Escolar Documentos
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Friction
Friction is the force resisting the relative
motion of surfaces or material elements in
contact.
The ratio of the force of friction between two bodies and the
force pressing them together is known as co-efficient of
friction ()
Ff/ N = constant ()
Ff = N
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Lubrication
Lubrication is the process, or technique
employed to reduce wear on surfaces in
close proximity, and moving relative to
each another
Lubrication is effected by introducing a
substance called lubricant. The lubricant
film can be a solid, (graphite), a liquid, a
semi solid (grease) or exceptionally a gas
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Objectives of Lubrication
To reduce frictional resistance
To reduce wear on the bearing surfaces
To protect the bearing surfaces from
corrosion
To carry away heat from the bearing
To reduce noise from the moving
components of the machine
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VISCOMETRICS
VISCOSITY, POUR, VI
SATURATES, SULPHUR
NITROGEN
BASESTOCK
QUALITY
COMPATIBILITY
ANILINE POINT
DEMULSIBILITY
VOLATILITY
GCD, NOACK
APPEARANCE
SAFETY
FLASHPOINT
TOXICITY
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COLOUR, CLEANLINESS
CLARITY, ODOUR
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POUR POINT
VERY HIGH
HIGH
HIGH
LOW
MODERATE
LOW
LOW
LOW
BASE OILS ALSO CONTAIN SULPHUR, OXYGEN AND METAL COMPOUNDS (Dibenzo, Thiophene)
e.g
S
PARAFFINIC
AROMATIC
45-60%
20-25%
PARAFFINIC COMPOUNDS
AROMATIC COMPOUNDS
NAPHTHENIC
65-75%
NAPHTHENIC COMPOUNDS
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Backup slide
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Alkanes
Alicyclic
Aromatics
Density
Low
High
High
Velocity
Low
High
High
VI
Good
Low
Poor
Melting point
High
Low
low
Oxidation
Good
Low
poor
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Physical Properties
Low Temperature Properties
*Cloud Point
*Pour Point * Flow by gravitation
Viscosity of oil at low
*Cold Crank Stimulation *Apparent
tem. And hight share rate
*Low Temp. Viscosity of gear and
*Brookfiled Viscosity
hydraulic fluid under low share stress
High Temperature Properties
*Volatility : Tendency of an oil to be lost
* Flash Point : Auto Ignition of Vapors
*Detection of 1st formation of wax
*Haziness or milky white appearance appear
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Physical Properties
Viscosity: ability of an oil to form lubricating film
Absolute Viscosity:
Kinetmaic Viscosity
Other properties
Density
Demulsification
Foam Characteristics
Thermal Conductivity
Electrical properties
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Chemical Properties
Oxidation
Corrosion
Carbon Residue
Seal Compatibility
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ATMOSPHERIC DISTILLATION
LPG *
In an atmospheric distillation
tower liquid petroleum gas
(LPG), gases and various
liquid petroleum fractions are
produced
NAPTHA
KEROSENE
GAS OIL
HEAVY GAS OIL
CRUDE OIL
RESIDUE
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Vacuum Distillation
LIGHT SPINDLE OIL
BRIGHTSTOCK
RESIDUE
FROM
ATMOSPHERIC
DISTILLATION
DEASPHALTOR
RESIDUE
ASPHALT
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Cost
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SOLVENT EXTRACTION
Viscosity index
Colour
WAXY RAFFINATE
SPECIAL
SOLVENT
MIX
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Oxidation stability
FROM VACUUM
TOWER
SOLVENT EXTRACT
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SOLVENT DEWAXING
Effect
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By-product is wax
DEWAXING
SOLVENT
WAX
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HYDROFINING
Improves colour
Reduces acidity
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FINAL
PRODUCT
HYDROGEN
AND
CATALYST
By product naphtha
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FUEL
EXTRACTION
TOWER
VACUUM
STILL
DEWAXING
UNIT
(Removes
Aromatics)
(Removes
Wax)
HYDROFINISHING
TOWER
FINAL
(Removes N & S PRODUCT
compounds)
BASE OIL
*
*
CRUDE
RESIDUE
SOLVENT
SOLVENT
HYDROGEN
DEASPHALTER
RESIDUE
SOLVENT
EXTRACT
WAX
NAPTHA
SOLVENT
NEUTRAL
ASPHALT
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Additives
The properties of a lubricant can be improved
by adding certain chemicals
Anti oxidants
Foam depressants
Corrosion inhibitors
Detergent Dispersers
Oiliness improvers
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Selection of Lubricant
The selection of lubricant depend on:
Type of mechanism being lubricated
Type of lubricating system
Rate of heat removal
Cost
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Lubricant
Lubricating
system
Heat removal
Plain
bearing
Oil
Hand
Low
High
Light duty
Circulating
High
Low
Continuous
Porous
Low
Low
Low speeds
Grease
Hand
Nil
High
Light duty
Oil
Oil mist
low
Low
High cost
Oil bath
low
Low
Churning
Splash
Moderate
Low
Used in gear
box
Packed
Nil
Low
Long life
Central
Nil
Low
Convenient
Bath
Moderate
Low
Simple gear
box
High
Low
Hi-duty gears
Hand
Nil
High
Hi-duty gears
Housing filled
Nil
Low
Low speeds
Rolling bearing
Grease
Gears
Oil
Circulating
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Grease
Maintenance
cost
Comments
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Distillation columns
1.
2.
3.
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Where extra feed exits when used to help with the separation:
4.
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Sieve trays
Sieve trays are simply metal
plates with holes in them. Vapour
passes straight upward through
the liquid on the plate. The
arrangement, number and size of
the holes are design parameters.
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Packings
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Basic operation
The feed is introduced somewhere
near the middle of the column to a
tray known as the feed tray.
The feed tray divides the column into
a top (enriching or rectification) and
a bottom (stripping) section.
The feed flows down the column
where it is collected in the reboiler.
Heat (usually as steam) is supplied to
the reboiler to generate vapour.
The vapour from the reboiler is reintroduced into the unit at the bottom
of the column.
The liquid removed from the reboiler
is known as the bottoms product or
simply, bottoms.
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Basic operation
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Propane deasphalting
Coke-forming tendencies of heavier distillation products
are reduced by removal of asphaltenic materials by solvent
extraction.
Liquid propane is a good solvent (butane and pentane are
also commonly used).
Deasphalting is based on solubility of hydrocarbons in
propane
Vacuum residue is fed to a countercurrent deasphalting
tower. Alkanes dissolve in propane whereas asphaltenic
materials (______________), coke-precursors do not.
Asphalt is sent for thermal processing.
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Propane deasphalting
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SOLVENT DEASPHALTING
A physical separation based residue upgradation process, separates vacuum
residue on the basis of both molecular
type & size.
Produces extra heavy viscosity lube base
stock and / or feedstock for conversion
units.
Pitch or Asphalt is obtained as bottom
product
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Deasphalting Solvents
Commercially used solvents are
LIGHTER SOLVENTS : PROPANE & ISOBUTANE
Higher selectivity
Reject all resins and asphaltenes
Suitable for production of lubes oils
HEAVIER SOLVENTS : n-BUTANE, PENTANE (n& i) and LIGHT
NAPHTHA
-- Less selective than the lighter solvents
Produce higher yields of DAO
(suitable as conversion feedstocks)
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Processing of DAO
PROCESSING FOR
LUBE
CRACKING
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Processing of Asphalt
Process
BLENDING
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DEASPHALTING:
PROCESS VARIABLES
SOLVENT COMPOSITION
Blends of light hydrocarbon solvents
Increased operating flexibility
SOLVENT-TO-FEED RATIO (S/F)
Selectivity improves by increasing S/F at constant DAO
yield
Economically optimum S/F is used
TEMPERATURE / TEMPERATURE GRADIENT
Oil solubility in solvent
Decreases with increase in temp. (optimum temps)
Temp. gradient improves separation between DAO-Asphalt
phases
PRESSURE
Maintained above V.P. of solvent at operating temperatures.
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PROPANE
BUTANE
PENTANE
EXTRACTION
RANGE (C)
50 80
100 130
170 210
PRESSURE
RANGE (MPa)
3.5 4.0
~ 4.0
~ 4.0
SOLVENT
RATIO (VOL.)
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3-5
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Solvent extraction
The purpose of solvent extraction is to prevent corrosion, protect catalyst
in subsequent processes, and improve finished products by removing
unsaturated, aromatic hydrocarbons from lubricant and grease stocks.
The solvent extraction process separates aromatics, naphthenes, and
impurities from the product stream by dissolving or precipitation. The
feedstock is first dried and then treated using a continuous countercurrent
solvent treatment operation.
In one type of process, the feedstock is washed with a liquid in which the
substances to be removed are more soluble than in the desired resultant
product. In another process, selected solvents are added to cause
impurities to precipitate out of the product. In the adsorption process,
highly porous solid materials collect liquid molecules on their surfaces.
The solvent is separated from the product stream by heating, evaporation,
or fractionation, and residual trace amounts are subsequently removed
from the raffinate by steam stripping or vacuum flashing.
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Solvent extraction
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Solvent dewaxing
Usually two solvents are used: toluene, which dissolves the oil and
maintains fluidity at low temperatures, and methyl ethyl ketone (MEK),
which dissolves little wax at low temperatures and acts as a wax
precipitating agent.
Other solvents sometimes used include benzene, methyl isobutyl ketone,
propane, petroleum naphtha, ethylene dichloride, methylene chloride,
and sulfur dioxide.
In addition, there is a catalytic process used as an alternate to solvent
dewaxing.
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A frictional force tangential to the direction of a flowing fluid, the force of which is
directly related to the fluids viscosity shear stress. In bloodvessels, shear stress act
s on endothelium and is the mechanical force responsible for the acute changes in l
uminal diameter.
Stress parallel to a given surface (e.g., a fault plane) that results from forces applied
parallel to the surface or from remote forces transmitted through surrounding rock.
T=F/A
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Detergenets/Disperants
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61
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63
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Types of Lubrication
Hydrodynamic
Boundary
Mixed
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Hydrodynamic Lubrication
Occurs when machine parts are completely separated
by a full and continuous film of lubricant
Contact between the parts does not occur.
Full-fluid-film lubrication is hydrodynamic lubrication,
the oil adheres to the moving part and is drawn into
the area between the rotating surfaces, where it forms
a pressure, or hydrodynamic, wedge.
A less common form of full-fluid-lubrication is
hydrostatic lubrication, where the oil is supplied to the
bearing area under pressure to separate the sliding
surfaces.
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Hydrodynamic Lubrication
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Boundary Lubrication
Under certain conditions such as shock loading,
heavy loads, high temperature, slow speed and
critically low viscosity, the lubricant is no longer
hydrodynamic
Frequent contact between the surfaces, resulting in
a significant rise in temperature and subsequent
destruction of the contacting surfaces.
Under these circumstances, the fluid film is no
longer capable of adequately protecting the
surfaces.
Solid additives are mixed into the grease
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Mixed Lubrication
Although not a true mode of lubrication in the
sense of hydrodynamic or boundary, mixed
lubrication occurs more frequently then is
realized.
Mixed lubrication is a transitional mode of
lubrication between hydrodynamic and boundary
Mixed lubrication is characterized by the
likelihood of intermittent surface contact
Anti-wear are essential properties in the lubricant
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Mineral or Synthetic
NOW SELECT THE
REQUIRED
VISCOSITY.
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Viscosity
(Thin)
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Viscosity
(Thick)
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Product enhancements:
Extreme Pressure (EP) Additives
CHEMICAL
SOLUTIONS
Chlorine
Sulphur
Phosphorous
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SOLID
LUBRICANTS
Graphite
Molybdenum disulphide
(MoS2)
PTFE (Teflon)
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Product enhancements
OXIDATION INHIBITORS
Longer wet life
CORROSION INHIBITORS
Improves corrosion protection.
TACKY ADDITIVES
Improves adhesion
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General
Purpose
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Soap
Thickeners
Lithium complex
Calcium complex
Aluminium complex
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Thickener Properties
Lithium
Good multi-purpose, good mechanical stability,
limited other properties
Lithium Complex
Excellent high temp & mechanical stability
capability
Calcium Complex
Excellent load carrying and water resistance
Aluminium Complex
Excellent temperature capability & water
resistance
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BLOCK GREASE
Old Technology
NLGI No 5
SEMI-SOLID ELASTIC-LIKE
GREASE
NLGI No 4
NLGI No 3
HEAVIER GREASE
NLGI No 2
85% OF MARKET
NLGI No 1
THINNER GREASE
NLGI No 0
SEMISEMI
FLUID/
FLUID GREASE
NLGI No 00
FLUID GREASE
NLGI No
000
FLUID GREASE
Generally
applied
by and automatic
Used
in semi-auto
systems
Automatic
Lubricator
Used in some gearboxes and
semi & auto lube systems with
longer pipe lines
Premium EP 2
Premium EP 1
Premium EP 000
NLGI 6
NLGI 5
NLGI 4
NLGI 3
NLGI 2
NLGI 1
NLGI 0
NLGI 00
NLGI 000
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Outer Race
Balls or
Rollers
Shaft
Inner Race
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Lubricant
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Plain Bush
Lubricant
Shaft
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FRICTIONAL HEAT
WHY LUBRICATE?
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FRICTIONAL HEAT
FRICTIONAL WEAR
WHY LUBRICATE?
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Thank You
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Supporting slides
VISCOMETRICS : a device for measuring viscosity
The pour point of a liquid is the temperature at which it becomes semi solid
and loses its flow characteristics. In crude oil a high pour point is generally
associated with a high paraffin content, typically found in crude deriving from
a larger proportion of plant material.
VOLATILITY
Evaporating readily at normal temperatures and pressures
ANILINE POINT. : the lowest temperature at which anilineand a solvent (as
gasoline) are completely miscible and which serves as an indication of the type
of hydrocarbons present in the solvent, the content of aromatics being higher
according as the temperature is lower.
Demulsibility is the ability to release water. This is important when the
equipment is operating in humid climates or in a plant atmosphere that is wet or
humid. Paper mills, steel mills and food-processing operations have significant
exposure
to water-based process fluids.
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