Escolar Documentos
Profissional Documentos
Cultura Documentos
4/22/2014
Air pollution is basically the presence of foreign substances in air in excessive concentration which adversely affects the well being of an individual.
Presence of one or more than one contaminants of dust, smoke, different type of gases and vapours in the atmosphere which affect the quality and property of air which is injurious to human health, plant and animal life is called Air Pollution. The substance / material causing pollution is known as
Pollutant
4/22/2014 2
4/22/2014
1.
According to Origin
Secondary Pollutants: Which are derived from the primary pollutants due to chemical or photochemical reaction. Examples: PAN (Per Oxy - Acyl Nitrate).
4/22/2014
Organic Pollutants: Hydrocarbons, Aldehydes, Ketones and Amines etc Inorganic Pollutants:
4/22/2014
Gaseous Pollutants: Which get mixed with air & dont normally settle out. Examples: CO, NOx and SO2 .
Particulate Matters:
Finely divided/suspended solids or liquids, Example: Smoke, fumes, dust, fog and smog.
4/22/2014
PRIMARY
POLLUTANTS
1. CO
2. Nox
3. Sox
4. Hydrocarbons
5. Particulate Matters
4/22/2014
Properties :
4/22/2014
4/22/2014
combustion (IC) engines. Motor vehicles, aircrafts, railways, Iron and steel industries, Petroleum and paper industries, Agricultural burning.
4/22/2014
10
[HbO2 ] + CO
Oxyhaemoglobin
[HbCO]
O2
4/22/2014
11
Conc.
10 ppm 100 ppm
Effects
Decreases visibility Headache, vascular disorder
250 ppm
750-1000ppm
Loss of consciousness
Death of human beings.
4/22/2014
12
automobiles.
4/22/2014
13
Oxides of Sulphur
Oxides of Sulphur : They are represented/ indicated by (SOx). In air pollution SO2 and SO3 are the two major pollutants.
4/22/2014
14
Oxides of Sulphur
1. Sulphur monoxide (SO) 2. Sulphur dioxide (SO2) 3. Sulphur trioxide (SO3) 4. Sulphur tetra oxide (S2O4) 5. Sulphur sesquioxide (S2O3) and 6. Sulphur heptaoxide (S2O7).
4/22/2014
15
Oxides of Sulphur
SO2
It is a colourless, non-flammable Suffocating pungent odour
4/22/2014
16
Oxides of Sulphur
Production : Produced from the combustion of sulphur bearing materials. S + O2 SO2 2SO2 + O2 2SO3 SO2 + H2O H2 SO3 (Sulphurous acid) SO3 + H2 O H2 SO4 (Sulphuric acid)
4/22/2014
17
Oxides of Sulphur
Sources Natural Sources: [67%] of SOx are emitted by natural agencies from volcanic eruption, decomposition of fossil fuels and bacterial
decomposition of organic substance. Anthropogenic Sources: [33%] Combustion of S containing coal & fuel. Roasting of sulphide ore in smelting industries. Cu2 S + O2 (Copper pyrite)
4/22/2014
2 Cu + SO2
18
Oxides of Sulphur
Harmful effects : These affect human being as well as plants. In Human Being H2SO4 & SO3 irritate the mucous membrane and respiratory tract. It causes bronchitis. The SO2 particulate combination (smog) has been cited as cause of death.
4/22/2014
19
Oxides of Sulphur
In plants SO2 if present only 0.03 ppm concentration shows Damage of chlorophyll and stop photosynthesis plants called chlorosis disease in green
buildings.
CaCO3 + H2SO4 CaSO4 + CO2 + H2O
4/22/2014 20
Oxides of Sulphur
Effects of SO2 on human health .
Conc.ppm
1.0 - 2.0 1.0 - 5.0
Effects
Cardio respiratory response Chest pain
5.0 - 10.0
10.0 - 20.0 20.0 400 to 500
4/22/2014
21
Oxides of Sulphur
Control: Removal of SOx from fuel gases. Use of low sulphur fuels. Converting coal by liquefaction or gasification. Using chemical scrubbers like CaCO3.
4/22/2014
22
i)
NO:
It
is
a
gas,
colourless,
produced
odourless,
by rapid
paramagnetic
combustion of fuels.
4/22/2014
24
4/22/2014
25
lower atmosphere.
Anthropogenic sources : Combustion of fossil fuel, coal, natural gases. Power plants produce high conc. of NOx at high temperature. HNO3 is end product of Nox.
4/22/2014
26
4/22/2014
27
N2O Nitrous oxide or laughing gas It is often used as a dental anaesthetic is an important green house gas. One N2O molecule is about 200 times as effective as one CO2 molecule, as a green house gas.
4/22/2014
29
20 to 50
50 to100 100 to 150
Pulmonary discomfort
Inflammation of lung tissues Bronchitis
4/22/2014
30
Control The use of catalytic converter for the control of automotive emissions.
4/22/2014
31
Hydrocarbons (HC)
4/22/2014
32
Hydrocarbons (HC)
HYDROCARBONS
Aromatic
Aliphatic
Alkane
Alkene
Alkyne
4/22/2014
33
Hydrocarbons (HC)
1. Alkanes : Alkanes are HC with only single bonds between the atoms. Alkanes can be either straight-chain or branched chain Straight-chain alkanes are the simplest Saturated HCs e.g. CH4 are inert and not active in photo chemical reactions.
4/22/2014
34
Hydrocarbons (HC)
2. Alkenes :
3. Alkyne :
4/22/2014
35
Hydrocarbons (HC)
4/22/2014
36
Hydrocarbons (HC)
Sources of Hydrocarbon 1. Natural Sources: Some HC come from geothermal areas, coal fields, natural gas from petroleum fields and natural fires. HC are also produced by plants & trees (terpenes, isoprene)
4/22/2014
37
Hydrocarbons (HC)
Transportation,
HC emissions from solid waste disposal, Agricultural burning and coal waste fires.
4/22/2014
38
Hydrocarbons (HC)
Harmful Effects of HC:
HC are generally non toxic, but their role in the formation of Photo chemical Smog is important.
4/22/2014
39
Hydrocarbons (HC)
Control Methods: HC are controlled by physical and chemical methods
4/22/2014
40
Small,
solid
particles
and
liquid
droplets
are
collectively termed as
Particulates.
Pollen, viruses,
volcanic dust etc.
4/22/2014
41
3.
4. 5.
Fumes
Mist Fog
6.
Aerosol
4/22/2014
42
1.
Dust: Dispersion aerosols with solid particles are called dusts. They are heterogeneous in composition.
2.
Smoke: Condensation of aerosols with a solid & a solid dispersed phase / a liquid and a liquid dispersed phase are called smokes.
3.
Fumes: Solid particles of the size 0.1 to 1mm which are released from chemical or metallurgical process.
4/22/2014
43
4.
Mist : It is made up of liquid droplets generally smaller than 10 mm formed by condensation in the
atmosphere or are released from industrial operation. 5. Fog : It is mist in which the liquid is water and is
4/22/2014
44
Sources of Particulates
Man made activities such as burning of wood, coal, oil and gaseous fuels. Fly ash emissions from power
4/22/2014
45
Aerosols cause allergies to sensitive persons. The sprays of insecticides and pesticides affect the central nervous system. Control: Various types of equipments are used for the removal of particulate matter from gas streams.
4/22/2014
46
1. Acid Rain
SECONDARY POLLUTANTS
4/22/2014
47
ACID RAIN
Presence of excessive acid in rain water is called acid rain. by Robert Angus in 1872 Acid rain is a mixture of H2SO4 and HNO3
H2SO4 and HNO3 Combined with HCl generate acidic precipitation which is widely known as Acid Rain Precipitation that has a pH of less than that of natural rainwater.
4/22/2014
48
ACID RAIN
4/22/2014
49
ACID RAIN
Sources:
Human activities- gaseous emissions from Car, homes, Factories and Power Station. Volcanoes Burning of fossil fuels. Industrialization Automobiles.
4/22/2014
50
ACID RAIN
Reactions in the Atmosphere :
SO2 + H2O H2SO3 (Sulphurous acid) SO3 + H2 O H2SO4 (Sulphuric acid) NO2 + O3 NO3 + O2 NO3 + NO2 N2O5 N2O5 + H2O 2HNO3 (Nitric acid)
4/22/2014
51
ACID RAIN
4/22/2014
52
ACID RAIN
Harmful Effects
1. On Terrestrial Ecosystem / Vegetation
2. On Buildings
3. On Aquatic Biota. 4. On Human health
4/22/2014
53
ACID RAIN
Effect on Terrestrial Ecosystem / Vegetation Acid rain damages leaves of plants and trees Increased acidity in soil Leeches nutrients from soil, slowing plant growth Pea, Beans, Radish, Potato, etc Leeches toxins from soil, poisoning plants Creates brown spots in leaves of trees, impeding photosynthesis Allows organisms to infect through broken leaves
4/22/2014 54
ACID RAIN
Effect on Buildings Accelerates weathering in metal and stone structures, Example:- Parthenon in Athens, Greece; The Taj Mahal of Agra is also suffering at present due to SO2 and H2SO4 fumes. Extensive damage of buildings and rapid attack of materials of marble limestone. CaCO3 + H2SO4 CaSO4 + H2S + CO2 The attack on marble is termed as Acid Leprosy.
4/22/2014
55
ACID RAIN
Effect on Aquatic Biota
acidification.
Biological effects on aquatic biota decline the productivity of fish and amphibians. Stops eggs of certain organisms (e.g. fish) to stop hatching & Changes population ratios
4/22/2014
56
ACID RAIN
Effect on Human Health Respiratory problems, asthma, dry coughs, headaches and throat irritations Leeching of toxins from the soil by acid rain can be absorbed by plants and animals. When consumed, these toxins affect humans severely. Brain damage, kidney problems, and Alzheimer's
4/22/2014
58
ACID RAIN
Control The simplest solutions to the problem is to neutralize the acid with time. Powdered limestone/limewater added to water and soil to neutralize acid To reduce the emissions of SOx and NOx from industries. Desulphurisation and denitrification.
4/22/2014
59
Photochemical Smog
The majority of the harmful effects of hydrocarbon pollution is not due to the
hydrocarbons, but due to the products of photochemical reactions in which these are involved. Smog originally means an odd combination of Smoke and Fog.
4/22/2014
61
Photochemical Smog
The condition for the formation of chemical smog areA. Stagnant air masses, B. Abundant sunlight, C. High concentration of hydrocarbon and Nox pollutants.
4/22/2014
62
Photochemical Smog
Photochemical smog is characterized by Brown, hazy fumes Irritates the eyes and lungs Lead to the cracking of rubbers Cause extensive damage of plants life. Is an oxidising smog & has high concentration of oxidants.
4/22/2014
63
Photochemical Smog
Reactions Involved in Photochemical Smog: Reactive hydrocarbons from automobile exhaust interact with O3 to form a free radical RCH2 . Reactive HC + O3 RCH2* RCH2* reacts with O2 to form another free radical. RCH2* + O2 RCH2O2. RCH2O2* reacts with NO to produce NO2 and the free radical RCH2O* RCH2O2* + NO
4/22/2014
RCH2O* + NO2
64
Photochemical Smog
This new free radical with O2 to yields a stable
free
Photochemical Smog
4/22/2014
66
Photochemical Smog
RCHO interacts with the HO. radical and form acyl radical RC* = O RCHO + HO. RC* = O + H2 O ( acyl Radical)
Acyl radical further change into peroxyacyl radical by the absorption of O2 and RC = O.
O
+ O2
RC*
O OO O
Which finally changes into the RCO3NO2 Peroxyacyl Nitrate (PAN) RC*
OO
+ NO2 RC
OONO2
+ HO.
4/22/2014
67
Reactive Hydrocarbon
RCH2O*2
+NO
Photochemical Smog
RCH2O*+ NO2
+NO
+O2
+
RCHO
HO* RC * = O +O2
RC *
Peroxyacyl Radical
OO
+ NO2
O RC
4/22/2014
68
4/22/2014
69
4/22/2014
70
40 units are radiated by clouds, 21 units are radiated by water vapour and gases.
4/22/2014
71
4/22/2014
72
CO2 : 50%
4/22/2014
74
4/22/2014
75
4/22/2014
76
impenetrable gases. Plants will be less rich in nitrogen & more susceptible to pests.
4/22/2014
77
4/22/2014
78
4/22/2014
79
Ozone
Ozone is a bluish gas with an pungent odour. Water soluble, unstable, sweetish odour. It can be produced by passing a high voltage through dry air between two electrodes. It is unstable and breaks down to O2 and nascent oxygen ( a powerful oxidizing agent).
4/22/2014
80
Occurrence Natural ozone mainly occurs in the stratosphere where it serves a vital biological role in absorbing high energy photons of UV rays.
4/22/2014
81
4/22/2014
82
Sources
1. Mainly it is present in stratosphere but small concentration diffuses downwards. 2. Also small amount is produced by lighting forest fires. 3. The emission of hydrocarbons, CO and NOx mainly from
4/22/2014
83
Effects on Human being Ozone is a poisonous gas. At higher concentration Ozone is a major component of photochemical smog along with PAN.
4/22/2014
84
Control
Tropospheric ozone conc. can be reduced by controlling the emission of the anthropogenic precursors of ozone which are HCs, NOx and CO for this Reduce NOx emissions from power stations and vehicle exhausts. Reduce volatile organic compounds (VOC) emissions from vehicle exhausts. Reduce CO emissions from vehicles.
4/22/2014
85
Its conc. at tropopause is < 1.0ppm and then starts Increasing to a maximum value of 8.0 ppm at 30 km. and
then again decreases to a value of 2.0ppm at 40 km.
4/22/2014
86
Formation of Ozone Layer:In stratosphere, O3 is formed naturally when oxygen is dissociated by UV solar radiations. O2 + h (242 nm) O + O2 + M O+O
O3 + M
4/22/2014
87
Cause of Depletion of Ozone Layer:1. Water vapour and nitrogen oxides released by high attitude aircrafts. 2. Nitrous oxides (N2O) produced by the bacteria in soil
refrigeration. So depletion of ozone takes place and result in increase in u v rays reaching the earth.
4/22/2014
88
It includes :
(1) The natural process. (2) The anthropogenic process.
4/22/2014
89
1.The Natural Process: The atmospheric oxygen absorbs UV radiation at < 240 nm. And photo dissociate into two oxygen atoms.
4/22/2014
90
This ozone again react with nascent oxygen and dissociates into molecular oxygen. 240 260 nm O2 + O+O
O3 + O
O2 + O2
4/22/2014
91
The CFC s (like chlorofluoro methane or freon) are inert in normal and physical reactions but they
4/22/2014
92
CF2Cl2 + h CF2Cl
Cl + CF2Cl
----
(1) (2)
ClO
Cl + O
ClO + O2
------------
(3)
(4) (5)
Cl + O3
destroyed.
4/22/2014
93
4/22/2014
94
CFCs and halons (bromochlorofluoro carbon) remain inactive in the troposphere and it takes about 20 -40 years
4/22/2014
95
4/22/2014
96
4/22/2014
97
h H2 O .OH + H.
.OH
+ O3 H O 2 + O2
.OH
H. + O3
+ O2
4/22/2014
98
1.
2. 3.
Causes skin cancer, reduce resistance. Increase in UV radiation have damaging effects on the DNA of exposed cells of organisms and cause Skin Cancer.
4/22/2014
99
4/22/2014
100
4/22/2014
101
Ozone reduction in stratosphere may drastically change the weather elements like temperature or wind pattern.
4/22/2014
102
Ozone Depletion Create Ecological Disbalance: The depletion of ozone if not controlled would effect the ecosystem productivity, ecological stability and environmental equilibrium. This also cause certain physiological changes in
4/22/2014
103