2018 NEET Chemistry Solved Paper

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Previous Year
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Chemistry - 2018
Chemistry Exam
NEET Year
2018 2018
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Multiple Choice Questions
1. Consider the change in oxidation state of Bromine corresponding to different emf values as shown in the
diagram below :
BrO4- →1.82BrO3-→1.5 VHBrO→1.595Br2→1.0652 VBr-
Then the species undergoing disproportionation is
BrO3-
BrO4-
HBrO
Br2
Answer
2. Which one of the following conditions will favour maximum formation of the product in the reaction, A2
(g) + B2 (g) ⇋ X2 (g)∆r H = - XkJ?
Low temperature and high pressure

Low temperature and low pressure
High temperature and low pressure
High temperature and high pressure
Answer
3. The bond dissociation energies of X 2 , Y 2 and

XY are in the ratio of 1 : 0.5: 1. ΔH for the
formation of XY is
–200 kJ mol–1. The bond dissociation energy

of X 2 will be
200 kJ mol - 1
100 kJ mol - 1
400 kJ mol - 1
800 kJ mol - 1
Answer
4. The correction factor ‘a’ to the ideal gas equation corresponds to
Density of the gas molecules
Volume of the gas molecules
Forces of attraction between the gas molecules
Electric field present between the gas molecules
Answer
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5. Which one is a wrong statement?
Page 2 of 13
Chemistry Exam
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Forever.
Total orbital angular momentum of electron in 's' orbital is equal to zero

An orbital is designated by three quantum numbers while an electron in an atom is designated by four
quantum numbers
The value of m for d z 2 is zero
The electronic configuration of N atom is
Answer
6. Magnesium reacts with an element (X) to form an ionic compound. If the ground state electronic
configuration of (X) is 1s 2 2s 2 2p 3 , the simplest formula for this compound is
Mg 2 X 3
MgX 2 Mg 3 X 2
Mg 2 X
Answer
7. In the structure of ClF 3 , the number of lone pair of electrons on central atom ‘Cl’ is One
Two
Three
Four
Answer
8. The correct order of atomic radii in group 13 elements is B
< Al < In < Ga < Tl
B < Al < Ga < In < Tl
B < Ga < Al < In < Tl
B < Ga < Al < Tl < In
Answer
9. Which of the following oxides is most acidic in nature?
MgO
BeO
CaO
BaO
Answer
Page 3 of 13
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10. Which oxide of nitrogen is not a common pollutant introduced into the atmosphere both due to natural and
human activity?
N2 O 5
NO 2
NO
N2 O
Answer
11. Which of the following molecules represents the order of hybridisation sp 2 , sp 2 , sp, sp from left to right
atoms?
HC≡C-C≡CH
CH 2 =CH-C≡CH
CH 3 -CH=CH-CH 3
CH 2 =C H -CH =C H 2
Answer
12. Which of the following
is correct with respect
to – I effect of the
substituents? (R =
alkyl)
-NH 2 < - OR < - F
-NR 2 < - OR <-F
-NR 2 >- O R >-F
-NH 2 >-OR>-F
Answer
13. In which ca se is a number of molecules of water maximum?
18 mL of water
0.18 g of water
10 - 3 mol of water
0.00224 L of water vapours at 1 atm and 273K
Answer
14. Among CaH 2 , BeH 2 , BaH 2 , the order of ionic character is
BeH 2 < CaH 2 <BaH 2
CaH 2 <Be H 2 <BaH 2
BaH 2 <BeH 2 <CaH 2
BeH 2 < BaH 2 < CaH 2
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Page 4 of 13
Chemistry Exam
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15. For the redox reaction

MnO4- + C2O4-2 + H + → Mn2+ + CO2 + H2O
The correct coefficients of the reactants for the balanced equation are
MnO4- C2O42- H+
16 5 2
- 2-
MnO 4 C 2O 4 H+
2 5 16
- 2-
MnO 4 C 2O 4 H+
5 16 2
- 2-
+
MnO 4 C 2O 4 H
2 16 5
Answer
16. Which one of the following elements is unable to form MF6-3 ion? G a
Al
In
B
Answer
17. Considering the Ellingham diagram, which of the following metals can be used to reduce alumina? Fe
Zn
Cu
Mg
Answer
18. Which of the following statements is not true for halogens?
All form monobasic oxyacids
Page 5 of 13
Chemistry Exam
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All are oxidizing agents

Chlorine has the highest electron-gain enthalpy
All but fluorine show positive oxidation states
Answer
19. A mixture of 2.3 g formic acid and 4.5 g oxalic acid is treated with conc. H 2 SO 4 . The evolved gaseous
mixture is passed through KOH pellets. Weight (in gram) of the remaining product at STP will be
1.4
3.0
4.4
2.8
Answer
20. Match the metal ions given in Column I with the spin magnetic moments of the ions given in Column II and
assign the correct code :
Column I Column II
a. Co
3+ i. 8 BM
b. Cr 3 +
ii. 35 BM
c. Fe 3 +
iii. 3 BM
d. Ni
2+ iv. 24 BM
v. 15 BM
a bcd
iv v ii i
a bc d
i ii iii iv
a bcd
Page 6 of 13
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iii v i ii
a bcd
iv i ii
iii
Answer
21. Which one of the following ions exhibits d-d transition and paramagnetism as well?
CrO42-
Cr2O72-
MnO42-
MnO4-
Answer
22. Iron carbonyl,
Fe(CO) 5 is
Tetranuclear
Mononuclear
Dinuclear
Trinuclear
Answer
23. The type of isomerism shown by the complex [CoCl 2 (en) 2 ] is
Geometrical isomerism
Coordination isomerism
Linkage isomerism
Ionization isomerism
Answer
24. The geometry and magnetic behaviour of the complex [Ni(CO) 4 ] are
Square planar geometry and diamagnetic

Tetrahedral geometry and diamagnetic
Tetrahedral geometry and paramagnetic
Square planar geometry and paramagnetic
Answer
25. Following solutions were prepared by mixing
different volumes of NaOH and HCl of different
concentrations
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a) 60 mL M10 HCl + 40 mL M10 NaOHb) 55 mL

Page 7 of 13
M10HCl + 45 mL M10 NaOHc) 75 mL M5 HCl +
Chemistry Exam
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Forever.
aOHd) 100 mL M10 HCl + 100 mLM10 NaOH

pH of which one of them will be equal to 1?
d
Answer
26. On which of the following properties does the coagulating power of an ion depend?
The magnitude of the charge on the ion alone
Size of the ion alone
The sign of the charge on the ion alone
Both magnitude and sign of the charge on the ion
Answer
27. Given van der Waals constant for NH 3 , H 2 , O 2 and CO 2 are respectively 4.17, 0.244, 1.36 and 3.59, which one
of the following gases is most easily liquefied?

NH 3
H2
CO 2
O2
Answer
28. The
solubility
of BaSO
in water
is 2.42 ×
10 – 3 gL – 1
at 298 K.
The value
of its
solubility
product
(K will
be
4
s
p
)
(Given the
molar
massLike. of Share. Bookmark. Download. Make Notes. Print - Your Favourite Questions. Join www.zigya.com
BaSO =
233 g Page 8 of 13
mol – 1 )
4
Chemistry Exam
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2018 2018
Forever.
The rate of a first-order reaction does depend on reactant concentrations; the rate of a second-order
reaction does not depend on reactant concentrations
A first-order reaction can catalyzed; a second-order reaction cannot be catalyzed
Answer
30. When initial concentration of the reactant is doubled, the half-life period of a zero order reaction Is
halved
Is doubled
Remains unchanged
Is tripled
Answer
31. Iron exhibits bcc structure at room temperature. Above 900°C, it transforms to fcc structure. The ratio of
density of iron at room temperature to that at 900°C (assuming molar mass and atomic radii of iron remains
constant with temperature) is
32
4332
1/2
3342
Answer
32. Consider the following species:
CN + , CN – , NO and CN
Which one of these will have the highest bond order?
NO
CN -
CN
CN
+
Answer
33. The correct order of N-compounds in its decreasing order of oxidation states is
HNO 3 , NH 4 Cl, NO, N 2
HNO 3 , NO,NH 4 Cl, N 2
HNO 3 , NO, N 2 , NH 4 Cl
NH 4 Cl, N 2 , NO, HNO 3
Answer
34. Identify the major products
P, Q and R in the following
sequence of reactions:
Page 9 of 13
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Forever.
Answer
35. Which of the following compounds can form a zwitter ion?
Page 10 of 13
Chemistry Exam
NEET Year
2018 2018
Forever.
Aniline
Acetanilide
Glycine
Benzoic acid
Answer
36. Regarding cross-linked or network polymers, which of the following statements is incorrect?
They contain covalent bonds between various linear polymer chains.
They are formed from bi- and tri-functional monomers. They
contain strong covalent bonds in their polymer chains.
Examples are bakelite and melamine.
Answer
37. Nitration of aniline in strong acidic medium also gives m-nitroaniline because
Inspite of substituents nitro group always goes to only m-position.
In electrophilic substitution reactions amino group is meta directive.
In acidic (strong) medium aniline is present as anilinium ion.
In absence of substituents nitro group always goes to m-position.
Answer
38. The difference between amylose and amylopectin is
Amylopectin have 1 → 4 α-linkage and 1 → 6 α-linkage Amylose
have 1 → 4 α-linkage and 1 → 6 β-linkage Amylose is made up of
glucose and galactose Amylopectin have 1 → 4 α-linkage and 1
→ 6 β-linkage
Answer
39. The compound A on treatment with Na gives B, and with PCl 5 gives C. B and C react together to give diethyl
ether. A, B and C are in the order

C 2 H 5 OH, C 2 H 6 , C 2 H 5 Cl
C 2 H 5 OH, C 2 H 5 Cl, C 2 H 5 ONa
C 2 H 5 OH, C 2 H 5 ONa, C 2 H 5 Cl
C 2 H 5 Cl, C 2 H 6 , C 2 H 5 OH
Answer
40. The compound C 7 H 8 undergoes the following reactions:
C7H8 →3Cl2/∆A →Br2/Fe B →Zn/HCl C

The product 'C' is
m-bromotoluene
Page 11 of 13
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o-bromotoluene
p-bromotoluene
3-bromo-2,4,6-trichlorotoluene
Answer
41. Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wurtz reaction is
converted to a gaseous hydrocarbon containing less than four carbon atoms. (A) is
CH ≡ CH
H 2 C = CH 2
CH 4
CH 3 -CH 3
Answer
42. Which of the
following
carbocations is
expected to be
most stable?
Answer
Page 12 of 13
Chemistry Exam
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2018 2018
Forever.
43. In the reaction,
The electrophile involved is
Dichloromethyl cation (C + HCl )

2
Formyl cation (C + HO)
Dichlorocarbene (:CCl 2 )
Dichloromethyl anion
(C - HCl )
2
Answer
44. Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of comparable
molecular mass. It is due to their
Formation of intramolecular H-bonding
Formation of intermolecular H-bonding
Formation of intermolecular H-bonding
More extensive association of carboxylic acid via Vander Waals force of attraction
Answer
45. Compound A, C 8 H 1 0 O, is found to react with NaOI (produced by reacting Y with NaOH) and yields a yellow
precipitate with characteristic smell. A and Y are respectively
Answer
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Multiple Choice Questions

Low temperature and high pressure

3. The bond dissociation energies of X 2 , Y 2 and

–200 kJ mol–1. The bond dissociation energy

Total orbital angular momentum of electron in 's' orbital is equal to zero

The electronic conﬁguration of N atom is

conﬁguration of (X) is 1s 2 2s 2 2p 3 , the simplest formula for this compound is

-NR 2 < - OR <-F

-NR 2 >- O R >-F

14. Among CaH 2 , BeH 2 , BaH 2 , the order of ionic character is

BeH 2 < CaH 2 <BaH 2

CaH 2 <Be H 2 <BaH 2

BaH 2 <BeH 2 <CaH 2

BeH 2 < BaH 2 < CaH 2

15. For the redox reaction

All are oxidizing agents

23. The type of isomerism shown by the complex [CoCl 2 (en) 2 ] is

Square planar geometry and diamagnetic

a) 60 mL M10 HCl + 40 mL M10 NaOHb) 55 mL

aOHd) 100 mL M10 HCl + 100 mLM10 NaOH

of the following gases is most easily liqueﬁed?

HNO 3 , NH 4 Cl, NO, N 2

HNO 3 , NO,NH 4 Cl, N 2

NH 4 Cl, N 2 , NO, HNO 3

35. Which of the following compounds can form a zwitter ion?

ether. A, B and C are in the order

C 2 H 5 OH, C 2 H 5 Cl, C 2 H 5 ONa

40. The compound C 7 H 8 undergoes the following reactions:

C7H8 →3Cl2/∆A →Br2/Fe B →Zn/HCl C

43. In the reaction,

The electrophile involved is

Dichloromethyl cation (C + HCl )

Formyl cation (C + HO)

precipitate with characteristic smell. A and Y are respectively

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