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V
n
n
n = unit outward normal to the surface
h Ts ( x , y ) T k f
T ( x, y)
n
Then
kf
h( x , y )
T ( x, y)
Ts ( x , y ) T n
Ts ( x , y ) is the temperature at the surface and
k f is the thermal conductivity of the fluid
C ( x, y)
n
Then
D AB
hm ( x , y )
C ( x, y)
C s ( x , y ) C n
C s ( x , y ) is the concentration at the surface and
D AB is the diffusion coefficient.
Conservation Laws
Conservation of Mass: When mass is neither
added nor removed at any point
V t dV B ( v n)dA 0
using the divergence theorem (discussed previously )
V t div ( v) dV 0
so that at every point
div ( v) 0
t
( u) ( v ) ( w ) 0
t x
y
z
( v i ) 0
t x i
or
v i
vi
0
t
x i
x i
. v 0
t
Conservation of Momentum
Momentum: The rate of change of linear momentum of the fluid
equals the total force acting on the fluid
( v )
dV v( v n )dA
B
t
gdV fdA
V
For a continuum
f n
or using indical notation
f i ij n j
where ij
( v i )
dV v i v j n j dA
B
t
g i dV ij n j dA
V
V t x j gi x j
dV 0
gi
0
t
x j
x j
or, using the conservation of mass or continuity,
v i
ij
v
i
vj
gi
t
x
x j
j
With
e internal energy per unit mass of the material
and the energy per unit volume
1
1
E (e v v) (e v jv j )
2
2
E
dV E ( v n )dA
B
t
( v g )dV ( v f )dA
B
qdV (q n )dA
B
where
q heat flux per unit area
q rate at which energy is generated per unit mass
E
dV Ev j n j dA
B
t
v j g j dV v i ij n j dA
V
V qdV B q j n j dA
or, using the divergence theorem, as
E ( Ev j )
(v i ij )
q j
V t x j v j g j x j q x j
dV 0
v j g j
q
0.
t
x j
x j
x j
Expanding,
v j
E
E
vj
E
t
x j
x j
ij
q j
v i
v i ( g i
)
ij q
0.
x j
x j
x j
v i
vj
( E / )
vi
x
x i
x i
j
t
v i
q j
v
ij
i
i
vi
vj
gi
ij q
0,
x j
x j x j
x j
t
q j
e
i
vj
ij q
t
x
x j
x j
j
The term
v i
ij ij ij
x j
represents the heat generated by the stress
per unit volume of the material
constant
Stress :
If p denotes the pressure , the viscosity ,
1 v i v j
ij
2 x j x i
ij p ij 2 ij
T
qi k
x i
de
c
dT
In general
the viscosity ,
the internal energy, e
and the thermal conductivity and heat capacity, k , c
are specified functions of the temperature T .
x1 , x 2 , x 3 , t
Dependant Variables :
v1 , v 2 , v 3 , p, T
Equations :
Mass :
v i
0
x i
Momentum :
v i
v
p
vj
gi
t
x i x j
x j
v i v j
x j x i
Energy :
T
T
c
vj
t
x j
v i
x j
v i v j
x j x i
x j
k T
x j
vi
p
i
vj
gi
t
x i
x j
x j x j
Energy :
T
T
c
vj
t
x j
T
j
i
i
q k
x j x j x i
x j x j
the equations governing the motion of the fluid : first the motion of the fluid
can be calculated and then the variation in the temperature
constant , D AB constant
Mass :
v i
0
x i
Momentum :
2
v i
vi
p
i
vj
gi
x j
x j x j
x i