160 1000

With HTA Pd(2)/SSZ-13 IWI

140 Blank Total Difference 900

bypass TPD (bypass +

120
TPD)
0.035
800
concentration (ppm)

2.297 1.346 0.916 2.262

700

Temperature ( C)
(1.5 %)
100
Blank (at 120 °C without catalyst, black)
600
80
500
60 Bypass; unadsorbed NOx species (red)
400
Temperature (during TPD, blue)
40 NO


on 300
20 TPD (during temperature ramping, blue)
200
0 100
0 1000 2000 3000 4000
Time (sec)

Fig. S1. NOx concentration of blank (without catalyst, black), bypass

(with HTA Pd(2)/SSZ-13 IWI, red), and TPD (with HTA Pd(2)/SSZ-
13 IWI, blue) during NO adsorption/desorption process as a function
of time. Insertion: Quantitative analysis of NOx amount (μmol)
calculated by integration method.
Fig. S2. NO, NO2 and NOx concentration of HTA Pd(2)/SSZ-13 IWI during desorption.

14
NO
12 NO2
NOx
Concentration (ppm)

10

0
150 200 250 300 350 400 450 500

Temperature ( C)
 Fig. S3. XRD patterns in the region of PdO of (a) fresh and (b) HTA
Pd/SSZ-13 IWI catalyst with various Pd loading.

H-SSZ-13 H-SSZ-13
a Pd(0.2)
Pd(0.5)
b Pd(0.2)
Pd(0.5)
Pd(1) Pd(1)
Pd(2) Pd(2)
Intensity (a.u.)

Intensity (a.u.)
Pd(3) Pd(3)
Pd(5) Pd(5)

30 32 34 36 30 32 34 36
2degree) 2degree)
 Fig. S4. XPS spectra with surface atomic composition (insertion)
for fresh and HTA Pd(1)/SSZ-13 catalyst.

Pd : Al : Si : O
Fresh: 0.99 : 2.26 : 30.59 : 58.77
HTA: 0.38 : 3.53 : 33.94 : 56.56 336.7
Intensity (a.u.)

Fresh

336.7
HTA

346 344 342 340 338 336 334

Binding Energy (eV)
 Fig. S5. Oscillations of k3-weighted Pd K edge EXAFS for Pd/SSZ-13 IWI with different
Pd loading and PdO.

PdO Fresh Pd(2)

Fresh Pd(0.5) HTA Pd(2)

Fresh Pd(3)
HTA Pd(0.5)

k  (k)
k  (k)

HTA Pd(3)

Fresh Pd(1)

3
3

Fresh Pd(5)

HTA Pd(1) HTA Pd(5)

0 5 -1
10 15 0 5 -1
10 15
k (Å ) k (Å )
Fig. S6. DRIFT spectra during NO adsorption as a function of time
(min) over HTA Pd(2)/SSZ-13 IWI in the range of 2000 – 1450 cm-1.

0.30
1 min
0.25 3 min
5 min

1800
Absorbance (a.u.)

0.20 10 min
30 min
0.15 60 min

1524
0.10
1860

0.05

0.00
2000 1900 1800 1700 1600 1500
-1
Wavenumber (cm )
Fig. S7. NOx desorption curves of HTA Pd(2)/SSZ-13 IWI with different NO adsorption time:
100 sec for cold start NO adsorption (black) and 1 hr for Pd ion titration (red).
20
IWI HTA NO adsorption for 100 sec
18 IWI HTA NO adsorption for 1 hr
16
NOx concentration (ppm)

14
12
10
8
6
4
2
0
150 200 250 300 350 400 450 500

Temperature ( C)