Escolar Documentos
Profissional Documentos
Cultura Documentos
TECHNOLOGY FOR
PRODUCTION OF
BIOFUELS AND
BIO-DERIVED
CHEMICALS
Bio-fuels
Green Diesel
Jet Fuels
Transesterification
Homogeneous catalysts
Poor Glycerin Quality
High Feedstock Cost
Emissions issues
Transesterification
Heterogeneous catalysts
Difficult Separation of Glycerin
Lower Feedstock cost
High Capital Investment
Heterogeneous catalysts
Easy separation of high quality Glycerin
Lowest Feedstock cost
Lower Capital Investment
FFA
CONTENT
RELATIVE
PRICE
PRICE
( / #)
85-90%
Low
27
5-6%
Medium
32
10%
Medium
30
10-35%
Low
31
Grease
White A,B
Yellow
House
Brown (trap)
8-10%
15%
20%
50%
Medium
Medium
Low
Low
32
28
26
25
OIL
PFAD (Palm Fatty Acid Distillate)
Poultry Fat
30
Algae Oil
4-15%
Medium
Soybean Oil
2-3%
High
39
HYDROTHERMAL DECARBOXYLATION
No hydrogen needed
Simplified separations
DECARBOXYLATION Hydro-decarboxylation
Less hydrogen used
Some complicated separations, purge loss
Hydrogen recycle expensive
HYDROTREATING Hydrodeoxygenation
High hydrogen consumption
Complicated separations
Low value side products
Green Diesel
NATURAL
TRIGLYCERIDES
LOW TO MEDIUM
FATTY ACID
CONTAINING OILS
MEDIUM TO HIGH
FATTY ACID
CONTAINING OILS
SPLITTING TO MAKE
FATTY ACIDS
GLYCEROL
GREEN DIESEL
HYDROGENATION
TRANSESTERIFICATION
BIODIESEL/
BIOLUBRICANTS
Fatty Acid Methyl Ester
Biodiesel
15 mols H2/mol
triglyceride
Parrafinic Biodiesel
DECARBOXYLATION
1 mol CO2 removed/
mol fatty acid
Parrafinic Biodiesel
MILD
HYDROCRACKING/
ISOMERIZATION
Biojet Fuel
CATALYTIC
DISTILLATION
BIODIESEL/
BIOLUBRICANTS
Fatty Acid Methyl
Ester Biodiesel
Reactor Type
Volume of
Catalyst
Transesterification
Packed Bed
2,000 ml
Green Diesel
Hydrodeoxidation
(HDO)
Packed
BedMolten Salt
Bath Furnace
250 ml
Catalytic Distillation
Heterogeneous
Catalyst
Loaded
Column
2x20 ft.
Catalytic
Decarboxylation
(CDC)
Packed Bed 5
zone electric
heater
50 ml
Hydrothermal
Decarboxylation
Packed Bed 5
zone electric
heater
50 ml
Mild Hydrocracking/
Isomerization
Packed bed 5
zone electric
furnace
50 ml
Pilot Plant
Design
Pressure
Design
Temp.
100 bar
300C
(1500 psig)
(575F)
70 bar
375C
(1000 psig)
(700F)
50 bar
200C
(750 psig)
(400F)
30 bar
350C
(450 psig)
(650F)
180 bar
350C
(2600 psig)
(650F)
100 bar
375C
(1500 psig)
(700F)
Liquid
Feeds
Gas
Feeds
Feedstock
Product
Triglycerides
Biodiesel /
Biolubricants
Triglycerides
Diesel range
parrafins
Fatty acids
Biodiesel /
Biolubricants
Fatty acids
Diesel range
parrafins
Triglycerides
Green Diesel
Biodiesel
range
parrafins
Bio-SPK
(biojet fuel)
Catalyst volume will change as a function of catalyst type and whether the catalyst is incorporated within
structured catalytic packing or whether the catalyst is conventionally charged
1st GENERATION
2nd GENERATION
Cellulosic ethanol
Solves debate
Earns higher credit
Same issues as traditional
ethanol
3rd GENERATION
Solves debate
Can be put into pipeline
Energy density closer to gasoline
(110,000 Btu/gal 29.2 MJ/L)
No Corrosion issues
Can be put into diesel as well.
Blend wall is increased to 12%
More toxic to the organisms. Lower yields make batch process un-economical
Most organisms make iso-butanol
100C
SOLVENT COLUMN
DECANTER
FEED FROM
FERMENTER
AQUEOUS SEPARATOR
117C
BUTANOL
WATER
MIXED
ALCOHOL
Jet Fuels
Modularity
The concept of modularity for the design of pilot plants,
demonstration plants and small commercial plants was
pioneered by our group.
This concept now has found
universal acceptance in terms of maintaining QA/QC
controls, assembly procedures and reducing overall project
costs .
Phase
Phase 11
Aspen Plus
Simulation
Heat &
Material
Balances
Process Flow
Diagrams
Phase
Phase 22
Process &
Instrumentation
Diagrams
Equipment
Specs
Instrument
Specs
Control
Philosophy
Phase
Phase 33
Detailed
Engineering
3D Plant
Design
Phase
Phase 44
Procurement
Construction
Field Testing
The choice of a suitable reactor for carrying out experiments under conditions
where meaningful kinetic rate expressions can be obtained is of very great
importance.
Energy
Research
Petrochemicals
Polymerization
Environmental
PE
Petroleum
Refining
Pharmaceutical
&
Nutraceutical
Catalyst
Research
Misc. Unit
Operations
Gasification
Transesterification
+ 15H2
hydrogen
propane
diesel
CO2 + H2 CO + H2O
CO + 3H2 CH4 + H2O
CO2 + 4H2 CH4 + 2H2O
R 1 C OH + OH CH 2
H
O
R 2 C OH + OH CH 2
H
O
R 3 C OH + OH CH 2
H
Fatty Acids
Methanol
R 1 C O CH 2 H + H 2O
Catalytic
Distillatio
n
O
R 2 C O CH 2 H + H 2O
O
R 3 C O CH 2 H + H 2O
Methyl Ester
Water
Catalytic DeCarboxylation
(CDC) Pilot Plant
Catalytic DeCarboxylation
(CDC) Pilot Plant
Mild Hydrocracking
Isomerization Pilot Plant
R 1H
Paraffinic
Hydrocarbon
n-C 17H 34
Heterogeneous
Catalyst
Mild
Hydrocracking &
Hydroisomerizatio
n
C 10-C 15
Branched
Paraffins
Mild Hydrocracking
Isomerization Pilot Plant
TI
TE
xxx
xxx
TE
xxx
xxx
TE
xxx
xxx
TE
xxx
xxx
TE
xxx
xxx
TI
TI
PI
PI
xxx
xxx
PT
xxx
PT
xxx
FT
xxx
xxx
PI
xxx
PT
xxx
VENT
FV
xxx
MASS
THERMAL
TSS
FC
FC
TIC
xxx
CK-xxx
PI
xxx
PCV
xxx
TIC
xxx
VENT
FV
xxx
MASS
THERMAL
F-xxx
XV
xxx
XY
xxx
CK-xxx
TSS
xxx
TIC
xxx
xxx
TE
xxx
xxx
XY
xxx
TIC
FC
FC
HV-xxx
TE
xxx
F-xxx
LIC
xxx
TE
xxx
LV
xxx
RX-xxx
TUBULAR
REACTOR
LY
xxx
IA
XV
xxx
xxx
F-xxx
TO GC /
ANALYTICAL
LIT
xxx
FV
xxx
MASS
THERMAL
TSS
IA
VENT
VENT
HV-xxx
TE
xxx
TY
xxx
PSV
xxx
PI
xxx
HS
xxx
KY
xxx
FT
xxx
PCV
xxx
AS
KV
xxx
FRN-xxx
SPLIT TUBE MULTI
ZONE FURNACE
HS
xxx
PI
xxx
FC
TE
xxx
FC
FIC
NITROGEN
(>10 BAR)
TO VENT
VENT
TY
xxx
FC
FC
FQI
xxx
IA
VENT
PSV
xxx
PI
xxx
xxx
xxx
FT
xxx
LOW PRESSURE
H2/H2S ACTIVATION GAS
(>10 BAR)
TE
xxx
TY
xxx
TSS
HS
xxx
FQT
xxx
FQI-xxx
F-xxx
CK-xxx
F-xxx
FIC
IA
VENT
FO
TY
xxx
XY
xxx
xxx
F-xxx
PV
xxx
E
IA
XV
xxx
PCV
xxx
PY
xxx
PSV
xxx
PCV
xxx
S
VENT
PSV
xxx
PCV
xxx
PI
xxx
PT
xxx
xxx
PI
xxx
PI
xxx
PI
xxx
HS
xxx
HIGH
PRESSURE
HYDROGEN
(>100 BAR)
PI
xxx
TI
VENT
FIC
PI
PSV
xxx
TI
TE
xxx
TE
xxx
CK-xxx
TY
xxx
PI
xxx
PCV
xxx
TSS
xxx
TIC
VENT
xxx
Set at xxx bar
ALKANE FEED
HS
xxx
TIC
M
xxx
TE
xxx
xxx
WAL
V-xxx
FEED TANK
HTR
xxx
WI
xxx
DRAIN
Catalyst charge: 50 mL
Reactor internal volume: 100 mL
Maximum system pressure: 100 bar (~1500 psig)
Maximum system temperature: 375C (~700F)
Number of liquid feeds: 1
Maximum LHSV of liquid feed: 2
Number of gas feeds: 3
(1 high pressure, 2 low pressure)
PT
xxx
HS
xxx
E
HV-xxx
CK-xxx
V-xxx
HYDROISOMERIZED
PRODUCT RECEIVER
HV-xxx
DRAIN
WT
xxx
HV-xxx
xxx
PI
xxx
PI
xxx
TY
xxx
TE
xxx
PI
PSV
xxx
xxx bar
HV-xxx
WAH
TE
xxx
HV-xxx
P-XXX
DIAPHRAGM
METERING FEED
PUMP
CONFIDENTIAL
WAH
HV-xxx
F-xxx
WAL
WI
xxx
WT
xxx
HV-xxx
HYDROISOMERIZED
PRODUCT
Sheet No.:
5/5
Project No.:
xxx
Drawn by:
JAB
Rev No.:
0
Date:
8/26/10
xxx
The objectives of a pilot plant, therefore, can differ depending on the specific
circumstances of each project, and the decision for its construction can include one or
several of the following objectives:
To obtain process information necessary to specify and design the full scale plant,
To gain operating experience. and to train the personnel that will operate the full scale
plant,
To identify hazards in the process and ensure safety in design and operation, including
the disposal of radioactive wastes,