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Hydrogen
Economy
10 Nonfossil
Hydrogen
Hydrogen / Carbon Ratio
0.01
1800 1850 1900 1950 2000 2050 2100 2150 2200
Year
• Hydrogen
• Biofuels- Biodiesel,SVO, ethanol,
Biogas
• CNG ,LPG, DME
• HEV, Solar, Wind
Technology Evaluation
Criteria
• Drivers • Criteria
– Emission Reduction – Technical Risk,
potential – Commercial Risk and
– Import independence – Customer Acceptance
IC-Hydrogen
Conv. Fuel
Bio-diesel
Hydrogen
On-board
Reformer
Ethanol
Stored
Solar
CNG
HEV
LPG
EV
Scale of 10 rating
1 Drivers (x0) 12 13 17 13 14 17 16 20 10 9 7
3 Criteria (x2/3) 28 26 20 23 9 9 19 3 28 28 30
4 Time-line (x2/3) 30 26 24 17 6 6 14 3 29 29 30
5 Investment (x2) 8 7 7 5 2 2 7 1 9 9 10
Grand Total (150) 121-124 108 108 98-101 51 47 80 42 122 118 130-133
Diesel Fuel
Vegetable Oil
Issues With Use of SVO
• Oxidation , gum formation, fuel line and filter
clogging
• About 10 % lower efficiency due to effect of high
viscosity on mixture preparation and combustion
• Higher Smoke, HC and CO emissions .
• SVO fuel properties vary very widely between
feedstocks used .
• USA • Soybean
• Europe • Rapeseed
oil,Sunflower oil
• Ireland • Frying oil
• Thailand,Malaysia • Pam oil
• India • Jatroffa, Pongamia
(Honge)
Non-edible oil seeds
• Abundant availability
• Extracted oil is used: [~20% of seed]
– In soap making
– As bio-fuel
Oil or fat (carbon no: no 14:0 16:0 18:0 18:1 18:2 18:3 20:0 22:1
. Of double bonds)
Soybean 6-10 2-5 20-30 50-60 5-11
Corn 1-2 8-12 2-5 19-49 34-62 trace
Peanut 8-9 2-3 50-65 20-30
Olive 9-10 2-3 73-84 10-12 trace
Cottonseed 0-2 20-25 1-2 23-35 40-50 trace
Hi linoleic Safflower 5.9 1.5 8.8 83.8
Hi Oleic Safflower 4.8 1.4 74.1 19.7
Hi Oleic Rapeseed 4.3 1.3 59.9 21.1 13.2
Hi Erucic Rapeseed 3.0 0.8 13.1 14.1 9.7 7.4 50.7
Butter 7-10 24-26 10-13 28-31 1-2.5 .2-.5
Lard 1-2 28-30 12-18 40-50 7-13 0-1
Tallow 3-6 24-32 20-25 37-43 2-3
Linseed Oil 4-7 2-4 25-40 35-40 25-60
Tung Oil 3-4 0-1 4-15 75-90*
Yellow grease 1.27 17.44 12.38 54.67 7.96 0.69 0.25 0.52
Definition of “Biodiesel”
• Biodiesel – a fuel comprised of mono-alkyl
esters of long chain fatty acids derived
from vegetable oils or animal fats,
designated
B 100.
• Biodiesel must meet the specifications of
ASTM D 6751
Biodiesel Properties
No sulfur contents (in most biodiesel fuels)
No aromatics contents
About 11% oxygen content (petro-diesel contains no
oxygen)
Cetane value comparable to Indian Diesel
Lower heating value
Better lubricity
Higher viscosity
Higher freezing temperature
Higher flash point
No toxicity or low toxicity
Biodegradability
Worse corrosive properties.
BIODIESEL SPECIFICATIONS
PROPERTIES UNIT DIN 51606 (1997) ASTM (2001)6751
DISTILLED
PROTEIN MEAL REFINED OIL BIODIESEL
GLYCERINE
CONCENTRATED
DEGUMMED OIL
GLYCERINE
Process Sections (high FFA oils)
DISTILLED
PRETREATED OIL BIODIESEL
GLYCERINE
CONCENTRATED
GLYCERINE
What is Biodiesel (Methylester)?
Transesterification
Feedstocks Used in Biodiesel
Production
• Triglygeride or fats and oils (e.g. 100 kg SVO) –
vegetable oils, animal fats, greases, soapstock,
etc.
• Primary alcohol (e.g. 10 kg methanol) –
methanol or ethanol (44% more ethanol is
required for reaction)
• Catalyst (e.g. 0.3–1.0 kg sodium hydroxide)
• Neutralizer (e.g. 0.25 kg sulfuric or hydrochloric
acid)
Reaction time
• Transesterification reaction will proceed at
ambient (35°C) temperatures but needs 4-8
hours to reach completion.
• Reaction time can be shortened to 2-4 hours at
45°C and 1-2 hours at 50°C.
• Higher temperatures will decrease reaction
times but require pressure vessels because
methanol boils at 65°C.
• High shear mixing and use of cosolvents have
been proposed to accelerate reaction.
Processing Lower Quality
Feedstocks
Biodiesel feedstocks vary in the amount of free fatty acids
they contain:
• Refined vegetable oils < 0.05%
• Crude soybean oil 0.3-0.7%
• Restaurant waste grease 2-7%
• Animal fat 5-30%
• Trap grease 75-100%
Price decreases as FFAs increase but processing
demands increase, also.
Not suitable for high FFA feeds because of soap formation.
Product Quality
• Product quality is important – modern
diesel engines are very sensitive to fuel.
• It is not biodiesel until it meets ASTM
D6751.
• Critical properties are total glycerol
(completeness of reaction) and acid value
(fuel deterioration). Reaction must be
>98% complete.
Competing Reactions
• Free fatty acids are a potential
contaminant of oils and fats.
O
||
HO - C - R
Oleic Acid
Fatty acids react with alkali
catalyst to form soap.
O
|| + KOH
HO - C - (CH2)7 CH=CH(CH2)7CH3
O
||
→ K+ -O - C - (CH2)7 CH=CH(CH2)7CH3 + H2 O
180
170
Greater the gap,
flash point, degree celcius
160
greater the amount
150
of organic
140
compound that can
130
be added
120
110
100
100% 95% 90% 85% 80% 75%
Biodiesel percentage
High viscosity of soybean oil is due to high molecular mass and large chemical structure.
Free fatty acids or compounds with hydroxy groups possess significantly higher viscosity
measures the flow resistance of the fuel, e.g., the time for a volume of liquid to
flow under gravity through a calibrated glass capillary viscometer.
Cetane Number
Method: ASTM D 613
Limit: 47 min.
Passed ASTM
52
50
standard
Cetane number
48
46
44
Failed to meet
42 ASTM standard
40
38
100% 95% 90% 85% 80% 75%
Biodiesel Percentage
0.14
0.12
0.04
0.02
Passed ASTM
0 standard
100% 95% 90% 85% 80% 75%
Biodiesel Percentage
Determines the amount of carbon residue left after evaporation and pyrolysis of an oil,
indicating its relative propensity to form coke.
Total and Free Glycerol Content
Method: ASTM D 6584
Limit:
Total glycerol: 0.24 max (% m/m)
Free Glycerol: 0.02 max (% m/m)
2.5
0.025
2
Total Glycerin (%)
Failed to 0.02
ASTM
ASTM 1 0.01
Standard
Standard 0.5 0.005
0
0 100% 95% 90% 85% 80% 75%
100% 95% 90% 85% 80% 75%
Biodiesel Percentage
Biodiesel Percentage
Effect of raw oil presence in Biodiesel on total and free glycerol content
Very low CN
Diesel CN ~50-51
Very high CN
Very low CN
Fuel Chemistry is Important
2000
CO (%)
0.2
1500
0.15
1000
0.1
500
0.05
0
0 1 2 3 4 5 0
Brake pow er (kW) 0 1 2 3 4 5
Brake pow er (kW)
1600
diesel 5
diesel
karanja oil
1400 4.5 karanja oil
karanja ester
karanja ester
co-ester 4
1200 co-ester
3.5
1000
Smoke (BSU)
NO (ppm)
800 2.5
600 2
1.5
400
1
200
0.5
0 0
0 1 2 3 4 5 0 1 2 3 4 5
Brake pow er (kW) Brake pow er (kW)
Basic Emission Effects_EPA
Study
Heat release pattern
Fig.12. Variation of heat release rate
70
diesel
karanja oil
60
karanja ester
co-ester
50
Heat release rate (kJ/°CA)
40
30
20
10
0
300 350 400 450
-10
Crank Angle- degree )
Effect of Biodiesel Blend on Heat
Release Pattern
ENGINE SPECIFICATIONS
Automotive engine
• Makers Name :Mahindra & Mahindra Limited
• Type of engine : DI diesel engine
• No of cylinders :4
• Type of cooling :water cooling
• Compression Ratio: 17.5
• Cubic Capacity :2.6 litre
• Brake Power :72 bhp
• Speed :3200
• Injection Press. :900 bar
Jatroff based biodiesel( B20) Vs diesel fuel
Parameters HS Diesel BD 20 Indication
Max. Power @ 2300 rpm ( hp ) 44.7 43.8 2%
50 100
diesel
45 bio diesel (20%)
90
40 Test cycle 80
35 70
CO (mass)
30 60
Speed
25 50
20 40
15 30
10 20
5 10
0 0
0 500 1000
Tim e
Fig.15 Variation of NOx between diesel fuel and B
20 Jatropha based biodiesel blend, R83 test cycle
50 diesel
100
35 70
NOx (mass)
30 60
Speed
25 50
20 40
15 30
10 20
5 10
0 0
0 500 1000
Tim e (s e c)
Fuel Injection and Bulk Modulus
biodiesel
Issues with biodiesel
Filter Trends