Escolar Documentos
Profissional Documentos
Cultura Documentos
Jul-Dec 2006
Instructor: Dr. S. Ramanathan
Office: CHL 210
Email: srinivar@iitm.ac.in
Class Notes: http://www.che.iitm.ac.in/~srinivar
Overview
Chemical Engineering
Transport Phenomena
Reaction Kinetics
Momentum
Mass
Heat
Background :
Most of the momentum transfer equations are similar to heat and
mass transfers
Momentum transfer: Focus is on fluids
Heat and Mass Transfer: Also include solid
Heat Transfer: Radiation (no corresponding phenomena in
momentum and mass transfer)
Similarities in problems will be discussed as appropriate
IIT-Madras, Momentum Transfer: July 2005-Dec 2005
Motivation
Momentum Transfer: Fluid Mechanics
Understanding Lab Results
Design
Manufacturing (Production/ Maintenance)
Troubleshooting
Course Syllabus:
What will be covered? And to what extent?
Fundamentals (ideal cases)
Some applications (more realistic, but not very)
Most real-life issues, ==> kinetics & heat/mass/momentum transfer
together
Analytical solutions not possible in many cases
What will not be covered?
Compressible , supersonic flows
Only limited exposure to non-newtonian fluids
Computational Fluid Dynamics (CFD)
limited exposure to Perturbation methods
...and so on
IIT-Madras, Momentum Transfer: July 2005-Dec 2005
Course Syllabus:
Statics:
To refresh the basics
Dynamics:
Mass Balance
Momentum Balance (Linear & Angular)
Energy Balance
Frictional losses
Boundary layer theory
Flow past/through
Examples
Pumps, Turbines
Heat Exchangers, Distillation column
Fluidized or Fixed bed reactors
CVD reactors (micro electronics)
Artificial blood vessels (Bio)
Examples
Production of Sulfuric Acid
used in fertilizers, car batteries etc
S O2 SO2
2 SO2 O2
Catalyst
2 SO3
H 2O SO3 H 2 SO4
Examples
Monsanto Process
Pump air (N2+O2) and burn Sulfur
Provide large area of catalyst
Scrub with water
Store the sulfuric acid
For a given production (ton per day),
What is the pump capacity needed?
Design and operation of reactor
How to measure the flow rate?
What if something goes wrong? How to detect it and how to
respond? (Detection of leak through chemical sensor, pressure sensor
etc)
IIT-Madras, Momentum Transfer: July 2005-Dec 2005
Goals:
Understanding and approaching problems which involve Momentum Transfer
==> Pumps, flow through pipes
==> Separation (filtration, adsorption etc)
More emphasize on application and less on proof
Also prepare for future courses
Momentum Transfer Lab
Transport phenomena
Calculus (PDE), Complex Variables
Little bit of programming
Final Exam - 40
Quizzes - 2 * 20 = 40
and Project/Assignment -20
IIT-Madras, Momentum Transfer: July 2005-Dec 2005
Tentative Schedule
Section Focus Area
1 Statics
2 Conservation of Mass
3 Conservation of momentum - linear
4 Conservation of Energy (no friction)
5 Friction (Shear Stress) & models
6 Navier Stokes eqn
7 Dimensional Analysis
8 Stream Lines
9 Inviscid flow
10 Viscous flow & BL theory, Drag on particles
11 Turbulence
12 pipe flow (with friction factors)
13 Fixed bed & Fluidized beds
14 Pumps and Turbines
No.
Classes
1
1
3
2
4
7
3
2
2
7
2
4
2
1
Quiz-1
Quiz-2
Statics
Statics
Fluid: changes shape continuously when a tangential force is applied
Pressure at any point in a stationary fluid is same in all directions
Pressure vs Distance
Consider only gravity effects
ie. Ignore electromagnetic, chemical (eg.osmosis) and other forces
dp
g
dz
Statics
Constant Density
(eg Liquids)
Po = atm
P bottom = Po + g h
P g z
Application: Manometer
IIT-Madras, Momentum Transfer: July 2005-Dec 2005
Statics
Variable Density
eg Gases
80
PV n R T
n P
V RT
dp
g
dz
p
RT
Height
(km) 50
10
-120
Temp (C)
-60
Example
Pbm. 2.13
B
B
10 cm
Water
PA-PB=?
PB-PB= 1 * g * h1
25 cm
Hg
PA-PB = 2 * g * h2 - 1 * g * h2
Actually used for flow rate measurement
Example
0e
Pbm 2.22
z
Patm
Patm P
21136 atm
kg
0 1027 3
m
dp
g
dz
P
P Patm
dp 0 g dz
0
Example
Coin on water: Surface Tension
d2
Weight
4
F Y d sin
h g
Statics
Acceleration due to other forces
eg centrifuge, accelerating vehicle
In centrifuge, usually g is negligible compared to a
Otherwise use vector algebra to add g and a
dp
a
dz
dp
gF
dz
IIT-Madras, Momentum Transfer: July 2005-Dec 2005
Example: Centrifuge
dp
2
r
dr
r
a
dp r dr g dz
2
P2
r2
z2
P1
r1
z1
2
dp
r dr g dz
h1
2 2 2
P2 P1
r2 r1 g Z 2 Z1
2
At z=h1, r=0, P = Patm
On the surface, P = Patm
Z h1
IIT-Madras, Momentum Transfer: July 2005-Dec 2005
2g
Conservation of Mass
In any control volume
Mass flux in - mass flux out = Mass accumulation rate.
If (mass in) is taken as -ve, then
Accumulation rate + Flux(out -in) =0
S
V-velocity
n-normal vector
Vol
Conservation of Mass
d (Vol ) 0
s V . n dA t
Vol
Reynolds Theorem (generalization)
For a property B (Mass, for example)
and corresponding b (per unit mass)
dA A A dx A dy A dz
dt t x dt y dt z dt
DB
b V . n dA b d (Vol )
Dt
t Vol
s
Mass conservation
d (Vol ) 0
s V . n dA t
Vol
Simplifications
Steady State : (gas or liquid)
d/dt =0
Mass in = Mass out
For liquids (Volume in = Volume out)
Constant density & fixed control Volume:
d/dt (V) =0
Volume in = Volume out
True even for unsteady state
Examples
Pbm. 4.8, 4.5, 4.12, 4.18, 4.11,4.9 4.15, 4.20, 4.22, 4.21, 4.24
Examples
Pbm. 4.18, steady state
V1
d1 = d2 = 2 cm
V3
Q1 = 0.0013 m3/s
V2 = 2.1 m/s
A3 = 100 * ( 1e-3*1e-3/4)
There are 100 holes of 1 mm dia in the shower
V2
Examples
Pbm. 4.8
A1
V1,a1
Area =A, Velocity =V, Acclrn = a. Find V2,
A2
V1 (t) A1 = V2 (t) A2
a1A1 = a2A2
IIT-Madras, Momentum Transfer: July 2005-Dec 2005
V2,a2
A2
Examples
Pbm. 4.5, steady state
6 m/s
V/2 m/s
V m/s
d (Vol ) 0
s V . n dA t
Vol
Vside
Vout x
2 L
dA 2R dx
VoutR
SideVside dA L 0 xdx
L
Examples
Pbm. 4.11
M 2 AX 1 AY
2 V2
Vw
1
V1
d (Vol ) 0
s V . n dA t
Vol
dx
dy
Vw
dt
dt
V . n dA AV
1
2 AV2
t Vol
M 2 AX 1 AY
Examples
Pbm. 4.11
dx
dy
Vw
dt
dt
2 V2
Vw
1
V1
d (Vol ) 0
s V . n dA t
Vol
Consider control volume moving @ Vw
V . n dA AV
1
V1 2 AVw V2
Examples
Pbm. 4.9, one dimension, steady flow
d (Vol ) 0
s V . n dA t
Vol
d VA 0
d dV dA
V
A
VA Const
d VA d dV dA
0
VA V A
Compressib le gas, energy balance
dV
1
dA
ideal gas law
V
1 Ma 2 A
Examples
Pbm. 4.12
r
V Vmax 1
R
VAverage ?
r
Vmax 2 1 rdr
R
0
r
1
n
;x
7
R
1
1 x
n
1 x xdx
n 1
n 1
1 x
dx
0 n 1
0
n 1
1
7
Examples
Pbm. 4.15
h
V0
Steady flow
liquid film thickness is h
width into the paper is W
2 y y2
Vx V0
2
h h
X
h
Q Vx dA
dA W dy
2 y y2
Q WV0
2 dy
h h
0
h
Examples
Pbm. 4.14
Constant Velocity V
Varying thickness b
Infinitely long plate (in one direction)
Exit velocity is (a) flat or (b)
parabolic
2L
Y direction
d (Vol ) 0
s V . n dA t
Vol
Mass Flux
Accmln rate
db
Rate of change of Mass 2 L
2LV
IIT-Madras, Momentum Transfer: July 2005-Dec 2005
dt
Examples
Pbm. 4.14
Y direction
( y)
dA
side
2L
Mass Flux
2 V( y ) dy
0
Vavg
L
V
b
V( y ) y y 2
V( 0 ) V(b ) 0,Vmax V b
2
IIT-Madras, Momentum Transfer: July 2005-Dec 2005
V( y )
y y2
4Vmax 2
b b
Examples
Pbm. 4.21
d1
d2
V . n dA
1g
cm3
d (Vol ) 0
t Vol
Accmln rate
cm 3 g
g
6
1 3 6 Leakage
s cm
s
IIT-Madras, Momentum Transfer: July 2005-Dec 2005
Examples
Pbm. 4.13
Vx =V0
V0
0
Height=6d
V0
V . n dA
s
Vx =V0
V0
d (Vol ) 0
t Vol
Mass Flux
3d
y
6d V0 2 V0
dy Mass Out Horizontal 0
3d
0
IIT-Madras, Momentum Transfer: July 2005-Dec 2005