CEMENTS BASED ON ORGANOMETALLIC

CHELATE COMPOUND

Bbrp semen kg memp. karakteristik in rx setting
divalent metallic ions ( Zn ion) + orthodisubstituted
aromatic compound chelate compound

Tipe aromatic compound adalah :
1. ZnO / Eugenol cements
2. Ortho-ethoxybenzoic acid (EBA) cements
3. Calcium hydroxide cements , in which the aromatic
liganda are silicate
Dasar rx : Asam + Basa garam gel
KOMPONNEN UTAMA :

+
Amfoter Asam
/ basa

Proton Proton
Aceptor Donor

SERBUK
CAIRAN PASTA KENTAL
MASA SOLID
/ PADAT
REAKSI UMUM
MO + H
2
A MA + H
2
O
proton proton gel-salt
acceptor donor

MxSiO + H
2
A MA + xSiO
2
+ H
2
O

Setting tda :
1. Inti (sisa serbuk)
2. Matrik (gel-salt)
1. Cavitiy lining
2. Cementing agent
3. Temporary restoration
4. Restorastion : Decidui, anterior, posterior
5. Pit : Fissure salent
6. Pulp capping
7. Root canal filling materials
8. Periodntal dressing
Diagram cavity lining protects the dental pulp
VITAL PULP
CAVITY LINING
CHEMICAL
ATTACK
THERMAL
SHOCK
GALVANIC
EFFECT
FUNGSI SEMEN
Final cementation of completed
restoration
ZnPO
4
, ZnSilikoPO
4,
rein-forced
ZnOE, Znpolikar-boksilat, SIK
Temporary cementation of
completed restoration or cemen-
tation of temporary restoration
ZnOE, Non-Eugenol ZnO
High strength bases ZnPO
4
, reinforced ZnOE,
Zn polikarboksilat
Temporary fillings ZnOE, reinforced ZnOE,
Zn polikarboksilat
Low strength bases ZnOE, CaOH
Liners CaOH in a suspension
Varnish Resin in a solvent
SPECIAL APPLICATION
FUNGSI SEMEN
Root canal sealer ZnOE, Zn Polikarboksilat
Gingival tissue pack ZnOE
Surgical dressing ZnOE, ZnOPreparation
Cementation of
orthodontic bands
ZnPO
4
, Zn Polikarboksilat
Orthodontic bonding Resin akrilik, Resin
komposit
Syarat ideal
1. Non toksik, non iritan
2. Melindungi pulpa dari material restorasi
- thermal insulation eq. Dibawah amalgam
- proteksi kimiawi dr m. restorasi
- electrical insulation
3.Tidak larut in saliva & cairan in mulut.
4. Sifat adesif thd gigi & material restorasi
5. Sifat mekanis ttn
6. Sifat optik menyerupai s. optis jar gigi
7. Sifat reologi adonan viskositas rendah lap
semen tipis & wkt kerja cukup

Sifat karakteristik semen kg
Tebal
(m)
Set time
(Mnt)
Compressive
Str (MPa)
Zn Ph (luting) 25 2,5 - 8 70
Zn Polikarboksil (lt) 25 2,5 - 8 70
Zn Ph (base/liner) 25 2,5 6 70
Zn Poli (base/liner) 25 2,5 - 6 70
SIK (Lt ) - 2,5 - 8 70
SIK Base/liner) - 2,5 6 70
SIK restorative - 2,5 8 130
Dental cements classified
by ingredient and application
I. Water-Bases Cements
1. Glass and resin-modified glass ionmer cements
2. Zinc polyacrylate
3. Zinc phosphate
II. Resin Bases Cements
1. Composites and adhesive resins
2. Compomers
III. Oil Based Cements
1. Zinc oxide Eugenol
2. Non eugenol zinc oxide
Glass and resinmodified glass ionomer cements
Class 5 restoration
Retention of convensional alloy based
restorations
Retention of alumina or zirconia-bases all-
ceramic restorations
Retention of orthodontic bands
High strength bases
Long-term profesional restoration
Zinc polyacrylate = polikarboksilat
Retention of alloy restoration, orthodontic bands and
pediatric stainless steel crowns
High strength bases
Long term provesional restorations
- CH
2
CH CH
2
CH

C = O C = O

O O

H H

Asam poliakrilat = polikarboksilat
Zinc phosphate semen
Retention of conventional restorations,
orthodontic bands
High strengh bases
Long-term provesional restorations

Komposisi ZnPO
4
semen
POWDER Weight (%)
ZnO 90,2
MgO 8,2
SiO
2
1,4
Bi
2
O
3
0,1
Misc. BaO, Ba
2
SO
4
, CaO 0,1

LIQUID Weight (%)
H
2
PO
4
(free acid) 38,2
H
3
PO
4
(combined with Al & Zn) 16,2
Al 2,5
Zn 7,1
H
2
O 36

Serbuk
MgO + ZnO sampai 10 % (-) suhu pemanasan in
proses kalsinasi.
Serbuk dibakar in suhu 1000C---1300 C4-8 jam
(-) reaktivitasnya
memberikan working/ setting time sesuai dgn semen.
Tanpa proses pembakaran semen setting terlalu cpt

Cairan
Al + Zn larutan asam ortoposporik.
As. Posporik----------- larutan buffe
(85 %)
Manipulasi
P/L ratio : 1,4 gm / 0,5 ml
Diaduk diatas glass slab dgn stainless spatula, gerakan
memutar
Lama pencampuran : 15 20 dt
Reaksi setting

Ketika serbuk ZnPO
4
semen kontak dgn cairan-nya
percampuran.
Pada tahap inisiasi terjadilah pembasahan & rx kimia.
Permukaan serbuk alkalin terurai oleh cairan asam
menghasilkan reaksi eksotermis.

3 ZnO + 2 H
3
PO
4
+ H
2
O Zn
3
(PO
4
)
2
. 4 H
2
O
Hidrat amorphous Zn phospat
Isolator termis & me(-) efek galvanik
Composite and adhesive resins
Bonded conventional alloy-based restoration
Bonded ceramic crowns, bridges, veneers, inlays, and
onlays
Bonded laboratory composite crown, bridges, veneers,
inlays , and onlays
Bonded posts and cores
Retention of provisional restoratui
Retention of orthodontic brackets
Compomer
Bonded conventional alloy-based
restoration
Retention of alumina or zinkonia based all-
ceramic restoration
Zinc oxide-Eugenol
High strength bases
Provesional restorations
Root canal sealers
Gingival tissue packs
Surgical dressings
Komposisi ZnO/Eugenol semen
Komponen Fungsi
Powder ZnO Primary reactive ingredient
Zn Acetat
(1-5%)

Accelerator
Liquid Eugenol Primary reactive ingredient
Olive oil
(5-15 %)
To control viscosity
Komposisi EBA semen
Component Function
Powder ZnO (60%) Primary reactive
ingredient
Quartz (35%) Reinforcing -
Hydrogenated rosin
(5%)
agent
Liquid O-Ethoxybenzoic acid Reactive ingridient
Eugenol
Ortho-ethoxybenzoic acid
(EBA) cement

CO
2
H
OC
2
H
5


Ratio asam orthoetoksibensoik : eugenol : 2 : 1
Cavity lining u/amalgam
Luting semen
Compressive strength 85 MPa
Non eugenol- zinc oxide
Provesional restorations
Root canal sealers
Gingival tissue packs
Surgical dressings
Calsium hidroxide cements
Tda 2 pasta
Setting time : 2,5 5,5 menit
Reaksi setting :
CaOH + ester salisilat Chelate viz. Amorphous
calsium disalicylate
Etilen glikol salisilat
CH
3

CH
2
CH
2
CH

CO
2
CO
2
OH OH





Komposisi Ca OH semen
Component Function
Paste 1
CaOH 50 % Primary reactive ingridient
ZnO 10 % - ,, -
Zn stearat 0,5 % Accelerator
Ethyl toluene sulphon-
amide 39,5 %
Oil compound, acts as carrier
Paste 2
Glycl salicylate 40 % Primer reactive ingridient
Titanium dioxide Inert, fillers, pigments, radiopa-
cifers
Calsium sulphate - ,, -
Callsium tungstate
- ,, -