mercury show that altered kidney dysfunction does not occur until the urine mercury level is more than 25 times higher than that associated with dental amalgam fillings. on humans by weismann and hoffmannn (pharmaco toxicology 1995/76/47-49) showed no evidence of kidney impairment after measuring urine mercury and n acetyl pglucosaminidase (nag) levels in 100 subjects.
* Studies
were without fillings. No significant difference between the groups. no evidence dysfunction. linking dental amalgam with kidney
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*
* Studies
by wilheim,dunninger (clinical investigation 1992/70/728-734) compared 2 patient groups,1 having st amalgam fillings for 1 time other having all existing amalgam fillings removed. determined before and after these treatments.
* No
difference between 2 groups and no effects of amalgam fillings on any white blood cells or immunocompetence.
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*
*
Study showed by summers and wireman (antimicrobial agents chemotherapy 1993/37/825-834),changes in antibiotic resistance of oral and intestinal bacteria in monkeys with 12 amalgam restoration for 5 weeks did not show any change in the pattern of antibiotic resistance to these bacteria.
*
*
This was because there were a large no. Of antibiotic resistant bacteria present in the gut both before and after this experiment.
No evidence to support that mercury from amalgam fillings can increase the no. Of antibiotic resistant bacteria in the mouth or gut
74
*
* Human studies (kuntz d,pitkin american journal obstestrics gynaecology
-1982/143/440-443) attempted to relate still birth and birth defect to mercury level in maternal and umbilical cord blood.
* No
significant association with the no. Of amalgam fillings in the mothers. survey of dentists and dental nurses(brodshy and cohen jada 1985/111/779-780) found no difference in the rates of spontaneous abortion and fetal abnormalities in subjects exposed to high low level of mercury.
* Ada
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*
*A
large survey was conducted on 1024 subjects (aged 38-72 by ahlgwist and bengtsson cdoe/1988/16/227-231) by questioning on specific symptoms and complaints to the no. And size of amalgam restoration in their mouth.
* No
corelation were found between them instead those with dental amalgam fillings showed better general health than those without fillings probably reflecting greater concern for health matters.
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*
* * *
SYMPTOMS KNOWING POTENTIAL HAZARDS, eg SENSITIVITY AND NEUROPATHY Hazards - potential sources of mercury vapor, eg spills, leaky dispensers,polishing and removal of amalgams,heating of contaminted instruments. Ventilation proper ventilation in work place by having fresh air exchanges and periodic replacement of filters which may trap mercury.
Monitor office the mercury vapor level should be periodically monitored by dosimeter badges.THE CURRENT OSHA LIMIT FOR MERCURY VAPOR IS 50 gm/cubic meter IN ANY 8 HR WORK SHIFT OVER A 40 HR WEEKLY WORK
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*
* Monitor * Office
personnel periodic analysis (avg.Mercury level in urine is 6.1g/lt FOR DENTAL OFFICE PERSONNEL. design proper work area design to facilitate spill containment and clean up. or store mercury in unbreakable containers.
* Precapsulated alloys to eliminate the possibility of a bulk mercury spill * Amalgamator cover it should be fitted with a cover.
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*
*Handling
care avoid skin contact with mercury or freshly mixed amalgam. system high volume evacuation when finishing or removing amalgam. Evacuation systems should have traps or filters,check clean or replace traps and filters periodically. change mask more often when removing amalgam.
*Evacuation
*Masks
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*
* Recycling
store amalgam scrap under radiographic fixer solution in a covered container. items dispose of mercury contaminated items in sealed bags according to regulations. clean up spilled mercury by using trap bottles,tapes or fresh mixes of amalgam to pick up droplets or use comercial clean up kits.
* Contaminated * Spills
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*
*
Dental amalgam raw materials being stored for use.
*
* * *
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*
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*
*Glasses, mercury
filter and mouth masks should be used.
*Routine exposure
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*
*In
plastic wrapping packages leakage is possible. in closets or
*Stored
cabinets.
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*
*During *To
trituration small amount of material escape. minimize this precapsulated capsules of alloy and mercury are available.
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*
* DURING
TRITURATION HIGH FREQUENCY CAN FORCE hg RICH MATERIAL OUT TO CREATE AEROSOL OF LIQUID DROPLETS AND VAPOR. minimize this amalgamator with covers are preferred. reduce mercury content, reduced mercury : alloy ratio, known as minimal mercury or eames technique is used.
* To * To
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*
*Small
droplets that spill on floor or carpets are best advised to deal with help of a vacuum aspirator.
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*
* The
scrap after condensation should be collected and stored under water,glycerine or x-ray fixer in a tightly capped jar, which should be almost filled with liquid to minimize the gas space where mercury can collect. in the office at any time.
* Once
dental amalgam is solidified mercury is tightly bound but can be easily liquified during polishing procedures that generate heat when adequate cooling water is not used.
89
*
*THE
Ag Hg PHASE IS MELTED PRODUCING A MERCURY LIQUID RICH PHASE THAT IS EASILY SMEARED OVER DENTAL AMALGAM SURFACE MAKING IT LOOK BRIGHT AND SHINY. is deceptive to the dentist as he can misinterpret this appearance as a highly polished surface.
90
*It
*
* It is common where high speed
burs contact tooth structure, increase of temperature leading to release of mercury vapors. dam, high volume evacuation and water cooling should be used to control this situation.
* Rubber
91
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21.09.2006
*
*Instruments
which are used for inserting, finishing, polishing or removing dental amalgam restoration contain some amalgam material on their surfaces. sterilization techniques mercury vapors are released on heating so proper isolation or venting the air from sterilization areas should be done.
*During
93
*
* Capsules
and mercury contaminated cotton rolls or paper napkins should not be thrown out in regular trash. They should be kept in separate plastic containers for disposal.
94
* Best non mercury alternative. * It has similar atom structure and characteristics to mercury. * Used in the same manner as mercury based amalgam. * They
are 16 times more expensive than similar amount of mercury based amalgam.
*
*Metal alloys (gold)
The only real alternative to amalgam in moderate to large cavities. Demands high levels of clinical and lab skills in fabrication. Costs 7 -8 times the amount of an equivalent amalgam restoration.
96
*
* * * * * *
Glass ionomer cement Composite resins Glass ionomer resin hybrids Compomers Ceramics Ormocers used in restoring anterior and cervical cavities in primary and permanent teeth and restorations of posterior teeth of primary dentition. All these have shorter life span than amalgam.
97
AMALGAM FAILURES
*
*
* Inadequate condensation * Material pulling away or breaking from the
* Potential solutions include: * Proper condensation technique * Careful carving of marginal areas, especially
bonded amalgam restorations
*
* Causes of marginal ridge fractures: * Axiopulpal line angle not rounded in Class II tooth
preparations
* Marginal ridge left too high * Occlusal embrasure form incorrect * Improper removal of matrix * Overzealous carving * Potential solutions include: * Proper rounding of axiopulpal line angles in Class II tooth
preparations
*
*Causes of amalgam scrap and mercury
*Careless handling * Inappropriate collection technique *Potential solutions include: *Careful attention to proper collection and
disposal
*
* Amalgam has been used in clinical dentistry for about 200 years.
* Approximately
* However
* Enviornmental
contamination from dental practices should cut down to low levels or this could be the main reason for government action against the use of amalgam in the future.
102
*
*THERE IS A PRINCIPLE
WHICH IS PROOF AGAINST ALL ARGUMENT, AND WHICH CANNOT FAIL TO KEEP MAN IN EVERLASTING IGNORANCE.
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