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PHYSICAL SORPTION :
CHEMICAL SORPTION
ADSORBATE
Adsorben Properties
TYPE
The size of
Solubility of Adsorbent
the Surface Area Temperature pH
adsorbate Purity
adsorbate
Instantenous Adsorption Models
= .
S = concentration adsorbed per unit mass or sorbent weight ( mg/l)
Kd = Coefficient distribution-equilibrium adsorption
C = the concentration of substances in equilibrium solution (mg/l)
ADSORPTION
1 1 1 1
= + .
.
FREUNDLICH ISOTHERM
In log S trial data plotted against Log C it
Freundlich Isotherm expressed as :
will form a straight line. The intersection
with the Y axis represents the log value of
= . K and the slope is the value of n.
Pb-Cellulose Bond
Adsorption
Driving Force
adsorbate affinity
Metal-Ligan and
to solvent and
solvent
adsorbate affinity
properties, pH Affinity is tendency of an unsure
to adsorbent
or element to bond with other
unsure or element
Characteristic of Clay
Clay
Soil
Consist of very fine sand which
has good properties of cohesion
and plasticity
Soil Grain Water Air It is a pore material which has high
absorptivity and used by industry
to reduce metal ion in waste
It is a good absorbent because it
Coarse (Sand, has high specific surface and
gravel) negative charge
It should be activated to get its
optimum adsorption capacity
Fine sand (silt, Physi-activation: Heating the clay
clay) Chemi-activation: using acid
solution
Previous Research
Researcher Topic Methods Result
Cindy Rianti Priadi et Zn and Pb adsorption Batch Adsorption for The most effective contact time 15min @
al. (2014) by Ceramics Industry in determine adsorbent pH8 and 5 g/l of adsorbent concentration
Clay concentration and effective
contact time
I.A Gede Widihati Pb adsorption by 0.2 gr modified bentonite with Interconnected clay with addition of
(2009) surfactan addition of ammonium palmitate acid increase distance between
interconnected Clay quaternary salt and palmitate clay layer resulting bigger adsorption
acid using X light diffraction capacity
method, uv vis
spectrophotometer
Putra et al. (2015) Pb ion adsorption by Modified kaolin increase adsorption
modified kaolin with capacity because kaolin anionic add
surfactant as negative ions in adsorbent
adsorbent
Ghorbel-Abid (2015) The competitiveness of Local Tunisian clay used as The adsorption of Criii is faster than Cdii
heavy metal in local sorbent while Criii and Cdii Adsorption time for Cr : 15 minutes,
landfill solution was used as metal Cd : 2 hours
sorbate
Previous Research
Researcher Topic Methods Result
Gier (2000) Heavy metal adsorption Cs, Ba, Cu, Zn an Pb ion acted Surface charge magnitude play role in
by mica and clay as heavy metal while adsorption capability. The higher ionic
mineral using X-ray characterized silicate 2:1 potential of metal ion, the higher surface
photoelectron (mica and illite) acted as charged, the higher adsorption capability.
spectrophotometry sorbent
Chen et al. (2016) The content of heavy Urban water catchment area The most finest clay has bad crystalline
metal in surface sediment is taken and divided structure after treatment which means has
sediment clay mineral to three different size of biggest absorption capacity
mineral.
1000-2000 (clay), 450-1000
(fine clay), 220-450 (very fine
clay). And evaluated by X-ray,
SEM and chemical analysis
Iannicelli-Zubiani Using clay and organo- Metal contained in e-waste is Type of metal that can be recovered is
(2017) clay to recover metal dissolved using strong acid lanthanum and copper
from e-waste and adsorbed using clay and
organo-clay
Previous Research
Researcher Topic Methods Result
Veli (2007) Cu and Zn adsorption Solution contained Cu and Zn Cu and Zn tend to adsorpt with 2nd order
using natural clay is mixed with cankiri bentonite kinetic.
(as natural clay). The valuated
parameters is pH, amount
and concentration of clay and
adsorption time
D. Schmitt et al. (2002) Natural organic matter Ion metal: Al, Fe, Zn and Pb Al and Fe adsorption is affected by natural
effect in metal ion pH: 5 and 7 organic matter while Zn and Pb is not
adsorption by mineral Treatment: with and without affected. This is happening because
clay organic matter aggregation process affect with specific ion
metal and decrease in presence of organic
matter and high value of pH
S. P. Singh et al. (2000) Phosphate-heavy metal Phosphate obtained form by- Metal absorption in clay: Pb>Cd>Zn.
ion interaction product mining industrial is
used to immobilized Pb, Cd
and Zn.
T H A N K
Y O U
Soil and Groundwater Pollution | Environmental Engineering | 2017