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Lets Recall
Homologous Functional
Formula
Series
Group
Alkane
Alkyl
RH
Alkene
Alkenyl
R2C=CR2
General Formula
(m0, n1)
Suffix
Example
Lets Recall
Homologous Functional
Formula
Series
Group
General Formula
(m0, n1)
Suffix
Example
Alkane
Alkyl
RH
CnH2n+2
-ane
Ethane
Alkene
Alkenyl
R2C=CR2
CnH2n
-ene
Ethene
Lesson objectives
1. Describe the alcohols as a homologous series
containing the OH group.
2. Draw the structures of alcohol, C1 to C5, and name
the unbranched alcohols, methanol to butanol
3. Describe the properties of alcohols in terms of
combustion and oxidation to carboxylic acids
4. Describe the formation of ethanol by the fermentation
of glucose
The
Chemical Formula
C2H5OH (molecular formula)
OH
or
CH3CH2OH
OH
OH
Methanol
Ethanol
Propanol
Total of one
carbon atom
(meth-)
CH3OH
Total of two
carbons atoms
(eth-)
CH3CH2OH
Total of three
carbon atoms
(propan-)
C2H5CH2OH
Naming Alcohol
Replace
Example:
H H
ethane
H
H
C
H
H
O
I
I
H
ethananol
Methanol
Molecular
Formula
CH3OH
OH
Ethanol
CH3CH2OH
C2H5OH
OH
Propanol
CH3(CH2)CH2OH
C3H7OH
OH
Butanol
C4H9OH
OH
Pentanol
C5H11OH
Condensed
Structural Formula
CH3OH
OH
Structural Formula
CH3(CH2)2CH2OH
CH3(CH2)3CH2OH
Name
Molecular formula
Solubility In Water
Methanol
CH3OH
Very Soluble
Liquid
Ethananol
C2H5OH
Soluble
Liquid
Propananol
C3H7OH
Soluble
Liquid
Butananol
C4H9OH
Slightly soluble
Liquid
(solid/liquid/gas)
Physical Properties of
Alcohols
Alcohols are soluble in water
but
Unlike
Although
Chemical Properties of
Alcohols
Alcohols
Combustion and
Oxidation
reactions:
Combustion
An alcohol burns in air to produce
carbon dioxide and water vapour.
ethanol + oxygen carbon dioxide + water vapour
C2H5OH + 3O2 2CO2 + 3H2O
Combustion
Flame
produced is clean
Combustion
Oxidation
We can oxidise an alcohol (for example,
ethanol) by warming it with acidified potassium
dichromate(VI).
Experimental setup:
(ethanol)
C2H5OH
+ acidified K2Cr2O7
cold
water
heat
CH3COOH
(ethanoic acid)
Oxidation
Chemical
equation:
+ 2 [O]
Ethanol
Ethanoic
acid
H 2O
Oxidation
Formation of ethanol
Ethanol can be manufactured from:
1. hydration of ethene
2. fermentation of carbohydrates
Formation of ethanol
- Hydration of ethene
Ethanol is manufactured by the catalytic
addition of steam to ethene.
Conditions:
phosphoric(V) acid at 300 C and 60 atm.
Phosphoric(V) acid (H3PO4) acts as a catalyst.
Formation of ethanol
-Fermentation of carbohydrates
Fermentation is a chemical process in
which microorganisms such as yeast act on
carbohydrates to produce ethanol and
carbon dioxide.
Formation of ethanol
-Fermentation of carbohydrates
Instructions:
In your own groups of four, set up an experiment
according to the experimental set up (A, B, C or
D) which you can find on the last page of your
worksheet.
Each group will only be allocated to one of the
four set ups.
Formation of ethanol
-Fermentation of carbohydrates
Instructions:
Record your observations under the observations
column after one week and upload your
observations onto the class blog according to
your allocated set up.
Your group is suppose to complete a series of
questions pertaining to the experiment and hand
in one set of answers per group two weeks later.
(You can find the questions on the class blog).
Uses of Ethanol?
solvents for paints,
varnishes, perfumes
alcoholic
drinks
oxidation
ethanol