Atoms, Molecules, and Ions: Theodore L. Brown H. Eugene Lemay, Jr. and Bruce E. Bursten

Atoms,
Molecules,
and Ions
2009, Prentice-Hall, Inc.
Chapter 2
Atoms, Molecules,
and Ions

John D. Bookstaver
St. Charles Community College
Cottleville, MO
Chemistry, The Central Science, 11th edition
Theodore L. Brown; H. Eugene LeMay, Jr.;
and Bruce E. Bursten
Atoms,
Molecules,
and Ions
Atomic Theory of Matter
The theory that atoms are the fundamental
building blocks of matter reemerged in the early
19th century, championed by John Dalton.
Atoms,
Molecules,
and Ions
Dalton's Postulates
#1. Each element is composed of extremely
small particles called atoms.
Atoms,
Molecules,
and Ions
Dalton's Postulates
#2. All atoms of a given element are identical to
one another in mass and other properties, but
the atoms of one element are different from the
atoms of all other elements.
Atoms,
Molecules,
and Ions
Dalton's Postulates
#3. Atoms of an element are not
changed into atoms of a different
element by chemical reactions;
atoms are neither created nor
destroyed in chemical reactions.
Atoms,
Molecules,
and Ions
Daltons Postulates
#4. Compounds are formed when
atoms of more than one element
combine; a given compound always
has the same relative number and kind
of atoms.
Atoms,
Molecules,
and Ions
Law of Constant Composition
Proposed by Joseph Proust (17541826)
This is also known as the law of definite
proportions.
It states that the elemental composition
of a pure substance never varies.
Atoms,
Molecules,
and Ions
Law of Multiple Proportion
Methane 12g C and 4g H (3:1)
Ethane 24g C and 6g H (4:1)
Atoms,
Molecules,
and Ions
Law of Conservation of Mass
The total mass of substances present at
the end of a chemical process is the
same as the mass of substances
present before the process took place.
2H
2
+ O
2
2H
2
O
(4g) (32g) (36g)

What happens if you use 6g H
2
in this reaction?
Atoms,
Molecules,
and Ions
The Electron
Streams of negatively charged particles were
found to emanate from cathode tubes.
J. J. Thompson is credited with their
discovery (1897).
Atoms,
Molecules,
and Ions
The Electron
Thompson measured the charge/mass ratio
of the electron to be 1.76 10
8
coulombs/g.
charge on the electron / mass of the electron
= 1.76 10
8
coulombs/g

Atoms,
Molecules,
and Ions
Charge and mass of elctron?
Once the charge/mass ratio of
the electron was known,
determination of either the
charge or the mass of an
electron became a challenge.

Charge of an electron = 1.602 X
10
-19
Coulombs

Atoms,
Molecules,
and Ions
Millikan Oil Drop Experiment
Robert Millikan (University
of Chicago) determined
the charge on the electron
in 1909.

Electron mass = e/(e/m)
= 9.10 X10
-28
g
Atoms,
Molecules,
and Ions
Radioactivity
Radioactivity is the spontaneous
emission of radiation by an atom.
It was first observed by Henri
Becquerel.
Marie and Pierre Curie also studied it.
Atoms,
Molecules,
and Ions
Radioactivity
Three types of radiation were discovered by
Ernest Rutherford:
particles
particles
rays
Atoms,
Molecules,
and Ions
The Atom, circa 1900
The prevailing theory
was that of the plum
pudding model, put
forward by Thompson.
It featured a positive
sphere of matter with
negative electrons
imbedded in it.
Atoms,
Molecules,
and Ions
Discovery of the Nucleus
Ernest Rutherford
shot particles at a
thin sheet of gold foil
and observed the
pattern of scatter of
the particles.
Atoms,
Molecules,
and Ions
The Nuclear Atom
Since some particles
were deflected at
large angles,
Thompsons model
could not be correct.
Atoms,
Molecules,
and Ions
The Nuclear Atom
Rutherford postulated a very small,
dense nucleus with the electrons
around the outside of the atom.
Most of the volume of the atom is empty
space.
Atoms,
Molecules,
and Ions
Mass of an atom is in the nucleus.
It is extremely dense.
Density of the nucleus = 10
13
-10
14
g/cm
3

A match box filled with this material will weigh 2.5
billion tons!

Atoms,
Molecules,
and Ions
Other Subatomic Particles
Protons were discovered by Rutherford
in 1919.
Neutrons were discovered by James
Chadwick in 1932.
Atoms,
Molecules,
and Ions
Subatomic Particles
Protons and electrons are the only particles that have a
charge.
Protons and neutrons have essentially the same mass.
The mass of an electron is so small we ignore it.
1 amu = 1.66054 X 10
-24
g
1 g = 6.02214 X 10
23
amu
Atoms,
Molecules,
and Ions
Symbols of Elements
Elements are symbolized by one or two
letters.
Atoms,
Molecules,
and Ions
Atomic Number
All atoms of the same element have the same
number of protons:
The atomic number (Z)
Atoms,
Molecules,
and Ions
Atomic Mass
The mass of an atom in atomic mass units
(amu) is the total number of protons and
neutrons in the atom.
Atoms,
Molecules,
and Ions
Isotopes
Isotopes are atoms of the same element with different masses.
Isotopes have different numbers of neutrons.
Atomic Mass for each isotope and their % can be determined
11
6
C
12
6
C
13
6
C
14
6
C
Atoms,
Molecules,
and Ions
Atomic Mass
Atomic and
molecular masses
can be measured
with great accuracy
with a mass
spectrometer.
Atoms,
Molecules,
and Ions
Average Mass
Because in the real world we use large
amounts of atoms and molecules, we
use average masses in calculations.
Average mass is calculated from the
isotopes of an element weighted by
their relative abundances.
11
C,
12
C,
13
C,
14
C
Atoms,
Molecules,
and Ions
Periodic Table
It is a systematic
catalog of the
elements.
Elements are
arranged in order
of atomic number.
Atoms,
Molecules,
and Ions
Periodicity
When one looks at the chemical properties of
elements, one notices a repeating pattern of
reactivities.
Atoms,
Molecules,
and Ions
Periodic Table
The rows on the
periodic chart are
periods.
Columns are groups.
Elements in the same
group have similar
chemical properties.
Atoms,
Molecules,
and Ions
Groups
These five groups are known by their names.
Atoms,
Molecules,
and Ions
Periodic Table
Nonmetals are
on the right
side of the
periodic table
(with the
exception of
H).
Atoms,
Molecules,
and Ions
Periodic Table
Metalloids
border the
stair-step line
(with the
exception of
Al, Po, and
At).
Atoms,
Molecules,
and Ions
Periodic Table
Metals are
on the left
side of the
chart.
Atoms,
Molecules,
and Ions
Chemical Formulas
The subscript to the right
of the symbol of an
element tells the number
of atoms of that element
in one molecule of the
compound.
Atoms,
Molecules,
and Ions
Chemical Formulas
Molecular compounds
are composed of
molecules and almost
always contain only
nonmetals.
Atoms,
Molecules,
and Ions
Diatomic Molecules
These seven elements occur naturally as
molecules containing two atoms.
Atoms,
Molecules,
and Ions
Types of Formulas
Empirical formulas give the lowest whole-
number ratio of atoms of each element in a
compound.
Molecular formulas give the exact number of
atoms of each element in a compound.
CH
2
O
C
6
H
12
O
6
Atoms,
Molecules,
and Ions
Presentation of Formulas
Structural formulas show the
order in which atoms are
bonded.
Perspective drawings also
show the three-dimensional
array of atoms in a
compound.
Atoms,
Molecules,
and Ions
Ions and Ionic Compounds
When atoms lose or gain electrons, they
become ions.
Cations are positive and are formed by elements
on the left side of the periodic chart.
Anions are negative and are formed by elements
on the right side of the periodic chart.
Atoms,
Molecules,
and Ions
Ionic Bonds
Ionic compounds (such as NaCl) are
generally formed between metals and
nonmetals.
Atoms,
Molecules,
and Ions
Writing Formulas
Because compounds are electrically neutral, one can determine
the formula of a compound this way:
The charge on the cation becomes the subscript on the
anion.
The charge on the anion becomes the subscript on the
cation.
If these subscripts are not in the lowest whole-number ratio,
divide them by the greatest common factor.

Ca
+2
O
-2
Al
+3
PO
4
-3
N
-3
Atoms,
Molecules,
and Ions
Common Cations
Atoms,
Molecules,
and Ions
Common Anions
Atoms,
Molecules,
and Ions
Inorganic Nomenclature
Write the name of the cation.
If the anion is an element, change its
ending to -ide; if the anion is a
polyatomic ion, simply write the name of
the polyatomic ion.
If the cation can have more than one
possible charge, write the charge as a
Roman numeral in parentheses.
Atoms,
Molecules,
and Ions
Patterns in Oxyanion Nomenclature
When there are two oxyanions involving
the same element:
The one with fewer oxygens ends in -ite.
NO
2

: nitrite; SO
3
2
: sulfite
The one with more oxygens ends in -ate.
NO
3

: nitrate; SO
4
2
: sulfate
Na
2
SO
3
Ca(NO
3
)
2
Atoms,
Molecules,
and Ions
Patterns in Oxyanion
Nomenclature
The one with the second fewest oxygens ends in -ite.
ClO
2

: chlorite
The one with the second most oxygens ends in -ate.
ClO
3

: chlorate
Atoms,
Molecules,
and Ions
Patterns in Oxyanion Nomenclature
The one with the fewest oxygens has the prefix hypo-
and ends in -ite.
ClO

: hypochlorite
The one with the most oxygens has the prefix per- and
ends in -ate.
ClO
4

: perchlorate
Atoms,
Molecules,
and Ions
Acid Nomenclature
If the anion in the acid
ends in -ide, change
the ending to -ic acid
and add the prefix
hydro- .
HCl: hydrochloric acid
HBr: hydrobromic acid
HI: hydroiodic acid
Atoms,
Molecules,
and Ions
Acid Nomenclature
ends in -ite, change
the ending to -ous
acid.
HClO: hypochlorous
acid
HClO
2
: chlorous acid

Atoms,
Molecules,
and Ions
Acid Nomenclature
ends in -ate, change
the ending to -ic acid.
HClO
3
: chloric acid
HClO
4
: perchloric acid
Atoms,
Molecules,
and Ions
Nomenclature of Binary
Compounds
The less electronegative
atom is usually listed first.
A prefix is used to denote
the number of atoms of
each element in the
compound (mono- is not
used on the first element
listed, however) .
Atoms,
Molecules,
and Ions
Compounds
The ending on the more
electronegative element
is changed to -ide.

CO
2
: carbon dioxide
CCl
4
: carbon tetrachloride
Atoms,
Molecules,
and Ions
Compounds
If the prefix ends with a or o
and the name of the element
begins with a vowel, the two
successive vowels are often
elided (joined together) into
one.
NO: nitrogen monoxide
N
2
O
5
: dinitrogen pentoxide
XeF
6
:
Atoms,
Molecules,
and Ions
Nomenclature of Organic
Compounds
Organic chemistry is the study of carbon.
Organic chemistry has its own system of
nomenclature.
Atoms,
Molecules,
and Ions
Compounds
The simplest hydrocarbons (compounds
containing only carbon and hydrogen) are
alkanes.
Atoms,
Molecules,
and Ions
Compounds
The first part of the names above correspond
to the number of carbons (meth- = 1, eth- = 2,
prop- = 3, etc.).

Atoms,
Molecules,
and Ions
Compounds
When a hydrogen in an alkane is replaced with
something else (a functional group, like -OH in
the compounds above), the name is derived from
the name of the alkane.
The ending denotes the type of compound.
An alcohol ends in -ol.
Atoms,
Molecules,
and Ions
Practice problems
The following problems have been selected from the exercises
at the end of chapter 2 for your mastery of the contents in this
chapter: 2.2, 2.4, 2.16, 2.26, 2.32, 2.38, 2.44, 2.50, 2.58, 2.66,
2.72, 2.78

Atoms,
Molecules,
and Ions
Chemical Equations
Chemical equations are concise
representations of chemical reactions.
Atoms,
Molecules,
and Ions
Anatomy of a Chemical Equation
CH
4 (g)
+ 2 O
2 (g)
CO
2 (g)
+ 2 H
2
O
(g)

Atoms,
Molecules,
and Ions
Reactants appear on the left
side of the equation.
CH
4 (g)
+ 2 O
2 (g)
CO
2 (g)
+ 2 H
2
O
(g)

Atoms,
Molecules,
and Ions
Products appear on the
right side of the equation.
CH
4 (g)
+ 2 O
2 (g)
CO
2 (g)
+ 2 H
2
O
(g)

Atoms,
Molecules,
and Ions
The states of the reactants and products
are written in parentheses to the right of
each compound.
CH
4 (g)
+ 2 O
2 (g)
CO
2 (g)
+ 2 H
2
O
(g)

Atoms,
Molecules,
and Ions
Coefficients are inserted
to balance the equation.
CH
4 (g)
+ 2 O
2 (g)
CO
2 (g)
+ 2 H
2
O
(g)

Atoms, Molecules, and Ions: Theodore L. Brown H. Eugene Lemay, Jr. and Bruce E. Bursten

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