Escolar Documentos
Profissional Documentos
Cultura Documentos
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PLASTIC MATERIALS
PLASTICS 20th CENTURY
1908-Phenolic(Backlite)
1931-Acrylics
1938-Nylon
1959-Polycarbonate
1970-Engineering Plastics
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PLASTIC MATERIALS
What is a polymer ?
Substance in which molecules form long chains usually
several thousands of atoms together starting from a single
molecule.
Single molecule is called Monomer
EXAMPLE :
ETHYLENE,PROPYLENE,VINYL CHLORIDE
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PLASTIC MATERIALS
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PLASTIC MATERIALS
Basically, all polymers are formed by the creation of
Nature
The behaviour and structure of the polymers are
based both on the chemical nature and the way in
which the chains fit together.
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PLASTIC MATERIALS
Advantages over Metal
•Low weight
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PLASTIC MATERIALS
Advantages over Metal
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PLASTIC MATERIALS
Disadvantages over Metal
•Low strength
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PLASTIC MATERIALS
Types of Plastics
•Thermoplastic
•Thermoset plastics
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PLASTIC MATERIALS
Thermoplastics
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PLASTIC MATERIALS
Thermoplastics can be again classifieds as
commodity and engineering plastics
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According to structure
Crystalline
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PLASTIC MATERIALS
Amorphous
They are having molecules going in all different directions are normally
transparent. They will under go small volumetric changes when on processing.
They are tougher and more flexible.
They will often soften gradually as they are heated but they do not flow easily.
Therefore it is easy to process amorphous plastic.
A crystalline plastic is heated to a particular temperature and sudden
quenching give amorphous structure.
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PLASTIC MATERIALS
PROPERTIES
Crystalline Amorphous
Fibers Elastomers
Crystalline Amorphous
Plastics Plastics
Tough Brittle
Opaque Transparent
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PLASTIC MATERIALS
Flow Ratio
It depends on MFI
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PLASTIC MATERIALS
Different types of material
Around 150 plastics and its different grades are available in the world
market of which some commonly used thermoplastic materials are given below
ABS -ArylonitrileButadieneStyrene PMMA - Polymethylmethacrylate
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PLASTIC MATERIALS
Sl. no Name of plastic Chief Properties Applications
High Density Higher density, rigidity, The property of high
3 Polyethylene tensile strength and stiffness combined with
(HDPE) hardness. Higher high impact strength
chemical resistance and low weight makes
Density = 0.95 gm./cc
while comparing LDPE. it popular material for
Shrinkage HDPE= 3.0 – Extremely resistant to moulding articles like
4.0% fresh and salt water, milk bottle crates, fish
One of the group in food, and most water- boxes, containers used
Polyethylene, first based solutions. Very for refrigeration and
synthesized in 1933, looks cheap and particularly transport. Pipes from
like the simplest of easy to mould and dia 25mm to 800mm
molecules, but the number fabricate. Accepts a wide for carrying water and
of ways in which the PE range of colours, can be chemicals, packing
units can be linked in large. transparent , films, woven sacks,
It is the first of the translucent or opaque, monofilament for
polyolefin, the bulk fishing nets, rope, cane
thermoplastic polymers that for furniture, coating on
account for a dominant paper etc.
fraction of all polymer
consumptions.
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PLASTIC MATERIALS
Sl. no Name of plastic Chief Properties Applications
Low Density Crystalline and not Shopping baskets,
Polyethylene available in transparent. waste paper baskets,
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(LDPE) Tough and moderate artificial flowers and
tensile strength. It can fruits, hair brushes,
Density = 0.92 gm./cc
be coloured. Oxidation and blow moulded
Shrinkage LDPE= 0.8 – occurs when overheated components, pipes up
1.5% in barrel. So necessary to 150mm diameter for
One of the group in to add antioxidants. transporting water,
Polyethylene, first packaging films,
synthesized in 1933, looks coating paper, textiles
like the simplest of etc. Linear LDPE is
molecules, but the number used for overhead
of ways in which the PE water tanks.
units can be linked in large.
It is the first of the
polyolefin, the bulk
thermoplastic polymers that
account for a dominant
fraction of all polymer
consumptions..
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PLASTIC MATERIALS
Sl. no Name of plastic Chief Properties Applications
Ionomer High strength, good Food packaging,
(I) adhesion and chemical athletic soles with
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stability. It is highly metal inserts, ski
Density = gm./cc
transparent particularly boots, ice skate shells,
Shrinkage =0.2 – 0.8% resistant to wrestling mats, thermal
Introduced by Dupont in pipe insulations,
1964, Ionomers are flexible license plate holder,
thermoplastics but they golf ball covers,
have ionic cross-links, from automotive bumpers,
which they derived their snack food packaging,
name. Their thermoplastic blister packs, bottles.
character allows them to be
processed by blow
moulding injection moulding
rotational moulding and
thermoforming. But cooled
below 40o C, they acquire
the characteristics of
thermoset
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PLASTIC MATERIALS
Sl. no Name of plastic Chief Properties Applications
Nylon (Polyamide) Tough and can withstand Light duty gears,
(PA) repeated impacts. High bushings, sprockets and
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rigidity whose properties bearings, electrical
Density = 1.1 gm./cc
can be increased by equipment housings,
Shrinkage =0.7-1.5% glass reinforcement. lenses, containers, tanks,
Nylon is a general Excellent abrasion tubing, furniture casters,
term for polyamides resistance and plumbing connections,
exceptionally low co- bicycle wheel covers,
efficient of friction. High ketchup bottles, chairs,
chemical resistance and toothbrush bristles,
high temperature handles, food packaging,
resistance. It can be hot melt adhesives for
machined. Partially book binding, ropes,
crystalline, therefore fishing nets, carpeting,
cloudy or white and not cables, protective
transparent. clothing, electrical
insulations.
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PLASTIC MATERIALS
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PLASTIC MATERIALS
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PLASTIC MATERIALS
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PLASTIC MATERIALS
Sl. no Name of plastic Chief Properties Applications
Polymethyl Best transparency and Lenses of all types,
methacrylate optical properties. cockpit canopies and
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(PMMA - Acrylic) Colourless with 92% light aircraft windows, signs,
transmition. Exceptional domestic baths,
Density = 1.18 gm./cc packaging, containers,
resistant to sunlight and
Shrinkage =0.2-0.8% outdoor exposure and electrical components,
when you think of ultra violet radiation. drafting equipments, tool
PMMA, think Unaffected by human handles, automotive tail
transparency. This is tissues lights, chairs, contact
a family of acrylic lenses, advertising signs,
group. compact discs.
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PLASTIC MATERIALS
Sl. no Name of plastic Chief Properties Applications
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PLASTIC MATERIALS
Sl. no Name of plastic Chief Properties Applications
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PLASTIC MATERIALS
Sl. no Name of plastic Chief Properties Applications
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PLASTIC MATERIALS
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PLASTIC MATERIALS
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PLASTIC MATERIALS
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PLASTIC MATERIALS
Sl. no Name of plastic Chief Properties Applications
Polyurethane Very tough, extremely Used for PUR springs.
(PUR) abrasion resistant. Used for making forms.
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Posses good electrical
Density = gm./cc
properties and
Shrinkage =0.8-1.0% chemical resistance. It
can be made in solid
moulding or flexible
forms.
Advantages for thermosets are high thermal stability, resistance to creep and
deformation under load, high dimensionally stability, high rigidity , hardness,
light weight ,excellent electrical insulating properties, low cost etc.
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THERMOSET MATERIAL
Properties:
• Resistance to creep
• Light weight
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THERMOSET MATERIAL
Moulding compound consists of two ingredients
This effects on
-determining cost to a great extend
-dimensional stability
-electrical quality
-heat resistance
-chemical resistance
-decorative possibilities
-flammability
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THERMOSET MATERIAL
This effects on
-more strength
-more toughness
-all the properties that resin system gives in varying degrees.
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PLASTIC MATERIALS
Different types of Thermoset material
Alkyds, - Alkyds
Epoxy - Epoxy
Polyesters - Polyester
Urethanes.- urethane
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PLASTIC MATERIALS
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PLASTIC MATERIALS
Sl. Applications
Name of plastic Chief Properties
no
2 •Relatively costlier •in circuit breaker
Allylics
•Posses excellent
(DAP) dimensional stability insulation
DiallylPhthalate •High insulation resistance •electronic component
•Can withstand temp. of
1500C to 1700C encapsulation
•Reinforced with glass
asbestos, acrylic and
polyester fibers
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PLASTIC MATERIALS
Sl. Applications
Name of plastic Chief Properties
no
3 Epoxies •Excellent electrical •in aircraft components
properties •filament wound rocket motors.
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PLASTIC MATERIALS
Sl. Applications
Name of plastic Chief Properties
no
4 •Excellent colourability •Lighting fixtures
Ureas
•
(Urea Formaldehyde)
•Moderately good strength •Wiring devices
•
•Low strength •buttons
•
•Poor dimensional stability
•
•Poor impact strength
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PLASTIC MATERIALS
Sl. Applications
Name of plastic Chief Properties
no
5 •Lower in cost •moulding wiring
Phinolics devices
(Phenol •Posses good electrical
Formaldehyde) properties •moulding switch
Bakelite gears, relay
•Excellent heat resistance
system,
•Good mechanical connectors
properties
•Excellent mouldability
•Can be used at temp. up
to 1500C
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PLASTIC MATERIALS
•Arc resistance
•Non-cracking
characteristics
•Self extinguishing.
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PLASTIC MATERIALS
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