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Alcohols
You should be able to:
Ethanol C2H5OH 46
Propanol C3H7OH 60
Butanol C4H9OH 74
Chapter 16
Alcohols and Carboxylic Acids
Properties of Ethanol
• Ethanol is the most important alcohol in the
homologous series.
• Only ethanol can be consumed.
• Ethanol is a colourless liquid with a strong
smell.
• It has a boiling point of 78 °C and is volatile.
• It mixes readily with water.
• It is neutral to litmus.
Chapter 16
Alcohols and Carboxylic Acids
Quick Check 1
1. (a) Name an alcohol with three carbon atoms.
(b) State its
(i) molecular formula.
(ii) structural formula.
Solution
Chapter 16
Alcohols and Carboxylic Acids
Solutions to Quick Check 1
1. (a) Propanol
(b) (i) C3H7OH (ii)
2. (a) CnH2n+1OH
(b) C20H41OH
(c) Solid, its melting point is high because it has
very large molecular mass.
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Chapter 16
Alcohols and Carboxylic Acids
Chemical Reactions
1. Reaction with a reactive metal like sodium
• When a small piece of sodium is dropped into some
ethanol, it reacts steadily to give off bubbles of hydrogen
gas leaving behind a colourless solution of sodium
ethoxide, CH3CH2ONa.
H+/K2Cr2O7
C2H5OH + 2[O] CH3COOH + H2O
H+/K2Cr2O7
+ 2[O] H H
+
O
H H
O
Solution
Chapter 16
Alcohols and Carboxylic Acids
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Chapter 16
Alcohols and Carboxylic Acids
Making Ethanol by Fermentation
of Carbohydrates
• Large quantities of ethanol are made for consumption by
fermentation.
• Depending on the raw materials used, the ethanol is
produced in different kinds of alcoholic drinks such as wine,
whisky, brandy, and beer.
Quick Check 3
Solution
Chapter 16
Alcohols and Carboxylic Acids
Step 2:
zymase
C6H12O6 2C2H5OH + 2CO2
glucose ethanol
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Chapter 16
Alcohols and Carboxylic Acids
Carboxylic Acids
• The general formula is CnH2n+1COOH, where n is an
integer.
• They have an acid functional group:
Molecular Structural
Name
formula formula
Methanoic acid HCOOH
Solution
Chapter 16
Alcohols and Carboxylic Acids
Solution to Quick Check 4
1. (i) CnH2n+1COOH
(ii) C10H21COOH
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