The document describes a methodology to extract urea from human urine for use as fertilizer. Urine samples from 150 people were collected and introduced to a double-effect evaporator. This process evaporated 90% of the urea and uric acid, yielding 5.004 kg of a product containing concentrated urea and uric acid. The evaporation was carried out at the average air temperature in Tuguegarao City of 305.233K. Through two stages of evaporation, 90% of the urea and uric acid was isolated from the original urine sample to produce a crystalline material suitable for use as a fertilizer.
The document describes a methodology to extract urea from human urine for use as fertilizer. Urine samples from 150 people were collected and introduced to a double-effect evaporator. This process evaporated 90% of the urea and uric acid, yielding 5.004 kg of a product containing concentrated urea and uric acid. The evaporation was carried out at the average air temperature in Tuguegarao City of 305.233K. Through two stages of evaporation, 90% of the urea and uric acid was isolated from the original urine sample to produce a crystalline material suitable for use as a fertilizer.
The document describes a methodology to extract urea from human urine for use as fertilizer. Urine samples from 150 people were collected and introduced to a double-effect evaporator. This process evaporated 90% of the urea and uric acid, yielding 5.004 kg of a product containing concentrated urea and uric acid. The evaporation was carried out at the average air temperature in Tuguegarao City of 305.233K. Through two stages of evaporation, 90% of the urea and uric acid was isolated from the original urine sample to produce a crystalline material suitable for use as a fertilizer.
excreted by the body. Secreted by the renal tubules, it accumulates in the urinary bladder and is excreted via the urethra. While it is composed of 91 to 96 percent water, it contains many other components, both solid and liquid. Over ninety-nine percent of urinary solutes are composed of only sixty-eight chemicals which have a concentration of 10 mg/L or more. Forty-two compounds are actually involved. They are classified as electrolytes such as sodium, potassium, calcium, magnesium and chloride, nitrogenous chemicals such as urea and creatinine, vitamins, hormones, organic acids such as uric acid and other organic compounds. Uric acid as one of the major components of urine, is the major hazard when mixed with water. It is a heterocyclic purine derivative that is the final oxidation product of purine metabolism. It is produced by the enzyme xanthine oxidase, which oxidizes oxypurines such as xanthine into uric acid. Water containing this acid is harmful to humans when consumed because it causes gout, a painful condition resulting from needle- like crystals of uric acid precipitating in joints, capillaries, skin, and other tissues. But not all components of urine are hazardous, one example of urines major components which people can use if being isolated from it is the urea. Urea , also known as carbamide, is an organic compound with the chemical formula CO(NH2)2. This amide has two NH2 groups joined by a carbonyl (C=O) functional group. Urea serves an important role in the metabolism of nitrogen-containing compounds by animals and is the main nitrogen- containing substance in the urine of mammals. This component is feasible to use as a fertilizer. The researchers aimed to isolate urea having a relatively small amounts of vitamins and proteins (almost negligible) from animal urine and transformed it into a crystalline material in order for it to be used as a fertilizer. REVIEW OF RELATED LITERATURE Urine Specific gravity = 1.002 to 1.037 Water content = 91-96 % Overall composition: 94% water 6% solid 3% urea Other solute compositions: Creatinine = 0.670 g/d.L Na = 1.17 g/L K = 0.750 g/L Cl = 1.87 g/L Uric Acid (C5H4N4O3) Average uric acid content of urine (male and female) = 4.7 mg/d.L (0.047 g/L) Uric acid composition in urea = 25.8242 % Solubility: 0.006 g/L water at 20 C Urea (CO(NH2)2) Normal average urea content of urine = 13.5 mg/d.L (0.135g/L) Solubility: 500 g/L glycerol 50 g/L ethanol 1079 g/L water at 20 C Evaporation process Feed = 100 kg Xf1 = 0.05 Tf1 = 305.233 K (average temperature in Tuguegarao City in a year) P1 = 101.325 kPa T1 = 373.15 K U = 2000W/m2K METHODOLOGY Evaporation 100 kg of urine sample was taken from 150 people in order to obtain the average compositions of the primary compounds (urea and uric acid) needed for the processing of urine. The feed, which is the urine sample containing 5 percent uric acid and urea was introduced to the double-effect evaporator at the average air temperature in Tuguegarao City (305.233 K). After the said process, it was able to obtain 90 percent of urea and uric acid from the feed (5.004 kg). At Evaporator 1: OMB: 100 = F2 + V1 , V1 = 90 kg/hr Solute Balance: 0.05(100) = 0.5(F2) , F2 = 10 kg/hr Take note that there is no boiling point rise since the feed is composed of almost 96 % water so it is assumed that the boiling point of the solution is precisely at 373.15 K temperature and 101.325 kPa pressure. From steam table: At P1 = 101.325 kPa H(liq) = 419.535 kJ/kg H(vap) = 2677.77 kJ /kg = 2677.77 419.535 = 2252.24 kJ /kg Cp at Tf1 (305.233 K) = 4.184 kJ /kg Cp at Tf2 (373.15 K) = 40219 kJ/kg Cp ave = 4.202 kJ /kg Hv = = 2252.24 Kj/kg 1 = ((V1 Hv F cp. ave Tf T1 )/ 1 = 102.671 / Steam economy = V/S = 0.877 Area = (ms ) / U(Ts-Tp) = 3.261 m2 At evaporator 2: OMB: 10 = V2 + P2 , V2 = 4.444 kg/hr Solute Balance: 0.5(10) = 0.9(P2) . P2 = 5.556 kg/hr At pressure 2 = pressure 1 = 101.325 kPa and T2 = 373.15 K = 2252.24 kj/kg Since the temperature at F2 is equal to temperature at the final product, Cp(ave) = 4.219 kj/kg 2 = ((V2 Hv F cp. ave Tf2 T2 )/ = 4.444 Steam economy = 1