Escolar Documentos
Profissional Documentos
Cultura Documentos
Multiphase System
Example 6.1-1
Antoine Equation
The minimum number of degrees of freedom for any system is zero. When F = 0,
the system invariant.
This value of is the maximum number of phases witch can coexist at equilibrium
for a system containing C chemical species.
Example
How many degrees of freedom have each of the following systems?
(a) Liquid water in equilibrium with its vapor.
(b) Liquid water in equilibrium with a mixture of water vapor and nitrogen.
(c) A liquid solution of alcohol in water in equilibrium with its vapor.
Solution
(a) The system contains a single chemical species existing as two phases (one
liquid and one vapor). Thus,
(b) In this case two chemical species are present. Again there are two phases.
Thus,
pi is the partial pressure of chemical i in the vapor phase, and pi* is the vapor pressure
of pure chemical i at the same temperature.
Example 6.3-1
Problem 6.29
Example 6.3-2
Example 6.3-3
Raoults Law
pA: the partial pressure of A in the gas phase; yA: the mole fraction of A
in the gas phase; xA: the mole fraction of A in the liquid phase; pA*: the
vapor pressure of pure liquid A at temperature T.
Roaults law is an approximation that is generally valid when xA is close
to 1.
Henrys law
Where HA(T) is the Henrys law constant for A in a specific solvent.
Henrys law is generally valid for solutions in which xA is close to 0 (dilute
solutions)
Example 6.4-2
Problem 6.52
Problem 6.56
The diagraphs show the different contents of A and B in vapor and liquid phases.
If one component is evaporated, the fraction of liquid phase changed, so the boiling
temperature also moved along the curves.
Example 6.5.1
Problem 6.78
Colligative property:
lowering vapor pressure, depressing freezing point, increasing boiling point, and increasing
osmotic pressure by dissolving (or dispersing) substance in solvent
Example 6.7-1