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Alexandre-Edmond Becquerel.
1883: First solar cell was built by Charles Fritts, who coated the
semiconductor selenium with an extremely thin layer of gold to form the
junctions (1% efficient).
1946: Russell Ohl patented the modern solar cell
1954: Modern age of solar power technology arrives - Bell Laboratories,
experimenting with semiconductors, accidentally found that silicon doped
with certain impurities was very sensitive to light.
The solar cell or photovoltaic cell fulfills two fundamental functions:
Photogeneration of charge carriers (electrons and holes) in a lightabsorbing
material
Separation of the charge carriers to a conductive contact to transmit
electricity
First Generation
Single crystal silicon wafers (c-Si)
Second Generation
Amorphous silicon (a-Si)
Polycrystalline silicon (poly-Si)
Cadmium telluride (CdTe)
Copper indium gallium diselenide (CIGS) alloy
Third Generation
Nanocrystal solar cells
Photoelectrochemical (PEC) cells
Polymer solar cells
Dye sensitized solar cell (DSSC)
Fourth Generation
Hybrid - inorganic crystals within a polymer matrix
http://science.nasa.gov/science-news/science-atnasa/2002/solarcells/
There are several varieties of cells today that can be used to absorb sunlight and
convert those photons into electrical energy. These include:
CIS (Copper Indium Diselenide) Cells
CdTe cells (Cadmium Telluride) Cells
Organic Cells
Multi-junction Cells
Although multi-junction cells have the highest efficiency among solar cells
achieved in a laboratory setting (demonstrated by the following graph), Silicon
Cells (monocrystaline, polycrystaline and amorphous) due to their low cost and
decent efficiency are the most feasible for wide production and will thus be the
main interest of our study.
Crystalline
Silicon
Semiconductor
Non-crystalline
Solar
Cell
Compound
Semiconductor
Organic
Semiconductor
Single crystal
10 - 17%
Poly crystalline
10 - 13%
Amorphous
18 - 30%
Dye-sensitized Type
7 - 8%
2 - 3%
7 - 10%
x 100%
Lets calculate.
Fill Factor
.A photocell has a short circuit current of 25 mA, an open
circuit voltage of 0.6 V and a maximum power output of
12 mW. What is its fill factor?
80%
Lets calculate.
PV Cells Technologies
Characterization criterion:
Thickness:
Conventional thick cells (200 - 500 m)
Thin film (1 10 m). Tend to be less costly than conventional
(think) cells but they also tend to be less reliable and efficient.
Crystalline configuration:
Single crystal
Multicrystalline: cell formed by 1mm to 10cm single crystal areas.
Polycrystalline: cell formed by 1m to 1mm single crystal areas.
Microcrystalline: cell formed by areas of less than 1m across.
Amorphous: No single crystal areas.
p and n region materials:
Same material: homojunction (Si)
Different material: heterojunction (CdS and CuInSe2)
PV Technology Classification
Silicon Crystalline Technology
Mono Crystalline PV Cells
Cells
Multi Crystalline PV Cells
5. Types of Solar
cell on the types of crystal used, solar cells can be
Based
classified as,
1. Mono crystalline silicon cells
2. Polycrystalline silicon cells
3. Amorphous silicon cells
15
Made
Caste
Operating
Cell
efficiency up to 15%
Accounts
for 90% of
crystalline Si market
PROS
Low cost substrate and
fabrication process
CONS
Not very stable
PROS
Mature manufacturing
technologies available
CONS
Initial 20-40% loss in
efficiency
PROS
18% laboratory efficiency
>11% module efficiency
CONS
Immature manufacturing
process
Slow vacuum process
PROS
16% laboratory efficiency
6-9% module efficiency
CONS
Immature manufacturing process
Crystalline silicon
Cadmium telluride
Copper indium diselenide
Gallium arsenide
Indium phosphide
Zinc sulphide
24
High
Valence band
density
Low
25
Stage-1
When light falls on the semiconductor surface, the
electron from valence band promoted to conduction
band.
Therefore, the hole
(vacancy
position
left by the electron
in the valence band)
is generates. Hence,
there is a formation
of electron-hole pair
on the sides of p-n
junction.
Conduction band
density
High
Valence band
PH 0101 Unit-5 Lecture-2
Low density
26
Stage-2
In the stage 2, the electron and holes are diffuse
across the
p-n junction and there is a formation of
electron-hole pair.
Conduction band
density
High
junction
Valence band
Low density
27
Stage-3
In the stage 3, As electron continuous to diffuse, the
negative charge build on emitter side and positive
charge build on the base side.
Conduction band
density
High
junction
Valence band
Low density
28
Stage-4
When the PN junction is connected with external circuit,
the current flows.
Conduction band
density
High
junction
Valence band
Low density
Powe
r
29
Over 95% of all the solar cells produced worldwide
are
composed of the semiconductor material Silicon
(Si). As the
second most abundant element in earth`s
crust, silicon has the advantage, of being available in
sufficient quantities.
31
2. Photovoltaic effect
Definition:
The
generation
of
voltage
across
the PN junction in
a semiconductor
due
to
the
absorption
of
light radiation is
called
photovoltaic
effect.
The
Devices based on
this
effect
is
Light
energ
y
n-type semiconductor
p- type semiconductor
Electrica
l Power
p-n junction
32
3. electron-hole
formation
33
Conduction band
electron
Photons
hole
Valence band
34
Mechanism of
generation
(A)
Short Circuit
Current(I)
High insolation
Low insolation
IxV=W
(V)
Voltage(V)
35
Open Circuit
Fill Factor
The ratio of Maximum obtainable power to the product of
the open ckt voltage and s/c current.
FF = (Imp x Vmp) / (IL x Voc).
Cells with high Fill Factor have a low equivalent series
resistance and a high equivalent shunt resistance, so less of
the current produced by the cell is dissipated in internal
losses.
Whats in a Polycrystalline Si
Solar Cell?
Emerging Technologies
Discovering new realms of Photovoltaic Technologies
Cell efficiency ~ 7%
Emerging Technologies
Ultra Thin Wafer Solar Cells
Thickness ~ 45m
Cell Efficiency as high as 20.3%
Solar Cell
Properties
Open
circuit voltage (VOC)
Short circuit current (ISC)
Maximum power
Efficiency
Energy of a photon
A property of the
atoms of the
semiconductor
This is the energy
gap between two
bands of energy
between tow
electron states in a
solid
Only photon energy
which matches the
band gap energy of
the material can
free an electron
from that state.
Good efficiency
High Cost
Low Cost
Less Efficiency
Low Cost
Medium Efficiency
m22
11kw
kwPV
PVneed
need 10
10 m
Please
remember
20m(66feet)
(108 feet2)
Conference
Room
(We are now)
Parallel Connections
Loads/sources wired in parallel:
VOLTAGE REMAINS CONSTANT
CURRENTS ARE ADDITIVE
Two interconnection wires are used between two
components (positive to positive and negative to
negative)
Leave off of either terminal
Modules exiting to next
component can happen
at any parallel terminal