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Chemical Bonding
Bonding
Types of Bonds
Metallic
bonding
Io n ic B o n d in g
L e w is S tr u c tu r e s
C o v a le n t B o n d in g
R e s o n a n c e S tru c tu re s
O c te t R u le
P o la r M o le c u le s
M o le c u la r G e o m e tr ie s
VSEPR
B a s ic S h a p e s
3 -D N o ta tio n
H y b r id iz a tio n (L a b )
3 main kinds :
Covalent bond results from sharing electrons between
the atoms,usually found between non-metals.
Ionic bond results from the transfer of electrons from a
metal to a non-metal.
Metallic bond: attractive force holding pure metals
together.
Ionic
Bonds
Eg NaCl
Na: 1s2 2s2 2p6 3s1
Na+ (cation) : 1s2 2s2 2p6
CaCl2
Properties of ionic
Compounds
Electronegativity
Electronegativities of Elements
Electronegativity
Bonding Continuum
Covalent Bonding
Is the attraction of the nuclei in each atom to the valence electrons
they are sharing between them. They formed discrete separate
molecules
When bonds are formed, the atoms become lower in energy, so more
stable
The optimum distance between the two nuclei is the bond length
Chemical
Chemical Bonds
Bonds
Bond Type
Single
Double
Triple
# of es
Notation
Bond order
Bond
strength
Bond
length
Coordinate/Dative covalent
bonds
Example 2
Example 3
Hydronium (H3O+)
Carbon monoxide
(CO)
Carbon tetrachloride
Carbon is the central atom.
It has 4 bonding pairs.
Chlorine wants to share
one bonding site each.
Need 4 chlorines for every
one carbon
(Cl has 3 lone pairs and 1
bonding pair)
More examples
H2O
CH2O
O3
Lewis structure of O3
Molecular Shapes
Figure 9.3
HyperChem
VSEPR
Model
Summary
Summary of
of VSEPR
VSEPR Molecular
Molecular
Shapes
e-pairs
Notation
Name of VSEPR
Examples
Shapes
shape
AX2
Linear
AX3
Trigonal planar
BF3 , GaI3
AX2E
Non-linear (Bent)
SO2 , SnCl2
AX4
Tetrahedral
AX3E
(Trigonal) Pyramidal
NH3 , OH3-
AX2E2
Non-Linear (Bent)
H2O , SeCl2
AX5
Trigonal bipyramidal
PCl5 , PF5
AX4E
Distorted tetrahedral
(see-sawed)
TeCl4 , SF4
AX3E2
T-Shaped
ClF3 , BrF3
AX2E3
Linear
I3- , ICl2-
AX6
Octahedral
SF6 , PF6-
Square Pyramidal
IF5 , BrF5
AX5E
HyperChem
CyberChm Gems
See Ng Web-site
H N H
H
107O
H
H
104.5O
Resonance Structures
HyperChem
Figure 9.12
HyperChem
HyperChem
VSEPR
Model
C N
For C:
C N
For N:
We write:
C N
CyberChm Gems
Chemical
Chemical Bonding
Bonding
Types of Bonds
Io n ic B o n d in g
L e w is S tr u c tu r e s
C o v a le n t B o n d in g
R e s o n a n c e S tru c tu re s
O c te t R u le
P o la r M o le c u le s
Lewis
AXE notation
M o le c u la r G e o m e tr ie s
VSEPR
B a s ic S h a p e s
3 -D N o ta tio n
H y b r id iz a tio n (L a b )
VSEPR shapes
Polarity