Escolar Documentos
Profissional Documentos
Cultura Documentos
REACTIONS
Suhadi Ibnu
Catalyst:
Catalyst
From
Besides
Catalyst
Catalist
(2)
I2
2I.
I.
k = (k1/2k-1)1/2 k2
Acid-Base
Catalysts consists of
Acid-Base Catalysts
kkat
The
Cu,
Mechanism
of Reaction: diffusion,
adsorption, reaction, desorption, diffusion.
The most important step is reaction on the
surface of the metal, which has lower
activation energy than reaction without a
catalyst.
This reaction is influenced by the partial
pressure (pA) of the gas and the fraction of
the surface closed by reactant molecules ().
Rate
Rate
of desorption is proportional to
closed fraction of the surface (N)
Rate of desorption = kdes N
At equilibrium adsorption rate =
desorption rate
Reaction
rate = k = kpA/(pA + K)
Jika
Jika
Penggandaan
khet/khom = exp(-Eahet/RT)/exp(-Eahom/RT)
(Show
Kind of Catalists
Decomp.
HI
Au
Pt 14.0
25.0
44.0
N2O
Au
Pt 32.5
29.0
58.5
NH3
Mo
W 39.0
80
Os
47.0
32-42
CH4
Pt 55-60 80
* In k.cal mol
-1
Kind
of solid catalists
The strenghth of the adsorption of the
reactant (s) by the surface
Temperature
The
Weakly
Moderately
1)
Strongly
Temperature
Orders
Reaksi
1:
E + S ES d(ES)/dt = ka(E)(S)
2: ES E + S -d(ES)/dt = ka(ES)
3: ES P + E d(P)/dt = -d(ES)/dt =
kb(ES)
Dengan
d(ES)/dt
Penurunan
d(P)/dt
k
= k (E)0, di mana
= kb(S)/{(S) + Km}
Di
mana Km = ka + kb/ka
Km