Escolar Documentos
Profissional Documentos
Cultura Documentos
Introduction
What is Cryoscopy?
study or practice of determining the freezing point of liquids. Freezing point + solute Freezing point depression
Introduction
Baekmann method,
Introduction
Temperature readings
Introduction
Introduction
=
=molar mass of the unknown solute, = 4.90 / , = ; = = and is the mass of the solute and solvent, respectively
Introduction
In the experiment, the molar mass of the unknown solid was determined by the freezing point of the benzene and the freezing point depression of the solution when the unknown was added, =
10
12
10 temperature, C Temperature, C 8
4 2
Figure 2 cooling curve (a) pure solvent To= 5.330 C (b) solution Tf= 5.256 C
1 2
191.3 199.4
195.3
Discussion
No of solutes=
Freezing point
entropy
Discussion
When a known mass of solute is added in a solvent, the freezing point of the solvent decreases to an extent equal to the number of solute added. T1 T2 Molar mass T1
T2
Molar mass
Sample Calculation
(21.9125 )(0.049 )
= 288.88 /
Conclusion
Trial 1 2
To
Tf
M 191.3 199.4
Mave
195.3
Conclusion
The molar mass of the unknown solid was 195.3 g/mol . .;. It is potassium chromate K2CrO4 with 194.19 g/mol. %error= 0.588%