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ANTAR MUKA
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KELOMPOK 6
Surface behaviour
Conductance
of
the
ionic
Energetics of
micellisation
Sharpness of critical
micelle concentrations
The Krafft
phenomenon
Spreadin
g
Adhesion and
cohesion
Monomolecular
films
Surface pressure
Surface rheologi
Electron micrographs of
monolayers
Gaseous films
Condensed films
Expanded films
Factors influencing
the physical state of
monomolecular films
4. Bent hydrocarbon chains - e.g. brassidic acid (transCH3(CH2)7CH=CH(CH2)iiCOOH), which has a straight
hydrocarbon chain, gives a condensed film, whereas erucic acid
(cis- CH3(CH2)7CH=CH(CH2)iiCOOH), which has a bent
hydrocarbon chain, gives a very expanded flim.
5. Branched hydrocarbon chains.
The nature of the substrate, particularly pH, is important when
the monolayer is ionisable. When spread on alkaline substrates,
because of the ionisation and consequent repulsion between the
carboxyl.
Evaporation through
monolayers
Water conservation
The annual loss of water from hot country lakes and reservoirs
due to evaporation is usually about 3 m per year. This
evaporation can be reduced considerably by coating the water
surface with an insolublemonolayer; for example, a monolayer
of cetyl alcohol can reduce the rate of evaporation by as much
as 40 per cent. Insoluble monolayers also have the effect of
damping out surface ripples. To attain minimum permeability
to evaporation, a close-packed monolayer under a sufficient
state of compression to squeeze out any surface impurities is
required. The monolayer must also be selfhealing in response
to adverse meteorological conditions such as wind, dust and
rainfall, so that spreading ability is also needed. To
compromise between these requirements, commercial cetyl
alcohol (which also contains some steryl, myristyl and oleyl
alcohol) has been used successfully.
Monolayers on droplets
Biological membranes