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Covalent Bonding
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Contents
Covalent Bonding
In elements
In compounds
Resonance
Fajans rules
Properties and parameters
Structures
Molecular orbitals
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Contents
Covalent Bonding
In elements
In compounds
Resonance
Fajans rules
Properties and parameters
Structures
Molecular orbitals
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Cl
HCl or H Cl
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O
H
H
H2O or H O H
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Electron
2.5
configuration
H
1
Electrons
needed
Ratio of
atoms
H
NH3 or H N H
H
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Electron
2.4
configuration
H
1
Electrons
needed
Ratio of
atoms
CH4
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H
or H C H
H
Contents
Covalent Bonding
In elements
In compounds
Resonance
Fajans rules
Properties and parameters
Structures
Molecular orbitals
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Resonance of Ozone
The structure of ozone, O3, can be represented by two
different Lewis electron-dot formulas.
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Resonance of Ozone
According to theory, one pair of bonding electrons is
spread over the region of all three atoms.
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Contents
Covalent Bonding
In elements
In compounds
Fajans rules
Properties and parameters
Structures
Molecular orbitals
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Fajans rules
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Fajans rules
Fajans said that a small cations able to polarize the electron cloud of
an anion that forms ions no longer spheric but elipsoid (distortion)
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Fajans rules
:
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Contents
Covalent Bonding
In elements
In compounds
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3) Triple Bond
The electron configuration of N (Ar = 7) was
2.5, so that nitrogen has 5 valence electrons, so it
should pair 3 electrons to be stable.
N2 bond formation.
: N : +: N: N N N2
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MOMENT DIPOLE
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Contents
Covalent Bonding
In elements
In compounds
I
I
O
H
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Allotropes of carbon
In the element carbon, atoms bond in different ways,
creating different kinds of giant structures.
Two of these structures are diamond and graphite.
They are called allotropes of carbon.
Allotropes have the same chemical properties because
they have the same number of electrons.
However, they have different physical properties because
the electrons are shared in different ways with other atoms.
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C
C
C
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C
C
C
weak forces of attraction
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C
C
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C
Boardworks Ltd 2005
2004
Sand
Sand is an impure form of silicon dioxide (quartz). It has a
giant covalent structure with certain similarities to diamond.
Each silicon atom (2.8.4) is bonded to four
oxygen atoms, and each oxygen atom (2.6)
is bonded to two silicon atoms.
O
Si
O
O
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Multiple-choice quiz
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Contents
Covalent Bonding
In elements
In compounds
Bonding theories
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Molecular orbitals
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Sigma bond ()
A Sigma Bond is when 2 atomic orbitals combine to form a
molecular orbital that is symmetrical around the axis
S orbitals
overlapping
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P orbitals overlapping
end-to-end
Pi bond ()
Pi bonding electrons are likely to be found in a sausageshape above and below the axis
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