Escolar Documentos
Profissional Documentos
Cultura Documentos
CHEMICAL-REACTION
EQUILIBRIA
Negative ( - ) for
Example :
CH4 + H2O CO + 3H2
The stoichiometric numbers are:
The stoichiometric number for an inert species is
zero
Since
(13.2)
dni = vi d
( i = 1 , 2 ,.N)
(i = 1,2, N)
(13.4)
Solution
Application of equation (13.4) and (13.5) yields
Multireaction Stoichiometry
Multireaction Stoichiometry
(13.7)
Also, by definition
(13.12)
K is a function of only temperature
In spite of its dependence on temperature , K is
called the equilibrium constant for the reaction; ,
represented by G , is called the standard Gibbsenergy change of reaction.
The dependence of G on T :
which can be re-written as
(13.14)
The equation gives the effect of temperature on
equilibrium constant and hence on the equilibrium
conversion.
When H
negative = exothermic reaction
positive = endothermic reaction
If H is assumed independent of T, then:
(13.15)
a plot of ln K versus the reciprocal of absolute
temperature is a straight line.
However,
so,
and,
(13.20)
G418
8,378 45,792
45,792
23.121
0.06924 1.9356
8.314 298.15 8.314 418.15 418.15
RT
G593
8,378 45,792
45,792
22.632
0.01731 5.8286
8.314 298.15 8.314 593.15 593.15
RT
18.473
K 0 exp
29.366
RT0 8.314 298.15
8.314 298.15
Example(13.4)(page496)
Moreover,
With these values, the following results are readily
obtained:
T/ K
K0
K1
K2
298.15
29.366
29.366
418.15
1.4025
29.366
4.985x10-3
0.9860
1.443x10-1
593.15
1.9894
29.366
1.023x10-4
0.9794
2.942x10-3