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INTRODUCTION
This PowerPoint presentation aims to give A-level students knowledge of the
topic Aluminium, for those who are already achieving in this subject and
those who are not performing up to their standards. In this presentation the
presenters wish to give every A-level student a better understanding on
what CXC CAPE Chemistry wants you to know about the element Aluminium
at this level and how to approach questions relating to Aluminium specific
to the objectives given by the syllabus. Relevant theory and explanation of
results is described for each objective which is accompanied by a worked
examples and past paper questions.
SPECIFIC OBJECTIVES
2.1. Describe the processes involved in the production of Aluminium from its ores
Explanatory Notes: Purification of the ores most be included. The Syllabus does not require
any technical details.
High energy consumption in the production of Aluminium most also be
accounted for.
2.2. Explain the uses of Aluminium in relation to its physical and chemical properties;
Explanatory Notes: Relate its physical and chemical properties to its uses.
2.3. Assess the IMPACT of Aluminium industry on the environment;
Explanatory Notes:
Aluminium ore
The usual Aluminium ore is bauxite. Bauxite is essentially an impure
aluminium oxide. The major impurities include iron oxides, silicon dioxide and
titanium dioxide
Purifying the Aluminium oxide - the Bayer Process
Reaction with sodium hydroxide solution
Crushed bauxite is treated with concentrated sodium hydroxide solution
which dissolves the Aluminium oxide and silicon (IV) oxide. The concentration,
temperature and pressure used depend on the source of the bauxite and
exactly what form of Aluminium oxide it contains. Temperatures are typically
from 140C to 240C; pressures can be up to about 35 atmospheres.
High pressures are necessary to keep the water in the sodium hydroxide solution liquid at
temperatures above 100C. The higher the temperature, the higher the pressure needed.
With hot concentrated sodium hydroxide solution, Aluminium oxide reacts to give a solution of
sodium tetrahydroxoaluminate.
Al2O3 + 2NaOH + 3H2O 2NaAl(OH)4
The iron (III) oxide and other basic materials remain undissolved and are removed by
filtration. The residue is highly toxic and red-brown in colour due the presence of iron (III)
oxide.
Looking at Figure 1.1 the cell itself is made of steel lined with graphite which acts as the cathode
and the molten electrolyte and graphite anodes suspended in the electrolyte.
Molten Aluminium is syphoned out of the cell from time to time, and new Aluminium oxide added
at the top. The cell operates at a low voltage of about 5 - 6 volts, but at huge currents of
100,000 amps or more. The heating effect of these large currents keeps the cell at a
temperature of about 900-1000C.
PROPERTIES
ALSO USED IT IS
FOR:
The high cost of the process because of the huge amounts of electricity it uses. This is so high ,because to produce 1 mole of Aluminium
which only weighs 27 g you need 3 moles of electrons. You are having to add a lot of electrons (because of the high charge on the ion) to
produce a small mass of Aluminium (because of its low relative atomic mass).
Energy and material costs in producing the Cryolite, some of which gets lost during the electrolysis.
Greenhouse gases also escaped during the production of Aluminium one significant example is the fluoride gas produce from electrolysis
of the Aluminium ore. which can escaped the production and enter the environment and although at low concentrations it is not
dangerous when it accumulates to large amounts it can be damaging to the environment. If you are ask how fluoride affects the
environment this is a good way of responding. If the examiner ask what symptoms are associated when fluoride is ingested you can
respond by saying it causes Anaemia, respiratory distress, stiffness in the knees and joints and dental mottling. Dental mottling or mottled
enamel is the hypo mineralization of the tooth enamel caused by ingesting excessive amounts of fluoride during enamel formation.
Causes immense degrees of intrinsic tooth discoloration. Carbon dioxide is a greenhouse gas that traps heat in the earths atmosphere
thus increasing the temperature which leads to global warming. Carbon monoxide is very dangerous and also known as the silent killer. It
has no scent and when inhaled it can affect the respiratory and circulatory system. It can replace oxygen and carbon dioxide in the blood
remain bonded to that blood cell throughout the body
The caustic residue is sometimes grounded and recycled in making construction materials, but when it is grounded, the caustic residue
can enter underground water. This can disrupt the pH of the water reservoirs causing marine animals to flee the area which later on
affects fishing industries.
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ANSWERS