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G.Vandoni,
G.Vandoni, CERN
CERN
Physics of gases
Flow regimes
Definitions
The pumpdown process
Conductance
Conductance calculation
2
Units and conversions
To
Pressure Pa mbar torr
From
7.5/100
Pa 1 0.01 x [unit 1] x factor [unit 2]
0
mbar 100 1 0.75
torr 133 1.33 1
To
l /s cm3/s m3/h
Pumping From
speed l /s 1 1000 3.60
Volumetric cm3/s 0.001 1 0.0036
flow
Conductanc m3/h 0.278 278 1 [Volume/time]
e
Flow or To Pa m3/s mbar torr l/s
Throughp From l/s
ut Pa m3/s 1 10 7.5
mbar 0.1 1 0.75 [Pressure
l/s
Volume/ti
torr l/s 0.133 1.33 1 me]
3
The physics of Gases
The ideal gas law An ideal gas is composed
of randomly-moving, non-
interacting point particles.
pV nm RT 12 units
1 dozen =
p = pressure
V = volume 1 mole = 6.022x1023 units
nm = amount of gas (number of moles)
T = temperature
R = general gas constant [8,314 J/(mol
K)]
4
The physics of Gases
seful forms of the ideal gas law
V1
V2
p1 p2
p1V1 p2V2
T1 T2
5
Gas Mixtures and Partial Pressures
DEFINITION
n1 n3 Partial pressure is the pressure which a gas
would exert if it occupied the volume of the
mixture on its own
n2 n1 RT n2 RT n3 RT
p1 p2 p3
V V V
Dalton law
The total pressure exerted by a mixture of (non-reactive) gases is
equal to the sum of the partial pressures of individual gases
p p1 p2 p3
RT
p n1 n2 n3
V
6
Flow regimes
7
Mean free path and density
verage distance traveled by a molecule between collisions with other molecules
n
Pressure Mean free
Vacuum range [molecules/
[mbar] path
cm3]
Ambient pressure 1013 2.5 1019 68nm
8
Mean Free Path
average distance traveled by a molecule between collisions with other molecules
1
n = density of molecules
2n = collisional cross section
For N2:
d mol 0.31 nm 0.3110 - 9 m
molecules proportional s s
approximatio to p kT
n p H2 12x10-3 CO 4 x10-3
2d mol
2
(d = p
2
Ideal gas n
diameter) N2 6.4x10-3 Ar 7x10-3
law kT
He 19x10-3 Ne 14x10-3
CO 7x10-3 Kr 5x10-3 9
Mean free path and flow regime
The flow dynamics is characterized by the comparison of the mean free
path to the dimension D of the vacuum vessel.
Collisions with wall
Knudsen number (much) more frequent
than with molecules
Free Molecular Flow >D Kn >1
Kn Transitional (or D/100< <
D 0.01<
intermediate) flow D Kn < 1
Viscous (continuum) flow < D/100 Kn< 0.01
Collisions with molecules
dominate
Applying the previous slide, we have a useful relation between pressure
and dimension of the vessel to distinguish flow regimes:
Molecular flow: pD<0.064 [mbar . mm] Room temperature, for N2
Viscous flow: pD>6.4 [mbar .
mm]
11
Gas Flow: throughput French: dbit
From the ideal gas law written per unit time, we see that this is a energy
flow rate.
dd((pV
pV)) dN dN mol Pam3s-1= Nms
Q
Q k BT RT -1
= Js-1= W
dt
dt dt dt
particle packet
flow of count money=count dwarfs
rate energy
This is equivalent to a particle flow rate only at constant
temperature.
When flow doesnt change with time (we say
steady state), Q has the same value at every
position along the pipework: mass is
conserved.
Qin Qout
Pumping speed is
usually depending on
pressure, so S=S(p)
Pumping speed is
different for different
gas species
13
The pumpdown process
14
The pumping process
vessel S* pumping speed of the pump
QL p S pumping speed at the vessel, of
pump volume V
QG p pressure in the vessel
Qp Qv S S* Qtot = sum of all gas loads entering the
V vessel: outgassing, leaks and
QTot process
permeation, QG QL gas
Q p etc
15
The pumping process
vessel S* pumping speed of the pump
QL S pumping speed at the vessel, of
p
pump volume V
QG p pressure in the vessel
Qp Qv S S* Qtot = sum of all gas loads entering the
vessel: outgassing, leaks and
V
permeation,
QTot process
QG QL gas
Q p etc
V.dp
To go
17
Example: continuity equation
After 3h pumping, pressure is presently 5.10-7mbar. The pumping speed
of the turbomolecular pump, including reduction by the conductance
connecting it to the vessel, is 10ls-1.
The vessel is a tube, 1m long and 400mm in diameter. Chronometer in
the hand, you notice that 40s later pressure has decreased to 4 .10-
7
mbar.
What is the rate of change of pressure in this moment?
In absence of leaks, can you evaluate the total outgassing rate of the
vacuum chamber in this moment?
p=510-7 mbar
dt =40s, dp =110-7 mbar dp/dt=2.510-9mbar/s
Seff =10 l/s
2
d
d =400mm, L=1000mm A 2 d L 1.5 m 2
2 2
d
V L 125.7 liters
2 Qoutg A
dp
Qtot Qoutg S p V Qoutg A 3.5 10 10 mbar l s 1 cm 2
dt
18
Pumpdown: initial phase
dp Qpumped
V QTot S p
dt
Initially, the pumpdown process is dominated by evacuation of the free
gas in the volume. Lets write Qtot=0 and lets call pinitial(t) the pressure
decrease curve in the initial phase of pumpdown.
Pressure
dt
102 p V
dp S
Volume S p V dt
depletio
ln pinitial ln po t
V 101 S
ln pinitial(t ) ln po t
n S V
t 1 2 3 4 5 6 7
t
pinitial po e V
po e time ln p versus t
Remember maths! A function
V
Characteristic time or time which changes with a rate
S proportional to the function itself
constant 19
is an exponential
Initial pumpdown time
Pressure
10-3
Volume S
depletio
ln pinitial ln po t
V 10-4
n
S 1 2 3 4 5 6 7
t
time
pinitial po e V
ln p versus t
k
pultimate kt n with 0.5n1.2
tn
n ~1 for metallic unbaked surfaces
~0.5 for elastomers, (for baked metallic surfaces)
21
Pumpdown: effect of outgassing on p(t)
Below 1 Pa=10-2mbar, (~roughing), the curve p(t) starts to deviate
from the free volume straight line. We cannot neglect outgassing Qout
anymore.
dp
V Qtot S p 10-2
ln pultimate k n ln t
dt
Pressure
10-3
Volume S
depletio
ln pinitial ln po t
V
n 10-4
S
t
pinitial po e V
22
Pumpdown: effect of outgassing on p(t)
Below 1 Pa=10-2mbar, (~roughing), the curve p(t) starts to deviate
from the free volume straight line. We cannot neglect outgassing Qout
anymore.
dp 10-2
V Qtot S p ln pultimate k n ln t
dt
Pressure
10-3
Volume S
depletio
ln pinitial ln po t
V 10-4
n
S 1 2 3 4 5 6 7
t
time
pinitial po e V
ln p versus t
k
pultimate kt n with 0.5n1.2
tn
n ~1 for metallic unbaked surfaces Eventually, the pressure
~0.5 for elastomers flattens down and becomes
constant on the time scale of
observation. On a long time
scale, it continues to decrease
slowly. 23
Pumpdown: when outgassing dominates
When pressure ceases to fall and becomes
dp
V Sp Qout constant on the time scale of observation,
dt dp/dt=0.
The equation becomes: Q
pultimate out
p S
mbar l 3 10 5 mbar l
n
For unbaked metals of standard rugosity, 1, 1h 3 10 5
Q (t ) s cm 2
m2 t[ h ]
24
Example: pumpdown with outgassing
Example:
A stainless steel vacuum vessel of 1m length and 250mm diameter is
evacuated by one pumping group of an effective pumping speed 50l/s.
After 5h pumping, pressure has stabilized at ~110-6mbar.
Do you consider that everything is running fine?
pS=510-7mbarl/s
A=7850 cm2
t=5hr=18,000s =310-9mbarl/cm2
8000 3 10 9 mbar l 4 9 mbar l
Qout 10
18,000 s 3 s
25
Conductance
26
Conductance
Q C ( pU pD )
Q
In parallel In series
Derivation:
Conservation of flux
Q Definition of C Q
Q C ( pu pd )
pU pDQ C1, 2 ( pu pd )pU pD
1, 2
Q Q1 Q2
C1
Q
C1 C2
pU pD
pU C2 pD
R R1 R2 etc...
1 1 1
C C1 C2 etc... etc...
C C1 C2
Approximate: it overestimate resistance, by neglecting beaming and
entrance resistance cancelling
28
Reduction of pumping speed by connecting pipe
0.6
S*/S
Ex: If the conductance is equal 0.4
to the pumps speed, we only
0.2
get 1/2 of it at the vessel. To
get 80% pumping speed at the 0
0 5 10 15 20
vessel, we need a conductance
4x larger than the pumping C=S C=4S C/S
29
Pressure profile in long tube with localized pumps
A tube under vacuum will outgas uniformly over its whole internal surface.
Pumps are installed along the tube. Due to the limited (i.e., not infinite)
conductance of the tube, pressure will have maxima at equal distance
from two pumps and minima above the pumps.
PRESSURE
From the continuity
PROFILE
equation, it is obvious
that: 2Q
P0
S
It is not difficult to show
also that
Q
P1 P0
2C
Q: outgassing flux
[mbar.l.s-1]
S: pumping speed [l/s]
C: tube conductance
Notice differences in pressure measurement in long tubes, depending on their distance
to the pump! [l/s] 30
Conductance calculation
Conductance
Conductance in
in viscous
viscous flow
flow
Conductance
Conductance in
in molecular
molecular flow
flow
31
Conductances and flow regimes
On the figure: the equal
conductivity curves on a p,d
10-4 10-3 10-2 10-1 1 10 [mbar] graph
- read for example: 106 l/s
Lets
and 1 anticipate,
l/s that the
us conductances of pipes will
s co
vi differ in different flow
regimes:
mo 10
lec 6
In continuum flow, they
ula
r are proportional to mean
pressure p.
In molecular flow they
1
are not a function of
100
pressure.
In Knudsen flow, a
transition between the two
Above pD>6.4 mbar.mm, flow is types of flow, conductances
viscous vary with Knudsen number.
Below pD<0.064 mbar.mm, flow is At the same diameter,
molecular conductance in continuum
32
Continuum (viscous) flow through pipes
Viscous gas flow may be:
LAMINAR: TURBULENT :
gas flows smoothly in stream gas flows chaotically and
lines, parallel to the duct irregularly brakes up into
walls. Invortexes.
most cases treated in
vacuum technology, we
Inertia forces
are in laminar conditions
compared to
viscous
forces
Viscous forces are Inertial forces are
stabilizing
Re<200
Re<200 destabilizing Re>200
Re>200
0
0 0
0
Reynolds number Re compares the two effects
D 4
C p p is the average pressure between entrance
128L
and exit pressure
34
Viscous regime: Short tubes conductance
The difficulty here is that the
velocity profile changes at the
aperture, with a minimum cross
section at the aperture, then with
oscillations of contraction/expansion
before reaching fully developed
flow.
35
Choked flow
effect of compressibility of a gas French: flux sonique
38
Conductance of an aperture
Aperture of area A in a thin wall
separating two regions of pressures p1
and p2 J A
dN dN
( J1 J 2 ) A Q kT 1 J
dt dt p1 , 2
p2,
Net flux= n1 n2
Ideal gas law:
difference definition of
between currents flow
in either direction
Q C ( p1 p2 ) Definition of
conductance
RT
Q A( p1 p2 ) For air at 20C
2m
CA 11,8 A l s1
RT T withAincm 2
CA A
2m m
39
Conductance of standard flanges
C A 11,8 A l s 1 Conductance of (infinitely thin) flange of standard openi
2
withA in cm
How to transform from N2 to other
CA
DN Conductance gases?
(l/s)
MEMO
16 24 Smallairmass large
2 conductance
C A 11.8 r
25 58
M air
40 148
C Aair C Agas
M gas
63 368
NB
100 927 Usually, we put a ~500l/s pump on a
DN150.
150 2085
The flanges conductance is >4x the
200 3707 pumps pumping speed.
Conductance of
standard flanges for N2 40
Maximal pumping speed
From the preceding, we can see that the maximal pumping speed of a
high vacuum pump cannot be larger than the conductance of its aperture.
41
Maximal pumping speed
From the preceding, we can see that the maximal pumping speed of a
high vacuum pump cannot be larger than the conductance of its aperture.
If the pumping
mechanism were 100%
efficient, the pumping
sped would be equal to
ping speed is highest when backstreaming into the the
vessel is lowest. of the
conductance
42
Transmission probability
If N molecules arrive at the entrance plane of a duct, a number N reach
the exit plane, with <1. A number N(1-) return to the entrance.
Remember that N=JA with A area and J impingement rate of molecules at
the aperture of the duct.
Of the J1A Of the J2A
molecules J1A molecules
J2A
entering the entering the duct
duct, J1A from
reach its exit downstream,
J2A reach its
Net flux from entrance to ( J 2 J 1 ) A
entrance plane
exit
Net throughput from entrance Q (J2 J1 ) A kT
to exit
p
Substituting the J we make p
expression 2mkT appear.
RoT The conductance of a
Q ( p2 p1 ) A C A ( p2 p1 )
2M component is the
conductance of its
C C A aperture times a
transmission probability 45
Transmission probability calculations
C CA
C AC L 12.4 D 3 / L
C D, L in [cm]
C A C L 1 4 D / 3L 1
3 L
CL CL 1
4 D
C A C A CL
Transmission probability of a cylindrical
tube, of diameter D and length L, or of
form factor L/D.
Dushman 1992
C A 9.3D 2 ls 1 D in [cm] Aperture
D 3 1
C L 12.4 ls D, L in [cm] Long tube
L
47
Cylindrical ducts
l/D [Cole]
0.05 0.952399
1
0.15 0.869928 0 1 2 3 4 5 6 7 8 9 10
0.25 0.801271
0.35 0.74341
0.45 0.694044
0.5 0.671984
0.6 0.632228
0.7 0.597364
0.8 0.566507
0.9 0.538975
1 0.514231
1.5 0.420055
0.1
2 0.356572
2.5 0.310525 l l/d
3 0.275438
3.5 0.247735
1
4 0.225263
0 5 10 15 20 25 30 35 40 45 50
4.5 0.206641
5 0.190941
10 0.109304 D
15 0.076912
20 0.059422 0.1
25 0.048448
30 0.040913
35 0.035415
40 0.031225
45 0.027925
0.01
50 0.025258
500 0.002646 l/d
48
Pumping speed measurement
q pV po Pressure when q pV 0
S
p p po
S
Gas flow qpV may be measured by a precise
flowmeter or in a double-dome with known
conductance between the domes
Measure pressure p in front of the pump is
problematic: directional gas flow!
Pressure is defined in an enclosed system, at
equilibrium.
To avoid perturbation of the isotropic (i.e. uniform) Maxwellian
distribution by the pump inlet, one would need an infinitely large
volume.
Solution: Fisher-Mommsen dome (double and isotropic)
49
Fisher-Mommsen dome
for pumping speed measurement
q pV p2
S C( 1)
p1 p1
50
Examples
51
Examples
A component has a molecular flow conductance of 500l .s-1 for
nitrogen. What will its conductance be for (a)hydrogen, (b)carbon
dioxide?
We have to multiply by the square root of the molar mass of nitrogen
(N2, M=28) and divide by the square root of the molar mass of
hydrogen (H2, M=2) or carbon dioxide (CO2, M=44).
In the first case, this gives a factor 3.74, in the second, a factor 0.8.
So the conductance for hydrogen will be 3.74 times larger, the one for
carbon dioxide 0.8 times larger. We get 1870l.s-1 for hydrogen and
399l.s-1 for carbon dioxide.
Notice that the square root factor damps the effect of mass, but
nevertheless this factor is ~4 for hydrogen if compared to air.
53
Example: pressure profile
In a SPS transfer line, the diameter of the pipe is ~60mm, the distance
between pumps ~60m. The effective pumping speed of each ionic pump is
~15 l/s, including a correction for the connecting element. Lets assume an
outgassing rate of 3.10-11mbar.l.s-1.cm-2, typical after 100h pumping time.
Calculate the maximum and minimum pressure measured at a pressure
gauge in a segment between 2 pumps.
Formulas to use:
D 3 1
C L 12.4 ls D, L in [cm]
L
2Q Q
Pmin Pmax Pmin
S 2C L
54
Example: pressure profile
D 3 1 2Q Q
C L 12.4 ls D, L in [cm] Pmin Pmax Pmin
L S 2C L
55